scholarly journals Comparison between Solar and Artificial Photocatalytic Decolorization of Textile Industrial Wastewater

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Falah H. Hussein
Keyword(s):  
Textile Industry ◽  
Industrial Wastewater ◽  
Uv Light ◽  
Complete Removal ◽  
Climatic Conditions ◽  
Solar Irradiation ◽  
Efficient Technology ◽  
Photocatalytic Decolorization ◽  
Catalyst Type ◽  
Colored Wastewater

The photocatalytic decolorization of industrial wastewater was investigated by using TiO2and ZnO photocatalysts. Heterogeneous photocatalytic processes applied under natural weathering conditions, in the presence of solar radiation show a promising degradation capability. The complete removal of color could be achieved in a relatively short time of about 20 minutes, when ZnO was used and about 100 minutes when TiO2was used under solar irradiation. However, in the presence of artificial UV-light, complete decolorization of textile industrial wastewater was obtained after less than one hour of irradiation when ZnO was used and in less than two hours, when TiO2was used at the same temperature. The results indicate that the degree of photocatalytic decolorization of textile industrial wastewater was obviously affected by different parameters. These parameters include catalyst mass, type of catalyst, type of reactor, type of dye, dye concentration, and temperature. The procedure used in this research can be used as an efficient technology for solar photocatalytic decolorization of the colored wastewater discharged from the textile industry under the climatic conditions of most countries.

scholarly journals Degradasi Zat Warna Direct Red-23 Secara Fotolisis dengan Katalis C-N-codoped TiO2

2017 ◽  
pp. 151-159
Author(s):  
Yuli Okta Fitriyani ◽  
Upita Septiani ◽  
Diana Vanda Wellia ◽  
Reza Audina Putri ◽  
Safni Safni
Keyword(s):  
Solar Radiation ◽  
Textile Industry ◽  
Uv Light ◽  
Solar Irradiation ◽  
Azo Compounds ◽  
Industrial Processes ◽  
Tio2 Catalyst ◽  
Codoped Tio2 ◽  
Optimum Weight

Zat warna direct red-23 merupakan pewarna sintetik dengan struktur senyawa organik yang bersifat non-biodegradable. Zat warna direct red-23 mengandung senyawa azo dan bersifat karsinogenik. Zat warna direct red-23 didegradasi secara fotolisis menggunakan sinar UV (ultraviolet), sinar matahari, tanpa dan dengan penambahan katalis C-N-codoped TiO2. Larutan zat warna direct red-23setelah dan sebelum didegradasi diukur dengan spektrofotometer UV-Vis pada panjang gelombang 400-800 nm. Penentuan berat optimum katalis C-N-codoped TiO2 dilakukan dengan metode fotolisis sinar UV dan didapatkan berat optimum 15 mg. Persen degradasi zat warna direct red-23 secara fotolisis sinar UV dan sinar matahari tanpa katalis C-N-codoped TiO2 27.47% dan 13.74%. Persen degradasi meningkat menjadi 68.68% dan 28.57% dengan penambahan 15 mg katalis C-N-codoped selama 120 menit fotolisis. Dari penelitian dapat disimpulkan metode fotolisis dengan sinar UV lebih efisien dibandingkan dengan sinar matahari. Direct red-23 dye is a synthetic dye that is widely used in textile industry. Wastes generated from textile industrial processes are generally non-biodegradable organic compounds containing azo compounds and carcinogenic. Direct red-23 dye was degraded by photolysis UV Light method,  solar irradiation, without and addition of C-N-codoped TiO2 catalyst. The results degradation of direct red-23 were measured with a UV-Vis spectrophotometer at wavelength of 400-800 nm. Determination of optimum weight of the C-N-codoped TiO2 catalyst was performedby photolysisUV Light methodand the optimum C-N-codoped TiO2catalyst is obtained 15 mg. Percent degradation of direct red-23 dye by photolysis of UV light and solar irradiation without C-N-codoped TiO2to 27.47% and 13.74%. Percent degradation increasedto 68.68% and 28.57% by addingC-N-codoped TiO2 catalyst was adding 120 menutes of photolysis.From the research it can be concluded by photolysis with UV Light methodis more efficient compared to solar radiation.

Degradation of organic pollutant in restaurant wastewater using the homogenous catalysis with Mn(II) and EDTA

2021 ◽  
Vol 10 (4) ◽  
pp. 46-51
Author(s):  
Tue Nguyen-Ngoc ◽  
Trung Nguyen-Duc
Keyword(s):  
Textile Industry ◽  
Industrial Wastewater ◽  
Plant Protection ◽  
Organic Pollutant ◽  
Paper Industry ◽  
Organic Pollution ◽  
Activation Process ◽  
Printing Industry ◽  
Transitional Metal ◽  
Restaurant Wastewater

It can be seen that the objects of wastewater that need to be treated are quite diverse in types and complex in terms of reaction mechanisms. The methods mainly focus on the treatment of toxic organic compounds, especially phenols or plant protection agents in industrial wastewater, paper industry, food production, textile industry, printing industry... The activation of H2O2 and O2 by complexes of transitional metal ions and suitable ligands creates oxidizing agents and ecologically healthy products. The intermediate substances arising in the activation process such as free radicals OH., O2., HO2., ... can oxidize many compounds, especially the ability to attack the aroma of organic pollutants. In this paper, the results of research on treating organic pollution in restaurant wastewater with H2O2 are presented as a catalyst of complexes between Mn2+ ions and EDTA. The conditions including pH, EDTA/Mn2+, the concentration of H2O2, Mn2+ were investigated to obtain the optimum conditions for improving COD treatment efficiency. This work proposes a method based on formation of the Mn(II)-EDTA complex,  b=1; with the optimal conditions of other factors as following [H2O2]0 = 0,75.10-3 mol/L; [Mn(EDTA)]2- = 33,33 mol/L, pH=10.5; t = 15 minutes. The initial COD of 1025 mg/L decreased to 135 mg/L after the proposed procedure.  The results provide solutions of homogeneous complex catalysts for domestic/restaurant and industrial wastewater treatment at room temperature and atmosphere.

Preparation and Photocatalytic Activity of TiO2/Opal Composite

2013 ◽  
Vol 668 ◽  
pp. 13-16
Author(s):  
Qing Shan Li ◽  
Biao Zhan ◽  
Wei Hong ◽  
Guang Zhong Xing
Keyword(s):  
Methylene Blue ◽  
Uv Light ◽  
Sol Gel ◽  
Tetrabutyl Titanate ◽  
Methylene Blue Solution ◽  
Photocatalytic Decolorization ◽  
Uv Light Irradiation ◽  
Photocatalytic Activities ◽  
Blue Solution ◽  
Gel Technique

Opal as a carrier, tetrabutyl titanate as a titanium source, TiO2 loaded on opal was prepared by sol-gel technique. The photocatalysts were characterized by XRD, TEM and UV-VIS absorption spectrum. Their photocatalytic activities were examined by the photocatalytic decolorization of methylene blue solution under UV light irradiation. The effects of calcination temperature, the amount of TiO2 loading and pH on photocatalytic activities were discussed. The results show that TiO2 supported on opal induced enhancement of photocatalytic decolorization rant and TiO2 doping is about 30 wt. % with 92.15% of decolorization rate at 700°C.

scholarly journals Performance study of MATLAB modelled PV panel and conventional PV panel interfaced with LabVIEW

2018 ◽  
Vol 7 (2.17) ◽  
pp. 70
Author(s):  
Jaiganesh K ◽  
Karuppiah N ◽  
Ravivarman S ◽  
Md Asif
Keyword(s):  
Electrical Energy ◽  
Black Body ◽  
Atmospheric Temperature ◽  
Climatic Conditions ◽  
Solar Irradiation ◽  
Irradiation Condition ◽  
Solar Pv ◽  
Performance Study ◽  
Pv Panel ◽  
Proposed Model

The maximum electrical energy conversion efficiency of the Solar PV panel is up to 22% in normal conventional roof- top system under the temperature of 25˚C on Standard Test Condition (STC). In Indian climatic conditions, the atmospheric temperature is mostly above 35˚C to 45˚C, it incites 35˚C to 80˚C temperature on the PV panel. The black body of the PV panel absorbs more heat. This temperature affects the electrical efficiency of the panel significantly. This paper proposes the mathematical modelling of the solar PV panel for different solar irradiation and the temperature. The experimental evaluation is conducted in the latitude of 11.36 (N) and longitude 77.82 (E). The testing and monitoring was done with LabVIEW based National Instruments hardware such as NI cDAQ-9178, NI DAQ - 9227 and NI DAQ 9225. The comparative study between the simulated result and real time hardware results are discussed in this paper. The test result shows that the output of the proposed model mismatches with the experimental output of the solar PV panel due to the negative correlation between the efficiency and temperature for variable irradiation condition. It shows a power difference of 9.41W between the output of the proposed model and the experimental setup.  

scholarly journals The Effects of rural income project on silk exports and livelihood of smallholder producers in Gatsibo District, Rwanda

2021 ◽  
Author(s):  
Abiola Ogunlusi ◽  
Olanrewaju Olaniyan
Keyword(s):  
Textile Industry ◽  
Positive Impact ◽  
Raw Materials ◽  
Climatic Conditions ◽  
High Yield ◽  
Continuous Training ◽  
Cocoon Production ◽  
Income Status ◽  
The Impact ◽  
Smallholder Producers

Abstract Sericulture has been seen in Rwanda as an opportunity for increasing raw materials for the textile industry. Therefore, it has provided a new source of income, reduced unemployment and most likely to improve the livelihood status of poor sericulture smallholder producers by increasing their income earnings. The high yield in silk production has been pleasing due to the favourable climatic conditions for mulberry cultivation, sericulture has been seen as a potential tool to reduce poverty and also to generate foreign exchanges from exportation. The broad objective of this paper focuses on the impact of the livelihood status of smallholder producers in Rwanda. Purposive and simple random sampling techniques were employed in selecting 286 sericulture households’ farmers in Gatsibo district. Data for this study were analysed using descriptive statistics, inferential statistics, paired-samples t-test, cross-tabulation and chi-square test of independence. The results of this study showed clearly a significant improvement in the livelihood of the farmers. It was gathered that 82% asserted there are organized markets available for silk exportation. 77% affirmed an improvement in their income status. The average level of income per year from cocoon production among the farmers was estimated to be $ 227.59. It is of topmost priority for this program to continue because its effect has a very positive impact on the livelihood status of the beneficiaries. Farmers should be provided with continuous training, access to credits. If sustained properly it will resolve future challenges and springs more opportunities for farmers and likewise to the country through exports.

scholarly journals The Effects of rural income project on silk exports and livelihood of smallholder producers in Gatsibo District, Rwanda.

2021 ◽  
Author(s):  
Abiola Ogunlusi ◽  
Olanrewaju Olaniyan
Keyword(s):  
Textile Industry ◽  
Positive Impact ◽  
Raw Materials ◽  
Climatic Conditions ◽  
High Yield ◽  
Continuous Training ◽  
Cocoon Production ◽  
Income Status ◽  
The Impact ◽  
Smallholder Producers

Abstract Sericulture has been seen in Rwanda as an opportunity for increasing raw materials for the textile industry. Therefore, it has provided a new source of income, reduced unemployment and most likely to improve the livelihood status of poor sericulture smallholder producers by increasing their income earnings. The high yield in silk production has been pleasing due to the favourable climatic conditions for mulberry cultivation, sericulture has been seen as a potential tool to reduce poverty and also to generate foreign exchanges from exportation. The broad objective of this paper focuses on the impact of the livelihood status of smallholder producers in Rwanda. Purposive and simple random sampling techniques were employed in selecting 286 sericulture households’ farmers in Gatsibo district. Data for this study were analysed using descriptive statistics, inferential statistics, paired-samples t-test, cross-tabulation and chi-square test of independence. The results of this study showed clearly a significant improvement in the livelihood of the farmers. It was gathered that 82% asserted there are organized markets available for silk exportation. 77% affirmed an improvement in their income status. The average level of income per year from cocoon production among the farmers was estimated to be $227.59. It is of topmost priority for this program to continue because its effect has a very positive impact on the livelihood status of the beneficiaries. Farmers should be provided with continuous training, access to credits. If sustained properly it will resolve future challenges and springs more opportunities for farmers and likewise to the country through exports.

scholarly journals Photocatalytic Activity and Optical Properties of Blue Persistent Phosphors under UV and Solar Irradiation

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
C. R. García ◽  
L. A. Diaz-Torres ◽  
J. Oliva ◽  
M. T. Romero ◽  
P. Salas
Keyword(s):  
Photocatalytic Activity ◽  
Annealing Temperature ◽  
Uv Light ◽  
Solar Irradiation ◽  
Photoluminescence Spectra ◽  
X Ray Diffraction ◽  
X Ray ◽  
Water Cleaning ◽  
Different Temperatures ◽  
The Eu

Blue phosphorescent strontium aluminosilicate powders were prepared by combustion synthesis route and a postannealing treatments at different temperatures. X-ray diffraction analysis showed that phosphors are composed of two main hexagonal phases: SrAl2O4and Sr3Al32O51. The morphology of the phosphors changed from micrograins (1000°C) to a mixture of bars and hexagons (1200°C) and finally to only hexagons (1300°C) as the annealing temperature is increased. Photoluminescence spectra showed a strong blue-green phosphorescent emission centered atλem=455 nm, which is associated with4f65d1→4f6  (8S7/2)transition of the Eu2+. The sample annealed at 1200°C presents the highest luminance value (40 Cd/m2) with CIE coordinates (0.1589, 0.1972). Also, the photocatalytic degradation of methylene blue (MB) under UV light (at 365 nm) was monitored. Samples annealed at 1000°C and 1300°C presented the highest percentage of degradation (32% and 38.5%, resp.) after 360 min. In the case of photocatalytic activity under solar irradiation, the samples annealed at 1000°C, 1150°C, and 1200°C produced total degradation of MB after only 300 min. Hence, the results obtained with solar photocatalysis suggest that our powders could be useful for water cleaning in water treatment plants.

scholarly journals Nucleophile sensitivity of Drosophila TRPA1 underlies light-induced feeding deterrence

eLife ◽  
2016 ◽  
Vol 5 ◽  
Author(s):  
Eun Jo Du ◽  
Tae Jung Ahn ◽  
Xianlan Wen ◽  
Dae-Won Seo ◽  
Duk L Na ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Free Radicals ◽  
Tissue Damage ◽  
Transient Receptor Potential ◽  
Uv Light ◽  
Receptor Potential ◽  
Solar Irradiation ◽  
Feeding Deterrence ◽  
Natural Sunlight ◽  
Transient Receptor

Solar irradiation including ultraviolet (UV) light causes tissue damage by generating reactive free radicals that can be electrophilic or nucleophilic due to unpaired electrons. Little is known about how free radicals induced by natural sunlight are rapidly detected and avoided by animals. We discover that Drosophila Transient Receptor Potential Ankyrin 1 (TRPA1), previously known only as an electrophile receptor, sensitively detects photochemically active sunlight through nucleophile sensitivity. Rapid light-dependent feeding deterrence in Drosophila was mediated only by the TRPA1(A) isoform, despite the TRPA1(A) and TRPA1(B) isoforms having similar electrophile sensitivities. Such isoform dependence re-emerges in the detection of structurally varied nucleophilic compounds and nucleophilicity-accompanying hydrogen peroxide (H2O2). Furthermore, these isoform-dependent mechanisms require a common set of TRPA1(A)-specific residues dispensable for electrophile detection. Collectively, TRPA1(A) rapidly responds to natural sunlight intensities through its nucleophile sensitivity as a receptor of photochemically generated radicals, leading to an acute light-induced behavioral shift in Drosophila.

scholarly journals Treatment of High-Strength Animal Industrial Wastewater Using Photo-Assisted Fenton Oxidation Coupled to Photocatalytic Technology

Water ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1553 ◽  
Author(s):  
Jae Hong Park ◽  
Dong Seok Shin ◽  
Jae Kwan Lee
Keyword(s):  
Light Intensity ◽  
Removal Efficiency ◽  
Industrial Wastewater ◽  
Uv Light ◽  
High Strength ◽  
Cod Removal ◽  
Fenton Oxidation ◽  
Optimal Conditions ◽  
Experimental Conditions ◽  
Animal Wastewater

Animal wastewater is one of the wastewaters that has a color and is difficult to treat because it contains a large amount of non-degradable organic materials. The photo-assisted Fenton oxidation technique was applied to treat animal wastewater, and the optimal conditions of chemical oxygen demands (COD) removal were analyzed according to changes in pH, ferrous ion, H2O2, and ultraviolet (UV) light intensity as a single experimental condition. Experimental results showed that, under the single-factor experimental conditions, the optimal conditions for degradation of animal wastewater were pH 3.5, Fe(II) 0.01 M, H2O2 0.1 M, light intensity 3.524 mW/m2. Under the optimal conditions, COD removal efficiency was 91%, sludge production was 2.5 mL from 100 mL of solution, color removal efficiency was 80%, and coliform removal efficiency was 99.5%.

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