Ordered Arrays of Magnetic Metal Nanotubes and Nanowires Encapsulated with Carbon Tubes

2008 ◽  
Vol 8 (9) ◽  
pp. 4494-4499
Author(s):  
Cuiling Gao ◽  
Feifei Tao ◽  
Weiwei Lin ◽  
Zheng Xu ◽  
Ziling Xue

The ordered arrays of magnetic metal (including Fe, Co and Ni) nanotubes and nanowires encapsulated with carbon tubes are controllably synthesized by employing the array of C tubes as second-order template and combining with electrodeposition technique. The wall thickness and diameter of carbon nanotubes are uniform along the whole tubes; also the wall thickness of inner metal nanotubes is adjustable from 25 nm to solid nanowires. These composite structures are characterized by X-ray diffractometer (XRD), energy-dispersive spectrometry (EDS), Raman scattering spectrum, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The magnetic properties show that coaxial nanotubes and nanocables composite arrays all exhibit magnetic anisotropy with the easy direction perpendicular to axis of the metal nanotubes or nanowires except the Ni@C coaxial nanotubes array that has no preferable magnetization axis.

2021 ◽  
Author(s):  
Olga Ageeva ◽  
Ge Bian ◽  
Gerlinde Habler ◽  
Rainer Abart

<p>Magnetite micro-inclusions in silicate minerals are important carriers of the remanent magnetization of rocks. Their shape orientation relationships (SOR) and crystallographic orientation relationships (COR) to the host crystal are of interest in the context of the bulk magnetic properties of the inclusion-host assemblage. We investigated the SOR and COR of magnetite (MT) micro-inclusions in plagioclase (PL) from oceanic gabbro using correlated optical microscopy, scanning electron microscopy, Electron backscatter diffraction analysis and Transmission electron microscopy.</p><p>In the mm-sized PL crystals of the investigated gabbros MT is present as equant, needle- and lath-shaped (sub)micrometer sized inclusions. More than 95% of the needle-shaped inclusions show SOR and specific COR to the plagioclase host. Most of the needles are elongated perpendicular to one of the MT{111} planes, which is aligned parallel to one of the (112), (1-12), (-312), (-3-12), (150), (1-50) or (100) planes of plagioclase. These inclusions are classified as “plane-normal type”. The needle elongation parallel to MT<111>, which is the easy direction of magnetization, ensures high magnetic susceptibility of these inclusions. The underlying formation mechanism is related to the parallel alignment of oxygen layers with similar lattice spacing across the MT-PL interfaces that are parallel to the elongation direction [1].</p><p>Apart from the SOR and the alignment of a MT{111} with one of the PL low index planes, the MT crystals rotate about the needle elongation direction. The rotation angles are statistically distributed with several maxima representing specific orientation relationships. In some cases one of the MT<001> axes is aligned with PL[14 10 7] or PL[-14 10 -7], which ensures that FeO<sub>6 </sub>octahedra of MT well fit into channels // [001] of PL, which are formed by six membered rings of SiO<sub>4</sub> and AlO<sub>4</sub> tetrahedra [2]. This COR is referred to as the “nucleation orientation” of magnetite with respect to PL. There are several other possibilities to fit FeO<sub>6</sub> octahedra into the [001] channels of PL, but the alignment stated above allows for the additional parallel alignment of one of the MT{111} with one of the above mentioned low index lattice planes of PL. MT crystals with one of these nucleation orientations can undergo directional growth to develop laths and needles. MT crystals with other nucleation orientations that do not allow for the parallel alignment of MT{111} with the above mentioned PL lattice planes, do not significantly grow and form the equant inclusions.</p><p>For some needles one or more of the MT{011} planes that are parallel to the needle elongation direction, are aligned with low-index planes of plagioclase such as PL (112), PL(150), PL(1-50) etc., and form MT facets. This situation corresponds to achievement of the best possible match between the two crystal lattices. This can either be generated during primary growth or during re-equilibration of the micro-inclusions and the plagioclase host.</p><p>Funding by RFBR project 18-55-14003 and Austrian Science fund (FWF): I 3998-N29 is acknowledged.</p><p>Reference</p><p>[1] Ageeva et al (2020) Contrib. Mineral. Petrol. 175(10), 1-16.</p><p>[2] Wenk et al (2011) Am. Min. 96, 1316-1324</p>


1997 ◽  
Vol 3 (S2) ◽  
pp. 521-522
Author(s):  
A.F. Marshall ◽  
L. Klein ◽  
J.S. Dodge ◽  
C.H. Ahn ◽  
J.W. Reiner ◽  
...  

SrRuO3 is a low temperature ferromagnet (Tc ≌ 150K) which has recently been investigated in thin film form due to its structural compatibility with other thin film perovskites materials of practical interest, including high-temperature superconductors. Magnetization studies of thin films of SrRuO3 deposited on cubic SrTiO3 indicate strong uniaxial anisotropy with the easy direction approximately along either the a or b axis, which are difficult to distinguish. The orthorhombic structure of SrRuO3 (a = 5.53, b = 5.57, c = 7.84 Å) has six symmetry-related orientations on the cubic substrate (a = 3.9Å). Using Lorentz transmission electron microscopy both the magnetic and the crystallographic domain microstructure are characterized.For TEM imaging the films are readily removed from the substrate by chemical etching, using a HF:HNO3:H2O etch of approximately 1:1:1 dilution. Free-floating SrRuO3 films of 300-1000Å in thickness are then supported on standard carbon/formvar films on Cu substrates.


2006 ◽  
Vol 514-516 ◽  
pp. 280-283
Author(s):  
Nikolai A. Sobolev ◽  
Marcio A. Oliveira ◽  
Vitor S. Amaral ◽  
Armando Neves ◽  
M. Celeste Carmo ◽  
...  

Ferromagnetism persisting above 375 K and anisotropic ferromagnetic resonance (FMR) spectra have been detected for the first time in Si co-implanted with Mn and As and annealed under appropriate conditions. For comparison, semi-insulating GaAs samples have been implanted with the same ions and subsequently annealed. They also exhibit ferromagnetism with a Curie temperature well in excess of 375 K. High-resolution transmission electron microscopy (TEM) performed on the samples with the best magnetic characteristics has shown the presence of nanoclusters due to the segregation of the implanted species in both Si and GaAs. The angular dependence of the FMR spectra also reveals the existence of magnetic clusters with the hard magnetization axis aligned along the four equivalent <111> crystal axes. The spectra are very similar in Si and GaAs, indicating that the clusters in both materials probably consist of hexagonal MnAs.


Author(s):  
Donald L. Gibbon

Severe intergranular attack (IGA) has occurred in Ni-based Alloy 600 under some use conditions, degrading as much as 40-60% of the wall thickness in heat exchanger tubes. In order to understand the IGA process more thoroughly, it was necessary to examine pristine samples of the attacked grain surfaces. Any preparation that involved use of liquids was ruled out because of possible contamination or removal of important constituents; ion-thinning for transmission electron microscopy would be difficult because of the extremely poor bonding between the grains in the IGA areas; simple fracture would be difficult because of the extremely plastic behavior of Alloy 600 (even at LN temperatures) and because of the irregular distribution of the attacked areas. The following preparation technique met all of these objections and even turned some of them into advantages.


2010 ◽  
Vol 663-665 ◽  
pp. 405-408
Author(s):  
Xiao Lan Sun ◽  
Yan Hua Dong ◽  
Chao Li ◽  
Xiao Hong Liu

The size of quantum dots (QDs), their shape, and ordered arrays have significant impact on electrical and optical properties of the QDs. We synthesized near-infrared-emitting PbSe QDs via an oil phase method in a noncoordinating solvent. Transmission electron microscopy (TEM) and photoluminescence (PL) spectroscopy were used to characterize the samples. Sizes of the QDs were accurately controlled from 4.2 nm to 10.2 nm through control of the reaction time as well as the growth temperature. The PL spectra showed strong size dependence, which is large red shift with increasing size of the QDs.


Chemotherapy ◽  
2009 ◽  
Vol 55 (5) ◽  
pp. 303-307 ◽  
Author(s):  
Ali Akbar Velayati ◽  
Parissa Farnia ◽  
Tengku Azmi Ibrahim ◽  
Rafiuz Zaman Haroun ◽  
Ho Oi Kuan ◽  
...  

Author(s):  
G. G. Shaw

The morphology and composition of the fiber-matrix interface can best be studied by transmission electron microscopy and electron diffraction. For some composites satisfactory samples can be prepared by electropolishing. For others such as aluminum alloy-boron composites ion erosion is necessary.When one wishes to examine a specimen with the electron beam perpendicular to the fiber, preparation is as follows: A 1/8 in. disk is cut from the sample with a cylindrical tool by spark machining. Thin slices, 5 mils thick, containing one row of fibers, are then, spark-machined from the disk. After spark machining, the slice is carefully polished with diamond paste until the row of fibers is exposed on each side, as shown in Figure 1.In the case where examination is desired with the electron beam parallel to the fiber, preparation is as follows: Experimental composites are usually 50 mils or less in thickness so an auxiliary holder is necessary during ion milling and for easy transfer to the electron microscope. This holder is pure aluminum sheet, 3 mils thick.


Author(s):  
R. W. Anderson ◽  
D. L. Senecal

A problem was presented to observe the packing densities of deposits of sub-micron corrosion product particles. The deposits were 5-100 mils thick and had formed on the inside surfaces of 3/8 inch diameter Zircaloy-2 heat exchanger tubes. The particles were iron oxides deposited from flowing water and consequently were only weakly bonded. Particular care was required during handling to preserve the original formations of the deposits. The specimen preparation method described below allowed direct observation of cross sections of the deposit layers by transmission electron microscopy.The specimens were short sections of the tubes (about 3 inches long) that were carefully cut from the systems. The insides of the tube sections were first coated with a thin layer of a fluid epoxy resin by dipping. This coating served to impregnate the deposit layer as well as to protect the layer if subsequent handling were required.


Author(s):  
S. Fujishiro

The mechanical properties of three titanium alloys (Ti-7Mo-3Al, Ti-7Mo- 3Cu and Ti-7Mo-3Ta) were evaluated as function of: 1) Solutionizing in the beta field and aging, 2) Thermal Mechanical Processing in the beta field and aging, 3) Solutionizing in the alpha + beta field and aging. The samples were isothermally aged in the temperature range 300° to 700*C for 4 to 24 hours, followed by a water quench. Transmission electron microscopy and X-ray method were used to identify the phase formed. All three alloys solutionized at 1050°C (beta field) transformed to martensitic alpha (alpha prime) upon being water quenched. Despite this heavily strained alpha prime, which is characterized by microtwins the tensile strength of the as-quenched alloys is relatively low and the elongation is as high as 30%.


Author(s):  
P.J. Dailey

The structure of insect salivary glands has been extensively investigated during the past decade; however, none have attempted scanning electron microscopy (SEM) in ultrastructural examinations of these secretory organs. This study correlates fine structure by means of SEM cryofractography with that of thin-sectioned epoxy embedded material observed by means of transmission electron microscopy (TEM).Salivary glands of Gromphadorhina portentosa were excised and immediately submerged in cold (4°C) paraformaldehyde-glutaraldehyde fixative1 for 2 hr, washed and post-fixed in 1 per cent 0s04 in phosphosphate buffer (4°C for 2 hr). After ethanolic dehydration half of the samples were embedded in Epon 812 for TEM and half cryofractured and subsequently critical point dried for SEM. Dried specimens were mounted on aluminum stubs and coated with approximately 150 Å of gold in a cold sputtering apparatus.Figure 1 shows a cryofractured plane through a salivary acinus revealing topographical relief of secretory vesicles.


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