Improving the tribological and mechanical properties of polyimide composites by incorporating functionalized graphene

2019 ◽  
Vol 32 (1) ◽  
pp. 21-29
Author(s):  
Yuqi Li ◽  
Qiu Zhang ◽  
Hong Ruan ◽  
Fengan Li ◽  
Xu Xu ◽  
...  

To explore the effect of added graphene sheets (GNs) and added perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) on the tribological and mechanical performances of polyimide (PI) matrix, GNs and PTCDA reinforced PI-based composites were synthesized via the blending method. The tribological properties of GNs/PTCDA/PI (GAPI) composites with different weight ratios of GNs and PTCDA under dry sliding, deionized water lubrication, and kerosene lubrication were comparatively investigated. A synergism was found between GNs and PTCDA; this synergism endowed filled PI composites with a lower friction coefficient and showed an improved wear rate under different lubrication conditions, especially when the weight ratio of GNs and PTCDA was 1:1 (GAPI-1). Under dry sliding, deionized water lubrication, and kerosene lubrication, the friction coefficient of GAPI-1 composites decreased by 41.1%, 70%, and 35.7%, respectively, while the wear rate decreased by 39%, 50%, and 25.1%, respectively. Meanwhile, the tensile strength, tensile modulus, and the elongation at break of GAPI-1 films increased by 40.8%, 51.3%, and 49.2%, respectively, relative to those of pure PI. We anticipate that this work can be used to exploit a simple and effective method for preparing materials for bearings and transmission parts that possess good tribological properties under harsh lubrication conditions.

2020 ◽  
Vol 2020 ◽  
pp. 1-18
Author(s):  
Pranav Dev Srivyas ◽  
M.S. Charoo

Advanced composites are the materials of the new generation. Hence, the focus of the study is to determine the tribological properties of the eutectic Al-Si alloy reinforced with (2, 4, 6, 8, and10 wt. %) of n-Al2O3 against chrome-plated steel ball under dry sliding conditions. The novelty of this work is the fabrication of the composite sample with this elemental composition, which is not done before. Spark plasma sintering (SPS) nonconventional fabrication method is used to fabricate advanced composite samples. Friction coefficient (COF) and wear rate of the composite samples were studied under high load, varying from 50 N to 300 N, using the ball-on-disc tribometer configuration, with other parameters such as stroke, frequency, sliding distance, and sliding velocity remaining constant at 2 mm, 30 Hz, 120 meter, and 0.120 m/s, respectively. Reduction in wear volume for the advanced composite was reported in the range 15.45–44.58% compared to the base alloy (eutectic Al-Si alloy). An increase in friction coefficient was reported in the range 28.80–35.65% compared to the base matrix alloy material. It was also reported that the wear rate increases and the friction coefficient of the composite sample decreases with an increase in load for the tribo-pair. It was observed that an increase in the wt. % of reinforcement influences the friction and wear behavior of the composite. Wear mechanism at high load was characterized by plastic deformation, adhesion, delamination, and abrasion wear. For pre- and postcharacterization of surface and worn tracks, scanning electron microscopy (SEM) electron dispersion spectroscopy (EDS), 3D surface profilometer, and optical microscopy were used. This work aimed to investigate the influence of load on the tribological properties of Al-Si eutectic reinforced n-Al2O3 under dry sliding conditions. Its main objective was to provide a new contribution to the tribological behavior of these composites fabricated using the nonconventional spark plasma sintering method.


2019 ◽  
Vol 71 (9) ◽  
pp. 1064-1071 ◽  
Author(s):  
Alagarsamy S.V. ◽  
Ravichandran M.

Purpose Aluminium and its alloys are the most preferred material in aerospace and automotive industries because of their high strength-to-weight ratio. However, these alloys are found to be low wear resistance. Hence, the incorporation of ceramic particles with the aluminium alloy may be enhanced the mechanical and tribological properties. The purpose of this study is to optimize the specific wear rate and friction coefficient of titanium dioxide (TiO2) reinforced AA7075 matrix composites. The four wear control factors are considered, i.e. reinforcement (Wt.%), applied load (N), sliding velocity (m/s) and sliding distance (m). Design/methodology/approach The composites were fabricated through stir casting route with varying weight percentages (0, 5, 10 and 15 Wt.%) of TiO2 particulates. The mechanical properties of the composites were studied. The specific wear rate and friction coefficient of the newly prepared composites was determined by using a pin-on-disc apparatus under dry sliding conditions. Experiments were planned as per Taguchi’s L16 orthogonal design. Signal-to-noise ratio analysis was used to find the optimal combination of parameters. Findings The mechanical properties such as yield strength, tensile strength and hardness of the composites significantly improved with the addition of TiO2 particles. The analysis of variance result shows that the applied load and reinforcement Wt.% are the most influencing parameters on specific wear rate and friction coefficient during dry sliding conditions. The scanning electron microscope morphology of the worn surface shows that TiO2 particles protect the matrix from more removal of material at all conditions. Originality/value This paper provides a solution for optimal parameters on specific wear rate and friction coefficient of aluminium matrix composites (AMCs) using Taguchi methodology. The obtained results are useful in improving the wear resistance of the AA7075-TiO2 composites.


2011 ◽  
Vol 133 (4) ◽  
Author(s):  
Licai Fu ◽  
Jun Yang ◽  
Qinling Bi ◽  
Weimin Liu

The dry-sliding tribological properties of the dendrite composite eutectic Fe-B alloys (Fe94.3B5.7, Fe75B25 Fe67B33) were studied comparatively with various sliding speeds. The friction coefficient of the Fe-B alloy changes slightly with the boron content. The wear rate of the Fe94.3B5.7 alloy with about 30 vol. % dendrite t-Fe2B is only one third of Fe75B25 alloy with 15 vol. % dendrite and Fe67B33 alloy with 90 vol. % dendrite in the high sliding speed. First, a hard t-Fe2B phase reduced the wear of the Fe-B alloy directly. Second, the compactly oxide layers resulting from oxidation of the α-Fe on the worn surfaces also decreases the wear rate of Fe-B alloys. On the whole, the wear rate of the Fe94.3B5.7 is lower than Fe67B33 and Fe75B25.


2014 ◽  
Vol 936 ◽  
pp. 2063-2067
Author(s):  
Chen Yue ◽  
Shang Guan Bao ◽  
Ying Yu Huang

The friction and wear properties of cast iron with different graphite morphologies and matrix microstructure were investigated at high speed dry sliding against GCr15 steel on the MMS-1G high-speed tribometer apparatus. The various wear micro-mechanisms and tribo-metallographic phases were studied by using scanning electron microscopy. The results show that as friction material, vermicular iron exhibits excellent comprehensive tribological properties. The friction coefficient of cast iron sliding against GCr15 decreases while the wear rate increases with the increase of sliding speed, friction coefficient and wear rate decline with the increase of pearlite content. Under the experimental condition, the main wear mechanisms of flake iron are abrasive wear, of vermicular iron are abrasive wear and oxidative wear and of nodular iron are oxidative wear, abrasive wear and fatigue spalling.


Author(s):  
Ying Yan ◽  
Xuelin Lei ◽  
Yun He

The effect of nanoscale surface texture on the frictional and wear performances of nanocrystalline diamond films under water-lubricating conditions were comparatively investigated using a reciprocating ball-on-flat tribometer. Although the untreated nanocrystalline diamond film shows a stable frictional state with an average friction coefficient of 0.26, the subsequent textured films show a beneficial effect on rapidly reducing the friction coefficient, which decreased to a stable value of 0.1. Furthermore, compared with the nanocrystalline diamond coating, the textured films showed a large decreasing rate of the corresponding ball wear rate from 4.16 × 10−3 to 1.15 × 10−3 mm3/N/m. This is due to the fact that the hydrodynamic fluid film composed of water and debris can provide a good lubrication environment, so the entire friction process has reached the state of fluid lubrication. Meanwhile, the surface texture can greatly improve the hydrophilicity of the diamond films, and as the texture density increases, the water contact angle decreases from 94.75° of the nanocrystalline diamond film to 78.5° of the textured films. The proper textured diamond film (NCD90) exhibits superior tribological properties among all tested diamond films, such as short run-in period, low coefficient of friction, and wear rate.


2010 ◽  
Vol 654-656 ◽  
pp. 2763-2766 ◽  
Author(s):  
Li Wen Mu ◽  
Xin Feng ◽  
Yi Jun Shi ◽  
Huai Yuan Wang ◽  
Xiao Hua Lu

The tribological properties of polyimide (PI) composites reinforced with graphite or MoS2 sliding in liquid alkali and water as well as dry friction were investigated using a ring-on-ring tester. The results show that the friction coefficient (μ) and wear rate (W) for both graphite/PI and MoS2/PI composites in different liquid mediums are μdry>μwater >μalkali and Wwater>Wdry >Walkali. Results also indicate that the friction coefficient and wear rate of the PI composites filled with different solid lubricants are μMoS2 >μgraphite and W MoS2 >Wgraphite in different liquid mediums. In addition, the hydrophobic inorganic fillers are fit for the reinforcement of polymer-based composites sliding in liquid mediums. It is also concluded from the authors’ work that the wear rate and friction coefficient of polymer-based (such as PI, PTFE) composites in the alkali lubricated conditions is lowest among all the friction conditions. This may be attributed to the ionic hydration in the alkaline solution.


2018 ◽  
Vol 18 (18) ◽  
pp. 18-23 ◽  
Author(s):  
Sandra Veličković ◽  
Slavica Miladinović ◽  
Blaža Stojanović ◽  
Ružica R. Nikolić ◽  
Branislav Hadzima ◽  
...  

Abstract Hybrid materials with the metal matrix are important engineering materials due to their outstanding mechanical and tribological properties. Here are presented selected tribological properties of the hybrid composites with the matrix made of aluminum alloy and reinforced by the silicon carbide and graphite particles. The tribological characteristics of such materials are superior to characteristics of the matrix – the aluminum alloy, as well as to characteristics of the classical metal-matrix composites with a single reinforcing material. Those characteristics depend on the volume fractions of the reinforcing components, sizes of the reinforcing particles, as well as on the fabrication process of the hybrid composites. The considered tribological characteristics are the friction coefficient and the wear rate as functions of the load levels and the volume fractions of the graphite and the SiC particles. The wear rate increases with increase of the load and the Gr particles content and with reduction of the SiC particles content. The friction coefficient increases with the load, as well as with the SiC particles content increase.


2020 ◽  
Vol 72 (6) ◽  
pp. 805-810
Author(s):  
Hua Zhang ◽  
Guangwu Zhou ◽  
Ping Zhong ◽  
Kepeng Wu ◽  
Xingwu Ding

Purpose The purpose of this paper is to study the influence of friction coefficient of materials with different elastic modulus on the variation of velocity and load under water lubrication and oil lubrication conditions. Design/methodology/approach Low-viscosity lubricating oil and water were used as lubricants to test the friction performance of the ball-disc contact friction pair in the lubrication state on the universal micro-tribometer multi-functional friction and wear test system. Findings In the same speed range, the lubrication states from soft to rigid materials are not necessarily similar to each other. Generally, the material with low elastic modulus is suitable in low-viscosity lubricant environments, while the material with high elastic modulus has relatively smaller friction coefficients in oil-lubricated environments compared with water lubrication. However, the coefficients of polyethylene, polytetrafluoroethylen and polyoxymethylene are exceeded by rubber’s coefficients under water lubrication in the same experiment environments, and their lubrication states are not affected by lubricants. The friction coefficient of the friction pair decreases with the increase of loads; however, it does not apply to all materials. The friction coefficients of materials with smaller elastic modulus such as rubber under high loads are rather large. Therefore, the elastic modulus of the material under high loads is a factor to be considered. Originality/value The Stribeck curves study of the ball-disk contact friction pair comprising soft and rigid materials, whose elastic modulus is from hundreds of GPa to a few of MPa, was carried out. The influence of different speeds, loads and lubricants on the friction coefficient of the friction pair was revealed, which provided a research basis for the selection and matching of friction pair materials.


Metals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1246
Author(s):  
Bo Mao ◽  
Shuangjie Chu ◽  
Shuyang Wang

Friction and wear performance of austenite stainless steels have been extensively studied and show a close relationship with the friction-induced martensitic transformation. However, how the grain size and associated friction-induced martensitic transformation behavior affect the tribological properties of austenite steels have not been systematically studied. In this work, dry sliding tests were performed on an AISI 304 stainless steel with a grain size ranging from 25 to 92 μm. The friction-induced surface morphology and microstructure evolution were characterized. Friction-induced martensitic transformation behavior, including martensite nucleation, martensite growth and martensite variant selection and its effect on the friction and wear behavior of the 304 stainless steel were analyzed. The results showed that both the surface coefficient of friction (COF) and the wear rate increase with the grain size. The COF was reduced three times and wear rate was reduced by 30% as the grain size decreased from 92 to 25 μm. A possible mechanism is proposed to account for the effect of grain size on the tribological behavior. It is discussed that austenite steel with refined grain size tends to suppress the amount of friction-induced martensitic transformed and significantly alleviates both the plowing and adhesive effect during dry sliding.


Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1854
Author(s):  
Fei-xia Zhang ◽  
Yan-qiu Chu ◽  
Chang-sheng Li

This paper presents a facile and effective method for preparing Ni/NbSe2 composites in order to improve the wettability of NbSe2 and copper matrix, which is helpful in enhancing the friction-reducing and anti-wear properties of copper-based composites. The powder metallurgy (P/M) technique was used to fabricate copper-based composites with different weight fractions of Ni/NbSe2, and tribological properties of composites were evaluated by using a ball-on-disk friction-and-wear tester. Results indicated that tribological properties of copper-based composites were improved by the addition of Ni/NbSe2. In particular, copper-based composites containing 15 wt.% Ni/NbSe2 showed the lowest friction coefficient (0.16) and wear rate (4.1 × 10−5 mm3·N−1·m−1) among all composites.


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