Assessment of physical, chemical, and tribochemical properties of biomedical alloys used in explanted modular hip prostheses

Author(s):  
Yesenia Gómez Taborda ◽  
Maryory Gómez Botero ◽  
Juan Guillermo Castaño-González ◽  
Angela Bermúdez-Castañeda

During their service life, modular interfaces experience tribological, and corrosion phenomena that lead to deterioration, which in turn can cause a revision procedure to remove the failed prosthesis. To achieve a clearer understanding of the surface performance of those biomedical alloys and the role of the surface properties in the mechanical and chemical performance, samples were taken from retrieval implants made of Ti6Al4V and Co28Cr6Mo alloys. Polarization resistance and pin-on-disk tests were performed on these samples. Physical properties such as contact angle, roughness, microhardness, and Young’s modulus were determined. A correlation between surface energy and evolution of the tribological contact was observed for both biomedical alloys. In tribocorrosion tests, titanium particles seem to remain in the surface, unlike what is observed in CoCr alloys. These metallic or oxidized particles could cause necrosis or adverse tissue reactions.

Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.


Biology ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 116
Author(s):  
Francisco Perez-Dominguez ◽  
Diego Carrillo-Beltrán ◽  
Rancés Blanco ◽  
Juan P. Muñoz ◽  
Grettell León-Cruz ◽  
...  

Pirin is an oxidative stress (OS) sensor belonging to the functionally diverse cupin superfamily of proteins. Pirin is a suggested quercetinase and transcriptional activator of the nuclear factor kappa-light-chain-enhancer of activated B cells (NF-κB) pathway. Its biological role in cancer development remains a novel area of study. This review presents accumulating evidence on the contribution of Pirin in epithelial cancers, involved signaling pathways, and as a suggested therapeutic target. Finally, we propose a model in which Pirin is upregulated by physical, chemical or biological factors involved in OS and cancer development.


Toxins ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 104
Author(s):  
Ferenc Peles ◽  
Péter Sipos ◽  
Szilvia Kovács ◽  
Zoltán Győri ◽  
István Pócsi ◽  
...  

Aflatoxins (AFs) are toxic secondary metabolites produced mostly by Aspergillus species. AF contamination entering the feed and food chain has been a crucial long-term issue for veterinarians, medicals, agroindustry experts, and researchers working in this field. Although different (physical, chemical, and biological) technologies have been developed, tested, and employed to mitigate the detrimental effects of mycotoxins, including AFs, universal methods are still not available to reduce AF levels in feed and food in the last decades. Possible biological control by bacteria, yeasts, and fungi, their excretes, the role of the ruminal degradation, pre-harvest biocontrol by competitive exclusion or biofungicides, and post-harvest technologies and practices based on biological agents currently used to alleviate the toxic effects of AFs are collected in this review. Pre-harvest biocontrol technologies can give us the greatest opportunity to reduce AF production on the spot. Together with post-harvest applications of bacteria or fungal cultures, these technologies can help us strictly reduce AF contamination without synthetic chemicals.


2015 ◽  
Vol 12 (14) ◽  
pp. 4261-4273 ◽  
Author(s):  
D. Hofmann ◽  
G. Preuss ◽  
C. Mätzler

Abstract. An unusual ice type, called hair ice, grows on the surface of dead wood of broad-leaf trees at temperatures slightly below 0 °C. We describe this phenomenon and present physical, chemical, and biological investigations to gain insight in the properties and processes related to hair ice. Tests revealed that the biological activity of a winter-active fungus is required in the wood for enabling the growth of hair ice. We confirmed the fungus hypothesis originally suggested by Wegener (1918) by reproducing hair ice on wood samples. Treatment by heat and fungicide suppresses the formation of hair ice. Fruiting bodies of Asco- and Basidiomycota are identified on hair-ice-carrying wood. One species, Exidiopsis effusa (Ee), was present on all investigated samples. Both hair-ice-producing wood samples and those with killed fungus show essentially the same temperature variation, indicating that the heat produced by fungal metabolism is very small, that the freezing rate is not influenced by the fungus activity, and that ice segregation is the common mechanism of ice growth on the wood surface. The fungus plays the role of shaping the ice hairs and preventing them from recrystallisation. Melted hair ice indicates the presence of organic matter. Chemical analyses show a complex mixture of several thousand CHO(N,S) compounds similar to fulvic acids in dissolved organic matter (DOM). The evaluation reveals decomposed lignin as being the main constituent. Further work is needed to clarify its role in hair-ice growth and to identify the recrystallisation inhibitor.


2021 ◽  
Vol 303 ◽  
pp. 01001
Author(s):  
Yu Haiyang ◽  
Ji Wenjuan ◽  
Luo Cheng ◽  
Lu Junkai ◽  
Yan Fei ◽  
...  

In order to give full play to the role of imbibition of capillary force and enhance oil recovery of ultralow permeability sandstone reservoir after hydraulic fracturing, the mixed water fracture technology based on functional slick water is described and successfully applied to several wells in oilfield. The core of the technology is determination of influence factors of imbibition oil recovery, the development of new functional slick water system and optimization of volume fracturing parameters. The imbibition results show that it is significant effect of interfacial tension, wetting on imbibition oil recovery. The interfacial tension decreases by an order of magnitude, the imbibition oil recovery reduces by more than 10%. The imbibition oil recovery increases with the contact angle decreasing. The emulsifying ability has no obvious effect on imbibition oil recovery. The functional slick water system considering imbibition is developed based on the solution rheology and polymer chemistry. The system has introduced the active group and temperature resistant group into the polymer molecules. The molecular weight is controlled in 1.5 million. The viscosity is greater than 2mPa·s after shearing 2h under 170s-1 and 100℃. The interfacial tension could decrease to 10-2mN/m. The contact angle decreased from 58° to 22° and the core damage rate is less than 12%. The imbibition oil recovery could reach to 43%. The fracturing process includes slick water stage and linear gel stage. 10% 100 mesh ceramists and 8% temporary plugging agents are carried into the formation by functional slick water. 40-70 mesh ceramists are carried by linear gel. The liquid volume ratio is about 4:1 and the displacement is controlled at 10-12m3/min. The sand content and fracturing fluid volumes of single stage are 80m3 and 2500 m3 respectively. Compared with conventional fracturing, due to imbibition oil recovery, there is only 25% of the fracturing fluid flowback rate when the crude oil flew out. When the oil well is in normal production, about 50% of the fracturing fluid is not returned. It is useful to maintain the formation energy and slow down the production decline. The average cumulative production of vertical wells is greater than 2800t, and the effective period is more than 2 years. This technology overcoming the problem of high horizontal stress difference and lack of natural fracture has been successfully applied in Jidong Oilfield ultralow permeability reservoir. The successful application of this technology not only helps to promote the effective use of ultralow permeability reservoirs, but also helps to further clarify the role of imbibition recovery, energy storage and oil-water replacement mechanism.


2018 ◽  
Vol 18 (2) ◽  
Author(s):  
Muhammad Junaidi ◽  
Nurliah Nurliah ◽  
Fariq Azhar

ABSTRAKMengingat peranan zooplankton dalam ekosistem perairan sangat penting, maka dilakukan penelitian dengan tujuan untuk menganalisis struktur komunitas zooplankton yang meliputi jenis, kelimpahan, dan indek ekologi, dan  kaitan  distribusi zooplankton dan kualitas perairan di Perairan Kabupaten Lombok Utara. Pengumpulan data dirancang dengan sistem informasi geografis (SIG) pada 23 stasiun pengamatan yang ditentukan dengan teknik acak sederhana.  Hasil penelitian menunjukkan bahwa jenis dan kelimpahan zooplankton yang ditemukan di Perairan Kabupaten Lombok Utara cukup bervariasi dengan jumlah genus  sebanyak 9 yang terbagi  dari  5 kelas.  Berdasarkan perhitungan indeks ekologi menunjukkan bahwa struktur  komunitas zooplankton dalam kategori perairan yang kurang stabil. Kelimpahan dan indeks ekologi zooplankton  dipengaruhi oleh kondisi lingkungan (fisik-kimia) perairan antara lain  kecerahan, pH dan oksigen terlarut. Kata kunci : zooplankton,  struktur komunitas, kualitas perairan, kelimpahanABSTRACTConsidering that the role of zooplankton in aquatic ecosystems is very  important, research is carried out with the aim of analyzing zooplankton community structure which includes the type, abundance, and ecological index, and the relation of zooplankton distribution and water quality in North Lombok Regency Waters. Data collection was designed with a geographical information system (GIS) on 23 observation stations that were determined by simple random techniques. he results of this study indicate that the type and abundance of zooplankton found in the waters of North Lombok Regency are quite varied with the number of genus as many as 9 which are divided into 5 classes. Based on the calculation of the ecological index shows that the zooplankton community structure is in the category of less stable waters. The abundance and ecological index of zooplankton is influenced by the environmental (physical-chemical) conditions of the waters including brightness, pH and dissolved oxygen. Keywords: zooplankton, community structure, water quality, abundance 


Author(s):  
Ramakoteswara Rao N ◽  
Kranthi kiran Reddy E ◽  
Leena Gahane ◽  
SV Ranganayakulu

Nano technology is the multi disciplinary science and technology, which has emerged as new science exploiting specific phenomena and direct manipulation of materials on nanoscale. Nanotechnology deals with the physical, chemical, and biological properties of structures and their parts at nanoscale dimensions. It's established on the concept by creating functional structures by controlling corpuscles and molecules on a one-by-one basis by different physical and chemical synthesis methods. Developments in materials science and, nano biotechnology is especially forestalled to provide elevates in dental sciences and initiations in oral health-related diagnostic and therapeutical methods. Keywords: Nano Science, dentistry, Nanocomposite, Nanorobots, Nanomaterials.


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