scholarly journals Acid red G dye removal from aqueous solutions by porous ceramsite produced from solid wastes: Batch and fixed-bed studies

2020 ◽  
Vol 9 (1) ◽  
pp. 770-782
Author(s):  
Tianpeng Li ◽  
Jing Fan ◽  
Tingting Sun
Keyword(s):  
Aqueous Solutions ◽  
Dye Removal ◽  
Coal Fly Ash ◽  
Exothermic Reaction ◽  
Fixed Bed ◽  
Column Experiment ◽  
Solid Wastes ◽  
Order Kinetic ◽  
Cost Effective Treatment ◽  
Acid Red G

AbstractA novel porous ceramsite was made of municipal sludge, coal fly ash, and river sediment by sintering process, and the performance of batch and fixed-bed column systems containing this material in the removal of acid red G (ARG) dye from aqueous solutions was assessed in this study. The results of orthogonal test showed that sintering temperature was the most important determinant in the preparation of porous ceramsite, and it possesses developed pore structure and high specific surface area. Batch experiment results indicated that the adsorption process of ARG dye toward porous ceramsite was a spontaneous exothermic reaction, which could be better described with Freundlich–Langmuir isotherm model (R2 > 0.992) and basically followed the pseudo-first-order kinetic equation (R2 > 0.993). Column experiment results showed that when the porous ceramsite was used as packing material, its adsorption capacity was roughly improved by 3.5 times compared with that in batch system, and the breakthrough behavior was simulated well with Yoon–Nelson model, with R2 > 0.954. This study suggested that the novelty man-made porous ceramsite obtained from solid wastes might be processed as a certain cost-effective treatment material fit for the dye removal in aqueous solutions.

scholarly journals Adsorption of Azo Dye Methyl Orange from Aqueous Solutions Using Alkali-Activated Polypyrrole-Based Graphene Oxide

Molecules ◽  
2019 ◽  
Vol 24 (20) ◽  
pp. 3685 ◽  
Author(s):  
Abdulaziz Ali Alghamdi ◽  
Abdel-Basit Al-Odayni ◽  
Waseem Sharaf Saeed ◽  
Mohammed S. Almutairi ◽  
Fahad A. Alharthi ◽  
...  
Keyword(s):  
Methyl Orange ◽  
Aqueous Solutions ◽  
Physical Adsorption ◽  
Fixed Bed ◽  
Column Experiment ◽  
Morphological Properties ◽  
Fixed Bed Column ◽  
Rate Limiting Step ◽  
Pseudo Second Order ◽  
Polymeric Wastes

The adsorption of methyl orange (MO) from aqueous solutions onto a KOH-activated polypyrrole-based adsorbent (PACK) was investigated using batch and fixed-bed column techniques. The structural, thermal, and morphological properties of the PACK, analyzed by various methods, support its applicability as an adsorbent. An adsorption kinetic study revealed a preferably pseudo-second-order (R2 = 0.9996) and rate-limiting step controlled by both film and intra-particle diffusions. The thermodynamic adsorption tests resulted in negative ΔG°, ΔH°, and ΔS° values, which decreased as the temperature and concentration increased, indicating the spontaneous and exothermic adsorption over 25–45 °C. The adsorption isotherms fit the experimental data in the order of Langmuir ≈ Freundlich > Temkin, with evidence of adsorption operating well via the monolayer physical adsorption process, and maximum monolayer adsorption ranging from 520.8 to 497.5 mg/g. The breakthrough curve of the fixed-bed column experiment was modeled using the Thomas, Yoon–Nelson, and Hill models, resulting in an equilibrium capacity of 57.21 mg/g. A 73% MO recovery was achieved, indicating the possibility of column regeneration. Compared to other adsorbents reported, PACK had comparable or even superior capacity toward MO. For cost-effectiveness, similar nitrogen-containing polymeric wastes could be exploited to obtain such excellent materials for various applications.

scholarly journals Mild Hydrothermal Synthesis of 11Å-TA from Alumina Extracted Coal Fly Ash and Its Application in Water Adsorption of Heavy Metal Ions (Cu(II) and Pb(II))

2022 ◽  
Vol 19 (2) ◽  
pp. 616
Author(s):  
Jingjie Yang ◽  
Hongjuan Sun ◽  
Tongjiang Peng ◽  
Li Zeng ◽  
Xin Zhou
Keyword(s):  
Fly Ash ◽  
Low Cost ◽  
Coal Fly Ash ◽  
Exothermic Reaction ◽  
High Alumina ◽  
Maximum Adsorption Capacity ◽  
Molten Salt Method ◽  
Order Kinetic ◽  
Isothermal Adsorption ◽  
Adsorption Characteristics

Non-biodegradable copper (Cu) and lead (Pb) contaminants in water are highly toxic and have series adverse effects. Therefore, it is very important to extract heavy metals from wastewater before it is discharged into the environment. Adsorption is a cost-effective alternative method for wastewater treatment. Choosing a low-cost adsorbent can help reduce the cost of adsorption. In this study, conversion of reside after extracting aluminum (REA) produced by sub-molten salt method transform high-alumina coal fly ash (CFA) into 11Å-tobermorite to adsorb Cu(II) and Pb(II) from aqueous solutions at room temperature. The synthesis of the adsorbent was confirmed using scanning electron microscope (SEM), X-ray diffractometer (XRD) and Brunauer–Emmett–Teller (BET) method surface analysis. To study the adsorption characteristics, factors such as initial Cu(II) and Pb(II) concentration, pH, contact time, adsorption characteristics and temperature were investigated in batch mode. The maximum adsorption capacity of Cu(II) and Pb(II) was 177.1 mg·g−1 and 176.2 mg·g−1, respectively. The Langmuir adsorption model was employed to better describe the isothermal adsorption behavior and confirm the monolayer adsorption phenomenon. The pseudo-second-order kinetic model was used to highlight Cu(II) and Pb(II) adsorption kinetics. Thermodynamic analysis indicated the removal Cu(II) and Pb(II) by TA-adsorbent was a nonspontaneous and exothermic reaction. The obtained results are of great significance to the conversion of industrial waste to low-cost adsorbent for Cu(II) and Pb(II) removal from water.

scholarly journals ADSORPTION OF REACTIVE BLACK 5 FROM AQUEOUS SOLUTION BY ZEOLITE FROM COAL FLY ASH: EQUILIBRIUM AND KINETIC STUDIES

2011 ◽  
Vol 08 (16) ◽  
pp. 17-24
Author(s):  
Patricia CUNICO ◽  
Denise Alves FUNGARO ◽  
Carina Pitwak MAGDALENA
Keyword(s):  
Fly Ash ◽  
Aqueous Solutions ◽  
Coal Fly Ash ◽  
Kinetic Studies ◽  
Reactive Black 5 ◽  
Order Kinetic ◽  
Zeolitic Material ◽  
Isotherm Adsorption ◽  
Coal Fly Ashes ◽  
Pseudo Second Order

Zeolite synthesized from coal fly ash (ZC) and coal fly ashes (CC) were used as adsorbents to remove Reactive Black 5 (RP5) dye from aqueous solutions. The equilibrium time was reached after 420 min. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetic and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism. The isotherm adsorption data fit accordingly to the Langmuir model for both adsorbents. The maximum adsorption capacities were 0.685 mg g-1 for RP5/ZC system and 0.577 mg g-1 for RP5/CC system. The efficiencies of adsorption were found to be between 47.7-88.1% for ZC and 65.4-99.6% for CC. The results indicate that zeolitic material is suitable as adsorbent for adsorption of reactive azodye from aqueous solutions.

scholarly journals Mercury Removal from Aqueous Solutions Using Modified Pyrite: A Column Experiment

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 43 ◽  
Author(s):  
Yucheng Zhu ◽  
Shuchuan Peng ◽  
Ping Lu ◽  
Tianhu Chen ◽  
Yan Yang
Keyword(s):  
Electron Microscopy ◽  
Aqueous Solutions ◽  
Field Emission ◽  
Photoelectron Spectroscopy ◽  
Fixed Bed ◽  
Column Experiment ◽  
Mercury Removal ◽  
Emission Standard ◽  
X Ray ◽  
Natural Pyrite

Modified pyrite (MPy), which was obtained from calcination in an N2 atmosphere, was used as a sorbent for removing Hg(II) from aqueous solutions. Fixed-bed column experiments were conducted to determine the Hg(II) removal ability of MPy from aqueous solutions. MPy was found to be much better than natural pyrite for mercury removal. The concentration of Hg(II) in effluents was much lower than that of the emission standard used for Hg wastewater in China (0.05 mg/L), and the removal efficiency of Hg(II) was greater than 99% before breakthrough. When the capacity was 3274 times the column bed volume (1 bed volume = 25.12 cm3), the column breakthrough and the sorption amount of Hg(II) were 54.44 mg/g. The Hg(II) content in the used MPy sorbent was up to 24.79%. The mechanism was analyzed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), field emission transmission electron microscopy (FE-TEM), and X-ray Photoelectron Spectroscopy (XPS). The main mechanism of Hg(II) removal by MPy was the chemical reactions between mercury ions and mineral fillers, and HgS precipitated on the surface of MPy to remove Hg(II). The reaction was also accompanied by surface complexation and adsorption. The results of this work show that MPy can be used as a sorbent for continuous Hg(II) removal.

scholarly journals Performance Evaluation and Optimization of Dyes Removal using Rice Bran-Based Magnetic Composite Adsorbent

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2764 ◽  
Author(s):  
Chih Ming Ma ◽  
Gui Bing Hong ◽  
Yi Kai Wang
Keyword(s):  
Aqueous Solutions ◽  
Rice Bran ◽  
Langmuir Isotherm ◽  
Dye Removal ◽  
Isotherm Model ◽  
Quadratic Model ◽  
Magnetic Composite ◽  
Order Kinetic ◽  
Study Results ◽  
Langmuir Isotherm Model

Although several studies have explored green adsorbent synthesized from many types of agriculture waste, this study represents the first attempt to prepare an environmentally friendly rice bran/SnO2/Fe3O4-based absorbent with economic viability and material reusability, for the promotion of sustainable development. Here, rice bran/SnO2/Fe3O4 composites were successfully synthesized and applied for adsorption of reactive blue 4 (RB4) and crystal violet (CV) dyes in aqueous solutions. The adsorption data were well-fitted by the Langmuir isotherm model and the pseudo-second-order kinetic model. The maximum adsorption capacities of the RB4 and CV dyes as indicated by the Langmuir isotherm model were 218.82 and 159.24 mg/g, respectively. As results of response surface methodology (RSM) showed, the quadratic model was appropriate to predict the performance of RB4 dye removal. The findings exhibited that an optimum removal rate of 98% was achieved at 60 °C for pH 2.93 and adsorption time of 360 min. Comparative evaluation of different agricultural wastes indicated that the rice bran/SnO2/Fe3O4 composite appeared to be a highly promising material in terms of regeneration and reusability, and showed that the composite is a potential adsorbent for dye removal from aqueous solutions. Overall, the study results clearly suggest that an adsorbent synthesized from rice bran/SnO2/Fe3O4 magnetic particle composites provides encouraging adsorption capacity for practical applications for environmental prevention.

Cobalt Ion Removal from Aqueous Solutions by Coal Fly Ash

2013 ◽  
Vol 864-867 ◽  
pp. 1732-1740
Author(s):  
Xiao Xu ◽  
Qiang Yang ◽  
Chao Yang Wang
Keyword(s):  
Fly Ash ◽  
Aqueous Solutions ◽  
Removal Rate ◽  
Coal Fly Ash ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Cobalt Ions ◽  
Freundlich Isotherms ◽  
Ion Removal ◽  
Low Concentrations

Cobalt ions, which are commonly found in low concentrations in industrial wastewater, are toxic, biocumulative, and hard to degrade. Therefore, the removal of these heavy metal ions from wastewater is highly important. The removal of Co (II) from aqueous solutions using untreated and alkali-modified coal fly ash was studied. The results for untreated fly ash show that the pseudo-second-order kinetic equation better fits the observed adsorption progress. The Langmuir and Freundlich isotherms could describe the reaction efficiently, and the maximum adsorption capacity for Co (II) was 237 mg·g-1at 20°C. Pretreating the fly ash with an alkali solution decreases the adsorption capability, possibly by destroying the zeolite structure. When the ratio of the fly ash dose and Co (II) concentration is between 40 and 60, the removal rate of Co (II) at a concentration of 20 mg·L-1reaches 99.95%.

Chitosan-based Magnetic Composites - Efficient Adsorbents for Removal of Pb(II) and Cu(II) from Aqueous Mono and Bicomponent Solutions

2018 ◽  
Vol 69 (9) ◽  
pp. 2323-2330 ◽  
Author(s):  
Daniela C. Culita ◽  
Claudia Maria Simonescu ◽  
Rodica Elena Patescu ◽  
Nicolae Stanica
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Chemical Properties ◽  
Order Kinetic ◽  
Mass Ratio ◽  
Magnetic Adsorbent ◽  
Magnetic Composites ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Physical And Chemical

A series of three chitosan-based magnetic composites was prepared through a simple coprecipitation method. It was investigated the influence of mass ratio between chitosan and magnetite on the physical and chemical properties of the composites in order to establish the optimum conditions for obtaining a composite with good adsorption capacity for Pb(II) and Cu(II) from mono and bicomponent aqueous solutions. It was found that the microspheres prepared using mass ratio chitosan / magnetite 1.25/1, having a saturation magnetization of 15 emu g--1, are the best to be used as adsorbent for the metal ions. The influence of different parameters such as initial pH values, contact time, initial concentration of metal ions, on the adsorption of Pb(II) and Cu(II) onto the chitosan-based magnetic adsorbent was investigated in details. The adsorption process fits the pseudo-second-order kinetic model in both mono and bicomponent systems, and the maximum adsorption capacities calculated on the basis of the Langmuir model were 79.4 mg g--1 for Pb(II) and 48.5 mg g--1 for Cu(II) in monocomponent systems, while in bicomponent systems were 88.3 and 49.5 mg g--1, respectively. The results revealed that the as prepared chitosan-based magnetic adsorbent can be an effective and promising adsorbent for Pb(II) and Cu(II) from mono and bicomponent aqueous solutions.

Comparison of the fixation of several metal ions onto a low-cost biopolymer

2002 ◽  
Vol 2 (5-6) ◽  
pp. 217-224 ◽  
Author(s):  
Z. Reddad ◽  
C. Gérente ◽  
Y. Andrès ◽  
P. Le Cloirec
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Low Cost ◽  
Operating Conditions ◽  
Order Kinetic ◽  
Adsorption Mechanisms ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Beet Pulp ◽  
Removal Of Metal Ions

In the present work, sugar beet pulp, a common waste from the sugar refining industry, was studied in the removal of metal ions from aqueous solutions. The ability of this cheap biopolymer to sorb several metals namely Pb2+, Cu2+, Zn2+, Cd2+ and Ni2+ in aqueous solutions was investigated. The metal fixation capacities of the sorbent were determined according to operating conditions and the fixation mechanisms were identified. The biopolymer has shown high elimination rates and interesting metal fixation capacities. A pseudo-second-order kinetic model was tested to investigate the adsorption mechanisms. The kinetic parameters of the model were calculated and discussed. For 8 × 10-4 M initial metal concentration, the initial sorption rates (v0) ranged from 0.063 mmol.g-1.min-1 for Pb2+ to 0.275 mmol.g-1.min-1 for Ni2+ ions, with the order: Ni2+ > Cd2+ > Zn2+ > Cu2+ > Pb2+. The equilibrium data fitted well with the Langmuir model and showed the following affinity order of the material: Pb2+ > Cu2+ > Zn2+ > Cd2+ > Ni2+. Then, the kinetic and equilibrium parameters calculated qm and v0 were tentatively correlated to the properties of the metals. Finally, equilibrium experiments in multimetallic systems were performed to study the competition of the fixation of Pb2+, Zn2+ and Ni2+ cations. In all cases, the metal fixation onto the biopolymer was found to be favourable in multicomponent systems. Based on these results, it is demonstrated that this biosorbent represents a low-cost solution for the treatment of metal-polluted wastewaters.

Synthesis and Characterization of Chitosan templated Mesoporous Silica: Efficient use of Mesoporous Silica in the removal of Cu(II) from Aqueous Solutions

2016 ◽  
Vol 4 (2) ◽  
pp. 105-112
Author(s):  
Lalchhing puii ◽  
◽  
Seung-Mok Lee ◽  
Diwakar Tiwari ◽  
◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Aqueous Solutions ◽  
Background Electrolyte ◽  
Second Order ◽  
Order Kinetic ◽  
Sorption Data ◽  
Column Reactor ◽  
Wide Ph Range ◽  
Freundlich Adsorption Isotherm ◽  
Pseudo Second Order

A mesoporous silica was synthesized by annealing (3-Aminopropyl) triethoxysilane grafted chitosan at 800˚C. The mesoporous silica was characterized by the XRD (X-ray diffraction) analysis. The BET specific surface area and pore size of silica was found to be 178.42 m2/g and 4.13 nm. The mesoporous silica was then employed for the efficient remediation of aqueous solutions contaminated with Cu(II) under batch and column reactor operations. The mesoporous silica showed extremely high per cent removal of Cu(II) at wide pH range i.e., pH ~2.0 to 7.0. Relatively a fast uptake of Cu(II) was occurred and high percentage removal was obtained at initial concentrations studied from 1.0 to 15.0 mg/L. The equilibrium state sorption data were utilized for the Langmuir and Freundlich adsorption isotherm studies. Moreover, the effect of an increase in background electrolyte concentrations from 0.0001 to 0.1 mol/L NaNO3 was assessed for the uptake of Cu(II) by mesoporous silica. The equilibrium sorption was achieved within 240 min of contact and the kinetic data is best fitted to the pseudo-second-order and fractal like pseudo-second-order kinetic models. In addition, the mesoporous silica was used for dynamic studies under column reactor operations. The breakthrough curve was then used for the non-linear fitting of the Thomas equation and the loading capacity of the column for Cu(II) was estimated.

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