The component composition of planted pine wood cultivated in the boreal zone

2020 ◽  
Vol 35 (4) ◽  
pp. 685-693
Author(s):  
D. A. Danilov ◽  
A. V. Griazkin ◽  
V. A. Sokolova ◽  
I. V. Bacherikov

AbstractThe present study analyzes the composition of pine wood cultivated on artificial plantations in the Leningrad Oblast (Region). Comparing to pine wood from natural stands, a smaller heartwood zone along the height of the pine trunk and a lower content of resinous substances are noted. The content of cellulose and lignin in the heartwood and sapwood of pine is distributed differently along the trunk. The distribution of pentosans and water-soluble substances in the heartwood and sapwood along the trunk is associated with the lignin complex. The component composition of the studied pine wood from planted stands is quite uniform in its indicators if compared to the wood of older natural stands. Sulphate pulping of planted pine wood showed a higher yield of technical cellulose than the average yield from wood obtained at natural stands of the studied region.

2008 ◽  
Vol 53 (No. 9) ◽  
pp. 375-381 ◽  
Author(s):  
J. Balík ◽  
D. Pavlíková ◽  
V. Vaněk ◽  
M. Kulhánek ◽  
B. Kotková

Model experiments using rhizoboxes were carried out in order to evaluate the influence of different plants (wheat, rape) on the changes in water extractable contents of P, the pH/H2O value and the activity of acidic and alkaline phosphatase in soil of plant rhizosphere. For this experiment, a Cambisol with different long-term fertilizing systems was used: (i) control (with no fertilizer application), (ii) sewage sludge, and (iii) manure. A lower content of water-soluble P was observed in close vicinities of root surfaces (up to 2 mm) at all the studied variants. The control (non-treated) variant reflected a significantly lower content of water-soluble P in the rhizosphere compared to the fertilized ones. The activities of the acidic and alkaline phosphatases were significantly higher in the rhizosphere compared to the bulk soil (soil outside the rhizosphere). The long-term application of organic fertilizers significantly increased phosphatase activity; the activity of the acidic phosphatase was significantly higher in the rhizosphere of rape plants compared to wheat. The variant treated with manure exhibited an increased activity of both the acidic and alkaline phosphatases compared to the variant treated with sewage sludge. In the case of the variant treated long-term with sewage sludge, the portion of inorganic P to total soil P content proportionally increased compared to the manure-treated variant. Soil of the rape rhizosphere showed a trend of lower pH/H<sub>2</sub>O value of all variants, whereas the wheat rhizosphere showed an opposite pH tendency.


Author(s):  
Lyudmila V. Rudakova ◽  
Sabukhi I. Niftaliev ◽  
Ekaterina S. Natarova

X-ray and laser diffraction methods were used to determine basic physical and chemical properties of conversion calcium carbonate. It was found that for obtaining standard product for use as a filler, it is necessary to regrind it. The results of dispersion changes in conversion chalk (chalk stone) were expressed in terms of median (D50), maximum (D98) and minimum (D10) particle size. It was established that during the grinding process a transition occurs from the initial odiomodal distribution to the bimodal distribution, which is characterized by a sufficiently wide range of the sizes of the particles of the crushed material. The optimum parameters of grinding were determined. With the help of SEM method, used before and after grinding of conversion calcium carbonate, it was established that the particles of primary material are represented by polycrystalline dense aggregates of spherical shape, due to mass crystallization of calcium carbonate at the condition of high supersaturation according to polynuclear growth mechanism. The component composition of water-soluble impurities was quantitatively estimated on the basis of the determination of the content of nitrate N-NO3- and ammonium N-NH4+ forms of nitrogen in various forms of presence-total, bound, water-soluble, and additional determination of the Ca2+ content of calcium ions in aqueous extract. It has been experimentally established that preliminary heat treatment of conversion calcium carbonate allows to significantly reduce the total content of water-soluble substances in the ground product by more than 5 times: at a temperature of 400 ° C, the degree of removal by NH4+ and NO3- ions is ~ 40-50%, and at 500 ° C - ~ 60% for NO3- and ~ 90% for NH4+. The estimation of the possibility of using the obtained product as a filler of polymer composite materials was done comparing the main parameters (CIELab  (W and L) color characteristics, bulk density, dispersed composition, specific surface, pH of aqueous extract) with known finely ground natural chalk and microcalcite. Forcitation:Rudakova L.V., Niftaliev S.I., Natarova E.S. Conversion calcium carbonate as filler of thermoplastics. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 4. P. 100-107.


2021 ◽  
Vol 1 (5) ◽  
pp. 86-96
Author(s):  
A. A. Savina ◽  
◽  
O. A. Voronina ◽  
L. P. Ignatieva ◽  
N. V. Bogolyubova ◽  
...  

The aim of the work was to study the component composition of milk of black-and-white cows in the winter-stall period and its main biochemical parameters. In this work, the total amount of water-soluble antioxidants (TAWSA) was assessed by the amperometric method (using "TsvetYauza 01-AA" device) and the average values of the milk component composition for four groups of cows, which were formed by the number of somatic cells (NSC) found in their milk. Milk of mastitis cows causes food poisoning that is why 1 groups were formed according to the NSC values: 200) less than 2 thousand units/ml, 200) from 499 to 3 thousand units/ml, 500) from 999 to 4 thousand units/ml and 1000) more than XNUMX thousand units/ml for milk samples of black-and-white cows of the Moscow region, which was used as raw material. The TAWSA values for 33 milk samples from cows in group 1 ranged from 6,80 to 27,91 mg/g (mean value 15,95±3,70 mg/g). The correlations between TAWSA and the following parameters of milk: mass fraction of fat (MFF) – 0,305; protein mass fraction true (PMF1) and total (PMF2) – 0,197 and 0,210; lactose – 0,156; dry fat-free milk residue (FFMR) – 0,276; total dry matter (TDM) – 0,399; freezing point (FP) – 0,112; pH – 0,114; the number of somatic cells (NSC) – (–0,052) are found. The TAWSA values for 15 milk samples from cows in group 2 ranged from 10,46 to 18,99 mg/g (average value 14,45±3,50 mg/g) are found. The correlations between TAWSA and the following parameters of milk: MFF – 0,332; PMF1 and PMF2 – 0,296 and 0,303; lactose – (–0,308); FFMR – 0,159; TDM – 0,391; FP – 0,226; pH – (–0,211); NSC – 0,193. The TAWSA values for 13 milk samples of cows in group 3 ranged from 10,46 to 18,99 mg/g (average value 16,04±3,60 mg/g) are found. The correlations between TAWSA and the following parameters of milk: MFF – (–0,352); PMF1 and PMF2 – (– 0,411) and (–0,401); lactose – (–0,166); FFMR – (–0,462); TDM – (–0,504); FP – (–0,766); pH – (–0,047); NSC – (–0,698). The TAWSA values for 12 milk samples from cows in group 4 ranged from 5,80 mg/g to 20,30 mg/g (average value 14,58±3,50 mg/g) are found. The correlations between TAWSA and the following parameters of milk: MFF – 0,159; PMF1 and PMF2 – 0,046 and 0,077; lactose – (–0,317); FFMR – (–0,237); TDM – 0,058; FP – (–0,036); pH – (–0,477); NSC – (–0,072) are found. These data obtained are of great importance both in assessing the physiological-biochemical status and the state of the antioxidant defense system of the cows' organism.


2019 ◽  
Vol 108 ◽  
pp. 02004 ◽  
Author(s):  
Mariusz Wądrzyk ◽  
Magdalena Berdel ◽  
Rafał Janus ◽  
Derk Willem Frederik Brilman

Hydrothermal liquefaction processes (HTL) comprise complex chemical and physical transformations of biomass under the conditions of high temperature and pressure, commonly near- or supercritical water. During this processes, the components of biomass undergo various complicated chemical reactions strongly influenced by process variables. In this study, lignocellulosic biomass (pine wood) has been converted via liquefaction in subcritical water to bio-oil, water-soluble organics, gas and solid products. The process parameters (i.e. temperature and time processing) affecting the bio-oil yields and composition were comparatively studied. The chemical composition of resulting bio-oils was analyzed by means of mid-infrared spectroscopy, gel permeation chromatography, gas chromatography coupled to mass spectrometry and elemental analysis. The maximum bio-oil yield (38.35 wt.%) was obtained at 350 ºC for 10 min. The HHV of the obtained resultant bio-oils varied in the range of 24-28 MJ kg-1. Bio-oils from HTL of pine wood are complex mixtures of aromatic and cyclic compounds with numerous hydroxyl and carboxyl functional groups. The experiments exhibited that the increase in the temperature results in adeeper decomposition of biomass manifested by the higher yield of bio-oil and its gradual deoxygenation. In fact, the obtained oil products are promising, valuable intermediates, which may act as a source of many valueadded chemicals.


2006 ◽  
Vol 70 (1) ◽  
pp. 203-210 ◽  
Author(s):  
Hiroaki KAJI ◽  
Akihiro TAI ◽  
Kazufumi MATSUSHITA ◽  
Hiroshi KANZAKI ◽  
Itaru YAMAMOTO

10.12737/4520 ◽  
2014 ◽  
Vol 4 (2) ◽  
pp. 155-158
Author(s):  
Снегирева ◽  
Svetlana Snegireva ◽  
Курьянова ◽  
Tatyana Kuryanova ◽  
Платонов ◽  
...  

Wood is a product of plant origin having complex element and component composition. Under the influence of temperature in the presence of moisture lignocarbohydrate complex decomposes and extraction of water soluble substances takes place. Aqueous distillate contains a large number of different chemicals, the most dangerous of which are furfural and formaldehyde. The intensity of the process of extraction in the wood depends on the temperature. The formation of these substances is observed even at low temperatures around 60-70 º C and long duration of exposure, which is characteristic of conditions during chamber wood drying.


2019 ◽  
pp. 85-94 ◽  
Author(s):  
Надежда (Nadezhda) Алексеевна (Alekseevna) Мамлеева (Mamleeva) ◽  
Андрей (Andrey) Николаевич (Nikolaevich) Харланов (Kharlanov) ◽  
Дмитрий (Dmitriy) Германович (Germanovich) Чухчин (Chukhchin) ◽  
Наталья (Natal'ya) Григорьевна (Grigor'evna) Базарнова (Bazarnova) ◽  
Валерий (Valeriy) Васильевич (Vasil'evich) Лунин (Lunin)

The pine wood degradation under ozonation was studied. It was determined the contents of lignin (LG) and cellulose (CL) in cellulose-containing material (CM) obtained from the ozonized wood. The degree of polymerization (DP) of cellulose from CM was determined. Samples of CM were investigated using IR diffuse reflectance (DRIFT) spectra and XRD analysis. HPLC analysis of water-soluble LG ozonolysis products was conducted. Ozonation results in 40–42% delignification degree of wood. Aromatics destruction is confirmed by DRIFT spectra. The intensity of stretching band at 1736 cm-1 of unconjugated C=O groups in LG or hemicelluloses markedly increases. A stoichiometric ratio of absorbed ozone and an amount of destructed guaiacylpropane units as well as a composition of water-soluble products show that ozonolysis is a primary mechanism of aromatics degradation in wood. The data on XRD analysis, the amounts of removed LG and the change of cellulose DP allow conclusion that the wood ozonation is accompanied by a destruction of hemicelluloses and amorphous cellulose in the wood. It is shown that the specific ozone uptake £1.5 mmol O3/g matches the domination of the wood delignification with the lowest degradation of cellulose fibers and acceptable efficiency in terms of the ozonation process.


Author(s):  
Э.И. Евстигнеев

Разработана схема анализа компонентного состава лиственницы, предусматривающая определение таких компонентов, как полисахариды, целлюлоза, нецеллюлозные полисахариды, лигнин, экстрактивные вещества и зола. В отличие от известных схем анализа химического состава древесины, она содержит новую стадию, а именно определение общего содержания полисахаридов фотоколориметрическим методом. Обычно для этой цели используют определение холоцеллюлозы, однако известные методы не позволяют выделить все полисахариды, поскольку в процессе выделения часть из них неизбежно утрачивается. Зная общее содержание полисахаридов, можно определить содержание нецеллюлозных полисахаридов. Такой подход имеет явное преимущество, по сравнению с традиционно используемым определением отдельно гемицеллюлоз и отдельно водорастворимых полисахаридов, так как в этом случае происходит потеря части полисахаридов. Предложенная схема дает возможность достаточно полно охарактеризовать компонентный состав древесины лиственницы, не прибегая к использованию специального оборудования. Разработанный метод определения арабиногалактана обладает высокой селективностью к определяемому компоненту древесины в присутствии большого количества примесей, в связи с чем он может быть рекомендован для количественного определения арабиногалактана как в водных растворах, так и в древесине. The scheme of the analysis of component structure of a larch providing determination of such components as polysaccharides, cellulose, not cellulose polysaccharides, lignin, extractive substances and ashes is developed. Unlike the known schemes of the analysis of the chemical composition of wood, it contains a new stage, namely determination of the general content of polysaccharides by a photocolorimetric method. Usually, for this purpose use definition of a holocellulose, however the known methods do not allow to emit all polysaccharides as in the course of allocation part of them is inevitably lost. Knowing the general content of polysaccharides, it is possible to determine the content of not cellulose polysaccharides. Such approach has clear advantage in comparison with traditionally used determination separately of hemicelluloses and separately water-soluble polysaccharides since in this case there is a loss of a part of polysaccharides. The scheme offered in work, gives the chance rather fully to characterize component composition of wood of a larch, without resorting to use of the special equipment. The developed method of an arabinogalactan determination has high selectivity to the defined wood component in the presence of a large amount of impurity in this connection it can be recommended for quantitative definition of an arabinogalactan both in water solutions, and in wood.


Author(s):  
A. V. Kryzhko ◽  
U. M. Budzhurova ◽  
E. D. Ametova ◽  
I. A. Novikov ◽  
E. E. Soboleva ◽  
...  

Abstract: This article aims to study the influence of the culture of the Bacillus thuringiensis var. thuringiensis 888 on the quality of the vegetative mass of Origanum vulgare in terms of the number of antioxidants and flavonoids, yield and composition of the essential oil. The research material included a liquid spore culture of the B. thuringiensis 888 strain, samples of oregano: sample no. g-4, containing 52.0% carvacrol in essential oil; No. 2 containing 59.85% α-terpineol; No. 1 with a predominant content of germacrene D (21.5%) and β- caryophyllene (19.4%). Soluble carbohydrates in the plants were determined using M.S. Dubois’s method, flavonoids – spectrophotometrically at 420 nm following R.A. Bubenchikov’s method. The total content of antioxidants was determined using the reduction of iron(III) chloride to iron(II) chloride. The essential oil content of Origanum vulgare was determined by using hydrodistillation following A.S. Ginsberg. Gas chromatography was used to determine component composition of the essential oil. The results show that treating the O. vulgare samples with the spore culture of B. thuringiensis 888 strain culture does not significantly affect the accumulation of terpenoid quinones, tochromanols and water-soluble antioxidants in leaves. It has been shown that treating oregano with an ordinary liquid spore culture of the B. thuringiensis 888 strain promotes the formation of a persistent tendency towards the accumulation of reducing sugars in the vegetative mass of plants — up to 30.8% compared to the control. Treating plants with a culture of B. Thuringiensis 888 strain promoted an increase in the essential oil content in O. vulgare plants of the sample no. 1 by 2.4 times, as compared to the control and did not significantly affect the essential oil content of the samples no. 2 and no. g-4. The sample no. g-4 was the most resistant to treatment with entomopathogenic bacteria, and the content of linalool and caryophyllene oxide in essential oils decreased by 44.6 and 37.1%, respectively, and linalyl acetate by 4.3 times compared with the control, as well as the accumulation of α-terpineol by 86.1%.


Sign in / Sign up

Export Citation Format

Share Document