scholarly journals Characterization of poly-hydroxybutyrate/luffa fibers composite material

BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 7159-7177
Author(s):  
Andrea Melina Avecilla-Ramírez ◽  
Ma. del Rocío López-Cuellar ◽  
Berenice Vergara-Porras ◽  
Adriana I. Rodríguez-Hernández ◽  
Edgar Vázquez-Núñez

Luffa fibers were evaluated as a reinforcement material in poly-hydroxy-butyrate matrix composites. The treatments consisted of varying the incorporation percentage of mercerized and non-mercerized luffa fibers in a poly-hydroxybutyrate (PHB) matrix (5%, 10%, and 20% w/v). Composites made with PHB and reinforced with luffa fibers (treated and non-treated) were mechanically evaluated (tensile strength, Young’s modulus, and percentage of elongation at break), the surface morphology was described by using scanning electronic microscopy, and the degradability behavior of composites was obtained. According to the results, mechanical properties decreased when the percentage of fibers increased and no significant effects were observed when compared with mercerized fiber composites. Degradability tests demonstrated that the weight loss increased with increased fiber content in composites, independent of the applied pretreatments. Microscopy images exhibited that mercerization improved the fiber incorporation into the polymeric matrix, diminishing the “pull out” effect; the above-mentioned result was supported by using the Fourier-transform infrared spectroscopy technique, observing the reduction of lignin and hemicellulose peaks in mercerized fibers. Based on the composite mechanical performance and degradability behavior, it was concluded that this material could be used in the packaging sector as biodegradable secondary packaging material.

Author(s):  
Faris M. AL-Oqla

The available potential plant waste could be worthy material to strengthen polymers to make sustainable products and structural components. Therefore, modeling the natural fiber polymeric-based composites is currently required to reveal the mechanical performance of such polymeric green composites for various green products. This work numerically investigates the effect of various fiber types, fiber loading, and reinforcement conditions with different polymer matrices towards predicting the mechanical performance of such natural fiber composites. Cantilever beam and compression schemes were considered as two different mechanical loading conditions for structural applications of such composite materials. Finite element analysis was conducted to modeling the natural fiber composite materials. The interaction between the fibers and the matrices was considered as an interfacial friction force and was determined from experimental work by the pull out technique for each polymer and fiber type. Both polypropylene and polyethylene were considered as composite matrices. Olive and lemon leaf fibers were considered as reinforcements. Results have revealed that the deflection resistance of the natural fiber composites in cantilever beam was enhanced for several reinforcement conditions. The fiber reinforcement was capable of enhancing the mechanical performance of the polymers and was the best in case of 20 wt.% polypropylene/lemon composites due to better stress transfer within the composite. However, the 40 wt.% case was the worst in enhancing the mechanical performance in both cantilever beam and compression cases. The 30 wt.% of polyethylene/olive fiber was the best in reducing the deflection of the cantilever beam case. The prediction of mechanical performance of natural fiber composites via proper numerical analysis would enhance the process of selecting the appropriate polymer and fiber types. It can contribute finding the proper reinforcement conditions to enhance the mechanical performance of the natural fiber composites to expand their reliable implementations in more industrial applications.


2017 ◽  
Vol 26 (5) ◽  
pp. 096369351702600 ◽  
Author(s):  
Wenjing Xia ◽  
Nianqing Zhu ◽  
Zhongbin Ni ◽  
Mingqing Chen

Biodegradable composites from poly (butylene succinate-co-butylene adipate) (PBSA) and Taihu Lake (Wuxi, China) blue algae were prepared by melt blending. The property and structure of biocomposites were investigated. By adding extra amount of water to blue algae, the formulated blue algae acted as a plastic in the composites during blending, and exhibited a reinforcing effect on the PBSA matrix. With increasing blue algae content, the thermal stability of the composites decreased; the tensile strength at break and elongation at break of the composites reduced, but the Young's modulus of the composites increased. However, the composite with 30% blue algae loading still exhibited good mechanical performance (tensile strength at break of 21.3 MPa, elongation at break of 180%). The fabrication of value-added PBSA/algae composites appeared as an effective approach to reduce the secondary environmental pollution of Taihu blue algae.


2017 ◽  
Vol 7 (1.1) ◽  
pp. 78
Author(s):  
C. Thiruvasagam ◽  
S. Prabagaran ◽  
P. Suresh

The research paper involves fiber composites form a special category materials that are contributing to present swaping of manufactured  hybrid  which finds traditional and non traditional applications. The study explains which are accentuates and optimizing for the recently recognized snake grass standard materials. In this article, the prospecting performance characterization of SG fiber is selected and contrasted as per the ASTM standard. This study additionally manages the examination apply different phenomena of this stages in Jute and snake as fortifications utilized index ended a try. Experiments have been conducted on normal Filaments, snake grass, Glass Fiber and Jute to analyse their Mechanical properties. The common strands are orchestrated in the flat and vertical heading as transferred quality on all sides. Microstructural analysis of these hybrid composite is observed using Scanning  Electron Microscope that reveals bonding and Filament breaksge, Voids and Fiber decover which are further investigated.


Author(s):  
A. G. Evans

In composite systems, the mechanical response of interfaces to the approach of cracks that initially form either in the matrix or in the fiber dominates the mechanical performance. In particular, in brittle matrix composites, the interface must have a sufficiently low fracture resistance compared with that of both the fiber and matrix that the crack diverts into the interface and debonds the fiber, Thereafter, the debonded fiber must be able to slide against the matrix with a low friction stress in order to inhibit fiber failure and thus enhance pull-out. These processes are schematically illustrated in Fig. 1. Mechanics investigations have established requirements concerning debonding and sliding that must be satisfied in order to achieve good composite properties. At the simplest level, these studies reveal that the fracture energy of the interface should be less than about one-third that of either the fiber or the matrix.


2011 ◽  
Vol 71-78 ◽  
pp. 1154-1157 ◽  
Author(s):  
Zhi Fei Liao ◽  
Guo Lin Song ◽  
Feng Shi ◽  
Zhan Song Yin ◽  
You Yang ◽  
...  

The PLA/Rice straw fiber composites with various content ratios were prepared by using an internal mixer and a flatten press. The thermal properties, interface effect and mechanical performance of as-prepared PLA/Rice straw fiber composites were studied by mechanical performance measurement, TG, DSC and SEM technique. It was found that increasing the content of rice straw fiber leads to the decrease of the melting temperature while the improvement of the crystallinity of these composites. Introducing the rice straw fibers into PLA matrix does not result in any enhancement of mechanical property. However, the tensile strength of the composite increases as the content of rice straw fiber increases from 10% to 30%. The interface effect between fibers and PLA was obviously observed by SEM photo. It was thought such an issue could be improved by the addition of appropriate coupling agents into the composites.


2020 ◽  
Vol 35 (2) ◽  
pp. 279-287
Author(s):  
Moe Fuchise-Fukuoka ◽  
Masatoshi Oishi ◽  
Shisei Goto ◽  
Akira Isogai

AbstractIn this study, CaCO3 nanoparticle/pulp fiber composites were prepared by formation of ultrafine bubbles of CO2 gas in aqueous Ca(OH)2 solution containing beaten or unbeaten pulp fibers. Scanning electron microscopy images of the fiber/CaCO3 composites showed that primary CaCO3 nanoparticles with average diameters of 50–80 nm densely formed on the pulp fiber surfaces. The average sizes and morphologies of the precipitated CaCO3 nanoparticles can be controlled by controlling the CO2 flow rate into the pulp slurry. From dynamic drainage analysis of the CaCO3/pulp slurries with high shear force, retention of the CaCO3 nanoparticles on the pulp fiber mats was ∼10 % higher for the slurry formed by the ultrafine bubble method than for that formed by mixing precipitated CaCO3 and pulp fiber. Therefore, precipitated CaCO3 nanoparticles stably formed on the pulp fiber surfaces in the slurry by the ultrafine bubble method. Compared with reference handsheets, handsheets prepared with the CaCO3 nanoparticle/pulp fiber composites had higher CaCO3 contents and had consequently higher specific surface areas and surface smoothness values. In contrast, the tensile strength and elongation at break decreased because the sheet density decreased with increasing CaCO3 content in the handsheets.


2021 ◽  
Author(s):  
Luigi Sanguigno ◽  
Marcello Antonio Lepore ◽  
Angelo Rosario Maligno

The mechanical and morphological properties of the unidirectional metal matrix composite (MMC) in titanium alloy reinforced with continuous silicon carbide (SiC) fibres are investigated. The lay-up manufacturing process known as the Foil / Fibre (FF) lay-up was compared with the matrix-coated-fibre (CF) method which promises a better final shape of the reinforcing fibre net. Tensile tests were performed to measure mechanical performance of the manufactured MMCs both longitudinally and transversely respect to the direction of SiC fibres. Elastic behaviour of the investigated MMCs was assumed orthotropic and related to mechanical properties and spatial distribution of the MMC constituents: SiC fibres and Titanium (Ti) matrix. This was achieved using micromechanical modelling based on Finite Element (FE) calculations. FE micromechanical modelling was carried out on the Representative Elementary Volume (REV) of the MMC microstructure resolved by non-destructive analysis such as X-Ray tomography. The analysis carried out highlighted and justified mechanical performance difference between composite laminates containing the same amount of SiC reinforcement fibres for unit of volume but made following different manufacturing routes. To compute overall orthotropic behaviour of the MMC laminate, each constituent was assumed as an elastic isotropic heterogeneity during the averaging. This simplify assumption was validated by comparison with experimental data during the mechanical characterization of the investigated MMC composites.


Author(s):  
Jun Shintake ◽  
Koya Matsuno ◽  
Kazumasa Baba ◽  
Hiromitsu Takeuchi

Abstract This paper investigates the characteristics of sliding ring materials (SRMs), which are promising elastomeric materials for dielectric elastomer actuators (DEAs). Two different types of SRMs with Young's modulus of 0.8 MPa and 3.3 MPa, respectively, are prepared, and their material and mechanical properties and electro-mechanical performances at electric fields of up to 30 V/um are characterized. For comparison, the same tests are also performed on several commercially available elastomers: Elastosil 2030, Ecoflex 00-30, CF19-2186, and VHB 4905. The results reveal that SRMs demonstrate negligible Mullins effect and hysteresis, while their dielectric strength (62.4‒112.4 V/µm) and viscoelasticity (tan⁡δ 0.07‒0.24 at 10 Hz) are comparable or even superior to those of other elastomers. In addition, elongation at break is found to be 163.8‒172.1%. SRMs exhibit excellent electro-mechanical performance; for instance, one of the two types has an actuation force 293.2 mN at 24.9 V/µm and a strain of 5.2% at 22.3 V/µm. These values are the largest or larger than most of the tested elastomers. The high performance of SRMs results from their dielectric constant, which ranges from 10.3‒13.4, leading to an electro-mechanical sensitivity of up to 15.3 MPa-1. These results illustrate SRMs as attractive material options for DEAs.


Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1471 ◽  
Author(s):  
Pingping Xu ◽  
Yuxiang Yu ◽  
Miaomiao Chang ◽  
Jianmin Chang

Introducing bio-oil into phenolic foam (PF) can effectively improve the toughness of PF, but its flame retardant performance will be adversely affected and show a decrease. To offset the decrease in flame retardant performance, montmorillonite (MMT) can be added as a promising alternative to enhance the flame resistance of foams. The present work reported the effects of MMT on the chemical structure, morphological property, mechanical performance, flame resistance, and thermal stability of bio-oil phenolic foam (BPF). The Fourier transform infrared spectroscopy (FT-IR) result showed that the –OH group peaks shifted to a lower frequency after adding MMT, indicating strong hydrogen bonding between MMT and bio-oil phenolic resin (BPR) molecular chains. Additionally, when a small content of MMT (2–4 wt %) was added in the foamed composites, the microcellular structures of bio-oil phenolic foam modified by MMT (MBPFs) were more uniform and compact than that of BPF. As a result, the best performance of MBPF was obtained with the addition of 4 wt % MMT, where compressive strength and limited oxygen index (LOI) increased by 31.0% and 33.2%, respectively, and the pulverization ratio decreased by 40.6% in comparison to BPF. These tests proved that MMT can blend well with bio-oil to effectively improve the flame resistance of PF while enhancing toughness.


Marine Drugs ◽  
2021 ◽  
Vol 19 (9) ◽  
pp. 486
Author(s):  
Yuan Zhou ◽  
Fu-Quan Chen ◽  
Si Chen ◽  
Qiong Xiao ◽  
Hui-Fen Weng ◽  
...  

In this work, the physicochemical properties of maleic anhydride (MAH)-modified κ-carrageenan (κCar) (MC) were characterized and compared with those of native κ-carrageenan (NC). The Fourier transform infrared spectrum of MC exhibited that κCar was successfully modified. Thermogravimetric analysis indicated that the thermal stability of MC was decreased. When the degree of substitution was 0.032, MC exhibited a low gel strength (759 g/cm2), gelling temperature (33.3 °C), and dehydration rate (60.3%). Given the excellent film-forming ability of κCar, MC films were then prepared and were found to have better mechanical and barrier properties (UV and water) than NC films. With regard to optical properties, MC films could completely absorb UV light in the range of 200–236 nm. The water contact angle of MC films was higher than that of NC films. Moreover, the elongation at break increased from 26.9% to 163%. These physicochemical property changes imply that MC can be employed in polysaccharide-based films.


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