scholarly journals Evaluating effects of activated sludge and nanochitosan on physical and strength properties of recycled pulp

BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 4237-4251
Author(s):  
Naghmeh Amani Bishehgah ◽  
Ramin Vaysi ◽  
Majid Kiaei ◽  
Abdollah Najafi ◽  
Seyed Eshagh Ebadi
Keyword(s):  
Acetic Acid ◽  
Activated Sludge ◽  
Water Absorption ◽  
Paper Mill ◽  
Strength Properties ◽  
Recycled Paper ◽  
Burst Strength ◽  
Recycled Pulp ◽  
Increased Strength ◽  
Shed Light

The present research aims to shed light on the effect of activated sludge (from a paper mill) and nanochitosan on the physical and strength properties of recycled pulp. Firstly, activated sludge was treated with 3% acetic acid for 30 min and then placed in a beaker for 90 min at 100 °C. Then, the ingredients were mixed and refined with recycled newsprint pulp in different proportions (0, 5, 10, and 15%). Finally, 2% nanochitosan was optionally added. Test specimens were prepared according to TAPPI standards with a basis weight of 120 g/m2, and their physical (water absorption) and strength (tear strength, tensile strength, burst strength, and ring crush test) properties were measured and compared. The results showed that with the increase of untreated activated sludge in recycled paper pulp, the indicators of tear resistance, ring crush test, and burst strength decreased and water absorption increased. Strength properties increased and water adsorption decreased when adding activated sludge treated with 3% acetic acid. Through the addition of nanochitosan to activated sludge treated with acetic acid, a significant increase in strength properties and a decrease in water absorption were observed.

scholarly journals Investigation of the Effect of Using Activated Sludge Treated with Acetic Acid on Physical and Strength Properties of Recycled Pulp

2021 ◽  
Vol 72 (3) ◽  
pp. 299-307
Author(s):  
Naghmeh Amani ◽  
Ramin Vaysi ◽  
Abdollah Najafi ◽  
Seyed Eshagh Ebadi
Keyword(s):  
Tensile Strength ◽  
Acetic Acid ◽  
Activated Sludge ◽  
Water Absorption ◽  
Paper Mill ◽  
Strength Properties ◽  
Paper Pulp ◽  
Tear Strength ◽  
Burst Strength ◽  
Mechanical Tensile

This study aimed to scrutinize chemical treatment of Mazandaran Wood and Paper mill activated sludge with 3 % acetic acid for the manufacture of environmentally eco-friendly bio composite. In this study, the paper pulp required was obtained from the waste newsprint paper. The activated sludge was treated in a beaker for 3 min in 3 % acetic acid and then in a water bath at 75 and 100 °C for 45 and 90 min. After that, the treated activated sludge was mixed and refi ned with waste newsprint paper pulp at ratios of 0, 5, 10, 15 and 20 %. The test specimens were prepared according to TAPPI standard and the physical properties (water absorption and porosity) and mechanical (tensile strength, tear strength, ring crush test, burst strength and folding strength) were measured. The results showed that the activated sludge treatment caused the increase in tear strength, ring crush test, burst strength and porosity as well as the decrease in water absorption, tensile strength and folding strength. FT-IR spectrum of the treated samples showed that the treatment with acetic acid strengthened and activated the functional groups on the surface of activated sludge fi bers. The activated sludge added at a level of 5 % at 100 °C for 90 min as well as at a level of 20 % at 75 °C for 45 min was more suitable than other treatments.

scholarly journals Reinforcement potential of modified nanofibrillated cellulose in recycled paper production

BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 911-941
Author(s):  
Ayhan Tozluoğlu ◽  
Hakan Fidan ◽  
Ahmet Tutuş ◽  
Recai Arslan ◽  
Selva Sertkaya ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Physical Properties ◽  
Cellulose Nanofibrils ◽  
Nanofibrillated Cellulose ◽  
Strength Properties ◽  
Process Conditions ◽  
Recycled Paper ◽  
Drainage Rate ◽  
Recycled Pulp ◽  
Mechanical And Physical Properties

The influence of nanofibrillated cellulose (NFC) was investigated as a reinforcing agent to improve strength properties of papersheets fabricated from recycled pulp fibers of mixtures of old newspapers, old magazines, and old corrugated cardboards. To determine the effects of the NFC on the mechanical and physical properties of the recycled pulp papers, cellulose nanofibrils (NFC) were isolated from wheat straw, pretreated chemically and enzymatically (NFC-OX), and then added to the bulk suspensions of papermaking pulp slurries at various percentages. The electrokinetic and drainage properties of the pulps and the mechanical and physical properties of the papersheets were analyzed and compared. As expected, the addition of NFC/NFC-OX significantly increased the strength properties of papers. Papers containing 4% of NFC-OX (periodate pretreated) presented higher increases in tensile index (43%) and burst index (59.3%) than other papers. However, a high addition of NFC/NFC-OX increased the water retention, which is undesirable for papermaking. Hence, with optimum selection of NFC/NFC-OX and process conditions, higher mechanical properties could be acquired without increasing drainage rate. Compared to the other pretreated NFC/NFC-OX types, sodium-periodate-oxidized NFC-OX samples significantly increased the mechanical properties of the papers fabricated from the recycled pulps.

scholarly journals Sludge Fiber Waste and Kraft Lignin Powder as Fillers in Polylactic Acid Biocomposites: Physical, Mechanical, and Thermal Properties

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 672
Author(s):  
Thiago Souza da Rosa ◽  
Rosilani Trianoski ◽  
Franck Michaud ◽  
Fábio Yamashita ◽  
Setsuo Iwakiri
Keyword(s):  
Water Absorption ◽  
Polylactic Acid ◽  
Paper Mill ◽  
Tensile Tests ◽  
Strength Properties ◽  
Kraft Lignin ◽  
Mechanical And Thermal Properties ◽  
Scanning Electron Micrographs ◽  
Alternative Materials ◽  
Fibre Waste

In this investigation, sludge fibre waste (SFW) and Kraft lignin powder (KLP) are introduced into polylactic acid (PLA) matrix biocomposites. These alternative materials allow for both the reuse of fibre waste from paper mill sludge and a reduction in the amount of high-cost biopolymer used in the same volume. Proportions from 10 to 40 wt.% of SFW with the addition of 2.5% and 5% of KLP are incorporated in PLA by extrusion and injection moulding. The thermogravimetric properties, water absorption, tensile and flexural properties, and morphology of the fabricated biocomposites were investigated. According to the results, KLP contributes to thermically stabilising the loss resulting from the incorporation of SFW. Flexural and tensile tests reveal a more pronounced decrease in strength with an SFW ratio above 10%. The modulus of elasticity increases significantly with an SFW ratio above 20%. The strength properties are stabilised with the addition of 5% KLP. The addition of KLP presents a tendency to reduce water absorption obtained by the incorporation of SFW into biocomposites. Scanning electron micrographs evidence that KLP improves the interfacial adhesion by reducing the voids between fibres and PLA.

Resource efficiency in deinked pulp production: a review

TAPPI Journal ◽  
2014 ◽  
Vol 13 (11) ◽  
pp. 37-43 ◽  
Author(s):  
LIISA KOTANEN ◽  
MIKA KÖRKKÖ ◽  
ARI ÄMMÄLÄ ◽  
JOUKO NIINIMÄKI
Keyword(s):  
Waste Disposal ◽  
Resource Efficiency ◽  
Raw Material ◽  
Ecological Strategy ◽  
Recycled Paper ◽  
Paper Production ◽  
Recycled Pulp ◽  
Current State ◽  
The Cost ◽  
Pulp Production

The use of recovered paper as a raw material for paper production is by far the most economical and ecological strategy for the disposal of waste paper. However, paper production from recovered paper furnish generates a great amount of residues, and the higher the demand requirements for the end product, the higher the amount of rejected material. The reason for this is that the selectivity of the deinking process is limited; therefore, some valuable components are also lost in reject streams. The rejection of usable components affects the economics of recycled paper production. As the cost of waste disposal continues to increase, this issue is becoming more and more severe. This paper summarizes the current state of the resource efficiency in recycled pulp production and provides information on the volumes of rejected streams and the usable material within them. Various means to use these reject streams are also discussed, including the main findings of a recent thesis by the main author. This review summarizes current internal and external use of reject streams generated in the deinking operations.

Chemical, anatomical, and technology aspects of Eucalyptus benthamii and Eucalyptus dunii for use in an integrated pulp and paper mill

TAPPI Journal ◽  
2015 ◽  
Vol 14 (2) ◽  
pp. 73-81 ◽  
Author(s):  
GISELY SAMISTRARO ◽  
PETER W. HART ◽  
JORGE LUIZ COLODETTE ◽  
RICARDO PAIM
Keyword(s):  
Energy Levels ◽  
Black Liquor ◽  
Basic Density ◽  
Paper Mill ◽  
Frost Tolerance ◽  
Strength Properties ◽  
Kappa Number ◽  
Pulp Yield ◽  
Chemical Compositions ◽  
Physical Strength

Eucalyptus dunii has been commercially used in southern Brazil because of its relatively good frost tolerance and adequate productivity in the winter months. More recently, interest has grown in cultivating Eucalyptus benthamii Maiden & Cambage, which presents even superior frost tolerance compared to E. dunii and is highly productive as well. The quality of E. benthamii for pulp production is not yet proven. Thus, the chemical, anatomical, and technological aspects of pulp made from E. benthamii were compared with those of E. dunii for unbleached paper production. Samples of E. benthamii chips were obtained and analyzed for their basic density, chemical composition, higher heating value, trace elemental analysis, and chip size distribution. The chips were kraft cooked using conditions that produced a 74 ± 6 kappa number. The pulps were characterized for kappa number, yield, viscosity, and morphologic characteristics (e.g., length, wall thickness, and coarseness). Black liquor was analyzed for total solids, organics, inorganics, sodium sulfide, sodium hydroxide, and sodium carbonate. Brownstocks were beaten at five different energy levels in a Valley beater, and the physical strength properties of 120 g/m² handsheets were measured to develop a beater curve. The results of this study showed differences in delignification between the two woods and lower pulp yield for E. benthamii , which are related to their chemical compositions and basic densities. The E. benthamii studied in this work exhibited higher amounts of lignin and extractives, lower carbohydrate content, and lower basic density. However, cooking a blend of the two woods afforded good results in pulping and in physical pulp properties.

Mutagenicity in Pulp and Paper Mill Effluents and in Recipient

1988 ◽  
Vol 20 (2) ◽  
pp. 143-152 ◽  
Author(s):  
A. Langi ◽  
M. Priha
Keyword(s):  
Activated Sludge ◽  
Mutagenic Activity ◽  
Chinese Hamster Ovary Cells ◽  
Chinese Hamster ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Pulp And Paper Mill ◽  
Sludge Treatment ◽  
Paper Mill Effluents ◽  
Kraft Mill

The mutagenic properties of pulp and paper mill effluents were studied in three mills: bleached kraft mill with aerated lagoon treatment (Mill 1), bleached kraft mill with activated sludge treatment (Mill 2) and mechanical pulp/paper mill (Mill 3). Both treated and untreated effluents, process streams and molecular fractions were tested for mutagenicity (Ames test. Salmonella typhimurium TA100 and SCE sister chromatid exchange test, Chinese hamster ovary cells). To verify the potential environmental effects the mutagenic activity of concentrated recipient lake water (Mill 2) was also studied. The Ames mutagenicity of the bleached kraft mill effluent (BKME) originated from the first chlorination filtrate, SCE mutagenicity also occurred in the alkali extraction stage filtrate (Mill 1). No Ames mutagenicity was detected in the paper mill effluent, but it was SCE mutagenic. Activated sludge treatment of BKME removed both Ames and SCE mutagenicity, but the aerated lagoon treated BKME was still SCE mutagenic. No mutagenic activity was detected in the recipient water concentrates.

Chemical characterization and biotreatability of effluents from an integrated alkaline-peroxide mechanical pulping/machine finish coated (APMP/MFC) paper mill

1997 ◽  
Vol 35 (2-3) ◽  
pp. 7-14 ◽  
Author(s):  
A. Schnell ◽  
M. J. Sabourin ◽  
S. Skog ◽  
M. Garvie
Keyword(s):  
Activated Sludge ◽  
Aquatic Toxicity ◽  
Wood Chip ◽  
Chemical Characterization ◽  
Toxicity Testing ◽  
Sampling Period ◽  
Paper Mill ◽  
Alkaline Peroxide ◽  
Conventional Activated Sludge ◽  
Treated Effluent

As part of an extensive audit of the Alkaline-Peroxide Mechanical Pulping (APMPTM) plant at the Malette Quebec Inc. mill in St. Raymond, Que., effluents were sampled from various stages of the process for comprehensive chemical characterizations, aquatic toxicity testing and anaerobic biotreatability assessments. In addition, untreated and secondary treated combined effluent from the integrated paper mill were sampled to determine the effectiveness of a conventional activated sludge process at the mill site. During the one-day sampling period, the APMP plant processed a mixed wood furnish consisting of 50% spruce/balsam fir and 50% aspen, with a chemical charge of 3.5% sodium hydroxide and 3.8% hydrogen peroxide on oven-dry fibre, while the Machine Finish Coated (MFC) paper production rate was 100 odt/d (oven dry metric tonnes per day). Measured production-specific contaminant discharge loadings from the novel APMP process were 56 kg BOD5/odt and 155 kg COD/odt in a combined effluent flow of 28 m3/odt. Sources of process effluent were chip washing, three stages of wood chip pretreatment and chemical impregnation (i.e., Impressafiner stages), interstate washing and pulp cleaning. The three Impressafiner pressates were found to be the most concentrated (i.e., 12-26 g COD/L) and toxic streams. Microtox testing of the pressates revealed EC50 concentrations of 0.07-0.34% v/v. The warm and concentrated effluents generated by the non-sulphur APMP process were found to be highly amenable to anaerobic degradation as determined by batch bioassay testing. Filterable BOD5 and COD(f) of the process effluents were reduced by 87-95% and 70-77%, respectively, with corresponding theoretical methane yields being attained. Acid-soluble dissolved lignin compounds exhibited biorecalcitrance, as revealed by limited removals of 34-55%, and were the main constituents contributing to residual COD(f), while resin and fatty acids (RFA) were reduced by 80-94%. The conservatively operated full scale activated sludge treatment process achieved a similar high 74% COD(f) removal from the whole mill effluent, while BOD5 and RFA reductions were virtually complete and the treated effluent was non-toxic, as measured by Microtox.

scholarly journals Absorption and Strength Properties of Short Carbon Fiber Reinforced Mortar Composite

Buildings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 300
Author(s):  
Md. Safiuddin ◽  
George Abdel-Sayed ◽  
Nataliya Hearn
Keyword(s):  
Tensile Strength ◽  
Carbon Fiber ◽  
Water Absorption ◽  
Carbon Fibers ◽  
Strength Properties ◽  
Fiber Content ◽  
Test Results ◽  
Air Content ◽  
Entrapped Air ◽  
Short Carbon

This paper presents the water absorption and strength properties of short carbon fiber reinforced mortar (CFRM) composite. Four CFRM composites with 1%, 2%, 3%, and 4% short pitch-based carbon fibers were produced in this study. Normal Portland cement mortar (NCPM) was also prepared for use as the control mortar. The freshly mixed mortar composites were tested for workability, wet density, and entrapped air content. In addition, the hardened mortar composites were examined for compressive strength, splitting tensile strength, flexural strength, and water absorption at the ages of 7 and 28 days. The effects of different carbon fiber contents on the tested properties were observed. Test results showed that the incorporation of carbon fibers decreased the workability and wet density, but increased the entrapped air content in mortar composite. Most interestingly, the compressive strength of CFRM composite increased up to 3% carbon fiber content and then it declined significantly for 4% fiber content, depending on the workability and compaction of the mortar. In contrast, the splitting tensile strength and flexural strength of the CFRM composite increased for all fiber contents due to the greater cracking resistance and improved bond strength of the carbon fibers in the mortar. The presence of short pitch-based carbon fibers significantly strengthened the mortar by bridging the microcracks, resisting the propagation of these minute cracks, and impeding the growth of macrocracks. Furthermore, the water absorption of CFRM composite decreased up to 3% carbon fiber content and then it increased substantially for 4% fiber content, depending on the entrapped air content of the mortar. The overall test results suggest that the mortar with 3% carbon fibers is the optimum CFRM composite based on the tested properties.

Dynamic-head space GC-MS analysis of volatile odorous compounds generated from unbleached and bleached pulps and effects on strength properties during ageing

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Izhar Alam ◽  
Swati Sood ◽  
Chhaya Sharma
Keyword(s):  
Volatile Compounds ◽  
Paper Mill ◽  
Strength Properties ◽  
Degree Of Polymerization ◽  
Ambient Conditions ◽  
Bleached Pulp ◽  
Tensile Index ◽  
Ms Analysis ◽  
Odorous Compounds ◽  
Unbleached Pulp

Abstract Mixed hardwood unbleached (UB) and final bleached (FB) pulp along with the pulp of intermediate bleaching stages from an integrated paper mill have been undertaken for this study. Headspace GC-MS analysis of these pulps was made to identify the odorous compounds which are volatile organic compounds (VOCs), generated during ageing for 60 days. The result showed that a number of pre-generated VOCs such as aliphatic hydrocarbons and aldehydes are observed in the pulp sample which might be came from the process and it has been observed that upon ageing at ambient conditions, some acid functionalized VOC were generated in the pulp. The generation of these VOCs were established by ATR-FTIR analysis and the results showed that intensity of peak absorbance near 3340  cm − 1 {\text{cm}^{-1}} and 1641  cm − 1 {\text{cm}^{-1}} which represents the –OH stretching of acidic functional group and C=O stretch of aldehyde and acidic functional groups increased after ageing. Generation of acid functionalized volatile compounds were observed more in bleached pulp than in unbleached pulp. Degree of polymerization (DP) is pretty much related to the strength of paper. DP of both unbleached and bleached pulp gets reduced upon ageing while more reduction were observed in bleached pulp. Bleached pulps are more prone to degrade as compared to the unbleached pulp in terms of strength properties such as tensile index, breaking length, burst and double fold were observed. 12.3 % and 21.8 % reduction in tensile index was observed for UB and final bleached FB pulp respectively. Burst index of UB and FB pulp were found reduced to 23.8 % and 41.9 % respectively due to ageing. Reduction in the mechanical and optical properties was also observed in intermediate bleaching stages. There is much evidence for the contribution of VOCs to the degradation of paper. The results are strongly suggested that acid functionalized volatile compounds can have strong effects on degradation of cellulosic paper.

Lipids from Wastewater‐Activated Sludge Cultivated on Acetic Acid as Potential Alternatives to High‐Value Oils and Fats

2019 ◽  
Vol 96 (9) ◽  
pp. 1073-1079
Author(s):  
Dhan Lord B. Fortela ◽  
Rafael Hernandez ◽  
Emmanuel Revellame ◽  
William Holmes ◽  
Wayne Sharp ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Activated Sludge
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