Rheology of aqueous boehmite-coated silicon nitride suspensions and gels

1995 ◽  
Vol 10 (11) ◽  
pp. 2808-2816 ◽  
Author(s):  
Wei-Heng Shih ◽  
Leh-Lii Pwu
Keyword(s):  
Silicon Nitride ◽  
Shear Modulus ◽  
Volume Fraction ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Exponential Behavior ◽  
Shear Rates ◽  
Wide Range ◽  
Density Relationship ◽  
Bingham Yield Stress

The rheological properties of boehmite-coated silicon nitride aqueous suspensions and gels are reported. In unidirectional rheological tests, it was found that the boehmite coating reduces the viscosity of the suspensions over a wide range of shear rates and volume fractions of particles. The suspension shear stress as a function of shear rate can be described by the Bingham model, and the Bingham yield stresses of boehmite-coated silicon nitride suspensions are lower than those of the uncoated suspensions. The reduction in the viscosity and the Bingham yield stress is attributed to a shallower secondary minimum in the Derjaguin-Landau-Verwey-Overbeek (DLVO) potential between coated particles than that for uncoated silicon nitride particles. Moreover, at low values of pH, the coated silicon nitride suspensions gelled over time, and the viscoelastic behavior of the gels was studied by dynamic oscillatory tests. It was found that the shear modulus (G′) and loss modulus (G″) remain constant up to a certain strain amplitude, γ°, beyond which G′ and G″ begin to vary. The value of G′ in the linear region increases exponentially, whereas γ° decreases exponentially with the volume fraction of coated silicon nitride particles. The exponential behavior of the shear modulus G′ of the gels is similar to the exponential pressure-density relationship found in the previous pressure filtration study, indicating that particulate rearrangement occurs as volume fraction of particles is increased.

Multicoating Inhomogeneities Problem for Effective Viscoelastic Properties of Particulate Composite Materials

2009 ◽  
Vol 131 (2) ◽  
Author(s):  
Yao Koutsawa ◽  
Mohammed Cherkaoui ◽  
El Mostafa Daya
Keyword(s):  
Loss Modulus ◽  
Micromechanical Model ◽  
Polymer System ◽  
High Capacity ◽  
Viscoelastic Behavior ◽  
Particulate Composite ◽  
Micromechanical Modeling ◽  
High Loss ◽  
Wide Range ◽  
The Matrix

The present work extends the multicoated micromechanical model of Lipinski et al. (2006, “Micromechanical Modeling of an Arbitrary Ellipsoidal Multi-Coated Inclusion,” Philos. Mag., 86(10), pp. 1305–1326) in the quasistatic domain to compute the effective material moduli of a viscoelastic material containing multicoated spherical inclusions displaying elastic or viscoelastic behavior. Losses are taken into account by introducing the frequency-dependent complex stiffness tensors of the viscoelastic matrix and the multicoated inclusions. The advantage of the micromechanical model is that it is applicable to the case of nonspherical multicoated inclusions embedded in anisotropic materials. The numerical simulations indicate that with proper choice of material properties, it is possible to engineer multiphase polymer system to have a high-loss modulus (good energy dissipation characteristics) for a wide range of frequencies without substantially degrading the stiffness of the composite (storage modulus). The numerical analyses show also that with respect to the relative magnitudes of the loss factors and the storage moduli of the matrix, inclusion and coating, the overall properties of the viscoelastic particulate composite are dominated by the properties of the matrices in some frequency ranges. The model can thus be a suitable tool to explore a wide range of microstructures for the design of materials with high capacity to absorb acoustic and vibrational energies.

Viscoelastic Properties of SBR Containing Particles of Crosslinked Polystyrene

1978 ◽  
Vol 51 (1) ◽  
pp. 110-116
Author(s):  
N. Nakajima ◽  
E. A. Collins
Keyword(s):  
Loss Modulus ◽  
Glassy State ◽  
Viscoelastic Behavior ◽  
Time Shift ◽  
Frequency Range ◽  
Shear Rates ◽  
High Shear Rates ◽  
Crosslinked Polystyrene ◽  
Temperature Time

Abstract It has been shown that methods are available for fundamental characterization of viscoelastic behavior of elastomers containing crosslinked particles. With the Rheometrics mechanical spectrometer and the Mooney rheometer operated at slow speeds, the elastic modulus and loss modulus were obtained at 100°C in the frequency range of 2.5×10−4−2.5×102 rad·s−1. In this frequency range, both the rubbery response of the SBR matrix and the response of polystyrene copolymer particles were observed. The former was in the higher frequencies and the latter in the lower frequencies, with a considerable overlap of both responses. From the magnitude of the temperature-time shift, it was learned that the deformations of both SBR matrix and polystyrene copolymer particles were involved. The steady-shear viscosities were measured with the Instron capillary rheometer. At extrusion temperatures of 85 and 100°C, the extrudates were distorted at the high shear rates. Calculations show that the polystyrene copolymer phase attains the glassy state, because pressure and frequency raise the glass transition from 51°C to the extrusion temperature.

scholarly journals Microrheology of DNA hydrogels

2018 ◽  
Vol 115 (32) ◽  
pp. 8137-8142 ◽  
Author(s):  
Zhongyang Xing ◽  
Alessio Caciagli ◽  
Tianyang Cao ◽  
Iliya Stoev ◽  
Mykolas Zupkauskas ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Melting Temperature ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Building Blocks ◽  
Diffusing Wave Spectroscopy ◽  
Wide Range ◽  
Transient Network ◽  
Gel Transition ◽  
Dna Hydrogels

A key objective in DNA-based material science is understanding and precisely controlling the mechanical properties of DNA hydrogels. We perform microrheology measurements using diffusing wave spectroscopy (DWS) to investigate the viscoelastic behavior of a hydrogel made of Y-shaped DNA (Y-DNA) nanostars over a wide range of frequencies and temperatures. We observe a clear liquid-to-gel transition across the melting temperature region for which the Y-DNA bind to each other. Our measurements reveal a cross-over between the elastic G′(ω) and loss modulus G″(ω) around the melting temperature Tm of the DNA building blocks, which coincides with the systems percolation transition. This transition can be easily shifted in temperature by changing the DNA bond length between the Y shapes. Using bulk rheology as well, we further show that, by reducing the flexibility between the Y-DNA bonds, we can go from a semiflexible transient network to a more energy-driven hydrogel with higher elasticity while keeping the microstructure the same. This level of control in mechanical properties will facilitate the design of more sensitive molecular sensing tools and controlled release systems.

Influence of κ-Carrageenan, Modified Starch and Inulin Addition on Rheological and Sensory Properties of Non-fat and Non-added Sugar Dairy Dessert

2020 ◽  
Vol 16 (4) ◽  
pp. 462-469
Author(s):  
Zhaleh Sheidaei ◽  
Bahareh Sarmadi ◽  
Seyede M. Hosseini ◽  
Fardin Javanmardi ◽  
Kianoush Khosravi-Darani ◽  
...  
Keyword(s):  
Storage Modulus ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Textural Properties ◽  
Complex Viscosity ◽  
Sensory Properties ◽  
Modified Starch ◽  
Consumer Health ◽  
Added Sugar ◽  
Textural Parameters

<P>Background: The high amounts of fat, sugar and calorie existing in dairy desserts can lead to increase the risk of health problems. Therefore, the development of functional and dietary forms of these products can help the consumer health. </P><P> Objective: This study aims to investigate the effects of &#954;-carrageenan, modified starch and inulin addition on rheological and sensory properties of non-fat and non-added sugar dairy dessert. </P><P> Methods: In order to determine the viscoelastic behavior of samples, oscillatory test was carried out and the values of storage modulus (G′), loss modulus (G″), loss angle tangent (tan &#948;) and complex viscosity (&#951;*) were measured. TPA test was used for analysis of the desserts’ texture and textural parameters of samples containing different concentrations of carrageenan, starch and inulin were calculated. </P><P> Results: All treatments showed a viscoelastic gel structure with the storage modulus higher than the loss modulus values. Increasing amounts of &#954;-carrageenan and modified starch caused an increase in G′ and G″ as well as &#951;* and a decrease in tan &#948;. Also, firmness and cohesiveness were enhanced. The trained panelists gave the highest score to the treatment with 0.1% &#954;-carrageenan, 2.5% starch and 5.5% inulin (sucralose as constant = 0.25%) and this sample was the best treatment with desirable attributes for the production of non-fat and non-added sugar dairy dessert. </P><P> Conclusion: It can be concluded that the concentration of &#954;-carrageenan and starch strongly influenced the rheological and textural properties of dairy desserts, whereas the inulin content had little effect on these attributes.</P>

scholarly journals Factors Affecting Acoustic Properties of Natural-Fiber-Based Materials and Composites: A Review

Textiles ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 55-85
Author(s):  
Tufail Hassan ◽  
Hafsa Jamshaid ◽  
Rajesh Mishra ◽  
Muhammad Qamar Khan ◽  
Michal Petru ◽  
...  
Keyword(s):  
Sound Absorption ◽  
Natural Fiber ◽  
Volume Fraction ◽  
Fiber Type ◽  
Alkali Treatment ◽  
Acoustic Properties ◽  
Synthetic Fiber ◽  
Sound Insulation ◽  
Factors Affecting ◽  
Wide Range

Recently, very rapid growth has been observed in the innovations and use of natural-fiber-based materials and composites for acoustic applications due to their environmentally friendly nature, low cost, and good acoustic absorption capability. However, there are still challenges for researchers to improve the mechanical and acoustic properties of natural fiber composites. In contrast, synthetic fiber-based composites have good mechanical properties and can be used in a wide range of structural and automotive applications. This review aims to provide a short overview of the different factors that affect the acoustic properties of natural-fiber-based materials and composites. The various factors that influence acoustic performance are fiber type, fineness, length, orientation, density, volume fraction in the composite, thickness, level of compression, and design. The details of various factors affecting the acoustic behavior of the fiber-based composites are described. Natural-fiber-based composites exhibit relatively good sound absorption capability due to their porous structure. Surface modification by alkali treatment can enhance the sound absorption performance. These materials can be used in buildings and interiors for efficient sound insulation.

scholarly journals Conduction and convection heat transfer characteristics of water-based au nanofluids in a square cavity with differentially heated side walls subjected to constant temperatures

2014 ◽  
Vol 18 (suppl.1) ◽  
pp. 189-200 ◽  
Author(s):  
Primoz Ternik ◽  
Rebeka Rudolf
Keyword(s):  
Heat Transfer ◽  
Rayleigh Number ◽  
Base Fluid ◽  
Volume Fraction ◽  
Heat Transfer Characteristics ◽  
Square Cavity ◽  
Onset Of Convection ◽  
Transfer Characteristics ◽  
Wide Range ◽  
Water Based

The present work deals with the natural convection in a square cavity filled with the water-based Au nanofluid. The cavity is heated on the vertical and cooled from the adjacent wall, while the other two horizontal walls are adiabatic. The governing differential equations have been solved by the standard finite volume method and the hydrodynamic and thermal fields were coupled together using the Boussinesq approximation. The main objective of this study is to investigate the influence of the nanoparticles? volume fraction on the heat transfer characteristics of Au nanofluids at the given base fluid?s (i.e. water) Rayleigh number. Accurate results are presented over a wide range of the base fluid Rayleigh number and the volume fraction of Au nanoparticles. It is shown that adding nanoparticles in a base fluid delays the onset of convection. Contrary to what is argued by many authors, we show by numerical simulations that the use of nanofluids can reduce the heat transfer rate instead of increasing it.

scholarly journals Microstructure and magnetic properties of Nd-Fe-B-(Re, Ti) alloys

Nukleonika ◽  
2015 ◽  
Vol 60 (1) ◽  
pp. 29-33
Author(s):  
Mariusz Hasiak
Keyword(s):  
Magnetic Properties ◽  
Phase Composition ◽  
Volume Fraction ◽  
Magnetic Characteristics ◽  
Ti Alloys ◽  
Wide Range ◽  
Magnetically Hard ◽  
Ti Addition ◽  
Microstructure And Magnetic Properties

Abstract The microstructure and magnetic properties of nanocomposite hard magnetic Nd-Fe-B-(Re, Ti) materials with different Nd and Fe contents are studied. The role of Re and Ti addition in phase composition and volume fraction of the Nd-Fe-B phase is determined. All samples are annealed at the same temperature of 993 K for 10 min. Mössbauer spectroscopy shows that the addition of 4 at.% of Re to the Nd8Fe78B14 alloy leads to creation of an ineligible amount of the magnetically hard Nd2Fe14B phase. Moreover, the microstructure and magnetic characteristics recorded in a wide range of temperatures for the Nd8Fe79−xB13Mx (x = 4; M = Re or Ti) alloys are also analyzed.

VISCOSITY OF NATURAL RUBBER SOLUTIONS AT VERY LOW RATES OF SHEAR

1957 ◽  
Vol 35 (4) ◽  
pp. 381-387 ◽  
Author(s):  
Morton A. Golub
Keyword(s):  
Experimental Data ◽  
Natural Rubber ◽  
Pressure Head ◽  
Viscosity Data ◽  
Theoretical Relation ◽  
Newtonian Flow ◽  
Shear Rates ◽  
Reduced Viscosity ◽  
Wide Range ◽  
Composite Data

The shear dependence of viscosity of benzene solutions of natural rubber was studied at rates of shear from about 500 down to less than 1 sec.−1. Measurements involved following the change of pressure head with time of the various solutions flowing in a capillary, U-tube viscometer. Curvature in the plots of the logarithm of pressure head versus time indicated non-Newtonian flow. From such curves, reduced viscosity data over the above-mentioned shear range were readily derived. As a check, data over the range 100–500 sec.−1 were also obtained with a five-bulb viscometer of the Krigbaum–Flory type, and these data overlapped those obtained with the U tube. The reduced viscosity increased very sharply with decrease in gradient, making extrapolation to the viscosity axis quite unreliable. However, a theoretical relation proposed by Bueche fitted the composite data rather well. This work furnished a nice technique for determining the zero shear reduced viscosity (ηap/c)0 without the necessity of performing an uncertain extrapolation: evaluate the parameters of the Bueche formula which best satisfies the experimental data over a fairly wide range of shear rates, and then calculate (ηap/c)0 directly.

Nanoemulsions: A Versatile Technology for Oil and Gas Applications

2021 ◽  
Author(s):  
Nouf AlJabri ◽  
Nan Shi
Keyword(s):  
Droplet Size ◽  
Large Scale ◽  
Oil And Gas ◽  
Volume Fraction ◽  
Oil Industry ◽  
Oil And Gas Industry ◽  
High Energy ◽  
Small Droplet ◽  
Gas Industry ◽  
Wide Range

Abstract Nanoemulsions (NEs) are kinetically stable emulsions with droplet size on the order of 100 nm. Many unique properties of NEs, such as stability and rheology, have attracted considerable attention in the oil industry. Here, we review applications and studies of NEs for major upstream operations, highlighting useful properties of NEs, synthesis to render these properties, and techniques to characterize them. We identify specific challenges associated with large-scale applications of NEs and directions for future studies. We first summarize useful and unique properties of NEs, mostly arising from the small droplet size. Then, we compare different methods to prepare NEs based on the magnitude of input energy, i.e., low-energy and high-energy methods. In addition, we review techniques to characterize properties of NEs, such as droplet size, volume fraction of the dispersed phase, and viscosity. Furthermore, we discuss specific applications of NEs in four areas of upstream operations, i.e., enhanced oil recovery, drilling/completion, flow assurance, and stimulation. Finally, we identify challenges to economically tailor NEs with desired properties for large-scale upstream applications and propose possible solutions to some of these challenges. NEs are kinetically stable due to their small droplet size (submicron to 100 nm). Within this size range, the rate of major destabilizing mechanisms, such as coalescence, flocculation, and Ostwald ripening, is considerably slowed down. In addition, small droplet size yields large surface-to-volume ratio, optical transparency, high diffusivity, and controllable rheology. Similar to applications in other fields (food industry, pharmaceuticals, cosmetics, etc.), the oil and gas industry can also benefit from these useful properties of NEs. Proposed functions of NEs include delivering chemicals, conditioning wellbore/reservoir conditions, and improve chemical compatibility. Therefore, we envision NEs as a versatile technology that can be applied in a variety of upstream operations. Upstream operations often target a wide range of physical and chemical conditions and are operated at different time scales. More importantly, these operations typically consume a large amount of materials. These facts not only suggest efforts to rationally engineer properties of NEs in upstream applications, but also manifest the importance to economically optimize such efforts for large-scale operations. We summarize studies and applications of NEs in upstream operations in the oil and gas industry. We review useful properties of NEs that benefit upstream applications as well as techniques to synthesize and characterize NEs. More importantly, we identify challenges and opportunities in engineering NEs for large-scale operations in different upstream applications. This work not only focuses on scientific aspects of synthesizing NEs with desired properties but also emphasizes engineering and economic consideration that is important in the oil industry.

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