The Optical Properties of Plasma-Deposited SiO2 and Si3N4 Bragg Reflectors in the Spectral Range from 1.8 to 3.0 eV

1992 ◽  
Vol 281 ◽  
Author(s):  
D. J. Stephens ◽  
S. S. He ◽  
G. Lucovsky ◽  
H. Mkkelsen ◽  
K. Leo ◽  
...  

ABSTRACTWe have prepared 19-layer Si3N4:SiO2/…‥Si3N4:SiO2/Si3N4 (HL/HL/…HL/H), Bragg reflectors by remote plasma-enhanced chemical-vapor deposition, and have adjusted the constituent layer thicknesses to generate highly reflecting films over the entire visible spectrum from approximately 1.8 eV (∼690 nm) to 3.0 eV (∼410 nm). Peak values of the reflectance, in spectral bands with half-widths of ∼0.4 to 0.5 eV, are in the range of 96 to 98 %. The spectral response functions of these stacks exhibit departures from the optical behavior as calculated for exactly periodic structures with λ/4 layer thicknesses, and can be accounted for by taking into account: i) dispersion and absorption in the optical properties of the constituent layers; and ii) departures from the idealized and constant layer thicknessses.

2017 ◽  
Vol 4 (6) ◽  
pp. 1024-1028 ◽  
Author(s):  
Rafael Sandoval-Torrientes ◽  
Joaquín Calbo ◽  
David García-Fresnadillo ◽  
José Santos ◽  
Enrique Ortí ◽  
...  

A series of new broad-absorbing rhodanine-fluorene dyes conjugated with triarylamines are presented. Spectroscopic and electrochemical characterizations, along with theoretical DFT calculations, unveil the electronic and optical properties of the dyes.


1996 ◽  
Vol 11 (1) ◽  
pp. 236-242 ◽  
Author(s):  
Justin F. Gaynor ◽  
Seshu B. Desu

For the first time, the refractive index of polyparaxylylene films, the only polymers grown commercially by chemical vapor deposition (CVD), is reported throughout the visible spectrum. This information is required if optical components such as antireflective coatings or waveguides are to be fabricated with CVD polymers. These properties are compared to a low-index CVD copolymer, poly(parachloroxylylene-co-perfluorooctyl methacrylate), invented in our laboratory. The ellipsometric constants psi and delta were measured for wavelengths between 400 nm and 1000 nm using variable angle spectroscopic ellipsometry; many samples of each film were grown to improve statistics. The data were modeled assuming a birefringent Cauchy dispersion; excellent agreement between models and experimental data was obtained. The refractive index (λ = 632.8 nm) of the copolymer in the film plane was 1.389, compared to 1.645–1.665 for the homopolymers. PPX, PPX-C, and the copolymer showed negative birefringence, while PPX-D showed positive bifringence. The optical properties of PPX showed little thickness dependence for films ranging from 36 nm to 2100 nm thick.


1993 ◽  
Vol 298 ◽  
Author(s):  
D.J. Stephens ◽  
S.S. He ◽  
G. Lucovsky ◽  
H. Mikkelsen ◽  
K. Leo

AbstractWe have fabricated stacked-structures comprised of i) fused silica substrates, and ii) near-periodic Si3N4/SiO2 bi-layers by low-temperature, 250°C, remote plasmaenhanced chemical-vapor deposition. Comparing the reflectance of these structures with model calculations, we have been able to identify the effects on the reflectance spectra of departures from i) exact periodicity, ii) not having the constituent dielectric layers each posses an ideal optical path length, OPL, exactly equal to λcentral/4, and iii) the intrinsic dispersion in the dielectric functions of the oxide and nitride materials. We have prepared quasi-periodic structures in which the OPL of the higher index Si3N4 layer was > λcentral/4, and in which the OPL of the lower index SiO2 layer was < λcentral/4. This promotes a second strong reflectance band at an energy that is approximately two times that of the primary band. Calculations have shown that the reflectance values in this band, and near a reflectance minimum on the high energy side of the band, are both very sensitive to changes in the optical properties of the nitride film. We present calculations that demonstrate the effects on the reflectance of this band by a temperature-induced modulation of the optical properties of the oxide and nitride layers.


Author(s):  
A. Strojnik ◽  
J.W. Scholl ◽  
V. Bevc

The electron accelerator, as inserted between the electron source (injector) and the imaging column of the HVEM, is usually a strong lens and should be optimized in order to ensure high brightness over a wide range of accelerating voltages and illuminating conditions. This is especially true in the case of the STEM where the brightness directly determines the highest resolution attainable. In the past, the optical behavior of accelerators was usually determined for a particular configuration. During the development of the accelerator for the Arizona 1 MEV STEM, systematic investigation was made of the major optical properties for a variety of electrode configurations, number of stages N, accelerating voltages, 1 and 10 MEV, and a range of injection voltages ϕ0 = 1, 3, 10, 30, 100, 300 kV).


Sensors ◽  
2020 ◽  
Vol 20 (14) ◽  
pp. 3995 ◽  
Author(s):  
Ning Liu ◽  
Ruomei Zhao ◽  
Lang Qiao ◽  
Yao Zhang ◽  
Minzan Li ◽  
...  

Potato is the world’s fourth-largest food crop, following rice, wheat, and maize. Unlike other crops, it is a typical root crop with a special growth cycle pattern and underground tubers, which makes it harder to track the progress of potatoes and to provide automated crop management. The classification of growth stages has great significance for right time management in the potato field. This paper aims to study how to classify the growth stage of potato crops accurately on the basis of spectroscopy technology. To develop a classification model that monitors the growth stage of potato crops, the field experiments were conducted at the tillering stage (S1), tuber formation stage (S2), tuber bulking stage (S3), and tuber maturation stage (S4), respectively. After spectral data pre-processing, the dynamic changes in chlorophyll content and spectral response during growth were analyzed. A classification model was then established using the support vector machine (SVM) algorithm based on spectral bands and the wavelet coefficients obtained from the continuous wavelet transform (CWT) of reflectance spectra. The spectral variables, which include sensitive spectral bands and feature wavelet coefficients, were optimized using three selection algorithms to improve the classification performance of the model. The selection algorithms include correlation analysis (CA), the successive projection algorithm (SPA), and the random frog (RF) algorithm. The model results were used to compare the performance of various methods. The CWT-SPA-SVM model exhibited excellent performance. The classification accuracies on the training set (Atrain) and the test set (Atest) were respectively 100% and 97.37%, demonstrating the good classification capability of the model. The difference between the Atrain and accuracy of cross-validation (Acv) was 1%, which showed that the model has good stability. Therefore, the CWT-SPA-SVM model can be used to classify the growth stages of potato crops accurately. This study provides an important support method for the classification of growth stages in the potato field.


Micromachines ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 637
Author(s):  
Hongliang Li ◽  
Zewen Lin ◽  
Yanqing Guo ◽  
Jie Song ◽  
Rui Huang ◽  
...  

The influence of N incorporation on the optical properties of Si-rich a-SiCx films deposited by very high-frequency plasma-enhanced chemical vapor deposition (VHF PECVD) was investigated. The increase in N content in the films was found to cause a remarkable enhancement in photoluminescence (PL). Relative to the sample without N incorporation, the sample incorporated with 33% N showed a 22-fold improvement in PL. As the N content increased, the PL band gradually blueshifted from the near-infrared to the blue region, and the optical bandgap increased from 2.3 eV to 5.0 eV. The enhancement of PL was suggested mainly from the effective passivation of N to the nonradiative recombination centers in the samples. Given the strong PL and wide bandgap of the N incorporated samples, they were used to further design an anti-counterfeiting label.


Nanophotonics ◽  
2020 ◽  
Vol 9 (14) ◽  
pp. 4233-4252
Author(s):  
Yael Gutiérrez ◽  
Pablo García-Fernández ◽  
Javier Junquera ◽  
April S. Brown ◽  
Fernando Moreno ◽  
...  

AbstractReconfigurable plasmonics is driving an extensive quest for active materials that can support a controllable modulation of their optical properties for dynamically tunable plasmonic structures. Here, polymorphic gallium (Ga) is demonstrated to be a very promising candidate for adaptive plasmonics and reconfigurable photonics applications. The Ga sp-metal is widely known as a liquid metal at room temperature. In addition to the many other compelling attributes of nanostructured Ga, including minimal oxidation and biocompatibility, its six phases have varying degrees of metallic character, providing a wide gamut of electrical conductivity and optical behavior tunability. Here, the dielectric function of the several Ga phases is introduced and correlated with their respective electronic structures. The key conditions for optimal optical modulation and switching for each Ga phase are evaluated. Additionally, we provide a comparison of Ga with other more common phase-change materials, showing better performance of Ga at optical frequencies. Furthermore, we first report, to the best of our knowledge, the optical properties of liquid Ga in the terahertz (THz) range showing its broad plasmonic tunability from ultraviolet to visible-infrared and down to the THz regime. Finally, we provide both computational and experimental evidence of extension of Ga polymorphism to bidimensional two-dimensional (2D) gallenene, paving the way to new bidimensional reconfigurable plasmonic platforms.


2020 ◽  
Vol 15 (1) ◽  
Author(s):  
Xiaowei Wang ◽  
Feng Liang ◽  
Degang Zhao ◽  
Zongshun Liu ◽  
Jianjun Zhu ◽  
...  

Abstract Three InGaN/GaN MQWs samples with varying GaN cap layer thickness were grown by metalorganic chemical vapor deposition (MOCVD) to investigate the optical properties. We found that a thicker cap layer is more effective in preventing the evaporation of the In composition in the InGaN quantum well layer. Furthermore, the quantum-confined Stark effect (QCSE) is enhanced with increasing the thickness of GaN cap layer. In addition, compared with the electroluminescence measurement results, we focus on the difference of localization states and defects in three samples induced by various cap thickness to explain the anomalies in room temperature photoluminescence measurements. We found that too thin GaN cap layer will exacerbates the inhomogeneity of localization states in InGaN QW layer, and too thick GaN cap layer will generate more defects in GaN cap layer.


Nanophotonics ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 3003-3010
Author(s):  
Jiacheng Shi ◽  
Wen Qiao ◽  
Jianyu Hua ◽  
Ruibin Li ◽  
Linsen Chen

AbstractGlasses-free augmented reality is of great interest by fusing virtual 3D images naturally with physical world without the aid of any wearable equipment. Here we propose a large-scale spatial multiplexing holographic see-through combiner for full-color 3D display. The pixelated metagratings with varied orientation and spatial frequency discretely reconstruct the propagating lightfield. The irradiance pattern of each view is tailored to form super Gaussian distribution with minimized crosstalk. What’s more, spatial multiplexing holographic combiner with customized aperture size is adopted for the white balance of virtually displayed full-color 3D scene. In a 32-inch prototype, 16 views form a smooth parallax with a viewing angle of 47°. A high transmission (>75%) over the entire visible spectrum range is achieved. We demonstrated that the displayed virtual 3D scene not only preserved natural motion parallax, but also mixed well with the natural objects. The potential applications of this study include education, communication, product design, advertisement, and head-up display.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 698
Author(s):  
Wenwang Wei ◽  
Yi Peng ◽  
Jiabin Wang ◽  
Muhammad Farooq Saleem ◽  
Wen Wang ◽  
...  

AlN epilayers were grown on a 2-inch [0001] conventional flat sapphire substrate (CSS) and a nano-patterned sapphire substrate (NPSS) by metalorganic chemical vapor deposition. In this work, the effect of the substrate template and temperature on stress and optical properties of AlN films has been studied by using Raman spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-visible spectrophotometer and spectroscopic ellipsometry (SE). The AlN on NPSS exhibits lower compressive stress and strain values. The biaxial stress decreases from 1.59 to 0.60 GPa for AlN on CSS and from 0.90 to 0.38 GPa for AlN on NPSS sample in the temperature range 80–300 K, which shows compressive stress. According to the TEM data, the stress varies from tensile on the interface to compressive on the surface. It can be deduced that the nano-holes provide more channels for stress relaxation. Nano-patterning leads to a lower degree of disorder and stress/strain relaxes by the formation of the nano-hole structure between the interface of AlN epilayers and the substrate. The low crystal disorder and defects in the AlN on NPSS is confirmed by the small Urbach energy values. The variation in bandgap (Eg) and optical constants (n, k) with temperature are discussed in detail. Nano-patterning leads to poor light transmission due to light scattering, coupling, and trapping in nano-holes.


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