scholarly journals On the Influence of Carbon Nanotubes on the Physical and Mechanical Properties of Polypropylene

2021 ◽  
pp. 27-36
Author(s):  
Irina Zaporotskova ◽  
◽  
Vladislav Kalinichenko ◽  
Lev Kozhitov ◽  
Pavel Zaporotskov ◽  
...  

One of the most interesting and promising materials of our time is carbon nanotubes. Most applications of nanotubes are associated with the possibility of combining them with other materials in the form of alloys, mixtures, composites or hybrid materials. In particular, the idea of including carbon nanotubes as a filler in various polymer-based matrices (for example, traditional polymers such as thermoplastics, thermosetting materials or elastomers, as well as conjugated polymers) for the formation of polymer/carbon nanotube nanocomposites has revolutionized materials science and engineering. The introduction of carbon nanotubes into the composite structure affects the structure and properties of the polymer binder, as well as the composite material as a whole. Currently, there are no experimental developments on the basis of which the introduction, distribution and stabilization of the dispersion of carbon nanotubes in polymer composites would be implemented in industrial technology. The development of the most effective methods for introducing carbon nanotubes into polymer materials and determining their effect on the physical and mechanical properties of polymers is an urgent and priority task. It is possible that these methods will be able to find application in the industrial production of polymer composite materials intended for use and operation in various extreme conditions (whether it is high temperatures, erosion, high force exposure or highly acidic/highly alkaline environments). The main physical and mechanical properties of polypropylene samples saturated with carbon nanotubes taken at different concentrations (0; 0.01; 0.05 and 0.1 wt. %), who found that the addition of CNT in large quantities negatively affects the tensile and bending strength limits, which may be associated with an increase in the degree of heterogeneity of the structure and the appearance of large agglomerates, which will be points of stress concentration. With an increase in the mass fraction of carbon nanotubes in the polymer nanocomposite, the tangent of the dielectric loss angle increases, which leads to better conductivity of the sample containing a larger number of nanotubes. This may be due to the fact that nanotubes become conductors of electric current in the volume of the polymer matrix.

2019 ◽  
Vol 895 ◽  
pp. 272-277
Author(s):  
Bheemappa Suresha ◽  
Achyutananta Padaki ◽  
Akash Jain ◽  
Bharath Kumar ◽  
Akshay A. Kulkarni

Hybrid composites based on high-density polyethylene-grafted maleic anhydride /ultra-high density HYPERLINK "https://www.sciencedirect.com/topics/materials-science/polypropylene" \o "Learn more about Polypropylene" polyethylene (HDPE/UHMWPE) loaded with short glass fiber (SGF) and zirconia (ZrO2) micron sized particles were fabricated by melt-mixing process and their physical and mechanical properties were determined. Physio-mechanical properties such as density, hardness, flexural properties and impact strength of these composites were studied. The presence of SGF and ZrO2 in the grafted HDPE/UHMWPE blend increased the hardness, bending strength and modulus. However, impact strength decreased with increase in ZrO2 loading. Further, it was found that the HDPE/UHMWPE blend with 25 wt. % SGF and 2.5 wt. %ZrO2 showed optimum mechanical properties due to improved fiber/matrix adhesion. Scanning electron microscope was used to identify the fractographic features of the selected fractured coupons.


2020 ◽  
pp. 39-48
Author(s):  
B. O. Bolshakov ◽  
◽  
R. F. Galiakbarov ◽  
A. M. Smyslov ◽  
◽  
...  

The results of the research of structure and properties of a composite compact from 13 Cr – 2 Мо and BN powders depending on the concentration of boron nitride are provided. It is shown that adding boron nitride in an amount of more than 2% by weight of the charge mixture leads to the formation of extended grain boundary porosity and finely dispersed BN layers in the structure, which provides a high level of wearing properties of the material. The effect of boron nitride concentration on physical and mechanical properties is determined. It was found that the introduction of a small amount of BN (up to 2 % by weight) into the compacts leads to an increase in plasticity, bending strength, and toughness by reducing the friction forces between the metal powder particles during pressing and a more complete grain boundary diffusion process during sintering. The formation of a regulated structure-phase composition of powder compacts of 13 Cr – 2 Mо – BN when the content of boron nitride changes in them allows us to provide the specified physical and mechanical properties in a wide range. The obtained results of studies of the physical and mechanical characteristics of the developed material allow us to reasonably choose the necessary composition of the powder compact for sealing structures of the flow part of steam turbines, depending on their operating conditions.


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 220
Author(s):  
Petar Antov ◽  
Viktor Savov ◽  
Ľuboš Krišťák ◽  
Roman Réh ◽  
George I. Mantanis

The potential of producing eco-friendly, formaldehyde-free, high-density fiberboard (HDF) panels from hardwood fibers bonded with urea-formaldehyde (UF) resin and a novel ammonium lignosulfonate (ALS) is investigated in this paper. HDF panels were fabricated in the laboratory by applying a very low UF gluing factor (3%) and ALS content varying from 6% to 10% (based on the dry fibers). The physical and mechanical properties of the fiberboards, such as water absorption (WA), thickness swelling (TS), modulus of elasticity (MOE), bending strength (MOR), internal bond strength (IB), as well as formaldehyde content, were determined in accordance with the corresponding European standards. Overall, the HDF panels exhibited very satisfactory physical and mechanical properties, fully complying with the standard requirements of HDF for use in load-bearing applications in humid conditions. Markedly, the formaldehyde content of the laboratory fabricated panels was extremely low, ranging between 0.7–1.0 mg/100 g, which is, in fact, equivalent to the formaldehyde release of natural wood.


2021 ◽  
Author(s):  
Prantik Mondal ◽  
Gourhari Jana ◽  
Tuhin Subhra Pal ◽  
Pratim K. Chattaraj ◽  
Nikhil K Singha

Nowadays, the design of functional polymer materials that can mimic natural phenomena, e.g., self-healing of skin cuts, has got a tremendous interest in materials science and engineering. Recently, 1,2,4-triazoline-3,5-dione (TAD)...


2021 ◽  
Vol 27 (1) ◽  
Author(s):  
Przemysław Marcin Pikiński ◽  
Jaroslav Szaban ◽  
Gerda Šilingienė ◽  
Robert Korzeniewicz ◽  
Witold Pazdrowski

The aim of this study was to assess the quality of Scots pine (Pinus sylvestris L.) wood depending on the age of trees, forest site conditions and social class of tree position in the stand. Analyses were based on the determination of specific density and static bending strength, as well as the strength quality coefficient. It was to determine changes in physical and mechanical properties of timber depending on tree age as well as growth conditions reflected in the forest site such as fresh mixed coniferous forests and fresh mixed broadleaved forests. Experimental plots were established in 6 localities with 30, 40 and 60-year-old trees. In each of the stands, a 1-hectare experimental plot was established. Based on the measured DBH and tree height, dimensions of three mean sample trees were calculated, while the classification of social class of tree position in the stand developed by Kraft (1884) was also applied. Analyses were conducted on wood samples with 12% moisture content. Strength tests on wood samples were performed on an Instron 33RH204 universal strength testing machine. A detailed analysis showed properties of pine wood are improved with an increase of tree age in both forest sites. Statistically significant differences were observed for wood density and static bending strength. More advantageous properties were observed for wood of pines from the less fertile forest site, i.e., fresh mixed coniferous forests. Density and static bending strength were markedly determined by tree age and growth conditions. The static bending strength quality coefficient from pines growing in the fresh mixed coniferous forests increased between 30 and 40 years, similarly as it was for the fresh mixed broadleaved forests, while between 40 and 60 years, it deteriorated for the fresh mixed coniferous forests. Wood density from the fresh mixed coniferous forests was by 3% to 7% greater than pines growing in fresh mixed broadleaved forests. In turn, static bending strength of wood from pines growing in fresh mixed coniferous forests was by 4% to 10% greater than trees from the fresh mixed broadleaved forests.  Keywords: Scots pine, wood properties, forest site, Poland


2021 ◽  
Vol 12 (2) ◽  
pp. 39
Author(s):  
Tuba Bahtli ◽  
Nesibe Sevde Ozbay

Studies in the literature show that the physical and mechanical properties of concrete could be improved by the incorporation of different kinds of industrial waste, including waste tire rubber and tire steel. Recycling of waste is important for economic gain and to curb environmental problems. In this study, finely ground CuAl10Ni bronze is used to improve the physical and mechanical properties, and freeze-thaw resistances of C30 concrete. The density, cold crushing strength, 3-point bending strength, elastic modulus, toughness, and freeze-thaw resistances of concrete are determined. In addition, the Schmidt Rebound Hammer (SRH) and the ultrasonic pulse velocity (UPV) tests, which are non-destructive test methods, are applied. SEM/EDX analyses are also carried out. It is noted that a more compacted structure of concrete is achieved with the addition of bronze sawdust. Then higher density and strength values are obtained for concretes that are produced by bronze addition. In addition, concretes including bronze sawdust generally show higher toughness due to high plastic energy capacities than pure concrete.


2021 ◽  
Vol 114 ◽  
pp. 70-75
Author(s):  
Radosław Auriga ◽  
Piotr Borysiuk ◽  
Alicja Auriga

An attempt to use „Tetra Pak” waste material in particleboard technology. The study investigates the effect of addition Tetra Pak waste material in the core layer on physical and mechanical properties of chipboard. Three-layer chipboards with a thickness of 16 mm and a density of 650 kg / m3 were manufactured. The share of Tetra Pak waste material in the boards was varied: 0%, 5%, 10% and 25%. The density profile was measured to determine the impact of Tetra Pak share on the density distribution. In addition, the manufactured boards were tested for strength (MOR, MOE, IB), thickness swelling and water absorption after immersion in water for 2 and 24 hours. The tests revealed that Tetra Pak share does not affect significantly the value of static bending strength and modulus of elasticity of the chipboard, but it significantly decreases IB. Also, it has been found that Tetra Pak insignificantly decreases the value of swelling and water absorption of the chipboards.


Forests ◽  
2019 ◽  
Vol 10 (12) ◽  
pp. 1102 ◽  
Author(s):  
Ladislav Reinprecht ◽  
Miroslav Repák

The European beech (Fagus sylvatica L.) wood was thermally modified in the presence of paraffin at the temperatures of 190 or 210 °C for 1, 2, 3 or 4 h. A significant increase in its resistance to the brown-rot fungus Poria placenta (by 71.4%–98.4%) and the white-rot fungus Trametes versicolor (by 50.1%–99.5%) was observed as a result of all modification modes. However, an increase in the resistance of beech wood surfaces to the mold Aspergillus niger was achieved only under more severe modification regimes taking 4 h at 190 or 210 °C. Water resistance of paraffin-thermally modified beech wood improved—soaking reduced by 30.2%–35.8% and volume swelling by 26.8%–62.9% after 336 h of exposure in water. On the contrary, its mechanical properties worsened—impact bending strength decreased by 17.8%–48.3% and Brinell hardness by 2.4%–63.9%.


Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1750 ◽  
Author(s):  
Radosław Mirski ◽  
Pavlo Bekhta ◽  
Dorota Dziurka

This study examined the effects of selected types of thermoplastics on the physical and mechanical properties of polymer-triticale boards. The investigated thermoplastics differed in their type (polypropylene (PP), polyethylene (PE), polystyrene (PS)), form (granulate, agglomerate) and origin (native, recycled). The resulting five-ply boards contained layers made from different materials (straw or pine wood) and featured different moisture contents (2%, 25%, and 7% for the face, middle, and core layers, respectively). Thermoplastics were added only to two external layers, where they substituted 30% of straw particles. This study demonstrated that, irrespective of their type, thermoplastics added to the face layers most favorably reduced the hydrophobic properties of the boards, i.e., thickness, swelling, and V100, by nearly 20%. The bending strength and modulus of elasticity were about 10% lower in the experimental boards than in the reference ones, but still within the limits set out in standard for P7 boards (20 N/mm2 according to EN 312).


2014 ◽  
Vol 92 ◽  
pp. 188-193 ◽  
Author(s):  
Tuna Aydin ◽  
Alpagut Kara

Spodumene, which is a lithium alumina silicate, has been used as a raw material in the production of thermal shock resistant whitewares and sanitarywares. The presence of spodumene results in enhancement of mullitization and imparts better physical and mechanical properties to ceramics. In this study, the influence of Lithium alumina silicate phases on the mechanical properties of standard porcelain stoneware body was investigated. Especially solid-solid reactions were observed between spodumene and quartz or spodumene and clay. These solid-solid reactions bring about a newly formed lithium alumina silicate (LAS) phases. Spodumene allows the development of a low viscosity liquid phase and results in a decrease in closed porosity, also with increase in bulk density, bending strength and elastic modulus.


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