scholarly journals Use of pedological maps in the identification of sensitivity of soils to acidic deposition: application to Brazilian soils

2004 ◽  
Vol 76 (1) ◽  
pp. 139-145 ◽  
Author(s):  
Adolpho J. Melfi ◽  
Celia R. Montes ◽  
Adilson Carvalho ◽  
Maria Cristina Forti
Keyword(s):  
Spatial Distribution ◽  
Clay Minerals ◽  
Acidic Deposition ◽  
Clay Fraction ◽  
Terrestrial Ecosystem ◽  
Environmental Studies ◽  
Saline Soils ◽  
Variable Amount ◽  
Brazilian Soils ◽  
Soil Distribution

The pedogeochemical maps present the spatial distribution of soils according to crystalochemical parameters (clay fraction) and physic-chemical aspects of the sorting complex (CEC and BS). These maps are adequate tool for environmental studies and particularly, for the analysis of the terrestrial ecosystem sensibility to acidic deposition. The pedogeochemical maps of the Brazilian soils, elaborated using FAO SoilWorld Map, allowed establishing the soil distribution according to 5 classes of vulnerability to acidic deposition, as defined by Stockholm Environmental Institute (SEI). From these maps, it is observed that about 50% of the Brazilian soils are high vulnerable to acidic deposition and can be included within the most sensitive class. This group is formed by well-developed and mature soils, constituted by clay minerals of kaolinite type associated with variable amount of gibbsite. About 8% of the soils can be considered as the least sensitive class. They correspond to Topomorphic Vertisols (Vertissolo, Embrapa 1999), Planosols (Planossolo, Embrapa 1999) and saline soils. Finally, the remaining soils represent the balanced media that dominate the northeastern semiarid zones and the south and northeastern subtropical zones.

scholarly journals Influence of Bottom Sediments Physicochemical Characteristics on Distribution of Microelements in the Crimean Shelf Water Areas

2020 ◽  
Author(s):  
E. A. Kotelyanets ◽  
K. I. Gurov ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Spatial Distribution ◽  
Organic Carbon ◽  
Bottom Sediments ◽  
Clay Fraction ◽  
Zinc Content ◽  
Physicochemical Characteristics ◽  
Water Area ◽  
Pollution Level

The paper presents the results of studies of the Kalamitsky Bay bottom sediments pollution level with microelements and heavy metals (Pb, Zn, Cu, Ni, Co, Cr, V, As, Sr, Ti, Fe, Mn) in comparison with the content of these microelements and heavy metals in the Balaklava Bay sediments. The paper analyzes data obtained during expeditions on the R/V Professor Vodyanitsky in the Kalamitsky Gulf in August 2011 (seaward part) and on the R/V Rioni in September 2012 (coastal area) as well as in the Balaklava Bay in October 2018. Content of microelements and heavy metals in bottom sediments of the studied water areas was determined by the X-ray fluorescence method using Spectroscan MAX-G device. For the water area of the Kalamitsky Gulf, the features of the studied trace element spatial distribution are considered, groups of trace elements with different spatial distribution patterns are identified. The correlation analysis determined influence of physicochemical characteristics of the sediments on distribution and accumulation of trace elements. In the water area of the Kalamitsky Gulf, a statistically significant correlation was observed of nickel, iron and zinc content with the clay fraction; dependance of increased concentrations of zinc, nickel and chrome on the content of organic carbon and predominance of lead in highcarbonate sediments. For the Balaklava Bay, the maximum positive values of correlations with the pelitic-silty fraction were noted for iron, manganese, vanadium and chrome; organic carbon correlates with chrome, iron, nickel and copper, whereas carbonates correlate with strontium. Similar patterns were observed earlier in the Sevastopol region bays, Feodosiya Gulf and Kerch Strait.

scholarly journals GENESIS AND PHYSICAL CHARACTERISTICS OF THE NEOGENE RED BEDS FROM THE CEDARHILS OF THESSALONIKI, MACEDONIA , GREECE

2018 ◽  
Vol 36 (2) ◽  
pp. 708 ◽  
Author(s):  
A. Tsirambides
Keyword(s):  
Clay Minerals ◽  
Urban Forest ◽  
Clay Fraction ◽  
Eastern Mediterranean Region ◽  
Physical Characteristics ◽  
Coarse Grained ◽  
Red Beds ◽  
Primary Minerals ◽  
In Situ Weathering

The genesis and the physical characteristics of the Neogene red beds of the cedar hills surrounding Thessaloniki are studied in this paper. The peri-urban forest, which covers these hills, has a 3,022 ha area. The topographic relief is smooth and is divided in eight small drainage basins, tapped through small creeks. The elevation of the surrounding hills varies between 85 and 560 m. The dominant land slopes vary between 20 and 55%. All the samples are coarse grained, poorly sorted and friable and present earthy lustre and red colour because of the extensive presence of iron oxides. Angular to sub-angular rock fragments derived from the metamorphic bedrock are very common. Petrographically, the studied red beds belong to the clayey sands. The extended presence (41-66%) of coarse silt and sand size grains (>20 pm) in the samples suggests a mild intensity of in situ weathering of the bedrock. X-ray diffraction analysis of the coarsest fractions 250-20 pm and 20-2 μιτι revealed in decreasing abundance the presence of quartz, feldspars, epidote, micas, chlorite, pyroxenes, amphiboles, and talc. These fractions contain the 2M polytype of mica, while in the fraction <2 pm the 1Μα polytype of illite predominates. In the clay fraction (<2 pm) illite, smectite, and chlorite predominate. The presence of mixed-layer minerals is limited, testifying the almost complete character of hydrolysis of the primary minerals. The formation of red beds took place on low relief land under alternating wet and dry seasons, which prevail in the eastern Mediterranean region since Neogene. The clay minerals are the in situ weathering products of the primary minerals of the greenschists, gneisses and gabbros predominating in the studied area. The extensive presence of clay size grains (11-26%) in the samples, their poor sorting, and their sub-angular morphology, indicate that the red beds are texturally immature. In addition, the abundance of feldspars and Fe-Mg minerals reflects mineralogical immaturity. The low relief and the long-lasting tectonic stability in the Thessaloniki district were essential for the significant thickness of the red beds. The oxygen isotope data of the <0.2 pm fraction (+18.2 to +18.8%o) confirm the pedogenic origin of the clay minerals present. The red beds studied present low plasticity with liquid limit (WÏ) 26.9 to 33.4% and plasticity index (lp) 9.1 to 17.3%. In addition, they have high consolidation index (lc) values (1.03 to 2.28). The swelling potential is low to medium and the activity varies between 0.5 and 1.0. The consolidation and induration degree of the samples analyzed is low, because of the great range of their mineralogical composition and the mild conditions of pressure and temperature to which they have been submitted. The studied red beds are not considered problematic for the foundation of various constructions on them.

scholarly journals The Occurrence of Authigenic Clay Minerals in Alkaline-Saline Lakes, Pantanal Wetland (Nhecolândia Region, Brazil)

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 718
Author(s):  
Isis Armstrong Dias ◽  
Leonardo Fadel Cury ◽  
Bruno Guimarães Titon ◽  
Gustavo Barbosa Athayde ◽  
Guilherme Fedalto ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Clay Minerals ◽  
Saline Lakes ◽  
Clay Fraction ◽  
Water Bodies ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Fine Clay ◽  
Pantanal Wetland

Mg clay minerals are usually associated with carbonates in alkaline-saline environments, precipitated from solution and/or transformation from other minerals. The aim of this research is to identify the mineralogy and geochemistry of clay minerals in different alkaline lakes in the Nhecolândia region, the southernmost region of the Pantanal wetland (Brazil). Sediment samples were analyzed by X-ray diffraction, X-ray fluorescence, scanning electron microscopy and transmission electron microscopy. Water samples were analyzed, determining their main cations and anions, in order to understand their relationship with the clays. The analyses allowed classifying the water bodies as saline, oligosaline and freshwater lakes. The sediments are composed mainly of quartz and a fine-clay fraction, dominated by illite, kaolinite and smectite. The XRD results showed illite and smectite mixed-layered in the saline lakes at Barranco Alto farm, whereas at Nhumirim farm, trioctahedral smectite was only observed in one lake. The smectite minerals were normally identified coupled with calcite at the top of the sequences, associated with exopolymeric substances (EPS) in the lakes, suggesting that these minerals are precipitating due to the physical-chemical and biological conditions of the water bodies.

Physicochemical properties of protein-smectite and protein-Al(OH)x-smectite complexes

Clay Minerals ◽  
1995 ◽  
Vol 30 (4) ◽  
pp. 325-336 ◽  
Author(s):  
A. Violante ◽  
A. de Cristofaro ◽  
M.A. Rao ◽  
L. Gianfreda
Keyword(s):  
Physicochemical Properties ◽  
Clay Minerals ◽  
Adsorption Isotherms ◽  
Electrostatic Interactions ◽  
Clay Fraction ◽  
Electrostatic Forces ◽  
Molecular Weights ◽  
Protein Molecules ◽  
Isoelectric Points ◽  
Heating Treatment

AbstractProteins (catalase, albumin, pepsin and lysozyme with different molecular weights and isoelectric points) were differently adsorbed at pH 7.0 on the clay fraction of three raw Na-saturated smectites (Crook and Uri montmorillonites and one hectorite). The adsorption isotherms of proteins on clay minerals showed typical Langmuir characteristics. Lysozyme was adsorbed under the effect of electrostatic interactions between the opposite charges of clay surfaces and protein molecules, whereas catalase and albumin were adsorbed under the effect of non-electrostatic forces. Pepsin was held in relatively high amounts only on the surfaces of hectorite. Proteins were intercalated in the interlayers spaces of smectites, usually undergoing extensive unfolding. Protein-smectite complexes showed different behaviour to heating treatment. Some complexes remained practically unchanged after heating at 200°C. Presence of ‘wrecks’ of interlayered materials was found after heating at 500°C for two hours. The amounts of proteins adsorbed on the external and interlamellar surfaces of clay minerals, partially coated with OH-Al species, were much lower than those fixed on the clean clays. Only lysozyme was intercalated in chlorite-like complexes.

Investigation of the Clay Fraction (<2 μm) of the Clay Minerals Society Reference Clays

2002 ◽  
Vol 50 (3) ◽  
pp. 388-400 ◽  
Author(s):  
Christoph Vogt ◽  
Jörn Lauterjung ◽  
Reinhard X. Fischer
Keyword(s):  
Clay Minerals ◽  
Clay Fraction

scholarly journals Competition between plant functional types in the Canadian Terrestrial Ecosystem Model (CTEM) v. 2.0

2016 ◽  
Vol 9 (1) ◽  
pp. 323-361 ◽  
Author(s):  
J. R. Melton ◽  
V. K. Arora
Keyword(s):  
Spatial Distribution ◽  
Large Scale ◽  
Terrestrial Ecosystem ◽  
Ecosystem Model ◽  
Plant Functional Types ◽  
Atmospheric Composition ◽  
Climate Modelling ◽  
Fractional Coverage ◽  
Terrestrial Ecosystem Model ◽  
Functional Types

Abstract. The Canadian Terrestrial Ecosystem Model (CTEM) is the interactive vegetation component in the Earth system model of the Canadian Centre for Climate Modelling and Analysis. CTEM models land–atmosphere exchange of CO2 through the response of carbon in living vegetation, and dead litter and soil pools, to changes in weather and climate at timescales of days to centuries. Version 1.0 of CTEM uses prescribed fractional coverage of plant functional types (PFTs) although, in reality, vegetation cover continually adapts to changes in climate, atmospheric composition and anthropogenic forcing. Changes in the spatial distribution of vegetation occur on timescales of years to centuries as vegetation distributions inherently have inertia. Here, we present version 2.0 of CTEM, which includes a representation of competition between PFTs based on a modified version of the Lotka–Volterra (L–V) predator–prey equations. Our approach is used to dynamically simulate the fractional coverage of CTEM's seven natural, non-crop PFTs, which are then compared with available observation-based estimates. Results from CTEM v. 2.0 show the model is able to represent the broad spatial distributions of its seven PFTs at the global scale. However, differences remain between modelled and observation-based fractional coverage of PFTs since representing the multitude of plant species globally, with just seven non-crop PFTs, only captures the large-scale climatic controls on PFT distributions. As expected, PFTs that exist in climate niches are difficult to represent either due to the coarse spatial resolution of the model, and the corresponding driving climate, or the limited number of PFTs used. We also simulate the fractional coverage of PFTs using unmodified L–V equations to illustrate its limitations. The geographic and zonal distributions of primary terrestrial carbon pools and fluxes from the versions of CTEM that use prescribed and dynamically simulated fractional coverage of PFTs compare reasonably well with each other and observation-based estimates. The parametrization of competition between PFTs in CTEM v. 2.0 based on the modified L–V equations behaves in a reasonably realistic manner and yields a tool with which to investigate the changes in spatial distribution of vegetation in response to future changes in climate.

Swelling clayey soils promote slope instability in the Muhunguzi watershed, western Burundi

2020 ◽  
Author(s):  
Bruno Delvaux ◽  
Clairia Kankurize ◽  
Gervais Rufyikiri
Keyword(s):  
Clay Minerals ◽  
Clay Fraction ◽  
Slope Instability ◽  
Atterberg Limits ◽  
Intense Rainfall ◽  
Angle Of Friction ◽  
Red Soils ◽  
Soil Cohesion ◽  
Internal Angle ◽  
Water Saturated

&lt;p&gt;In Burundi, landslides are frequent on the western slope of the Congo-Nile ridge. Unfortunately, they are poorly studied and understood despite their deadly consequences. Previous reports have suggested that slope steepness, lithology and clay soils expose this slope to landslides, while heavy and intense rainfall is a trigger. However, the role of soil in the vulnerability of this specific slope to landslides is unknown. Here we investigate on soil characteristics involved in land sliding in this area.&lt;/p&gt;&lt;p&gt;We selected and sampled black and red soils in two Muhunguzi landslides. We determined the soil plasticity from Atterberg limits as well as the particle size distribution. In addition, we measured the soil weathering stage, and further identified the clay minerals from measuring the cation exchange capacity of the clay fraction and analyzing clay samples with X-ray diffraction (XRD).&lt;/p&gt;&lt;p&gt;Both the black and red soils are moderately weathered since TRB values in the B horizons range between 330 and 425 cmol(+) kg&lt;sup&gt;-1&lt;/sup&gt;. The soils are loamy clayey to clayey (% clay: 33-55%), and contain high charge clay minerals. They do not differ in their Atterberg limits, which classify the soils as medium plasticity soils in the Casagrande plasticity diagram. Our data further show that both soils have a medium swelling potential. XRD show that the clay fraction consists of kaolinite and smectite and/or vermiculite. The latter 2:1 clay minerals are expandable and swelling clays, respectively. They give these two soils their plasticity and swelling properties. These two properties play an important role in the mechanical behavior of water-saturated soils. Indeed, swelling reduces soil cohesion while the plasticity index and the liquidity limit vary inversely with the internal angle of friction of the soil; cohesion and internal angle of friction being the fundamental parameters of the soil shear resistance. In addition, the soil mantle covers a hard schistose rock whose declivity is parallel to the soil surface slope. Thus, after intense rainfall during the wet season, the water-saturated soil reaches a level of liquidity sufficient to favor a landslide, all the more easily if the slope of the hard rock is inclined in the direction of the gravity flow.gru&lt;/p&gt;

scholarly journals Evolution with depth from detrital to authigenic smectites in sediments from AND-2A drill core (McMurdo Sound, Antarctica)

Clay Minerals ◽  
2012 ◽  
Vol 47 (4) ◽  
pp. 481-498 ◽  
Author(s):  
F. Iacoviello ◽  
G. Giorgetti ◽  
F. Nieto ◽  
I. T. Memmi
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Clay Minerals ◽  
Clay Fraction ◽  
Drill Core ◽  
Mcmurdo Sound ◽  
Volcanic Material ◽  
The Core ◽  
Diagenetic Processes ◽  
Scanning Electron

AbstractWe have examined the nature and origin of smectites in glaciomarine sediments of the AND-2A drill core (McMurdo Sound, Antarctica) by means of X-ray diffraction (XRD) analyses on the clay fraction, field emission scanning electron microscopy (FESEM), scanning electron microscopy (SEM) observations and SEM-EDS microanalyses on smectite particles. Relying on the smectite variation throughout the drill core it was possible to split the sequence into three units. Smectites throughout the core are either detrital or authigenic. Detrital smectites are close to montmorillonite-beidellite in composition while newly-formed smectites frequently have higher Fe-Mg contents and intermediate compositions between the saponite and nontronite field, with lower amounts in the montmorillonite-beidellite field. In the upper sedimentary sections (Unit I, and Unit II, 36-440 mbsf, 0.7-16.5 Ma) smectites are interpreted to be predominantly detrital, whereas in the lower portion of the core (Unit III, 440-1123.20 mbsf, 16.5-20.2 Ma) authigenic smectites are the most common feature. The predominance of mica, the abundance of chlorite, and the nature of smectites in the upper units indicate physical weathering under cold and dry climate, and a dominant provenance for the clay minerals from the Transantarctic Mountains. Smectites in the lower unit are considered mostly authigenic and they are most likely to be the result of early diagenetic processes, being formed from the alteration of volcanic material (glass, pyroxenes and feldspars) and/or through precipitation from fluids of a possible hydrothermal origin. Our survey attests to the importance of discriminating between a detrital and authigenic nature of smectites as the occurrence of authigenic clay minerals in ancient sedimentary successions might lead to incorrect palaeoclimatic interpretations, since they can be affected by diagenetic processes, thus obliterating the climatic signal.

scholarly journals Mineralogical Study of Levels with Magnesian Clay Minerals in the Santos Basin, Aptian Pre-Salt Brazil

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 970
Author(s):  
Maurício Dias da Silva ◽  
Márcia Elisa Boscato Gomes ◽  
André Sampaio Mexias ◽  
Manuel Pozo ◽  
Susan Martins Drago ◽  
...  
Keyword(s):  
Clay Minerals ◽  
Clay Fraction ◽  
Total Sample ◽  
Petrographic Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mineralogical Study ◽  
Original Rock ◽  
Mixed Layers

The object of this study is magnesian clay minerals present in carbonate rocks of the post-rift phase of the pre-salt in the Santos Basin. These rocks developed in an Aptian-age alkaline lacustrine environment. This study summarizes the formation of clay minerals associated with different lithotypes in a range of 19 m and a depth of more than 5100 m. They were characterized from petrographic analysis by optical microscopy, X-ray diffraction (total sample and clay fraction), and modeling by Newmod®; and examined and analyzed by scanning electron microscopy. An approach based on identifying lithotypes and characterization of microsites allowed us to understand the occurrence of different clay minerals. Kerolite was the most abundant mineral in the sampled range. It occurs in lamellar aggregates under greater preservation of the original rock lamination and in association with spherulites and shrubs. The Stv/Ker mixed layers occurs in the same association, and formed finer unlaminated aggregates associated with the more intense dolomitization and silicification processes. Saponite occurs associated with detrital minerals forming clayey levels intercalated with microcrystalline carbonates. Fluids with a high Mg/Si and pH < 9 favor the precipitation of kerolite. The increase in pH during diagenesis may be responsible for the formation of Stv/Ker mixed layers.

scholarly journals Mineralogical composition and physical characteristics of marly soils from Heraklion Crete

2001 ◽  
Vol 34 (3) ◽  
pp. 851
Author(s):  
Α. ΤΣΙΡΑΜΠΙΔΗΣ ◽  
Θ. ΠΑΠΑΛΙΑΓΚΑΣ
Keyword(s):  
Clay Minerals ◽  
Clay Fraction ◽  
Soil Classification ◽  
Mineralogical Composition ◽  
Liquid Limit ◽  
Silty Clay ◽  
High Plasticity ◽  
Degree Of Consolidation ◽  
Very High

The mainly white-yellow marly soils studied present medium degree of consolidation and induration. The predominant grain size of the non - carbonate constituents is that of silt varying from 34 to 64%. According to the textural classification of soils of the SSDS the samples are mainly silty-clay loams with moisture capacity 30-40%. In the untreated samples in decreasing abundance the following minerals predominate: calcite (31-59%), clay minerals (20-34%) and quartz (12-20%). In the clay fraction (<2μπι) in decreasing abundance the following clay minerals (in discrete and interstratified phases) predominate: illite, smectite and vermiculite. Chlorite and kaolinite are missing. Mineralogically the marly soils are immature, because of the extended presence of Fe-Mg minerals (i.e. amphiboles, pyroxenes and clay minerals). According to the Unified Soil Classification System of the ASTM the studied marly soils mainly belong to the groups MH and CH (inorganic silts and inorganic clays respectively with high plasticity and liquid limit >50%), as well as to the group CL (inorganic clays with low plasticity and liquid limit <50%). The degree of consolidation and induration, as well as of compaction of these soils is medium. They contain significant amounts of discrete or interstratified smectite and mainly present high to very high swelling potential and activity between 0.5 and 2.0. It is concluded that specific precautions must be taken into account, when it is unavoidable the foundation of various constructions on these marly soils, because they swell and shrink extensively.

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