MODELING OF THE CURING PROCESS OF A POLYMER RESIN AND CHANGES IN MICROHARDNESS IN ITS VOLUME

2021 ◽  
pp. 92-99
Author(s):  
V.I. Postnov ◽  
◽  
S.M. Kachura ◽  
E.A. Veshkin ◽  
◽  
...  

Curing parameters have the greatest impact on the physical and mechanical properties of FRP, therefore their optimum value is of particular importance for obtaining quality products. During curing temperature of the inner layers of the FRP can increase unevenly, which can lead to the formation of a gradient in the degree of conversion and heterogeneity of physical and mechanical properties. The article is devoted to the development of a mathematical model of the curing process of the EDT-69N resin, taking into account the kinetic parameters of curing and implementation thermophysical modeling using the finite element method. The correspondence of the family of curves for the degree of conversion along the sample cross-section and the family of microhardness curves is also shown.

2018 ◽  
Vol 7 (4.35) ◽  
pp. 258 ◽  
Author(s):  
Che Nor Aiza Jaafar ◽  
Muhammad Asyraf Muhammad Rizal ◽  
Ismail Zainol

The mechanical performance of silica modified epoxy at various concentration of sodium hydroxide for surface treatment of multi-axial kenaf has been analyzed. Epoxy resin with amine hardener was modified with silica powder at 20 phr and toughened by treated kenaf fiber that immerses in various concentrations of sodium hydroxide (NaOH) ranging from 0% to 9% of weight. The composite was analyzed through differential scanning calorimetry (DSC) to ensure complete curing process. The mechanical properties of the composites were analyzed through flexural test, Charpy impact test and DSC to ensure the complete curing process. DSC analysis results show epoxy sample was completely cured at above 73°C that verifies the curing temperature for preparation for the composite. Hence, 3% NaOH treated composite exhibits the best mechanical properties, with 10.6 kJ/m2 of impact strength, 54.1 MPa of flexural strength and 3.5 GPa of flexural modulus. It is due to the improvement of fiber-matrix compatibility. Analysis by SEM also revealed that a cleaner surface of kenaf fiber treated at 3% NaOH shown cleaner surface, thus, in turn, improve surface interaction between fiber and matrix of the composite. The composites produced in this work has high potential to be used in automotive and domestics appliances.


2019 ◽  
Vol 109 ◽  
pp. 00093 ◽  
Author(s):  
Olena Slashchova ◽  
Ihor Slashchov ◽  
Iryna Sapunova

The article is devoted to development of methods for geofiltration calculations with taking into account peculiarities of changes of the rock physical and mechanical properties at water saturation. Methods: mathematical modeling of geomechanical and filtration processes with the help of finite element method and laboratory and underground studies. A mathematical model was formulated for solving a problem of elasticity theory by the finite element method, which took into account peculiarities of water-saturated rocks. Pattern of stress-strain state changing in the fractured water-saturated rocks under the action of critical loads, which occurred around the preparatory roadways during their operation, were established. In order to solve the filtration problems, a bank of collected initial data on physical and mechanical properties of water-saturated rocks was processed with the help of variation coefficients, which were taken into account by the method, which assumed calculation of the model loading with critical parameters.


e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Morteza Ehsani ◽  
Ali Akbar Yousefi ◽  
Saeed Samiei Yeganeh

AbstractThe use of dynamic viscosity/time (temperature) cure curves is seen as a powerful technique to quantify formulation and resin design parameters. The behaviour of different thermoset powder coating systems, epoxy/polyester (50/50, 40/60 and 30/70) as well as the impact of the filler, the curing temperature and the frequency upon gel-time have been examined based upon the rheological measurements and compared with PE/TGIC systems. Two disparate methodologies have been utilized to determine gel-time. The behaviour of dissimilar systems bearing different formulations has been compared by means of the non-isothermal DSC test. The effects of resin percentage and the formulation on physical and mechanical properties of coating have been studied.


Author(s):  
Hiroyuki Sato ◽  
Qiang Yu ◽  
Ryusuke Sone

Since the flexural rigidity of thin semiconductor package becomes much lower than normal components, the warpage of the component becomes a much more important issue to evaluate the reliability. In this study the author propose a new practical method to measure the real time curing deformation and the elastic modulus of the resin during the whole curing process. The thermal deformation of the resin under curing was measured by using the optical digital image correlation method. Next, to examine the mechanical properties of the resin, the liquid resin was poured into an aluminum frame with thin sole, and the bending rigid of the aluminum frame was measured by the three points bending test every minutes at the curing temperature of the resin. Based upon the experimented result, the warpage of a package caused of curing shrinkage was simulated.


2017 ◽  
Vol 36 (15) ◽  
pp. 1099-1115 ◽  
Author(s):  
Yu Qing Cui ◽  
Zhong Wei Yin ◽  
Hu Lin Li

In recent years, composite bearings are increasingly employed in marine and heavy load situations due to the specific properties of composites. However, for the tape winding composite bearings, the tension in process has not been studied in depth. In this study, a device was manufactured to apply tension to the process and the prepreg tape was T300/epoxy. Specimens with different tension values were selected for the experiment and the autoclave technology was applied to the curing process. Then, the appearance image and roundness of the bearing composites were acquired. Meanwhile, physical and mechanical properties of the specimen as well as the residual stress were measured. The experimental results show that the influence of tension in winding process on bearing composites is significant and the optimum tension can be defined. Subsequently, the article analyzes the function of the tension and it is concluded that the wrinkles and waves on the surface of the T300/epoxy bearing composites can be eliminated using proper method and the optimum tension should be determined through testing and experiment.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1565
Author(s):  
Ehsan Rostami-Tapeh-Esmaeil ◽  
Ali Vahidifar ◽  
Elnaz Esmizadeh ◽  
Denis Rodrigue

With the ever-increasing development in science and technology, as well as social awareness, more requirements are imposed on the production and property of all materials, especially polymeric foams. In particular, rubber foams, compared to thermoplastic foams in general, have higher flexibility, resistance to abrasion, energy absorption capabilities, strength-to-weight ratio and tensile strength leading to their widespread use in several applications such as thermal insulation, energy absorption, pressure sensors, absorbents, etc. To control the rubber foams microstructure leading to excellent physical and mechanical properties, two types of parameters play important roles. The first category is related to formulation including the rubber (type and grade), as well as the type and content of accelerators, fillers, and foaming agents. The second category is associated to processing parameters such as the processing method (injection, extrusion, compression, etc.), as well as different conditions related to foaming (temperature, pressure and number of stage) and curing (temperature, time and precuring time). This review presents the different parameters involved and discusses their effect on the morphological, physical, and mechanical properties of rubber foams. Although several studies have been published on rubber foams, very few papers reviewed the subject and compared the results available. In this review, the most recent works on rubber foams have been collected to provide a general overview on different types of rubber foams from their preparation to their final application. Detailed information on formulation, curing and foaming chemistry, production methods, morphology, properties, and applications is presented and discussed.


2019 ◽  
Vol 974 ◽  
pp. 535-541
Author(s):  
Galina M. Kravchenko ◽  
Elena V. Trufanova ◽  
Artem S. Osadchiy ◽  
Alina Sazonova

The aim of the work is to study the ways to strengthen the elements of the parametric architecture object framework based on the use of the new materials. The problem of strengthening the elements of the building frame is particularly relevant in connection with the development of the parametric architecture. Unlike the traditional methods of regulation and amplification, composite materials allow to change the stress-strain state and improve the dynamic characteristics of the parametric architecture object without increasing its own structures weight. The studies were performed using numerical simulation by the finite element method. Recommendations are given on the use of the physical and mechanical properties of the composite materials when strengthening the building framework.


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