scholarly journals Assessment of K-Struvite Precipitation as a Means of Nutrient Recovery From Source Separated Human Urine

2021 ◽  
Author(s):  
Işık Kabdaşlı ◽  
Sezen Kuşçuoğlu ◽  
Olcay Tünay ◽  
Alessio Siciliano
Keyword(s):  
Human Urine ◽  
Solid Phase ◽  
Domestic Wastewater ◽  
Ammonia Removal ◽  
Effect Of Temperature ◽  
Recovery Efficiency ◽  
Struvite Precipitation ◽  
Reaction Stoichiometry ◽  
Performance Results ◽  
The Impact

The impact of nutrients on the environment, particularly on water bodies, has led to extensive studies for nutrient control. Within this context, studies have been focused on source separation of human urine from domestic wastewater to recover nutrients. Potassium is one of the most important components of human urine. However, data on potassium removal or recovery are quite limited except for some indirect information through use of zeolites for mostly ammonia removal. Potassium struvite or K-struvite (MgKPO4·6H2O) is a sparingly soluble salt belonging to struvite and has the potential of being used as a means of potassium and phosphate recovery from segregated human urine. This study aimed to assess the potential of K-struvite precipitation for control and recovery of nutrients. Within this context, K-struvite precipitation experiments were performed on both synthetically prepared samples and synthetic human urine solution to determine effect of operation parameters i.e. pH, stoichiometry, and temperature on potassium recovery performance. Results indicated that process performance as well as type of solid phases co-precipitated with K-struvite were closely related to initial potassium concentration, pH and reaction stoichiometry. At pH 10, the potassium recovery efficiency was maximized up to 87% by application of 100% excess dose of Mg and P for both synthetic samples and synthetic human urine solution. On the other hand, application of excess dose of K did not provide any improvement in K recovery efficiency. The effect of temperature on solubility of K-struvite was insignificant at the temperature of 24-90°C. Solid phase analyses confirmed that K-struvite was co-precipitated with either Mg3(PO4)2, MgNaPO4·7H2O, or MgHPO4·7H2O depending on pH and stoichiometry instead of a pure compound.

Effect of magnesium dose on amount of pharmaceuticals in struvite recovered from urine

2015 ◽  
Vol 72 (7) ◽  
pp. 1102-1110 ◽  
Author(s):  
Patiya Kemacheevakul ◽  
Surawut Chuangchote ◽  
Sosuke Otani ◽  
Tomonari Matsuda ◽  
Yoshihisa Shimizu
Keyword(s):  
Human Urine ◽  
Molar Ratio ◽  
Recovery Efficiency ◽  
P Recovery ◽  
Struvite Precipitation

Phosphorus (P) recovery was carried out through struvite precipitation from urines. Human urine, however, contains not only high nutrients for plants, such as P and nitrogen, but also pharmaceuticals and hormones. In this work, effects of magnesium (Mg) dose (in terms of Mg:P ratio) on P recovery efficiency and pharmaceutical amounts contained in struvite were investigated. Batch-scale experiments of synthetic and human urines revealed that struvite precipitation formed more X-shaped crystals with an increased molar ratio of Mg:P, while the amount of pharmaceuticals (tetracycline, demeclocycline, and oxytetracycline) in struvite decreased with an increased molar ratio of Mg:P. The lowest pharmaceutical amounts in struvite were found at the Mg:P ratio of 2:1 from both samples. Moreover, the maximum P recovery efficiency, quantity and purity of struvite were found in the range of 1.21 to 2:1. It indicated that the molar ratio of Mg:P has a significant impact on struvite precipitation in terms of pharmaceutical amounts in struvite; morphology, quantity and purity of struvite; and P recovery.

Integrating anaerobic processes into wastewater treatment

2011 ◽  
Vol 63 (7) ◽  
pp. 1459-1466 ◽  
Author(s):  
E. J. McAdam ◽  
D. Lüffler ◽  
N. Martin-Garcia ◽  
A. L. Eusebi ◽  
J. N. Lester ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Energy Balance ◽  
Domestic Wastewater ◽  
Granular Sludge ◽  
Ammonia Removal ◽  
Net Energy ◽  
Methane Recovery ◽  
Anaerobic Processes ◽  
Unit Operations ◽  
The Impact

Over the past decade, the concept of anaerobic processes for the treatment of low temperature domestic wastewater has been introduced. This paper uses a developed wastewater flowsheet model and experimental data from several pilot scale studies to establish the impact of integrating anaerobic process into the wastewater flowsheet. The results demonstrate that, by integrating an expanded granular sludge blanket reactor to treat settled wastewater upstream of the activated sludge process, an immediate reduction in imported electricity of 62.5% may be achieved for a treated flow of c. 10,000 m3 d−1. This proposed modification to the flowsheet offers potential synergies with novel unit processes including physico-chemical ammonia removal and dissolved methane recovery. Incorporating either of these unit operations can potentially further improve the flowsheet net energy balance to between +0.037 and +0.078 kWh m−3 of produced water. The impact of these secondary unit operations is significant as it is this contribution to the net energy balance that facilitates the shift from energy negative to energy positive wastewater treatment.

Development of Strategies for Glycopeptide Synthesis: An Overview on the Glycosidic Linkage

2020 ◽  
Vol 24 (21) ◽  
pp. 2475-2497
Author(s):  
Andrea Verónica Rodríguez-Mayor ◽  
German Jesid Peralta-Camacho ◽  
Karen Johanna Cárdenas-Martínez ◽  
Javier Eduardo García-Castañeda
Keyword(s):  
Chemical Synthesis ◽  
Solid Phase ◽  
Building Blocks ◽  
Heterogeneous Environments ◽  
Phase Synthesis ◽  
Low Concentrations ◽  
Biological Sources ◽  
Synthetic Routes ◽  
The Impact ◽  
Potential Use

Glycoproteins and glycopeptides are an interesting focus of research, because of their potential use as therapeutic agents, since they are related to carbohydrate-carbohydrate, carbohydrate-protein, and carbohydrate-lipid interactions, which are commonly involved in biological processes. It has been established that natural glycoconjugates could be an important source of templates for the design and development of molecules with therapeutic applications. However, isolating large quantities of glycoconjugates from biological sources with the required purity is extremely complex, because these molecules are found in heterogeneous environments and in very low concentrations. As an alternative to solving this problem, the chemical synthesis of glycoconjugates has been developed. In this context, several methods for the synthesis of glycopeptides in solution and/or solid-phase have been reported. In most of these methods, glycosylated amino acid derivatives are used as building blocks for both solution and solid-phase synthesis. The synthetic viability of glycoconjugates is a critical parameter for allowing their use as drugs to mitigate the impact of microbial resistance and/or cancer. However, the chemical synthesis of glycoconjugates is a challenge, because these molecules possess multiple reaction sites and have a very specific stereochemistry. Therefore, it is necessary to design and implement synthetic routes, which may involve various protection schemes but can be stereoselective, environmentally friendly, and high-yielding. This review focuses on glycopeptide synthesis by recapitulating the progress made over the last 15 years.

Introduction to geomicrobiology

2018 ◽  
Author(s):  
David L. Kirchman
Keyword(s):  
Fossil Fuels ◽  
Solid Phase ◽  
Direct Reduction ◽  
Iron Oxidation ◽  
Mineral Dissolution ◽  
Precipitation Process ◽  
Soluble Ions ◽  
Chemolithoautotrophic Bacteria ◽  
The Impact

Geomicrobiology, the marriage of geology and microbiology, is about the impact of microbes on Earth materials in terrestrial systems and sediments. Many geomicrobiological processes occur over long timescales. Even the slow growth and low activity of microbes, however, have big effects when added up over millennia. After reviewing the basics of bacteria–surface interactions, the chapter moves on to discussing biomineralization, which is the microbially mediated formation of solid minerals from soluble ions. The role of microbes can vary from merely providing passive surfaces for mineral formation, to active control of the entire precipitation process. The formation of carbonate-containing minerals by coccolithophorids and other marine organisms is especially important because of the role of these minerals in the carbon cycle. Iron minerals can be formed by chemolithoautotrophic bacteria, which gain a small amount of energy from iron oxidation. Similarly, manganese-rich minerals are formed during manganese oxidation, although how this reaction benefits microbes is unclear. These minerals and others give geologists and geomicrobiologists clues about early life on Earth. In addition to forming minerals, microbes help to dissolve them, a process called weathering. Microbes contribute to weathering and mineral dissolution through several mechanisms: production of protons (acidity) or hydroxides that dissolve minerals; production of ligands that chelate metals in minerals thereby breaking up the solid phase; and direct reduction of mineral-bound metals to more soluble forms. The chapter ends with some comments about the role of microbes in degrading oil and other fossil fuels.

scholarly journals Effect of temperature, CO2 and O2 on motility and mobility of Anisakidae larvae

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Aiyan Guan ◽  
Inge Van Damme ◽  
Frank Devlieghere ◽  
Sarah Gabriël
Keyword(s):  
Enzymatic Digestion ◽  
Infected Fish ◽  
Effect Of Temperature ◽  
Video Recordings ◽  
Different Temperatures ◽  
Semi Solid ◽  
Zoonotic Parasites ◽  
The Impact ◽  
Phosphate Buffered Saline

AbstractAnisakidae, marine nematodes, are underrecognized fish-borne zoonotic parasites. Studies on factors that could trigger parasites to actively migrate out of the fish are very limited. The objective of this study was to assess the impact of different environmental conditions (temperature, CO2 and O2) on larval motility (in situ movement) and mobility (migration) in vitro. Larvae were collected by candling or enzymatic digestion from infected fish, identified morphologically and confirmed molecularly. Individual larvae were transferred to a semi-solid Phosphate Buffered Saline agar, and subjected to different temperatures (6 ℃, 12 ℃, 22 ℃, 37 ℃) at air conditions. Moreover, different combinations of CO2 and O2 with N2 as filler were tested, at both 6 °C and 12 °C. Video recordings of larvae were translated into scores for larval motility and mobility. Results showed that temperature had significant influence on larval movements, with the highest motility and mobility observed at 22 ℃ for Anisakis spp. larvae and 37 ℃ for Pseudoterranova spp. larvae. During the first 10 min, the median migration of Anisakis spp. larvae was 10 cm at 22 ℃, and the median migration of Pseudoterranova spp. larvae was 3 cm at 37 ℃. Larval mobility was not significantly different under the different CO2 or O2 conditions at 6 °C and 12 ℃. It was concluded that temperature significantly facilitated larval movement with the optimum temperature being different for Anisakis spp. and Pseudoterranova spp., while CO2 and O2 did not on the short term. This should be further validated in parasite-infected/spiked fish fillets.

scholarly journals Effect of extreme cold temperatures on quasi-static indentation and impact behavior of woven carbon fiber epoxy composite sandwich panels with nomex honeycomb core

2021 ◽  
pp. 109963622199387
Author(s):  
Mathilde Jean-St-Laurent ◽  
Marie-Laure Dano ◽  
Marie-Josée Potvin
Keyword(s):  
Epoxy Composite ◽  
Impact Behavior ◽  
Effect Of Temperature ◽  
Cold Temperatures ◽  
Composite Sandwich Panels ◽  
Composite Sandwich ◽  
Static Indentation ◽  
Nomex Honeycomb ◽  
Extreme Cold ◽  
The Impact

The effect of extreme cold temperatures on the quasi-static indentation and the low velocity impact behavior of woven carbon/epoxy composite sandwich panels with Nomex honeycomb core was investigated. Impact tests were performed at room temperature, –70°C, and –150°C. Two sizes of hemispherical impactor were used combined to three different impactor masses. All the impact tests were performed at the same initial impact velocity. The effect of temperature on the impact behavior is investigated by studying the load history, load-displacement curves and transmitted energy as a function of time curves. Impact damage induced at various temperatures was studied using different non-destructive and destructive techniques. Globally, more damages are induced with impact temperature decreasing. The results also show that the effect of temperature on the impact behavior is function of the impactor size.

A solid-phase extraction method that eliminates matrix effects of complex pulp mill effluents for the analysis of lipophilic wood extractives

2020 ◽  
Vol 35 (4) ◽  
pp. 577-588
Author(s):  
Sebastian España Orozco ◽  
Philipp Zeitlinger ◽  
Karin Fackler ◽  
Robert H. Bischof ◽  
Antje Potthast
Keyword(s):  
Solid Phase Extraction ◽  
Matrix Effects ◽  
Solid Phase ◽  
Internal Standard ◽  
Pulp Mill ◽  
Phase Extraction ◽  
Wood Extractives ◽  
Wood Extractive ◽  
Pulp Mill Effluents ◽  
The Impact

AbstractThe extraction of lipophilic wood extractives from pulp and paper process waters proves to be a challenging task, due to harsh and alternating process and sample conditions. This study has determined the potential use of polymeric sorbents for solid-phase extraction (SPE) and compared to classical silica-based reversed-phase packed columns, with polymeric hydrophilic-lipophilic balanced (HLB) cartridges being the sorbent with the most potential. Recovery functions were obtained with an internal standard mixture representative for the main lipophilic wood extractive groups, which are fatty acids and alcohols, sterols, sterol esters and triglycerides. The impact of pH, sample volume and sample matrix, expressed as TOC and cations, on the retention behavior of lipophilic extractives during SPE of industrial samples were determined with polymeric HLB sorbent. High variations in the composition of pulp mill matrices led to different optimal extraction conditions. Thus, a new SPE protocol was developed, which bypasses matrix interferences and omits the loss of analytes due to sample preparation. The method is applicable to different pulp mill effluents with large discrepancies in pH and sample matrices, resulting in recoveries >90 % with RSD <5 % for all lipophilic wood extractives.

scholarly journals The modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo, China

2021 ◽  
Vol 22 (1) ◽  
Author(s):  
Rui Zhang ◽  
Yujie Meng ◽  
Hejia Song ◽  
Ran Niu ◽  
Yu Wang ◽  
...  
Keyword(s):  
Air Pollution ◽  
High Temperature ◽  
Air Pollutants ◽  
Meteorological Data ◽  
Effect Of Temperature ◽  
Distributed Lag ◽  
Modification Effect ◽  
Incidence Risk ◽  
The Impact ◽  
The Relationship

Abstract Background Although exposure to air pollution has been linked to many health issues, few studies have quantified the modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo, China. Methods The data of daily incidence of influenza and the relevant meteorological data and air pollution data in Ningbo from 2014 to 2017 were retrieved. Low, medium and high temperature layers were stratified by the daily mean temperature with 25th and 75th percentiles. The potential modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo was investigated through analyzing the effects of air pollutants stratified by temperature stratum using distributed lag non-linear model (DLNM). Stratified analysis by sex and age were also conducted. Results Overall, a 10 μg/m3 increment of O3, PM2.5, PM10 and NO2 could increase the incidence risk of influenza with the cumulative relative risk of 1.028 (95% CI 1.007, 1.050), 1.061 (95% CI 1.004, 1.122), 1.043 (95% CI 1.003, 1.085), and 1.118 (95% CI 1.028, 1.216), respectively. Male and aged 7–17 years were more sensitive to air pollutants. Through the temperature stratification analysis, we found that temperature could modify the impacts of air pollution on daily incidence of influenza with high temperature exacerbating the impact of air pollutants. At high temperature layer, male and the groups aged 0–6 years and 18–64 years were more sensitive to air pollution. Conclusion Temperature modified the relationship between air pollution and daily incidence of influenza and high temperature would exacerbate the effects of air pollutants in Ningbo.

scholarly journals Spatio-Temporal Variation Characteristics of Snow Depth and Snow Cover Days over the Tibetan Plateau

Water ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 307
Author(s):  
Chi Zhang ◽  
Naixia Mou ◽  
Jiqiang Niu ◽  
Lingxian Zhang ◽  
Feng Liu
Keyword(s):  
Tibetan Plateau ◽  
Snow Cover ◽  
Snow Depth ◽  
Feedback Effect ◽  
Effect Of Temperature ◽  
The Tibetan Plateau ◽  
Reanalysis Dataset ◽  
Spatio Temporal ◽  
The Impact ◽  
Main Factor

Changes in snow cover over the Tibetan Plateau (TP) have a significant impact on agriculture, hydrology, and ecological environment of surrounding areas. This study investigates the spatio-temporal pattern of snow depth (SD) and snow cover days (SCD), as well as the impact of temperature and precipitation on snow cover over TP from 1979 to 2018 by using the ERA5 reanalysis dataset, and uses the Mann–Kendall test for significance. The results indicate that (1) the average annual SD and SCD in the southern and western edge areas of TP are relatively high, reaching 10 cm and 120 d or more, respectively. (2) In the past 40 years, SD (s = 0.04 cm decade−1, p = 0.81) and SCD (s = −2.3 d decade−1, p = 0.10) over TP did not change significantly. (3) The positive feedback effect of precipitation is the main factor affecting SD, while the negative feedback effect of temperature is the main factor affecting SCD. This study improves the understanding of snow cover change and is conducive to the further study of climate change on TP.

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