scholarly journals Impact of Temperature on the Phase Transition TiO2 Nanoparticles

Author(s):  
Nagaraj G

Abstract Unadulterated TiO2 nanoparticles have been set up by a novel Photon Induced Method (PIM) without antecedent alteration. The pre-arranged example has been calcinated at 500°C, 700°C and 1000°C to consider the impact of calcinations temperature on the security, stage and morphology of TiO2. XRD investigation uncovers an intriguing aftereffect of increment with regards to stage dependability. This might be accounted to the oxygen extravagance of the example which has been affirmed through EDAX. XRD results likewise revel a stage change from anatase to rutile with expanding calcination temperature. The morphologic examination performed with HRSEM and HRTEM revel a change from nanoparticles to nanorods. The development of TiO2 is affirmed through the Ti-O vibrational tops in FTIR and the band hole of the examples have been inspected with UV-vis Spectrophotometer. The pre-arranged examples with such high stage steadiness might be applied for photocatalytic application.

2020 ◽  
Vol 10 (3) ◽  
pp. 993 ◽  
Author(s):  
Siripond Phromma ◽  
Tuksadon Wutikhun ◽  
Panita Kasamechonchung ◽  
Tippabust Eksangsri ◽  
Chaweewan Sapcharoenkun

In this work, TiO2 nanoparticles were successfully synthesized with narrow size distribution via a wet ball milling sol-gel method. The effect of calcination temperature on photocatalytic activity was observed from particle size, crystallite size, and phase transition of TiO2 nanoparticles. Increasing calcination temperature increased particle size, crystallite size, and the crystallinity of synthesized TiO2. Phase transition depended on variation in calcination temperatures. A two-phase mixture of anatase and brookite was obtained with lower calcination temperature whereas a three-phase mixture appeared when calcination temperature was 500–600 °C. With higher temperature, the rutile phase kept increasing until it was the only phase observed at 800 °C. Anatase strongly affected the photocatalytic activity from 300 °C to 600 °C while the particle size of TiO2 was found to have a dominant effect on the photocatalytic activity between 600 °C and 700 °C. A mixture of three phases of TiO2-600 exhibited the highest methylene blue degradation with the rate constant of 9.46 × 10−2 h−1 under ultraviolet (UV) irradiation.


2018 ◽  
Vol 1 (1) ◽  
pp. 1
Author(s):  
Murisal Murisal

Motif and Impact of Early Marriage in Indarung Ngalau Batu Gadang.Penelitian is motivated by teenagers who married early on. Today, young men and women have a tendency to be less prepared to enter the home life, they are only ready to marry (ready here can be interpreted, maturity in terms of financial, understand what the meaning of marriage according to marriage law) is the bond of inner birth between a man and a woman as husband and wife for the purpose of forming a happy and eternal family (household) based on the Supreme Godhead while they are not ready to set up a home, whereas to build a household requires preparation both physically and spiritually . The purpose of this study to determine the motives underlying adolescents to make early marriage and the impact caused in the household as a result of the marriage.


Author(s):  
Mark Burden

Much eighteenth-century Dissenting educational activity was built on an older tradition of Puritan endeavour. In the middle of the seventeenth century, the godly had seen education as an important tool in spreading their ideas but, in the aftermath of the Restoration, had found themselves increasingly excluded from universities and schools. Consequently, Dissenters began to develop their own higher educational institutions (in the shape of Dissenting academies) and also began to set up their own schools. While the enforcement of some of the legal restrictions that made it difficult for Dissenting institutions diminished across the eighteenth century, the restrictions did not disappear entirely. While there has been considerable focus on Dissenting academies and their contribution to debates about doctrinal orthodoxy, the impact of Dissenting schools was also considerable.


The theory of the vibrations of the pianoforte string put forward by Kaufmann in a well-known paper has figured prominently in recent discussions on the acoustics of this instrument. It proceeds on lines radically different from those adopted by Helmholtz in his classical treatment of the subject. While recognising that the elasticity of the pianoforte hammer is not a negligible factor, Kaufmann set out to simplify the mathematical analysis by ignoring its effect altogether, and treating the hammer as a particle possessing only inertia without spring. The motion of the string following the impact of the hammer is found from the initial conditions and from the functional solutions of the equation of wave-propagation on the string. On this basis he gave a rigorous treatment of two cases: (1) a particle impinging on a stretched string of infinite length, and (2) a particle impinging on the centre of a finite string, neither of which cases is of much interest from an acoustical point of view. The case of practical importance treated by him is that in which a particle impinges on the string near one end. For this case, he gave only an approximate theory from which the duration of contact, the motion of the point struck, and the form of the vibration-curves for various points of the string could be found. There can be no doubt of the importance of Kaufmann’s work, and it naturally becomes necessary to extend and revise his theory in various directions. In several respects, the theory awaits fuller development, especially as regards the harmonic analysis of the modes of vibration set up by impact, and the detailed discussion of the influence of the elasticity of the hammer and of varying velocities of impact. Apart from these points, the question arises whether the approximate method used by Kaufmann is sufficiently accurate for practical purposes, and whether it may be regarded as applicable when, as in the pianoforte, the point struck is distant one-eighth or one-ninth of the length of the string from one end. Kaufmann’s treatment is practically based on the assumption that the part of the string between the end and the point struck remains straight as long as the hammer and string remain in contact. Primâ facie , it is clear that this assumption would introduce error when the part of the string under reference is an appreciable fraction of the whole. For the effect of the impact would obviously be to excite the vibrations of this portion of the string, which continue so long as the hammer is in contact, and would also influence the mode of vibration of the string as a whole when the hammer loses contact. A mathematical theory which is not subject to this error, and which is applicable for any position of the striking point, thus seems called for.


2021 ◽  
Vol 13 (12) ◽  
pp. 6875
Author(s):  
Irene Poza-Casado ◽  
Raquel Gil-Valverde ◽  
Alberto Meiss ◽  
Miguel Ángel Padilla-Marcos

Indoor air quality (IAQ) in educational buildings is a key element of the students’ well-being and academic performance. Window-opening behavior and air infiltration, generally used as the sole ventilation sources in existing educational buildings, often lead to unhealthy levels of indoor pollutants and energy waste. This paper evaluates the conditions of natural ventilation in classrooms in order to study how climate conditions affect energy waste. For that purpose, the impact of the air infiltration both on the IAQ and on the efficiency of the ventilation was evaluated in two university classrooms with natural ventilation in the Continental area of Spain. The research methodology was based on site sensors to analyze IAQ parameters such as CO2, Total Volatile Organic Compounds (TVOC), Particulate Matter (PM), and other climate parameters for a week during the cold season. Airtightness was then assessed within the classrooms and the close built environment by means of pressurization tests, and infiltration rates were estimated. The obtained results were used to set up a Computational Fluid Dynamics (CFD) model to evaluate the age of the local air and the ventilation efficiency value. The results revealed that ventilation cannot rely only on air infiltration, and, therefore, specific controlled ventilation strategies should be implemented to improve IAQ and to avoid excessive energy loss.


2021 ◽  
pp. 112067212110307
Author(s):  
Julia Sieberer ◽  
Patrick Hughes ◽  
Indy Sian

Objectives: The coronavirus pandemic has forced healthcare staff across all medical specialties to adapt new and different ways of working. A new approach has been set up in the Acute Referral Clinic (ARC) at Musgrove Park Hospital and a survey has been conducted to measure the impact of the new method on patient and healthcare professionals’ satisfaction with the new service. Methods: A telephone-based consultation was introduced in ARC at Musgrove Park Hospital in March 2020 and patients were instructed to fill out a questionnaire containing eight items using a Likert Scale 1 (‘very poor/disagree’) to 4 (‘very good/strongly agree’) plus two boxes for open positive and negative comments respectively. Likewise a questionnaire was designed in order to assess the healthcare professionals’ satisfaction using the new approach. Data collection took place over a two month period between the end of March 2020 and end of May 2020. The data underwent quality control and was analysed using descriptive statistics. Results: Patient responses illustrated high satisfaction scores with an overall rating of very good (89.4%). The healthcare professionals’ rating of the service was good (28.6% – ‘very good/strongly agree’, 57.1% – ‘good/agree’). The safety rating of the new approach was overall rated ‘very good’ with 90.4% and 71.4% of patients and healthcare professionals respectively. Conclusions: The telephone consultations introduced in the wake of COVID-19 are well accepted by both patients and doctors. There are some limitations of the approach, foremost being consultation time and clinic space but these do not outweigh the general benefit of this format amidst a pandemic setting.


2014 ◽  
Vol 70 (a1) ◽  
pp. C67-C67
Author(s):  
Babak Mostaghaci ◽  
Brigitta Loretz ◽  
Robert Haberkorn ◽  
Guido Kickelbick ◽  
Claus-Michael Lehr

Calcium phosphate has been the point of interest for in vitro gene delivery for many years because of its biocompatibility and straight forward application. However, there are some limitations regarding in vivo administration of these particles mostly because of vast agglomeration of the particles and lack of strong bond between the particles and pDNA. We introduced a simple single step method to functionalize calcium phosphate nanoparticles with Aminosilanes having a different number of amine groups. The nanoparticles were characterized chemically and structurally and their toxicity and interaction with pDNA were studied as well. Results revealed that different crystalline phase of calcium phosphate nanoparticles (Brushite and Hydroxyapatite) with a size below 150 nm were prepared, depending on conditions of synthesis and phase, each with a narrow size distribution. The aminosilane agents caused oriented nucleation and growth of crystallites and can decrease the pH for producing hydroxyapatite phase. The phenomenon could be revealed with the presence of anisotropy in the structure of synthesized hydroxyapatite. The number of amine groups in the Aminosilane agent could change the phase transition pH. Brushite particles revealed to have stronger interaction with pDNA mostly because of their higher positive surface charge. Both particles showed blood compatibility and negligible toxicity. Transfection experiment revealed the capability of both brushite and hydroxyapatite particles to transfect A549 and HEK293 cells. The new modified nanoparticles can be stored in a dried state and re-dispersed easily at the time of administration. Moreover, the transfection efficiency is higher in comparison with conventional calcium phosphate. This study showed the impact of presence and type of the modifying agent on the crystal structure and the amount of surface functionalization of nanoparticles, which in consequence influenced their interaction with cells.


Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 602
Author(s):  
Elmar C. Fuchs ◽  
Jakob Woisetschläger ◽  
Adam D. Wexler ◽  
Rene Pecnik ◽  
Giuseppe Vitiello

A horizontal electrohydrodynamic (EHD) liquid bridge (also known as a “floating water bridge”) is a phenomenon that forms when high voltage DC (kV·cm−1) is applied to pure water in two separate beakers. The bridge, a free-floating connection between the beakers, acts as a cylindrical lens and refracts light. Using an interferometric set-up with a line pattern placed in the background of the bridge, the light passing through is split into a horizontally and a vertically polarized component which are both projected into the image space in front of the bridge with a small vertical offset (shear). Apart from a 100 Hz waviness due to a resonance effect between the power supply and vortical structures at the onset of the bridge, spikes with an increased refractive index moving through the bridge were observed. These spikes can be explained by an electrically induced liquid–liquid phase transition in which the vibrational modes of the water molecules couple coherently.


Author(s):  
Ana Guerberof Arenas ◽  
Joss Moorkens ◽  
Sharon O’Brien

AbstractThis paper presents results of the effect of different translation modalities on users when working with the Microsoft Word user interface. An experimental study was set up with 84 Japanese, German, Spanish, and English native speakers working with Microsoft Word in three modalities: the published translated version, a machine translated (MT) version (with unedited MT strings incorporated into the MS Word interface) and the published English version. An eye-tracker measured the cognitive load and usability according to the ISO/TR 16982 guidelines: i.e., effectiveness, efficiency, and satisfaction followed by retrospective think-aloud protocol. The results show that the users’ effectiveness (number of tasks completed) does not significantly differ due to the translation modality. However, their efficiency (time for task completion) and self-reported satisfaction are significantly higher when working with the released product as opposed to the unedited MT version, especially when participants are less experienced. The eye-tracking results show that users experience a higher cognitive load when working with MT and with the human-translated versions as opposed to the English original. The results suggest that language and translation modality play a significant role in the usability of software products whether users complete the given tasks or not and even if they are unaware that MT was used to translate the interface.


Water Policy ◽  
2013 ◽  
Vol 15 (S1) ◽  
pp. 9-25 ◽  
Author(s):  
Bharat R. Sharma ◽  
Devaraj de Condappa

The topography of the Ganges basin is highly variable, with the steep mountainous region of the Himalaya upstream and the large fertile plains in eastern India and Bangladesh downstream. The contribution from the glaciers to streamflows is supposed to be significant but there is uncertainty surrounding the impact of climate change on glaciers. An application of the Water Evaluation and Planning model was set up which contained an experimental glaciers module. The model also examined the possible impacts of an increase in temperature. The contribution from glaciated areas is significant (60–75%) in the Upper Ganges but reduces downstream, falling to about 19% at Farakka. Climate change-induced rise in temperature logically increases the quantity of snow and ice that melts in glaciated areas. However, this impact decreases from upstream (+8% to +26% at Tehri dam) to downstream (+1% to +4% at Farakka). Such increases in streamflows may create flood events more frequently, or of higher magnitude, in the upper reaches. Potential strategies to exploit this additional water may include the construction of new dams/reservoir storage and the development of groundwater in the basin through managed aquifer recharge. The riparian states of India, Nepal and Bangladesh could harness this opportunity to alleviate physical water scarcity and improve productivity.


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