Iron Oxide (U–Th)/He Thermochronology: New Perspectives on Faults, Fluids, and Heat

Elements ◽  
2020 ◽  
Vol 16 (5) ◽  
pp. 319-324
Author(s):  
Emily H. G. Cooperdock ◽  
Alexis K. Ault
Keyword(s):  
Fluid Flow ◽  
Iron Oxide ◽  
Heat Exchange ◽  
Iron Oxides ◽  
Fault Zone ◽  
Frictional Heating ◽  
Fault Zones ◽  
Chemical Behavior ◽  
Rock Interaction ◽  
Dynamic Motion

Fault zones record the dynamic motion of Earth’s crust and are sites of heat exchange, fluid–rock interaction, and mineralization. Episodic or long-lived fluid flow, frictional heating, and/or deformation can induce open-system chemical behavior and make dating fault zone processes challenging. Iron oxides are common in a variety of geologic settings, including faults and fractures, and can grow at surface-to magmatic temperatures. Recently, iron oxide (U–Th)/He thermochronology, coupled with microtextural and trace element analyses, has enabled new avenues of research into the timing and nature of fluid–rock interactions and deformation. These constraints are important for understanding fault zone evolution in space and time.

Faults and magma reservoirs along the Southern Andes Volcanic zone (SAVZ): linking oservations and numerical models of stress change controlling magmatic and hydrothermal fluid flow

2020 ◽  
Author(s):  
Javiera Ruz ◽  
Muriel Gerbault ◽  
José Cembrano ◽  
Pablo Iturrieta ◽  
Camila Novoa Lizama ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Stress Field ◽  
Fault Zone ◽  
Numerical Models ◽  
Fluid Pressure ◽  
Seismic Inversion ◽  
Fault Zones ◽  
Fault System ◽  
Far Field ◽  
Trigger Failure

<p> The Chilean margin is amongst the most active seismic and volcanic areas on Earth. It hosts active and fossil geothermal and mineralized systems of economic interest documenting significant geofluid migration through the crust. By comparing numerical models with field and geophysical data, we aim at pinning when and where fluid migration occurs through porous domains, fault zone conduits, or remains stored at depth awaiting a more appropriate stress field. <span>Dyking and volcanic activity occur within fault zones</span> <span>along the S</span><span>A</span><span>VZ, linked with stress field variations</span> <span>in spatial and temporal association with</span> –<span>short therm-</span> <span>seismicity</span> <span>and -long term- oblique </span><span>plate </span><span>convergence.</span> <span>Volcanoes and geothermal domains are mostly located along or at the intersection of margin-oblique fault zones (Andean Transverse Faults), and along margin-parallel strike slip zones, some which may cut the entire lithosphere (Liquiñe-Ofqui fault system). Wh</span><span>ereas</span><span> the big picture displays</span> <span>fluid flow straight to the surface, at close look significant offsets between crustal structures occur. 3D numerical models using conventional elasto-plastic rheology provide insights on the interaction of (i) an inflating magmatic cavity, (ii) a slipping fault zone, and (iii) regional tectonic stresses. Applying either (i) a magmatic overpressure or (ii) a given fault slip can trigger failure of the intervening rock, and generate either i) fault motion or ii) magmatic reservoir failure, respectively, but only for distances less than the structures' breadth even at low rock</span> <span>strength. However, at greater inter-distances the bedrock domain in between the fault zone and the magmatic cavity undergoes dilatational strain of the order of 1-5x10-5. This dilation opens the bedrock’s pore space and forms «pocket domains» that may store up-flowing over-pressurized fluids, which may then further chemically</span> interact<span> with the bedrock, for the length of time</span> <span>that</span> <span>these pockets remain open. These porous pockets</span> <span>can reach kilometric size, questioning their parental link with outcropping plutons along the margin. Moreover, bedrock permeability may also increase as fluid flow diminishes effective bedrock friction and cohesion. Comparison with rock experiments indicates that such stress and fluid pressure changes may eventually trigger failure at the intermediate timescale (repeated slip or repeated inflation). Finally, incorporating far field compression (iii)</span> <span>loads the bedrock to</span> <span>a state of stress at the verge of failure. Then, failure around the magmatic </span><span>reservoir</span><span> or </span><span>at</span> <span>the fault zone occurs for lower load</span><span>ing</span><span>.</span> <span>Permanent tectonic loading on the one hand, far field episodic seismic inversion of the stress field on the other, and localized failure all together promote a transient stress field, thus explaining the occurrence of transient fluid pathways on seemingly independent timescales. These synthetic models are then discussed with regards to specific cases along the SVZ, particularly the Tatara-San Pedro area (~36°S), where magnetotelluric profiles </span><span>document</span><span> conductive volumes at different depths underneath active faults, volcanic edifices and geothermal vents. We discuss the mechanical link between these deep sources and surface structures</span>.</p>

scholarly journals On morphology and amplitude of 2D and 3D thermal anomalies induced by buoyancy-driven flow within and around fault zones

2020 ◽  
Author(s):  
Laurent Guillou-Frottier ◽  
Hugo Duwiquet ◽  
Gaëtan Launay ◽  
Audrey Taillefer ◽  
Vincent Roche ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Fault Zone ◽  
3D Models ◽  
Fault Zones ◽  
Rock Properties ◽  
Thermal Anomalies ◽  
Flow Models ◽  
Temperature Anomalies ◽  
Vertical Fault ◽  
Dip Angle

Abstract. In the first kilometres of the subsurface, temperature anomalies due to heat conduction processes rarely exceed 20–30 °C. When fault zones are sufficiently permeable, fluid flow may lead to thermal anomalies much higher, as evidenced by the emergence of thermal springs or by fault-related geothermal reservoirs. Hydrothermal convection triggered by buoyancy effects creates thermal anomalies whose morphology and amplitude are not well known, especially when depth- and time-dependent permeability are considered. Exploitation of shallow thermal anomalies for heat and power production partly depends on the volume and on the temperature of the hydrothermal reservoir. This study presents a non-exhaustive numerical investigation of fluid flow models within and around simplified fault zones, where realistic fluid and rock properties are accounted for, as well as appropriate boundary conditions. 2D simplified models point out relevant physical mechanisms for geological problems, such as thermal inheritance or splitting plumes showing a pulsating behaviour. When permeability is increased, the classic finger-like upwellings evolve towards a bulb-like geometry, resulting in a large volume of hot fluid at shallow depth. In the simplified 3D models, where fault zone dip angle and fault zone thickness are varied, the anomalously hot reservoir exhibits a kilometre-sized hot air balloon morphology, or, when permeability is depth-dependent, a funnel-shape geometry. For thick faults, the number of thermal anomalies increases but not the amplitude. The largest amplitude (up to 80–90 °C) is obtained for vertical fault zones. At the top of a vertical, 100 m wide, fault zone, temperature anomalies greater than 30 °C may extend laterally over more than 1 km from the fault boundary. These preliminary results should motivate further geothermal investigations of more elaborated models where topography and fault intersections would be accounted for.

Geothermal manifestations in the Tyrrhenian area: the role of faults in channelling superhot geothermal fluids

2021 ◽  
Author(s):  
Martina Zucchi
Keyword(s):  
Fluid Flow ◽  
Fault Zones ◽  
Ore Deposits ◽  
Contact Metamorphism ◽  
Normal Faults ◽  
Geothermal System ◽  
Low Permeability ◽  
Geothermal Systems ◽  
Rock Interaction ◽  
Geothermal Fluids

<div> <p><span>Extensional tectonics and related magmatism affecting continental crust can favour the development of geothermal systems. Granitoids intruded in the upper crust represent the main expression of magmatism; they are strictly controlled by brittle structures during their emplacement and exhumation. The cooling of the magmatic bodies produce a thermal perturbation in the hosting rocks resulting in thermo-metamorphic aureoles of several meter thick, usually characterised by valuable ore deposits. After the emplacement and during the cooling stage such granitoids can promote the geothermal fluids circulation mainly through the fault zones. In case of favourable geological and structural conditions, geothermal fluids can be stored in geological traps (reservoirs), generally represented by rock volumes with sufficient permeability for storing a significant amount of fluid. Traps are confined, at the top, by rocks characterised by low, or very low permeability, referred to as the cap rocks of a geothermal system. Several studies are addressed to the study of fluid migration through the permeable rock volumes, whereas few papers are dealing with fluid flow and fluid-rock interaction within the cap rocks. </span></p> </div><div> <p><span>In this presentation, an example of fault-controlled geothermal fluid within low permeability rocks is presented. The study area is located in the south-eastern side of Elba Island (Tuscan Archipelago, Italy), where a succession made up of shale, marl and limestone (Argille a Palombini Fm, early Cretaceous) was affected by contact metamorphism related to the Porto Azzurro monzogranite, which produced different mineral assemblages, depending on the involved lithotypes. These metamorphic rocks were dissected by high-angle normal faults that channelled superhot geothermal fluids. Fluid inclusions analyses on hydrothermal quartz and calcite suggest that at least three paleo-geothermal fluids permeated through the fault zones, at a maximum P of about 0.8 kbar. The results reveal how brittle deformation induces fluid flow in rocks characterised by very low permeability and allow the characterisation of the paleo-geothermal fluids in terms of salinity and P-T trapping conditions. </span></p> </div>

Geometrical comparison of outcrop data and discrete element models of extensional fault zones in layered carbonates

2020 ◽  
Author(s):  
Hagen Deckert ◽  
Steffen Abe ◽  
Wolfgang Bauer
Keyword(s):  
Fluid Flow ◽  
Fault Zone ◽  
Seismic Data ◽  
Discrete Element ◽  
Fault Zones ◽  
Normal Faults ◽  
Small Displacement ◽  
Small Scale ◽  
Burial Depth ◽  
Multiple Fault

<p>In the course of hydrocarbon or geothermal exploration the characterisation of fault zone architectures is of interest for fluid flow modelling and geomechanical studies. Seismic data normally offer the best information for the identification of fault zone geometries in sedimentary basins. However, the internal structure or the damage zone of a fault can be hardly resolved with seismic data as displacements along single fault strands or fractures are by far too small. Thus, it is not possible to directly map small scale faults with seismic methods, though these structures might significantly influence fluid flow. We try to examine the architecture of extensional fault zones in carbonate rocks at subseismic scales by using discrete element method (DEM) techniques to numerically simulate the evolution of fault zones including their associated damage zones.</p><p>As a case study we have analysed the geometry, displacement and fault width of normal faults in fine grained jurassic limestones in a quarry in Franconia, Germany. The quarry shows a rather simple set of conjugated 60deg dipping normal faults. Displacement is rather small and varies between c. 5cm up to c. 2m, some faults show almost no offset. The fault thickness varies between 2cm and c. 1m. A closer investigation of the fault geometries reveals, next to planar parts, sometimes complex fault zone structures including restraining and releasing bends, multiple fault strands as well as lenses and associated riedel shears. Analysis of high resolution photogrammetric data revealed a high number of small scale fractures between neighbouring discrete fault surfaces which are interpreted as highly fractured damage zones. Some faults with rather small displacement suggest that the overall inclination of the fault is a result of small subvertical sections which are connected in a staircase like appearance. </p><p>The DEM models simulate normal faulting in a layered marl-limestone sequence driven by the displacement of an underlying basement fault. Different layer geometries and effective vertical stresses in the range of 15-45 MPa, equivalent to an overburden thickness of c. 1000-3000m, have been used in the models. The stress range covers the maximum burial depth of the carbonates, which is assumed to be c. 1500m. Material properties used in the DEM were calibrated based on laboratory data, i.e. results of triaxial deformation tests on the studied limestones.</p><p>Results of the models show fault geometries which resemble those observed in the studied outcrop. In particularly under low stress, small offsets and with strongly decoupled layers we observe steeply dipping faults (>70deg) which also show staircase structures composed of sub-vertical fractures within each of the layers and horizontal offsets along the layer interfaces. We also observe the development of multiple fault strands and associated damage zones. </p><p>Our study shows that the DEM models are capable to reproduce observed fault geometries and damage zones. The results help to understand fault zone architectures and depict highly fractured areas in a sub-seismic scale.</p>

scholarly journals On the morphology and amplitude of 2D and 3D thermal anomalies induced by buoyancy-driven flow within and around fault zones

Solid Earth ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 1571-1595 ◽  
Author(s):  
Laurent Guillou-Frottier ◽  
Hugo Duwiquet ◽  
Gaëtan Launay ◽  
Audrey Taillefer ◽  
Vincent Roche ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Fault Zone ◽  
3D Models ◽  
Fault Zones ◽  
Rock Properties ◽  
Thermal Anomalies ◽  
Flow Models ◽  
Temperature Anomalies ◽  
Vertical Fault ◽  
Dip Angle

Abstract. In the first kilometers of the subsurface, temperature anomalies due to heat conduction processes rarely exceed 20–30 ∘C. When fault zones are sufficiently permeable, fluid flow may lead to much larger thermal anomalies, as evidenced by the emergence of thermal springs or by fault-related geothermal reservoirs. Hydrothermal convection triggered by buoyancy effects creates thermal anomalies whose morphology and amplitude are not well known, especially when depth- and time-dependent permeability is considered. Exploitation of shallow thermal anomalies for heat and power production partly depends on the volume and temperature of the hydrothermal reservoir. This study presents a non-exhaustive numerical investigation of fluid flow models within and around simplified fault zones, wherein realistic fluid and rock properties are accounted for, as are appropriate boundary conditions. 2D simplified models point out relevant physical mechanisms for geological problems, such as “thermal inheritance” or pulsating plumes. When permeability is increased, the classic “finger-like” upwellings evolve towards a “bulb-like” geometry, resulting in a large volume of hot fluid at shallow depth. In simplified 3D models wherein the fault zone dip angle and fault zone thickness are varied, the anomalously hot reservoir exhibits a kilometer-sized “hot air balloon” morphology or, when permeability is depth-dependent, a “funnel-shaped” geometry. For thick faults, the number of thermal anomalies increases but not the amplitude. The largest amplitude (up to 80–90 ∘C) is obtained for vertical fault zones. At the top of a vertical, 100 m wide fault zone, temperature anomalies greater than 30 ∘C may extend laterally over more than 1 km from the fault boundary. These preliminary results should motivate further geothermal investigations of more elaborated models wherein topography and fault intersections would be accounted for.

Permeability contrasts of fault zones - from conceptual model to numerical simulation

2020 ◽  
Author(s):  
Ulrich Kelka ◽  
Thomas Poulet ◽  
Luk Peeters
Keyword(s):  
Fluid Flow ◽  
Fault Zone ◽  
Large Scale ◽  
Regional Scale ◽  
Damage Zone ◽  
Fluid Pressure ◽  
Fault Zones ◽  
Strong Impact ◽  
Fault Zone Architecture ◽  
The Impact

<p>Fault and fracture networks can govern fluid flow patterns in the subsurface and predicting fluid flow on a regional scale is of interest in a variety of fields like groundwater management, mining engineering, energy, and mineral resources. Especially the pore fluid pressure can have a strong impact on the strength of fault zones and might be one of the drivers for fault reactivation. Reliable simulations of the transient changes in fluid pressure need to account for the generic architecture of fault zones that comprises strong permeability contrast between the fault core and damage zone.</p><p>Particularly, the distribution and connectivity of large-scale fault zones can have a strong impact on the flow field. Yet, modelling numerically such features in their full complexity remains challenging. Often faults zones are conceptualized as forming exclusively either barriers or conduits to fluid flow. However, a generic architecture of fault zones often comprises a discrete fault core surrounded by a diffuse damage zone and conceptualizing large scale discontinuities simply as a barrier or conduit is unlikely to capture the regional scale fluid flow dynamics. It is known that if the fault zone is hosted in low-permeability strata, such as clays or crystalline rocks, a transversal flow barrier can form along the fault core whereas the fracture-rich fault damage zone represents a longitudinal conduit. In more permeable host-rocks (i.e. sandstones or carbonates) the reverse situation can occur, and the permeability distributions in the damage zones can be governed by the abundance of low-permeability deformation features. A reliable numerical model needs to account for the difference and strong contrasts in fluid flow properties of the core and the damage zone, both transversally and longitudinally, in order to make prediction about the regional fluid flow pattern.</p><p>Here, we present a numerical method that accounts for the generic fault zone architecture as lower dimensional interfaces in conforming meshes during fluid flow simulations in fault networks. With this method we aim to decipher the impact of fault zone architecture on subsurface flow pattern and fluid pressure evolution in fractures and faulted porous media. The method is implemented in a finite element framework for Multiphysics simulations. We demonstrate the impact of considering the more generic geological structure of individual faults on the flow field by conceptualizing discontinuities either as barriers, conduits or as a conduit-barrier system and show were these conceptualizations are applicable in natural systems. We further show that a reliable regional scale fluid flow simulation in faulted porous media needs to account for the generic fault zone architecture. The approach is finally used to evaluate the fluid flow response of statistically parameterised faulted media, in order to investigate the impact and sensitivity of each variable parameter.</p>

Modeling and Experiments of Laser Cladding With Droplet Injection

2005 ◽  
Vol 127 (9) ◽  
pp. 978-986 ◽  
Author(s):  
J. Choi ◽  
L. Han ◽  
Y. Hua
Keyword(s):  
Fluid Flow ◽  
Laser Cladding ◽  
Dynamic Motion ◽  
Cladding Layer ◽  
Melt Pool ◽  
Material Deposition ◽  
Modeling And Experiments ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
The Impact

Laser aided Directed Material Deposition (DMD) is an additive manufacturing process based on laser cladding. A full understanding of laser cladding is essential in order to achieve a steady state and robust DMD process. A two dimensional mathematical model of laser cladding with droplet injection was developed to understand the influence of fluid flow on the mixing, dilution depth, and deposition dimension, while incorporating melting, solidification, and evaporation phenomena. The fluid flow in the melt pool that is driven by thermal capillary convection and an energy balance at the liquid–vapor and the solid–liquid interface was investigated and the impact of the droplets on the melt pool shape and ripple was also studied. Dynamic motion, development of melt pool and the formation of cladding layer were simulated. The simulated results for average surface roughness were compared with the experimental data and showed a comparable trend.

scholarly journals Discovery of Fe7O9: a new iron oxide with a complex monoclinic structure

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Ryosuke Sinmyo ◽  
Elena Bykova ◽  
Sergey V. Ovsyannikov ◽  
Catherine McCammon ◽  
Ilya Kupenko ◽  
...  
Keyword(s):  
Applied Sciences ◽  
Crystal Structure ◽  
Iron Oxide ◽  
Iron Oxides ◽  
Industrial Applications ◽  
Ambient Conditions ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Pressure High Temperature ◽  
Insight Into

Abstract Iron oxides are fundamentally important compounds for basic and applied sciences as well as in numerous industrial applications. In this work we report the synthesis and investigation of a new binary iron oxide with the hitherto unknown stoichiometry of Fe7O9. This new oxide was synthesized at high-pressure high-temperature (HP-HT) conditions, and its black single crystals were successfully recovered at ambient conditions. By means of single crystal X-ray diffraction we determined that Fe7O9 adopts a monoclinic C2/m lattice with the most distorted crystal structure among the binary iron oxides known to date. The synthesis of Fe7O9 opens a new portal to exotic iron-rich (M,Fe)7O9 oxides with unusual stoichiometry and distorted crystal structures. Moreover, the crystal structure and phase relations of such new iron oxide groups may provide new insight into the cycling of volatiles in the Earth’s interior.

Waste Plastic Sachet as Alternative Anti-Corrosion Filler for Iron Oxide in Resin Coatings

2021 ◽  
Vol 877 ◽  
pp. 9-14
Author(s):  
Francis Darwin T. Eugenio ◽  
Bryan B. Pajarito
Keyword(s):  
Corrosion Resistance ◽  
Iron Oxide ◽  
Film Thickness ◽  
Iron Oxides ◽  
Water Resistance ◽  
Inorganic Compounds ◽  
Environmental Issues ◽  
Metal Coatings ◽  
Waste Plastic ◽  
Coating Mixture

Iron oxides and similar inorganic compounds have served as anti-corrosion fillers for metal coatings. Environmental issues related to the mining of metallic fillers have stimulated interest in alternative fillers such as organic fillers. This paper explores the use of comminuted waste plastic sachets (WPS) as an anti-corrosion filler to resin-based metal coating. Mixture design of experiment was used to study the effect of iron oxide-WPS blends on the film thickness, viscosity, corrosion behavior, and water resistance of the coating. Results show that the film thickness was affected by the presence of iron oxide while the viscosity of the coating was affected by high loads of WPS. Among all coatings, the blend containing 25% iron oxide and 75% WPS produced the highest corrosion resistance. In conclusion, comminuted WPS provided additional corrosion resistance and could serve as an alternative anti-corrosion filler.

DETAIL GRAVITY PROFILE ACROSS SAN ANDREAS FAULT ZONE

Geophysics ◽  
1967 ◽  
Vol 32 (2) ◽  
pp. 297-301 ◽  
Author(s):  
S. N. Domenico
Keyword(s):  
Fault Zone ◽  
Mojave Desert ◽  
San Andreas Fault ◽  
Surface Expression ◽  
Fault Zones ◽  
Rock Masses ◽  
San Andreas ◽  
Major Fault ◽  
Reduced Density ◽  
Gravity Profile

A gravity profile was obtained from closely spaced readings along a traverse approximately nine miles in length across the San Andreas fault zone immediately south of Palmdale, California in the western Mojave Desert. Corrected gravity values show a slight but distinctive minimum associated with the fault zone which may be attributed to the reduced density of the shattered rock masses in the fault zone. The existence of this minimum suggests that major fault zones may be traced across terrain, on which surface expression of the fault does not exist, by successive profiles across the suspected position of the fault zone.

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