A Systematic Review on Fluorescent and Colorimetric Chemosensors for Ion Recognition

2021 ◽  
Vol 01 ◽  
Author(s):  
Pravin R. Dongare ◽  
Govind B. Kolekar ◽  
Anil H. Gore
Keyword(s):  
Biological Sciences ◽  
Systematic Review ◽  
Response Time ◽  
Research Group ◽  
High Selectivity ◽  
Low Cost ◽  
Selective Recognition ◽  
Important Species ◽  
Target Metal ◽  
Significant Attention

: The development of fluorescent and colorimetric chemosensors for selective recognition and sensing of cations has received significant attention in recent decades attributed to their diverse applications in the area of environmental and biological sciences. Chemosensors for the detection of different ions offer advantages, such as high selectivity, sensitivity, low cost and rapid response time with versatility. Therefore, a large number of fluorescent/colorimetric chemosensors have been reported for the detection of biologically and environmentally important species. This review introduces the history, provides a general overview of the recent advances in the developments of fluorescent and colorimetric chemosensors, and discusses some innovative and representative works done by our research group and researchers in the field of chemosensors for target metal ions, such as Al3+, Fe3+, Cu2+, Ag+, Cd2+, Hg2+ and Sn2+ over 7 years’ period, from 2013 to 2020.

scholarly journals Estimation of the Inhaled Dose of Pollutants in Different Micro-Environments: A Systematic Review of the Literature

Toxics ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 140
Author(s):  
Francesca Borghi ◽  
Andrea Spinazzè ◽  
Simone Mandaglio ◽  
Giacomo Fanti ◽  
Davide Campagnolo ◽  
...  
Keyword(s):  
Systematic Review ◽  
Residence Time ◽  
Low Cost ◽  
Pulmonary Ventilation ◽  
Personal Exposure ◽  
Ventilation Rate ◽  
Atmospheric Pollutants ◽  
Active Commuting ◽  
Review Of The Literature ◽  
Future Studies

Recently, the need to assess personal exposure in different micro-environments has been highlighted. Further, estimating the inhaled dose of pollutants is considerably one of the most interesting parameters to be explored to complete the fundamental information obtained through exposure assessment, especially if associated with a dose-response approach. To analyze the main results obtained from the studies related to the estimation of the inhaled dose of pollutants in different micro-environments (environments in which an individual spends a part of his day), and to identify the influence of different parameters on it, a systematic review of the literature was performed. The principal outcomes from the considered studies outlined that (i) exposure concentration and residence time are among the most important parameters to be evaluated in the estimation of the inhaled dose, especially in transport environments. Further, (ii) the pulmonary ventilation rate can be of particular interest during active commuting because of its increase, which increases the inhalation of pollutants. From a methodological point of view, the advent of increasingly miniaturized, portable and low-cost technologies could favor these kinds of studies, both for the measurement of atmospheric pollutants and the real-time evaluation of physiological parameters used for estimation of the inhaled dose. The main results of this review also show some knowledge gaps. In particular, numerous studies have been conducted for the evaluation (in terms of personal exposure and estimation of the inhaled dose) of different PM fractions: other airborne pollutants, although harmful to human health, are less represented in studies of this type: for this reason, future studies should be conducted, also considering other air pollutants, not neglecting the assessment of exposure to PM. Moreover, many studies have been conducted indoors, where the population spends most of their daily time. However, it has been highlighted how particular environments, even if characterized by a shorter residence time, can contribute significantly to the dose of inhaled pollutants. These environments are, therefore, of particular importance and should be better evaluated in future studies, as well as occupational environments, where the work results in a high pulmonary ventilation rate. The attention of future studies should also be focused on these categories of subjects and occupational studies.

scholarly journals Broadening the problem agenda of biological individuality: individual differences, uniqueness and temporality

2021 ◽  
Vol 36 (2) ◽  
Author(s):  
Marie I. Kaiser ◽  
Rose Trappes
Keyword(s):  
Biological Sciences ◽  
Individual Differences ◽  
Research Group ◽  
Interdisciplinary Research ◽  
Evolutionary Biology ◽  
Biological Individuality ◽  
Problem Agenda

AbstractBiological individuality is a notoriously thorny topic for biologists and philosophers of biology. In this paper we argue that biological individuality presents multiple, interconnected questions for biologists and philosophers that together form a problem agenda. Using a case study of an interdisciplinary research group in ecology, behavioral and evolutionary biology, we claim that a debate on biological individuality that seeks to account for diverse practices in the biological sciences should be broadened to include and give prominence to questions about uniqueness and temporality. We show that broadening the problem agenda of biological individuality draws attention to underrecognized philosophical issues and discussions and thereby organizes and enriches the existing debate.

Metal-organic framework derived metal oxide/reduced graphene oxide nanocomposite, a new tool for the determination of dipyridamole

2021 ◽  
Author(s):  
Naeime Salandari-Jolge ◽  
Ali A. Ensafi ◽  
Behzad Rezaei
Keyword(s):  
Myocardial Infarction ◽  
Graphene Oxide ◽  
High Performance ◽  
High Selectivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Heart Patients ◽  
Reduced Graphene ◽  
Metal Organic

Dipyridamole is a prescribed medication used to treat cardiovascular diseases, angina pectoris, imaging tests for heart patients, and myocardial infarction. Therefore, high selectivity and sensitivity, low cost, and high-performance speed...

A High-Performance Free-Standing Zn Anode for Flexible Zinc-Ion Batteries

Nanoscale ◽  
2021 ◽  
Author(s):  
Chenxi Gao ◽  
Jiawei Wang ◽  
Yuan Huang ◽  
Zixuan Li ◽  
Jiyan Zhang ◽  
...  
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Low Cost ◽  
High Energy ◽  
Zinc Ion ◽  
High Energy Density ◽  
Free Standing ◽  
Energy Device ◽  
Zn Anode ◽  
Significant Attention

Zinc-ion batteries (ZIBs) have attracted significant attention owing to their high safety, high energy density, and low cost. ZIBs have been studied as a potential energy device for portable and...

PRODUCT DEVELOPMENT IN OPEN DESIGN COMMUNITIES: A PROCESS PERSPECTIVE

2011 ◽  
Vol 08 (04) ◽  
pp. 557-575 ◽  
Author(s):  
CHRISTINA RAASCH
Keyword(s):  
Product Development ◽  
Open Source ◽  
Low Cost ◽  
Industrial Practice ◽  
Open Design ◽  
Open Development ◽  
Development Processes ◽  
Design Projects ◽  
Process Perspective ◽  
Significant Attention

Open source (OS) has raised significant attention in industrial practice and in scholarly research as a new and successful mode of product development. This paper is among the first to study open source development processes outside their original context, the software industry. In particular, we investigate the development of tangible products in so-called open design projects. We study how open design projects address the challenges usually put forward in the literature as barriers to the open development of tangible products. The analysis rests on the comparative qualitative investigation of four cases from different industries. We find that, subject to certain contingencies, open design processes can be organized to resemble OSS development processes to a considerable degree. Some practices are established specifically to uphold OS principles in the open design context, while others starkly differ from those found in OSS development. Our discussion focusses on different aspects of modularity as well as the availability of low-cost tools.

scholarly journals Preparation of Cerium Oxide-MWCNTs Nanocomposite Bulk Modified Carbon Ceramic Electrode: A Sensitive Sensor for Tamoxifen Determination in Human Serum Samples

2021 ◽  
Author(s):  
Sepideh Shafaei ◽  
Elyas Hosseinzadeh ◽  
Gulsah Saydan Kanberoglu ◽  
Balal Khalilzadeh ◽  
Rahim Mohammad-Rezaei
Keyword(s):  
Cerium Oxide ◽  
Limit Of Detection ◽  
Low Cost ◽  
High Electron ◽  
Range Limit ◽  
Serum Samples ◽  
Important Species ◽  
Carbon Ceramic Electrode ◽  
Carbon Ceramic

Abstract In this study, cerium oxide and multi-walled carbon nanotubes nanocomposite was incorporated into the carbon ceramic electrode (CeO2-MWCNTs/CCE) as a renewable electrode for the electrocatalytic purposes. To demonstrate capability of the fabricated electrode, determination of Tamoxifen as an important anticancer drug with differential pulse voltammetry technique was evaluated. Linear range, limit of detection and sensitivity of the developed sensor were found to be 0.2-40 nM, 0.132 nM and 1.478 µA nM-1 cm-2, respectively. Ease of production, low cost and high electron transfer rate of CeO2-MWCNTs/CCE promise it as a novel electro-analytical tool for determination of important species in real samples.

scholarly journals Nucleic acid-based biosensors: analytical devices for prevention, diagnosis and treatment of diseases

Revista Vitae ◽  
2021 ◽  
Vol 28 (3) ◽  
Author(s):  
Laura Carvajal Barbosa ◽  
Diego Insuasty Cepeda ◽  
Andrés Felipe León Torres ◽  
Maria Mercedes Arias Cortes ◽  
Zuly Jenny Rivera Monroy ◽  
...  
Keyword(s):  
Food Safety ◽  
Nucleic Acid ◽  
Nucleic Acids ◽  
Pathogenic Bacteria ◽  
High Selectivity ◽  
Low Cost ◽  
Analytical Techniques ◽  
High Sensitivity ◽  
Disease Status ◽  
Public Health Issue

BACKGROUND : Biosensing techniques have been the subject of exponentially increasing interest due to their performance advantages such as high selectivity and sensitivity, easy operation, low cost, short analysis time, simple sample preparation, and real-time detection. Biosensors have been developed by integrating the unique specificity of biological reactions and the high sensitivity of physical sensors. Therefore, there has been a broad scope of applications for biosensing techniques, and nowadays, they are ubiquitous in different areas of environmental, healthcare, and food safety. Biosensors have been used for environmental studies, detecting and quantifying pollutants in water, air, and soil. Biosensors also showed great potential for developing analytical tools with countless applications in diagnosing, preventing, and treating diseases, mainly by detecting biomarkers. Biosensors as a medical device can identify nucleic acids, proteins, peptides, metabolites, etc.; these analytes may be biomarkers associated with the disease status. Bacterial food contamination is considered a worldwide public health issue; biosensor-based analytical techniques can identify the presence or absence of pathogenic agents in food. OBJECTIVES: The present review aims to establish state-of-the-art, comprising the recent advances in the use of nucleic acid-based biosensors and their novel application for the detection of nucleic acids. Emphasis will be given to the performance characteristics, advantages, and challenges. Additionally, food safety applications of nucleic acid-based biosensors will be discussed. METHODS: Recent research articles related to nucleic acid-based biosensors, biosensors for detecting nucleic acids, biosensors and food safety, and biosensors in environmental monitoring were reviewed. Also, biosensing platforms associated with the clinical diagnosis and food industry were included. RESULTS: It is possible to appreciate that multiple applications of nucleic acid-based biosensors have been reported in the diagnosis, prevention, and treatment of diseases, as well as to identify foodborne pathogenic bacteria. The use of PNA and aptamers opens the possibility of developing new biometric tools with better analytical properties. CONCLUSIONS: Biosensors could be considered the most important tool for preventing, treating, and monitoring diseases that significantly impact human health. The aptamers have advantages as biorecognition elements due to the structural conformation, hybridization capacity, robustness, stability, and lower costs. It is necessary to implement biosensors in situ to identify analytes with high selectivity and lower detection limits.

scholarly journals A water-soluble fluorescent chemosensor based on Asp functionalized naphthalimide for successive detection Fe3+ and H2PO4−

2018 ◽  
Vol 96 (4) ◽  
pp. 363-370 ◽  
Author(s):  
You-Ming Zhang ◽  
Xiao-Peng Chen ◽  
Guo-Yan Liang ◽  
Kai-Peng Zhong ◽  
Hong Yao ◽  
...  
Keyword(s):  
Fluorescence Quenching ◽  
Metal Ions ◽  
Aspartic Acid ◽  
High Selectivity ◽  
Fluorescent Sensor ◽  
Water Solution ◽  
Water Soluble ◽  
Selective Recognition ◽  
Actual Usage ◽  
Quenching Process

The selective recognition of target ions in water is very important and the development of novel water-soluble chemosensor is still an intriguing challenge. Herein, a novel water-soluble fluorescent sensor based on aspartic acid (Asp) functionalized 1,8-naphthalimide derivative (Asp-NI) has been designed and synthesized. The sensor Asp-NI could dissolve in water and successively detect Fe3+ and H2PO4− in water solution with high selectivity and sensitivity. The detection limits are 4.97 × 10−7 mol/L for Fe3+ and 5.27 × 10−6 mol/L for H2PO4−. Other coexistent competitive metal ions (Hg2+, Ag+, Ca2+, Cu2+, Co2+, Ni2+, Cd2+, Pb2+, Zn2+, Cr3+, and Mg2+) showed no interference in the Fe3+ detection process. The sensor Asp-NI could act as a Fe3+ and H2PO4− controlled “On–Off–On” fluorescent switch. More interestingly, the Fe3+ induced fluorescence quenching process could be totally reversed by the addition of H2PO4−, this “On–Off–On” switching process could be repeated several times with little fluorescence loss. Notably, the actual usage of sensor Asp-NI was further demonstrated by test kits.

PASSENGER RESPONSE TIME DATA- SETS FOR LARGE PASSENGER FERRIES AND CRUISE SHIPS DERIVED FROM SEA TRIALS

2021 ◽  
Vol 155 (A2) ◽  
Author(s):  
R Brown ◽  
E R Galea ◽  
S Deere ◽  
L Filippidis
Keyword(s):  
Response Time ◽  
Research Group ◽  
Data Sets ◽  
Time Data ◽  
Evacuation Time ◽  
The Public ◽  
Cruise Ships ◽  
Passenger Ships ◽  
Unique Nature ◽  
The Subject

The paper consists of 27 figures; numerous equations and 12 notes/ references, many of which are written by the authors of this paper. Whilst this may indicate a lack of “reading around the subject” it also indicates the unique nature of the topic and that little exists at present in the public domain about this topic. Indeed the authors and the research group they represent are the main contributors to the IMOs discussions and circulars on this subject. Given that background the paper is very detailed and consists of comparisons between the evacuation times of 3 passenger ships, 2 being Ro-Pax vessels and 1 a cruise liner. On board evacuation time statistics have been gathered from significant populations enabling the authors to draw significant conclusions relating to evacuation times in the presented scenarios. The paper is therefore a useful addition to the debates on this subject which is of major relevance to the understanding of evacuation times in passenger vessels. Data and research in this area is difficult to obtain thus the authors should be congratulated for their work.

Formation of Through-Glass-Via (TGV) by Photo-Chemical Etching with High Selectivity

2012 ◽  
Vol 2012 (1) ◽  
pp. 000785-000792
Author(s):  
Zingway Pei ◽  
Jui-Po Sun ◽  
Hsin-Chen Lai ◽  
Pei-Jer Tzeng ◽  
Cha-Hsin Lin ◽  
...  
Keyword(s):  
Chemical Etching ◽  
High Selectivity ◽  
Laser Energy ◽  
Low Cost ◽  
Etching Rate ◽  
Ultra Violet ◽  
Amorphous Region ◽  
Large Area ◽  
Micro Cracks ◽  
Via Hole

In this work, we utilize a photo-chemical etching (PCE) method to form through-glass-via (TGV). The PCE is a low cost, damage-free and potentially large-area method for TGV formation. An ultra-violet (355 nm) pulse laser was used to illuminate the glass surface. The illuminated region will crystallize after thermal annealing in a furnace. The crystallized glass shows much faster etching rate than the amorphous region in HF solution. For a relatively thick (600 nm) glass, a via-hole with diameter of around 60 μm was demonstrated in laser energy of 11 J/cm2. No laser damages were observed. In comparison, at least 10 times higher energy was required to drill a glass directly. Micro-cracks were form around the glass-via. In addition, a 40 selectivity was achieved to the crystallized and amorphous region. This simple and useful method paves a straight road for 3-D integration.

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