scholarly journals Modern quantitative microstructure analysis on the example of aicu5mg1 alloys

2002 ◽  
pp. 109-114
Author(s):  
Biljana Zlaticanin ◽  
Branislav Radonjic ◽  
Branka Jordovic

Using an automatic, QUANTIMET 500 MC, device for quantitative picture analysis and applying linear method of measurement on the example of AlCu5Mg1 alloys, the grain size (min, max and medium values), as well as relative standard measuring errors (RSE), dendrite arm spacing (DAS) and length eutectic (Le) and also distribution by size (histogram) and volume participation of ?-hard solution and eutectic have been determined. We have also studied the influence of grain-refining additives AlTi5B1 for the same chemical composition of the aluminium-capper-magnesium alloy. It has been concluded that with the increase of titanium content, the mean value of grain size decreases. We have also examined hardness and pressure strength.

2011 ◽  
Vol 702-703 ◽  
pp. 269-272 ◽  
Author(s):  
Abdelhak Ayad ◽  
Nathalie Allain-Bonasso ◽  
Nadjet Rouag ◽  
Francis Wagner

From an EBSD map made on a polycrystal one can define a set of grains using a criterion of misorientation between the adjacent pixels. Once such a list of grains is obtained, various quantities can be associated to each grain such as its size, (mean) orientation, GOS (Grain Orientation Spread) etc... The GOS associated to one grain is the mean value of the misorientations between all the pixels of the grain and the mean orientation of the grain. This value is quite sensitive to the state of the material (degree of plastic deformation, degree of recrystallization for example). Therefore it can help in interpreting the evolution of a microstructure during thermomechanical treatments. It is the purpose of this presentation to provide GOS values for an IF steel after several degrees of plastic deformation as well as after several annealing treatments which lead to partially or totally recrystallized states. The sources of influence on GOS values (as grain detection limit or grain size) are analyzed. The link between the values and the state of the material will be discussed at a global stage for a given population of grains.


The general problem .—“Stellar atmosphere" is the name given loosely to the outer portions of a star. The stellar atmosphere is divided observationally into three superincumbent layers, named the photospheric layers, the reversing layer and the chromosphere, in order of increasing level. The boundaries between these are only roughly defined, but broadly speaking the photospheric layers give rise to the continuous spectrum of the star, the reversing layer to the absorption-line spectrum and the chromosphere (when seen edgeways) to the flash spectrum. Mathematical analysis of the way in which gaseous material comprising the outer portions of a star may be expected to thin out into space confirms this threefold division. It also brings to light certain dynamical and thermal characteristics of the three layers. For example a definite temperature gradient in the photospheric layers shades off into an approximately isothermal state in the chromosphere; “local thermodynamic equilibrium” in the photospheric layers shades off into “monochromatic radiative equilibrium” in the upper chromosphere; and a somewhat unimportant general radiation pressure in the photospheric layers augments to a strong selective radiation-pressure in the reversing layer and chromosphere. The reversing layer is in most cases the transition layer. Assumptions valid for either photospheric layers or chromosphere separately cease to be so near their upper and lower boundaries respectively and so far it has not been possible to give a treatment which accurately deals with the regions of transition. In the present lecture it is proposed to consider chiefly the photospheric layers and the reversing layer. For these regions the dominant need is the determination of the general opacity—the fogginess—for this determines the depth we see into the star and so the pressures, densities, etc., at which the observed spectral phenomena originate. The abstract problem of the stellar atmosphere may be stated as follows. For many purposes the curvature of the outer regions of a star may be neglected and we consider only material stratified in parallel planes. The material is subject to ( a ) a gravitational field of acceleration g , ( b ) a net flux of energy of amount πF per unit area, incident on it from below and emergent into space above. This is determined by the evolution of energy in the interior of the star. The amount of energy actually incident on the atmospheric layers from below exceeds π F, but a portion is re-radiated downwards by the atmospheric layers, π F being the net amount passing through. If the atmospheric layers are in a steady state there is no accumulation of energy, and the net amount of energy crossing any surface of stratification is equal to that crossing any parallel surface, namely π F. The quantity F itself is the mean value of the emergent intensity of radiation at any point, or, what is the same thing, the mean intensity of radiation over the stellar disc. The abstract problem is:— Given the two parameters g and F, and given also the ultimate chemical composition of the material, to determine the distribution of temperature, pressure, density, ionization and chemical composition in the layers, and to determine also the complete intensity-distribution both in angle and in frequency, of the emergent radiation. The practical problem is to some extent the converse one of inferring the temperature and other physical quantities from the observed emergent radiation, i.e ., from the observed spectra, measured if possible spectro-photometrically. In many cases we do not know either g or F, and these also may have to be determined from the observed spectra.


2018 ◽  
Vol 4 ◽  
pp. 38
Author(s):  
Sébastien Lahaye

Nuclear data evaluation files in the ENDF6 format provide mean values and associated uncertainties for physical quantities relevant in nuclear physics. Uncertainties are denoted as Δ in the format description, and are commonly understood as standard deviations. Uncertainties can be completed by covariance matrices. The evaluations do not provide any indication on the probability density function to be used when sampling. Three constraints must be observed: the mean value, the standard deviation and the positivity of the physical quantity. MENDEL code generally uses positively truncated Gaussian distribution laws for small relative standard deviations and a lognormal law for larger uncertainty levels (>50%). Indeed, the use of truncated Gaussian laws can modify the mean and standard deviation value. In this paper, we will make explicit the error in the mean value and the standard deviation when using different types of distribution laws. We also employ the principle of maximum entropy as a criterion to choose among the truncated Gaussian, the fitted Gaussian and the lognormal distribution. Remarkably, the difference in terms of entropy between the candidate distribution laws is a function of the relative standard deviation only. The obtained results provide therefore general guidance for the choice among these distributions.


Author(s):  
F. Kelley St.Charles ◽  
Serban C. Moldoveanu

SummaryThe vapor pressure of nicotine has been reported for unprotonated nicotine and for nicotine-water solutions. Yet no published values exist for nicotine in any commercially relevant matrix or for protonated forms (e.g., tobacco, smoke, electronic cigarette solutions, nicotine replacement products, nicotine salts). Therefore a methodology was developed to measure nicotine activity (defined as the vapor pressure from a matrix divided by the vapor pressure of pure nicotine). The headspace concentration of nicotine was measured for pure nicotine and tobacco stored at 23, 30, and 40 °C which allowed for conversion to vapor pressure and nicotine activity and for the estimation of enthalpy of vaporization. Burley, Flue-cured, Oriental, and cigarette blends were tested. Experiments were conducted with pure nicotine initially until the storage and sampling techniques were validated by comparison with previously published values. We found that the nicotine activity from tobacco was less than 1% with Burley > Flue-cured > Oriental. At 23 °C the nicotine vapor pressure averaged by tobacco type was 0.45 mPa for Oriental tobacco, 1.8 mPa for Flue-cured, 13 mPa for Burley while pure nicotine was 2.95 Pa. In general, the nicotine activity increased as the (calculated) unprotonated nicotine concentration increased. The nicotine enthalpy of vaporization from tobacco ranged from 77 kJ/mol to 92 kJ/mol with no obvious trends with regard to tobacco origin, type, stalk position or even the wide range of nicotine activity. The mean value for all tobacco types was 86.7 kJ/mol with a relative standard deviation of 6.5% indicating that this was an intrinsic property of the nicotine form in tobacco rather than the specific tobacco properties. This value was about 30 kJ/mol greater than that of pure nicotine and is similar to the energy needed to remove a proton from monoprotonated nicotine.


1960 ◽  
Vol 11 (2) ◽  
pp. 149 ◽  
Author(s):  
CS Andrew

The effect of the rates of application of sodium phosphate, potassium chloride, and calcium carbonate on growth, chemical composition, and visual symptoms of deficiency in Trifolium repens var. Irrigation White, grown in a low humic gley soil under subtropical conditions in Queensland, has been investigated. The surface soil is grossly deficient in phosphorus, potassium, and calcium and consists almost entirely of sand (92 per cent.). Additions of sodium phosphate, potassium chloride, and calcium carbonate each increased the yield of clover, increased the phosphorus, potassium, and calcium contents respectively, and conditioned the uptake of other nutrients. Plant material for chemical analyses consisted of petioles and leaves (less senescent and expanding leaves), harvested at the immediate pre-flowering stage of growth. Critical percentages for phosphorus, potassium, and calcium under these conditions were established at 0.23, 1.1, and 1.0 per cent. respectively. Visual symptoms of phosphorus, potassium, and calcium deficiencies are discussed in relation to yield and nutrient content. The sum of the equivalents of potassium, calcium, and magnesium is approximately constant. The mean value of 18 analyses covering all treatments was 136 m-equiv. per cent. with a range of 116-148.


2007 ◽  
Vol 90 (1) ◽  
pp. 6-20 ◽  
Author(s):  
Eric L Miller ◽  
Anthony P Bimbo ◽  
Stuart M Barlow ◽  
Berni SHeridan ◽  
L B W Burks ◽  
...  

Abstract Ten fishmeal samples (hidden duplicates of 4 meals plus 2 high-protein meals as a Youden pair), tryptophan, and nicotinic acid were analyzed by 18 laboratories using the Dumas method. Thirteen of the laboratories also analyzed the same 12 samples using their current Kjeldahl method. Recoveries (± sR) of tryptophan and nicotinic acid were 99.3 ± 1.04 and 98.8 ± 2.11 by Dumas and 97.1 ± 3.03 and 74.6 ± 26.76 by Kjeldahl. The Dumas method gave significantly greater values (P < 0.001) than the Kjeldahl method. For fishmeals, Kjeldahl N 0.989 of Dumas N (P < 0.001). A similar proportionate difference (0.984 of Dumas N) was observed with tryptophan. Most laboratories failed to determine nicotinic acid correctly by Kjeldahl. For fishmeals, the relative standard deviations for repeatability and reproducibility were for Dumas 1.48 and 2.01% and Kjeldahl 1.62 and 2.37%, respectively. A single analysis conducted in 2 laboratories should not differ by more than 5.63% of the mean value when measured by Dumas or by more than 6.64% by Kjeldahl. It is concluded that with fishmeal, Dumas gives a more reliable measure of organic nitrogen than Kjeldahl, and, therefore, Dumas should be the method of choice.


2008 ◽  
Vol 604-605 ◽  
pp. 403-410 ◽  
Author(s):  
Ivan Saxl ◽  
Vaclav Sklenička

The results of intercept and profile counts are commonly interpreted as a suitable estimates of the mean grain size as represented e.g. by the grain density V. The term grain size is not explicitly defined even when some relation to grain volume and/or mean grain breadth (the mean Ferret diameter) is tacitly assumed. However, the intercept count L is directly related to the mean value of grain boundary area per unit volume SV and the profile count A is, under relatively general assumptions, directly related to the mean value of grain junctions per unit volume LV. Their relation to V can be generally written as V = c¢(A)3/2 = c²(L)3, but the coefficients c¢ and c² strongly depend on the structural characteristics like grain size dispersion, anisotropy etc. and their evaluation is far from being simple. Consequently, whereas the reliable estimates of SV and LV result from intercept and profile counts, the estimate of grain density based on them requires a careful consideration.


Author(s):  
Noriyuki Kuwano ◽  
Masaru Itakura ◽  
Kensuke Oki

Pd-Ce alloys exhibit various anomalies in physical properties due to mixed valences of Ce, and the anomalies are thought to be strongly related with the crystal structures. Since Pd and Ce are both heavy elements, relative magnitudes of (fcc-fpd) are so small compared with <f> that superlattice reflections, even if any, sometimes cannot be detected in conventional x-ray powder patterns, where fee and fpd are atomic scattering factors of Ce and Pd, and <f> the mean value in the crystal. However, superlattices in Pd-Ce alloys can be analyzed by electron microscopy, thanks to the high detectability of electron diffraction. In this work, we investigated modulated superstructures in alloys with 12.5 and 15.0 at.%Ce.Ingots of Pd-Ce alloys were prepared in an arc furnace under atmosphere of ultra high purity argon. The disc specimens cut out from the ingots were heat-treated in vacuum and electrothinned to electron transparency by a jet method.


1987 ◽  
Vol 26 (06) ◽  
pp. 253-257
Author(s):  
M. Mäntylä ◽  
J. Perkkiö ◽  
J. Heikkonen

The relative partition coefficients of krypton and xenon, and the regional blood flow in 27 superficial malignant tumour nodules in 22 patients with diagnosed tumours were measured using the 85mKr- and 133Xe-clearance method. In order to minimize the effect of biological variables on the measurements the radionuclides were injected simultaneously into the tumour. The distribution of the radiotracers was assumed to be in equilibrium at the beginning of the experiment. The blood perfusion was calculated by fitting a two-exponential function to the measuring points. The mean value of the perfusion rate calculated from the xenon results was 13 ± 10 ml/(100 g-min) [range 3 to 38 ml/(100 g-min)] and from the krypton results 19 ± 11 ml/(100 g-min) [range 5 to 45 ml/(100 g-min)]. These values were obtained, if the partition coefficients are equal to one. The equations obtained by using compartmental analysis were used for the calculation of the relative partition coefficient of krypton and xenon. The partition coefficient of krypton was found to be slightly smaller than that of xenon, which may be due to its smaller molecular weight.


1968 ◽  
Vol 20 (01/02) ◽  
pp. 044-049 ◽  
Author(s):  
B Lipiński ◽  
K Worowski

SummaryIn the present paper described is a simple test for detecting soluble fibrin monomer complexes (SFMC) in blood. The test consists in mixing 1% protamine sulphate with diluted oxalated plasma or serum and reading the optical density at 6190 Å. In experiments with dog plasma, enriched with soluble fibrin complexes, it was shown that OD read in PS test is proportional to the amount of fibrin recovered from the precipitate. It was found that SFMC level in plasma increases in rabbits infused intravenously with thrombin and decreases after injection of plasmin with streptokinase. In both cases PS precipitable protein in serum is elevated indicating enhanced fibrinolysis. In healthy human subjects the mean value of OD readings in plasma and sera were found to be 0.30 and 0.11, while in patients with coronary thrombosis they are 0.64 and 0.05 respectively. The origin of SFMC in circulation under physiological and pathological conditions is discussed.


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