scholarly journals EKSTRAKSI DAN PENENTUAN GUGUS FUNGSI ASAM HUMAT DARI PUPUK KOTORAN SAPI

2018 ◽  
Vol 1 (1) ◽  
pp. 30
Author(s):  
Nurlina Nurlina ◽  
Intan Syahbanu ◽  
Mirna Tersiana Tamnasi ◽  
Chyntia Nabela ◽  
Maria Desi Furnata

Cow manure fertilizer was used as raw material for the extraction of humic acid in this research. The aim of this research were  extraction of humic acid from cow manure fertilizer, characterization of functional groups based on FTIR spectra, and determination of humic acid functional groups. Humic acid extraction from cow manure used 0.050 M; 0.100 M; 0.250 M dan 0.500 M KOH solution. A cow manure fertilizer were shaken with KOH solution for 1; 2; 4 and 6 h. The quantitative determination of oxygen-containing functional groups of humic acid was conducted by titrimetri. The FTIR spectrum showed the presence of  –OH group and N-H stretching (bands 3361.46 cm-1); C-H aliphatic for CH2, CH3 (2946.52 cm-1 and 1442.24 cm-1); C=C aromatic components (1626.48 cm-1); COO- symmetric stretching (1521.71 cm-1); C-O stretching from –COOH (1229.74 cm-1). Total acidity value was 500 cmole.kg-1 (Baryta Absorption Method); carboxyl groups content was 250 cmole.kg-1 (Ca-Acetate Method); and phenol (OH) concentration was 250 cmole.kg-1. It can be concluded that humic acid successfully extracted from cow manure fertilizer using 0.250 KOH solution as extractant for 2 h, which has  yield of 4.486% humic acid.

2015 ◽  
Vol 1 (1) ◽  
pp. 9-17
Author(s):  
Abdullah Abdullah ◽  
Rina Twinasty ◽  
Taufiqur Rohman

Humic acid is a compound of colloidal,amorphous, and complex aromatic polymerwith functional groups of -COOH (carboxyl), -OH (phenol), and C = O (carbonyl). The presence of these functional groups provides a rationale for assuming that humic acids have a potential to produce phenolic, carboxylic and carbonylic compounds through cracking process. In this study the cracking was done by isolating humic acids from peat soil, and facilitated by a clay catalyst which had been activated. Humic acids were isolated by extracting the acids from the peat with NaOH and HCl. The characterization of humic acids included the determination of the ash content by gravimetric method and the analysis of the functional groups of humic acids by Infrared spectrometer (FTIR). The clay to be activated was shaped into two forms, pellets and 20-40 mesh granules. The clay was activated by immersing it in HCl and NH4NO3, and then calcined. The characterization of catalysts included the determination of acidity and the Si/Al ratio gravimetrically, as well as the analysis of the pore volume, maximum pore radius, surface area and average pore radius by Surface Area Analyzer NOVA-1000. Humic acid cracking was performed by a fixed-bed reactor system at a temperature of 400°C. The Liquid smoke, the product of cracking, was analyzed by GC and GC-MS to determine the number of compounds and major compounds contained in the liquid smoke. The results show that the isolated humic acid had ash content of 9.10%. Activated clay had acidity and Si/Al ratio higher than the clay before actifated. Based on the analyses of GC and GC-MS it can be found out that the major compounds contained in liquid smoke, the product of humic acid cracking with 20-40 mesh catalyst at a temperature of 400°C were phenolic compounds (74.56%), and no carboxylic and carbonylic compounds as the major compounds. The activated clay can be used as the catalyst for humic acid cracking.


2021 ◽  
Vol 6 (1) ◽  
pp. 1-6
Author(s):  
Fahrauk Faramayuda ◽  
Faizal Hermanto ◽  
Ari Sri Windyaswari ◽  
Soraya Riyanti ◽  
Viola Aditya Nurhayati

Bungur  (Lagerstroemia loudonii T. B) is a type of plant widely grown in Indonesia and can be found in teak forests, mixed forests, and is found as ornamental plants or protective trees on the roadside. In the fruit section, Lagerstroemia loudonii is used as antituberculous and antimalarial. On the bark, the part is used as antidiarrheal. Based on some parts of the Lagerstroemia loudonii  plants' activity data, this plant has the potential to be developed into traditional medicine. Standardized traditional medicine material is necessary to identify efficacious compounds and characterization in some parts of Lagerstroemia loudonii. The purpose of this research is to develop Lagerstroemia loudonii into traditional herbal medicine or standardized herbal medicine. Identification of efficacious compounds and characterization of crude leaf drugs, bark, stems, and fruit of Lagerstroemia loudonii. The phytochemical screening phase of the crude drugs of leaves, bark, stems, and fruit ofLagerstroemia loudonii against includes examining alkaloids, flavonoids,  quinones, tannins, polyphenols, saponins, steroids and triterpenes, monoterpenoids and sesquiterpenoids. The determination of the characteristics of raw material carried out includes nonspecific parameters. Nonspecific parameters are the determination of total ash content, water-soluble ash content, acid insoluble ash content. each experiment was carried out three times and calculated the average yield and deviation.  Identification results of the class of efficacious compounds in some parts of the Lagerstroemia loudonii  plant are on the leaves and fruits containing alkaloids, flavonoids, saponins, quinones, tannins, polyphenols, monoterpenoids, and sesquiterpenoids as well as steroids and triterpenoids. At the bark and stem, the bark contains alkaloids, flavonoids, saponins, quinones, tannins, polyphenols, monoterpenoids, and sesquiterpenoids. Characterization results of Lagerstroemia loudonii  leaf extract total ash content 4.45 ± 0.30% w/w, water-soluble ash content 4.08 ± 0.27% w/w, acid insoluble ash content 0.59 ± 0.06% w/w, the extract specific gravity was 0.59 ± 0.063. Lagerstroemia loudonii  stem bark extract, total ash content 1.94 ± 0.12% w/w, water-soluble ash content 1.47 ± 0.03% w/w, acid insoluble ash content 0.24 ± 0.02% w/w, the extract specific gravity is 0.82 ± 0.01. Lagerstroemia loudonii  stem extract, total ash content3.18 ± 0.16% w/w, water-soluble ash content 2.36 ± 0.38% w/w, acid insoluble ash content 0.43 ± 0.07% w/w, extract specific grafity 0.81 ± 0.01. Lagerstroemia loudonii  fruit extract, total ash content 11.45 ± 1.16%w/w, water-soluble ash content 10.1 ± 1.49% w/w, acid insoluble ash content 1.46 ± 0.88% w/w,extract specific grafity 0.81 ± 0.01. Based on phytochemical screening data and the characterization of bungur plants potential to be developed into raw materials for traditional medicineKeywords: Lagerstroemia loudonii, secondary metabolite, raw material characterization


2002 ◽  
Vol 90 (4) ◽  
Author(s):  
C. Barbot ◽  
K. Czerwinski ◽  
Gunnar Buckau ◽  
J. I. Kim ◽  
Valérie Moulin ◽  
...  

SummaryPurified humic acid has been covalently bound on activated epoxy silica gel particles. Determination of physical properties and chemical properties was conducted in order to characterize the material at different stages of the preparation. FTIR spectra and the PEC of the surface bound humic acid is very similar to that of humic acid starting material. This shows that the humic acid was not deteriorated during the surface binding process. This humic gel can be used as an analogue for sediment associated humic acid, with the advantage that covalently bound humic acid does not desorb, and thus allows for simple species separation between non-complexed and humic bound metal ions in batch and column experiments.


2014 ◽  
Vol 484-485 ◽  
pp. 66-69
Author(s):  
Xiu Li Zhao ◽  
Chang Bao Zhang ◽  
Cheng Chen ◽  
Guo Qiao Li ◽  
Da Liu

Description is given to preparation of three ionic liquid surfactants containing amine functional groups, characterization of their functional groups using the infrared spectrometer, determination of their surface tension and the oil displacement test in this paper to investigate the effect of alkane branch chains with different carbon numbers on the surface tension and the displacement efficiency. The result shows that, the surfactants exhibit the structural characteristic of the ionic liquid as the characteristic absorption peaks occur on C-N and C-H of the imidazole rings at the wave numbers of 1338cm-1, 1234cm-1, 1465cm-1 and 3142cm-1, respectively. The surface tension isothermal curves and the oil displacement test proved that the ionic liquid imidazole surfactants with shorter-chain groups are more active on surface, with the minimal surface tension up to 32.5 mN/m, and led to higher displacement efficiency, increasing by 3.3% at the concentration of 1000mg/L compared with the water flooding.


Author(s):  
Irina A. Chetvertneva ◽  
Oleg Kh. Karimov ◽  
Galina A. Teptereva ◽  
Eldar M. Movsumzade

The article proposes a method of increasing the amount of OH-phenolic functional groups in the composition of a macromolecule lignosulphonate, a sulfo-derivative natural lignin polymer, tested under laboratory conditions by step-by-step chemical treatment of the lignosulphonate matrix with a solution of a bromine derivative, then with a solution of neutral sodium sulfite. This makes it possible to solve the problem characteristic of modern lignosulphonates of neutral sulfite production method, which have low values of tannidicity index: content of OH-phenolic groups, quantitative content of which forms inhibitory (tanning) capacity of lignosulphonates. The proposed procedure involves carrying out said demethylation reaction with cleavage of methyl group contained in phenylpropane unit of lignosulfonate. Pyrocatechin groups are formed and methanesulfonic acid molecule is cleaved off. The obtained product was analyzed by UV spectroscopy and the increase in optical density in the area of absorption of 280 nm characteristic of OH-phenolic functional groups was shown, which is the basis for the appearance of pyrocatechin structures in the phenylpropane unit of lignosulfonate. Proposed method allows increasing quantitative content of OH-phenolic groups in macromolecule composition from 1.7% of initial to 6.5%. The obtained results are correlated with the data on determination of tannidicity index - one of objective characteristics of inhibitory (tanning) capacity of lignosulfnates, which is 32%, compared to similar characteristic of undemethylated neutral lignosulfonate, where the value did not exceed 21%. The data show that demethylation of the lignosulphonate matrix is possible by converting modern inactive neutral lignosulphonates from the low-demand waste category of the pulp and paper industry to a promising raw material component.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 695
Author(s):  
Azzeddine Benahsina ◽  
Yassine Taha ◽  
Rachida Bouachera ◽  
Mohamed Elomari ◽  
Mohammed Abdouh Bennouna

The purpose of this research was to evaluate the possibility of using gold mine waste rocks (GMWRs) as alternative raw material for the manufacturing of fired bricks. The feasibility study was assessed through (i) physical, chemical, mineralogical and environmental characteristics of GMWRs; (ii) determination of the natural clay (NC) substitution effect when using GMWRs; (iii) the effect of the firing temperature on the mechanical and physical properties of the fired bricks. Five mixtures of NC and GMWRs were studied. The percentages of substitution of NC with GMWRs varied from 0 to 100%. The brick specimens were fired at 900 °C, 1000 °C and 1050 °C. The results show that increasing the firing temperature improved the flexural strength and density of the bricks, while the substitution of NC with GMWRs caused a reduction in the mechanical resistance of the bricks and an increase in their porosity and, consequently, their water absorption rate. However, the properties of bricks that contained up to 80 wt% of GMWRs and fired at 1000 °C and 1050 °C satisfied the requirements set by the applicable civil engineering and environmental standards. This was found to be an efficient and sustainable solution to mitigate environmental hazards and better manage mining wastes, concurrently producing marketable products from them, which is in accordance with the circular economy concept.


2019 ◽  
Vol 70 (01) ◽  
pp. 37-41 ◽  
Author(s):  
ERDOGAN UMIT HALIS ◽  
DURAN HICRAN ◽  
SELLI FIGEN

Recently two significant topics that became important for textile industry namely ‘providing sustainability by reusing of textile wastes’ and ‘developing high-valued new textile raw materials. Cellulose, which is a fascinating polymer, has been used for years as a raw material to obtain various products such as papers, fibers and films. In this study, it is aimed to provide sustainability with recycling of cellulose from waste jute fibers, considering the amount of waste jute weft yarns released in the production process of machine carpets. For this purpose, pre-cleaning of waste fibers was carried out at first, and then extraction of cellulose was accomplished, and finally characterization of recycled cellulose was performed. Organic acid extraction method was effective for isolation of cellulose from waste fibers with 43.65% yield performance. Microscopic and experimental analyses confirmed that non-cellulosic part of waste fibers were removed successfully and recycled cellulose has similar structure with control cellulose. Our results suggest that, waste vegetable fibers can be used as a potential source for cellulose. Recycled cellulose can be used in the production of paper, composites, regenerated cellulose fibers and other industrial applications.


2020 ◽  
Vol 9 (4) ◽  
pp. 205-212
Author(s):  
Irma D. Oktavianta ◽  
Gusrizal Gusrizal ◽  
Nurlina Nurlina

Humic acid is a fraction of humic compounds that are part of soil organic matter. In this research, humic acid is extracted from oil palm empty fruit bunches compost. Compost is made from the process of counting the empty oil palm bunches, which are composted until the compost is cooked. The humic acid extraction process uses a strong base extraction method. The principle of humic acid extraction is to dissolve the humic compound with a base solution and then separate it by adding an acid solution (HCl solution). The extraction of humic acid from oil palm empty fruit bunches compost produced blackish-brown humic acid with a yield of 4.895%. The result showed that the main functional group content of palm oil empty fruit bunches compost humic acid was the -OH group and phenol group which had a conjugated carbonyl group and a more aliphatic humic acid structure. Quantitatively, the functional groups of humic acid functional groups each amounted to a total acidity of 7,400 cmol/kg, a carboxylic group of 520 cmol/kg, and a phenolic -OH group content of 6,880 cmol/kg. Research results show that oil palm empty fruit bunches compost can be used as a source of humic acid.


2021 ◽  
Vol 926 (1) ◽  
pp. 012060
Author(s):  
R O Asriza ◽  
Ropalia ◽  
D Humaira ◽  
G O Ryaldi ◽  
Zomi

Abstract The use of masks is very important to reduce transmission of the COVID 19 virus. Therefore, an innovation is needed from mask materials is that are environmentally friendly, have good filtration quality and have anti-virus agents. An alternative way to provide masks with good filterability using a raw material of cellulose acetate. Cellulose acetate has fibrils that are bonded together so that it can form dense fibers. Fiber is a semipermeable layer that functions as a particle filtration. Therefore, this study aims to get cellulose from corn husks via delignification. The research method consisted of extracting cellulose from corn husks and further synthesizing cellulose acetate. FTIR results showed an absorption peak at wave numbers 3349 cm-1, 1728 cm-1, 1252 cm-1, and 1031 cm-1. These peaks indicated the presence functional groups of OH, C=O, aryl ether, and C-O. This functional group indicates a cellulose acetate compound.


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