scholarly journals Analisis Pengaruh Waktu Aktivasi dan Adsorpsi dalam Pemanfaatan Karbon Aktif dari Serutan Kayu menjadi Adsorben Limbah Cair

2019 ◽  
Vol 3 (1) ◽  
Author(s):  
Vibianti Dwi Pratiwi ◽  
Netty Kamal ◽  
Suparman Juhanda

ABSTRAKIndustri pemanfaatan kayu cukup sering ditemukan di Indonesia, namun limbah yang dihasilkan tidak diolah dan hanya dibuang ke lingkungan. Limbah serutan kayu yang mengandung rantai karbon dapat dimanfaatkan menjadi karbon aktif. Pengaruh kualitas karbon aktif dari serutan kayu ini diuji berdasarkan waktu aktivasi dan daya adsorpsi limbah cair. Karbon aktif dibuat melalui pirolisis hingga mencapai suhu 5000C dengan ukuran 100-150 mesh dan diaktivasi dengan H3PO4 10% selama 6 jam, 12 jam, dan 18 jam. Karbon aktif yang dihasilkan digunakan sebagai adsorben dan diujikan pada limbah cair zat warna tekstil Sumikaron Yellow Brown S-2RL. Adsorpsi dilakukan dengan variasi waktu 1 jam, 2 jam dan 3 jam. Selanjutnya larutan zat warna yang telah dijerap oleh karbon aktif dianalisa menggunakan spektrofotometer dengan panjang gelombang 480nm. Berdasarkan absorbansi atau konsentrasi (%) pengurangan warna yang dihitung menggunakan anova dengan software Minitab 17, pengaruh yang lebih signifikan dalam pemanfaatan karbon aktif dari serutan kayu yaitu pada waktu aktivasi 12 jam dan waktu adsorpsi 3 jam. Karbon aktif dari limbah serutan kayu mampu mengurangi limbah cair zat warna sebesar 98,2519%. Hasil uji pendahuluan dengan menghitung bilangan iod dari adsorben karbon aktif yang telah diaktivasi selama 12 jam menjadi kondisi terbaik dengan menjerap iod sebanyak 144,8961 mg/g.Kata Kunci: limbah cair, karbon aktif, serutan kayu, MinitabABSTRACTThe wood utilization industry is quite often found in Indonesia, but the waste produced is not processed and is only disposed of into the environment. Wood shavings containing carbon chains can be used as activated carbon. The effect of the quality of activated carbon from wood shavings was tested based on the activation time and adsorption liquid waste’s capacity. Activated carbon is made through pyrolysis to reach a temperature of 5000C with a size of 100-150 mesh and activated with 10% H3PO4 for 6 hours, 12 hours, and 18 hours. The activated carbon produced was used as an adsorbent and tested on the liquid waste of textile dye Sumikaron Yellow Brown S-2RL. Adsorption is carried out with variations of 1 hour, 2 hours and 3 hours. Furthermore, the dye solution that has been absorbed by activated carbon is analyzed using a spectrophotometer with a wavelength of 480nm. Based on the absorbance or concentration (%) of color reduction calculated using anova with Minitab 17 software, a more significant effect on the utilization of activated carbon from wood shavings is the activation time of 12 hours and the adsorption time of 3 hours. Activated carbon from wood shavings waste is able to reduce dye wastewater by 98.2519%. The results of the preliminary test by calculating iodine number from the adsorbent of activated carbon which has been activated for 12 hours are the best conditions by absorbing iodine is 144.8961 mg/g.Keywords: liquid waste, activated carbon, wood shavings, Minitab

2013 ◽  
Vol 864-867 ◽  
pp. 1694-1698 ◽  
Author(s):  
Lin Zhi Zhai ◽  
Gang Li

Peanut shell-based activated carbon was prepared by 60% zinc chloride activation. The activation temperature was 923K and activation time was 90min. The activated carbon was applied on the removal of acid light yellow from wastewater. The effects of the amount of adsorbent, the initial dye concentration and pH value of solution were investigated. The results showed that the optimum conditions for dye removal: activated carbon dosage of 2.5g/L, initial dye concentration of 50mg/L, pH value of 3. The color removal efficiency attained above 95%. It is concluded that activated carbon developed from peanut shell could be effective and practical for utilizing in dye wastewater treatment.


Processes ◽  
2022 ◽  
Vol 10 (1) ◽  
pp. 129
Author(s):  
Yen-Hui Lin ◽  
Bing-Han Ho

The kinetics and performance of a biological activated carbon (BAC) reactor were evaluated to validate the proposed kinetic model. The Freundlich adsorption capacity (Ka) and adsorption intensity constants (n) obtained from the batch experiments were 1.023 ± 0.134 (mg/g) (L/mg)1/n and 2.036 ± 0.785, respectively. The effective diffusivity (Ds) of the substrate within the activated carbon was determined by comparing the adsorption model value with the experimental data to find the best fit value (4.3 × 10–4 cm2/d). The batch tests revealed that the yield coefficient (Y) was 0.18 mg VSS/mg COD. Monod and Haldane kinetics were applied to fit the experimental data and determine the biokinetic constants, such as the maximum specific utilization rate (k), half-saturation constant (KS), inhibition constant (Ki), and biomass death rate coefficient (kd). The results revealed that the Haldane kinetics fit the experimental data better than the Monod kinetics. The values of k, KS, Ki, and kdwere 3.52 mg COD/mg VSS-d, 71.7 mg COD/L, 81.63 mg COD/L, and 4.9 × 10−3 1/d, respectively. The BAC reactor had a high COD removal efficiency of 94.45% at a steady state. The average influent color was found to be 62 ± 22 ADMI color units, and the color removal efficiency was 73‒100% (average 92.3 ± 10.2%). The removal efficiency for ammonium was 73.9 ± 24.4%, while the residual concentration of ammonium in the effluent was 1.91 ± 2.04 mg/L. The effluent quality from the BAC reactor could meet the discharge standard and satisfy the reuse requirements of textile dye wastewater.


2011 ◽  
Vol 281 ◽  
pp. 276-279
Author(s):  
Xin Wang ◽  
Dan Su ◽  
Hai Bo Li

Electrocoagulation method for textile dye wastewater treatment was investigated in this study. Results show that electrocoagulation can be used powerfully and effectively in organic matter degradation of textile industrial wastewater, where the extent of COD removal and decolorization are achieved about 75.45% and 84.62% after 25 minutes, respectively. pH for textile dye wastewater ascended higher than that of raw wastewater and temperature increased with electrolysis time. GC-MS spectra suggest that organic pollutants in textile dye wastewater are effectively oxidized and decomposed by direct current electrolysis. In addition, the quality of the upper layer liquid after electrolysis nearly meets the criteria of Discharge Standard of Water Pollutants for Dyeing and Finishing of Textile Industry (GB4287-92) of China.


2018 ◽  
Vol 3 (1) ◽  
pp. 21-26
Author(s):  
Achmad Chusnun Ni’am ◽  
Jenny Caroline ◽  
M . Haris Afandi

The quality of environment especially the water bodies need to be improved on the pollution load of the household wastewater, which in general still does not have a liquid waste treatment plant. Electrocoagulation used in this research because of the simple and efficient method. The aim of study to know the ability of electrocoagulation method for reducing the concentration of COD and TSS in the wastewater from household textile industry.  The sample was taken from the residual wastewater of textile dye (sarung) with a liquid waste requirement of 36 liters. The data for the analysis is the initial and final parameters data were COD and TSS. The electrodes were used aluminum (Al) as an anode and iron (Fe) as a cathode. The research variations were used the number of electrodes and the voltage. The results showed that the treatment of 4 electrodes with 12volt voltage could reduce the COD concentration up to 76% and TSS up to 85% in household wastewater of household textile industry. Keywords: COD, electrocoagulation, liquid waste, TSS


2009 ◽  
Vol 60 (6) ◽  
pp. 1565-1574 ◽  
Author(s):  
S. Nilratnisakorn ◽  
P. Thiravetyan ◽  
W. Nakbanpote

Textile wastewater is contaminated by reactive dye causing unattractive levels of wastewater color, high pH and high salt content when discharged into public water systems. Decolorization of textile wastewater by plant, phytoremediation, is an alternative, sustainable method which is suitable for long term operation. Narrow-leaved cattails are one species of wetland plant with efficiency for decolorizing and remediating textile wastewater. In addition, chemical oxygen demand (COD) can be lowered and dye residue can be removed. The plant also showed a good salt tolerance even after being exposed to a salt solution for 15 days. The narrow-leaved cattails were set up in a constructed wetland model with a vertical flow system operating from bottom to top for synthetic reactive dye wastewater (SRDW) removal. Narrow-leaved cattails could achieve the removal of SRDW at approximately 0.8 gSRDW m−2 day−1. Decolorization of SRDW by this plant was approximately 60%. The advantage of this method is that it is suitable for textile wastewater management and improvement of wetland. These plants could lower COD, remove dye, sodium and total dissolved solids (TDS) whereas other biological and chemical methods could not remove TDS and dye in the same time. These results suggested that the spongy cell structure of this plant has the ability to absorb large amounts of water and nutrients. Physico-chemical analysis revealed increasing amounts of sulfur, silicon, iron and calcium in the plant leafs and roots after exposure to wastewater. Proteins or amide groups in the plant might help in textile dye removal. Regarding decolorization, this plant accumulates dye in the intercellular space and still grows in this SRDW condition. Hence, it can be noted here that narrow-leaved cattails are efficient for textile dye wastewater treatment.


2012 ◽  
Vol 184-185 ◽  
pp. 1110-1113 ◽  
Author(s):  
Li Fen He ◽  
Qi Xia Liu ◽  
Tao Ji ◽  
Qiang Gao

Various jute-based activated carbon fibers were prepared by using jute fibers as raw materials and phosphoric acid as activating agent. The effects of three main factors such as concentration of activating agent, activation temperature and activation time on the yield and adsorptive properties of active carbon fibers were investigated via orthogonal experiments. The surface physical morphology of jute-based activated carbon fiber was also observed by using Scanning Electron Microscope. Results showed that the optimum conditions were phosphoric acid concentration of 4 mol/L, activation temperature of 600 °C and activation time of 1h. The yield, iodine number and amount of methylene blue adsorption of the active carbon fiber prepared under optimum conditions were 37.99 %, 1208.87 mg/g and 374.65 mg/g, respectively.


2012 ◽  
Vol 3 (1) ◽  
pp. 41-48 ◽  
Author(s):  
S. Sathian ◽  
G. Radha ◽  
V. Shanmugapriya ◽  
M. Rajasimman ◽  
C. Karthikeyan

Author(s):  
В.А. Гвоздев ◽  
Л.В. Леонов ◽  
О.Н. Рублевская

Качество услуг водоснабжения и водоотведения за первые двадцать лет XXI века вывело на новый уровень развития ГУП «Водоканал Санкт-Петербурга» благодаря внедрению инновационных технологий в системах водоснабжения и водоотведения. Использование технологий, таких как двухступенчатое обеззараживание питьевой воды, дезодорирование полигонов, геотубирование, применение центрифуг «Флоттвег», порошкообразного однокомпонентного флокулянта, порошкообразного активированного угля, внедрение системы измерения осадков, осуществлялись при активном участии Федора Ивановича Лобанова – помощника генерального директора ГУП «Водоканал Санкт-Петербурга» по работе с промышленностью, которому в ноябре 2021 г. исполнилось 80 лет. The quality of water supply and wastewater disposal services over the first twenty years of the 21st century has brought SUE «Vodokanal of St. Petersburg» to a new level of development owing to the introduction of innovative technologies in water supply and wastewater disposal systems. The use of technologies, such as two-stage disinfection of drinking water, odor control of landfills, geotubing, the use of Flottweg centrifuges, powdered one-component flocculant, powdered activated carbon, the introduction of a precipitation measurement system, were carried out with the active participation of Fedor Ivanovich Lobanov, Assistant to the General Director of SUE «Vodokanal of St. Petersburg» on dealing with industries, who turned 80 in November 2021.


2021 ◽  
Vol 6 (2) ◽  
pp. 77-85
Author(s):  
Muhammad Al Kholif ◽  
Ida Istaharoh ◽  
Pungut ◽  
Joko Sutrisno ◽  
Sri Widyastuti

Tofu industrial wastewater is a contributor to environmental pollution. Wastewater contains high levels of COD and TSS. The purpose of this study was to determine the effectiveness of reducing pollutant loads in tofu liquid waste by using the phytoremediation method using water jasmine (Echinodorus Palaefolius). The initial stage of the research was a preliminary test to determine the initial content of the waste. The acclimatization process is carried out by observing the process of plant growth during the research process. To maximize plant growth, dilution is carried out with various concentrations of 25% wastewater with 75% diluting water and 50% wastewater with 50% diluting water. Sampling was carried out every 12 hours for 5 days. The results showed that the highest effectiveness of COD reduction occurred in RFT 25% with a residence time of 12 hours at 39.83%, while for TSS parameters the highest effectiveness was at RFT 25% with a residence time of 12 hours by 69%.


Sign in / Sign up

Export Citation Format

Share Document