scholarly journals Structural behavior of rf magnetron sputtered cupric oxide (CuO) films

2020 ◽  
Vol 25 (2) ◽  
pp. 1-7 ◽  
Author(s):  
Ali Khilkhal ◽  
Abdalhussain A. Khadayeir

In this paper a CuO thin film, has been deposited using RF sputtering technique, then the thin film has been characterized by XRD, result obtained showed that strongest peak was 48.6503 degree, and FWHM was 0.145 degree, while lattice constant was 4.65 Aº, and the average grain size was 62.78 nm. While AFM analysis showed that the increasing of another four samples temperature led to increase of roughness average from (3.77 to 15.7) nm, root mean square from (4.66 to 18.8) nm and ten points height from (22.6 to 52.6) at 250,300,350 and 400 C respectively. On the other hand granularity cumulation distribution charts showed average diameter has varied from (57.42, to 135.41) nm with grain numbers per line ( 364, to 135) respectively.

2020 ◽  
Vol 12 (02) ◽  
pp. 61-65
Author(s):  
Ali Nadhom Khilkhal ◽  
◽  
Abdalhussain A. Khadayeir ◽  
Sarah Al Dahhan ◽  

In this paper a Cu2O thin films, were deposited using RF sputtering technique. Sputtering process can be defined as ejection atoms of material surface due to positive ions bombardment of (mostly) inert gas, sometimes called cathode sputtering. Then the thin films were characterized by XRD. The results obtained showed that, the thin films had a polycrystalline structure with cubic lattice unit cell. strongest peak was seen at 61.3967 degree, and FWHM was at 0.215 degree, while lattice constant was 4.26 Aº. The average grain size was 44.87 nm. While AFM analysis showed that the increasing of four samples temperature (523, 573, 623 and 673) Kelvin, led to increase of roughness average from (3.39 to 9.2) nm, and ten points height from (13.7 to 36.3). On the other hand granularity cumulation distribution charts showed that the average diameter was varied from (43.31 to 51.28) nm with grain numbers ( 739, to 414) respectively


Coatings ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 23
Author(s):  
Weiguang Zhang ◽  
Jijun Li ◽  
Yongming Xing ◽  
Xiaomeng Nie ◽  
Fengchao Lang ◽  
...  

SiO2 thin films are widely used in micro-electro-mechanical systems, integrated circuits and optical thin film devices. Tremendous efforts have been devoted to studying the preparation technology and optical properties of SiO2 thin films, but little attention has been paid to their mechanical properties. Herein, the surface morphology of the 500-nm-thick, 1000-nm-thick and 2000-nm-thick SiO2 thin films on the Si substrates was observed by atomic force microscopy. The hardnesses of the three SiO2 thin films with different thicknesses were investigated by nanoindentation technique, and the dependence of the hardness of the SiO2 thin film with its thickness was analyzed. The results showed that the average grain size of SiO2 thin film increased with increasing film thickness. For the three SiO2 thin films with different thicknesses, the same relative penetration depth range of ~0.4–0.5 existed, above which the intrinsic hardness without substrate influence can be determined. The average intrinsic hardness of the SiO2 thin film decreased with the increasing film thickness and average grain size, which showed the similar trend with the Hall-Petch type relationship.


2016 ◽  
Vol 852 ◽  
pp. 1080-1086
Author(s):  
Xiao Xin Zhang ◽  
Jian Jun Xie ◽  
Ying Shi ◽  
Ling Cong Fan ◽  
De Bao Lin ◽  
...  

Lutetium oxyorthosilicate (Lu2SiO5, LSO) doped with Pr3+ was synthesized on cleaned silicon (111) substrates by sol-gel route with the spin-coating technique. XRD patterns indicated that the films were crystallized into A-type LSO phase at 1000 °C, followed by a phase transition to B-type LSO occurred at 1100 °C. SEM observations revealed that the surface of the films was smooth, homogeneous and crack-free. When the sintering temperature was 1000 °C, the average grain size of the crystal particles was 100-200 nm and the thickness of the thin film was about 380 nm when the coating layer number up to 10. While the sintering temperature was 1100 °C, the average grain size of the crystal particles was 200-300 nm and the thickness of the thin film was about 320 nm also 10 layers. PL spectra showed when under 1000 °C, the quenching concentration of Pr3+ was 0.3 mol%, the characteristic emission peaks was 289 nm and 340 nm and the dominant decay time was 4.64 ns; while under 1100 °C, the quenching concentration of Pr3+ was 0.4 mol%, the characteristic emission peaks was 280 nm and 320 nm and the dominant decay time was 2.61 ns.


2008 ◽  
Vol 38 ◽  
pp. 63-75 ◽  
Author(s):  
N.A. de Sánchez ◽  
Héctor Enrique Jaramillo Suárez (1) ◽  
Z. Vivas ◽  
W. Aperador ◽  
C. Amaya ◽  
...  

CrN/ZrN (1, 8, 15, and 30) bilayers were deposited onto AISI 420 steel substrates at 250 °C and 6.6x10-3 mbar with gas ratio Ar/N2 50:3.0 as gas mixture and bias -60V were applied. AFM analysis presented different morphologies, showing that the coatings with 15 bilayers had an average grain size of 49 nm; while the 30-bilayer coating exhibited grain sizes of 99 nm. Coating thicknesses were 3 μm, approximately. The Vickers Test revealed that coatings with 8, 15, and 30 bilayers bore better impact resistance than coatings with 1 bilayer. This result is considered, bearing in mind that in many bilayers propagation of fissures is slower, because the presence of layer inter-phases leads to fissures straying in other directions. Slight corrosion specks are present, but mass loss was around 40 mg. in one bilayer, a higher value than for the coatings with 15 bilayers that was near 18 mg. Homogeneity, grain size, fracture resistance, and corrosion resistance of the coatings with 15 and 30 bilayers are suitable for mechanical applications of these types of coatings, as shown in mechanical measurements. These results indicate that for engineering applications under corrosive environments, the use of these types of bilayer coatings on AISI 420 stainless steel is highly recommended.


2010 ◽  
Vol 44-47 ◽  
pp. 4151-4153 ◽  
Author(s):  
Rui Min Jin ◽  
Ding Zhen Li ◽  
Lan Li Chen ◽  
Xiang Ju Han ◽  
Jing Xiao Lu

Amorphous silicon films prepared by PECVD on glass substrate has been crystallized by rapid thermal annealing (RTA) at the same temperature for different time. From X-ray diffraction (XRD) and scanning electronic microscope (SEM), it is found that the grain size is biggest crystallized at 720°C for 8 min, an average grain size of 28nm or so is obtained. The thin film is smoothly and perfect structure.


1997 ◽  
Vol 493 ◽  
Author(s):  
YongSoo Choi ◽  
WooSik Kim ◽  
ChangEun Kim ◽  
WhanSik Yoo ◽  
BaeYeon Kim ◽  
...  

ABSTRACTStable SBT sols for FRAM application were made from Sr-isopropoxide, Bi-acetate, and Ta-ethoxide with 2-ethoxyethanol as a solvent and chelating agent, TEA. The sol were spin-on coated on the Pt /Ti/SiO2/Si substrate. From the IR and DTA/TGA, the 2-ethoxyethanol -triethanolamine sol system is quite stable against aging. 5% excess Bi added sol and 800°C heat treatment of the thin film revealed the most crystallinity. There is a change in the orientation of thin film above 800°C heat treatment from c-axis to(105). The average grain size of thin film is very small, i.e., 40 nm at 800°C, and it has very narrow distributions, and the thickness of the coating were about 100nm, which would promise smaller electrode area and higher yield.


2013 ◽  
Vol 677 ◽  
pp. 55-60 ◽  
Author(s):  
Bing Hu ◽  
Yang Cao ◽  
Rong Ying Huang ◽  
Jian Bo Fu ◽  
Hong Qiu

HCl-doped polyaniline (HCl-PANI) powder is synthesized by using a chemical polymerization procedure. Then Ag nanoparticles are deposited on the HCl-PANI at room temperature by RF sputtering. After this process, the nanocomposite is obtained by the chemical and physical combinative method. The nominal Ag content in the nanocomposite ranges from 1.0 wt% to 3.3 wt%. For all the nanocomposites, the Ag nanoparticles convert to AgCl nanoparticles. Namely, the HCl-PANI-AgCl nanocomposites are obtained. A content of the AgCl in the nanocomposite increases with increasing Ag content. The AgCl nanoparticle consists of many grains. An average grain size of AgCl is about 40 nm and is independent of the Ag content. A conductivity of the nanocomposite decreases with increasing Ag content.


2012 ◽  
Vol 1447 ◽  
Author(s):  
Kousik Midya ◽  
Abhishek Sharma ◽  
Anil Kottantharayil ◽  
Subhabrata Dhar

ABSTRACTIn this study indium tin oxide (ITO) thin films have been deposited by RF sputtering technique on quartz substrate. In all cases, the substrate was heated during deposition. Thin film deposited under various process conditions, shows characteristic XRD reflection corresponding to the (222) crystal orientation. Transmittance of the film has been measured for the wavelength range from 190 to 3300 nm. Average transmittance of 84.4%, 90.2% and 85.3% for wavelengths up to 800 nm, 2500 nm and 3300 nm respectively has been obtained. The resistivity in this case is found to be as low as ∼10 × 10-4 Ω-cm. Our study is focused on controlling the resistivity of the deposited film, without compromising transmittance in the near infra red (NIR) region of the spectrum. Substrate heating during deposition is found to result in films with grains which are oriented in (222) direction predominantly. Moreover, the average grain size is increased with subsequent annealing. It has been observed that though the transmittance for the samples doesn’t vary substantially upon annealing the resistivity decreases by several factors.


MRS Advances ◽  
2018 ◽  
Vol 3 (64) ◽  
pp. 3971-3978 ◽  
Author(s):  
O.E. Villanueva-Perez ◽  
I. Mejía ◽  
V. García-García ◽  
A. Bedolla-Jacuinde

ABSTRACTLow density (LD) steels have shown particular characteristics in terms of mechanical properties and microstructure, since they have high strength, high ductility and density reduction up to 18%. On the other hand, the addition of microalloying elements such as Ti and B generate hardening by solid solution and precipitation, as well as grain refinement effect. LD steels generate nano-sized kappa phase precipitated from the austenite matrix, and these advanced steels can reach strength and elongation up to 780 MPa and 60%, respectively. The main objective of this research work is the metallographic, structural and mechanical characterization of a LD steel microalloyed with Ti/B in as-cast and -homogenized conditions. For this purpose a Fe-27Mn-7Al-1.2C (%wt) LD steel microalloyed with Ti/B was melted in a vacuum-induction furnace and cast in metallic mold. LD-Ti/B steel samples were homogenized at 1100 °C during 20, 50, 100, 150 and 200 minutes followed by water quenching. Metallographic, structural and mechanical characterization was carried out by optical (LOM) and scanning electron (SEM) microscopy, X-ray diffraction (XRD) and microhardness Vickers testing (HV10), respectively. In general, results showed a typical dendritic microstructure with average grain size of 1256 μm in the as-cast condition. On the other hand, the as-homogenized condition showed an austenitic equiaxial microstructure with average grain size from 164 to 940 μm. Austenite, ferrite and kappa phases were detected by X-ray diffraction (XRD). Also, second-phase particles such as AlN, TiC and MnS were detected by LOM and SEM-EDS analysis. LD steel microalloyed with Ti/B exhibited the highest microhardness Vickers value (235 HV10) in the as-cast condition, whilst in the as-homogenized condition microhardness gradually decreases from 223 to 198 HV10 as holding time increases.


Author(s):  
Piotr Migon

The unifying theme for granite landscapes of the world is the granite itself, hence it is logical to start with a brief account of granite geology. For obvious reasons of space and relevance, this chapter cannot provide a comprehensive and extensive treatment of granite as a rock. Rather, its aim is to provide background information on those aspects of granite geology which are relevant to geomorphology and may help to explain the variety of landforms and landscapes supported by granite. The survey of literature about the geomorphology of granite areas reveals that in too many studies the lithology of granite and the structure of their intrusive bodies have not received adequate attention, especially if a ruling paradigm was one of climatic, or climato-genetic geomorphology. Granites were usually described in terms of their average grain size, but much less often of their geochemistry, fabric, or physical properties. Even the usage of the very term ‘granite’ may have lacked accuracy, and many landforms described as supported by granite may in fact have developed in granodiorite. On the other hand, it is true that granite may give way to granodiorites without an accompanying change in scenery. In the Yosemite National Park, Sierra Nevada, California, these two variants occur side by side and both support deeply incised valleys, precipitous slopes and the famous Sierran domes. Likewise, wider structural relationships within plutons and batholiths, and with respect to the country rock, have been considered in detail rather seldom. In analyses of discontinuities, long demonstrated to be highly significant for geomorphology, terms such as ‘joints’, ‘faults’, and ‘fractures’ have not been used with sufficient rigour. But it has to be noted in defence of many such geologically poorly based studies that adequate geological data were either hardly available or restricted to a few specific localities within extensive areas, therefore of limited use for any spatial analysis of granite landforms. Notwithstanding the above, there exist a number of studies in which landforms have been carefully analysed in their relationships to various aspects of the lithology, structure, and tectonics of granite intrusions.


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