scholarly journals Variations of arsenic in groundwater from a transect in Van Phuc village, Hanoi

2021 ◽  
Vol 63 (11) ◽  
pp. 17-22
Author(s):  
Thi Duyen Vu ◽  
◽  
The Anh Lang ◽  
Thi Kim Trang Pham ◽  
Hung Viet Pham ◽  
...  

In this study, the author report detailed results of the variation of arsenic in groundwater along a transect in an area near the Hanoi city centre. The results showed that 64% of collected samples exceeded the WHO guideline value for arsenic concentration in drinking water. The arsenic concentration varied in a wide range, strongly depending on the sediment characteristics of each zone along the transect. Aside from As, groundwater in this area also was contaminated by elevated concentrations of Fe, Mn, and ammonium. The study also pointed out a positive correlation between As and reductive chemical species, namely DOC, NH4+, and CH4 in groundwater. Although there is no clear trend in the correlation between As and Fe, Mn, it can be concluded that the formation of arsenic in groundwater in the study area was due to the reductive dissolution of As-bearing iron minerals under the presence of organic matter.

2021 ◽  
Vol 63 (11) ◽  
pp. 19-23
Author(s):  
Thi Duyen Vu ◽  
◽  
Thi Mai Tran ◽  
Thi Kim Trang Pham ◽  
Mai Lan Vi ◽  
...  

Arsenic contamination in groundwater is commonly found in alluvial plains of major river basins, in which the Red river delta has also been reported to be contaminated with high levels of arsenic. In this study, groundwater from 50 household wells was collected to study the spatial distribution of arsenic in northwestern Hanoi. The results showed that arsenic concentration in groundwater varied in a wide range of less than 5 to 334 μg/l, of which up 62% of the wells exceeded the WHO guideline value of 10 μg/l for arsenic content in drinking water. Arsenic groundwater in this area is unevenly distributed throughout the area, high arsenic concentrations are found in a narrow band between Red river and Day river. This pattern of arsenic distribution is strongly related to the sediment age, sedimentary processes, and it is also modified by local groundwater flow parts and the occurrence of hydraulic connection between aquifers, which are observed in the study area. Arsenic is released into the groundwater during the reductive dissolution of arsenic-bearing minerals under the presence of organic matter.


2006 ◽  
Vol 41 (2) ◽  
pp. 216-225 ◽  
Author(s):  
M. Amir Hossain ◽  
Amitava Mukharjee ◽  
Mrinal Kumar Sengupta ◽  
Sad Ahamed ◽  
Bhaskar Das ◽  
...  

Abstract The effectiveness of arsenic removal plants (ARPs) to provide safe water was evaluated based on a study of 577 ARPs out of 1900 installed in 5 arsenic-affected districts of West Bengal, India. Out of 577, 145 (25.1%) were found in defunct condition. Both raw and filtered water from 305 ARPs were analyzed for total arsenic concentration. Forty-eight ARPs were installed despite raw water arsenic concentrations below the Indian standard (50 µg/L) and in 22 cases even below the WHO guideline value (10 µg/L). Among the 264 ARPs having raw water arsenic above 50 µg/L, 140 (53.1%) and 73 (27.7%) failed to remove arsenic below the WHO guideline value and Indian standard, respectively. The highest arsenic concentration in treated water was 705 µg/L. Analysis of 217 treated water samples for iron showed that 175 (80.6%) failed to remove iron below 300 µg/L. The treated water became coloured on standing 6 to 8 h, for 191 (44.2%) ARPs and 25 (5.8%) produced bad-odoured water. Overall, the study showed that 475 (82.3%) of the ARPs were not useful. The reasons for ineffectiveness and poor performance of these ARPs include improper maintenance, sand gushing problems, a lack of user-friendliness and absence of community participation. A comparative study of ARPs in two different blocks (Domkol in Murshidabad district and Swarupnagar in North 24 Parganas) showed that 39 (80%) and 38 (95%) ARPs, respectively, were not useful. Further study in Gram Panchayet Kolsur, Deganga block, North 24 Parganas, showed that 14 (87.5%) ARPs were not useful. Proper watershed management with active participation from the villagers is urgently required for successful mitigation.


2019 ◽  
Vol 70 (7) ◽  
pp. 2330-2334
Author(s):  
Mihaela Ciopec ◽  
Adina Negrea ◽  
Narcis Duteanu ◽  
Corneliu Mircea Davidescu ◽  
Iosif Hulka ◽  
...  

Arsenic content in groundwater�s present a wide range of concentration, ranging from hundreds of micrograms to thousands of micrograms of arsenic per litter, while the maximum permitted arsenic concentration established by World Health Organization (WHO) is 10 mg L-1. According to the WHO all people, regardless of their stage of development and their social economic condition, have the right to have access to adequate drinking water. The most efficient and economic technique used for arsenic removal is represented by adsorption. In order to make this remediation technique more affordable and environmentally friendly is important to new materials with advance adsorbent properties. Novelty of present paper is represented by the usage of a new adsorbent material obtained by physical - chemical modification of Amberlite XAD polymers using crown ethers followed by iron doping, due to well-known affinity of arsenic for iron ions. Present paper aims to test the obtained modified Amberlite polymer for arsenic removal from real groundwater by using adsorption in a fixed bed column, establishing in this way a mechanism for the adsorption process. During experimental work was studied the influence of competing ions from real water into the arsenic adsorption process.


Ecotoxicology ◽  
2021 ◽  
Author(s):  
Daesik Park ◽  
Catherine R. Propper ◽  
Guangning Wang ◽  
Matthew C. Salanga

AbstractNaturally occurring arsenic is toxic at extremely low concentrations, yet some species persist even in high arsenic environments. We wanted to test if these species show evidence of evolution associated with arsenic exposure. To do this, we compared allelic variation across 872 coding nucleotides of arsenic (+3) methyltransferase (as3mt) and whole fish as3mt gene expression from three field populations of Gambusia affinis, from water sources containing low (1.9 ppb), medium-low (3.3 ppb), and high (15.7 ppb) levels of arsenic. The high arsenic site exceeds the US EPA’s Maximum Contamination Level for drinking water. Medium-low and high populations exhibited homozygosity, and no sequence variation across all animals sampled. Eleven of 24 fish examined (45.8%) in the low arsenic population harbored synonymous single nucleotide polymorphisms (SNPs) in exons 4 and/or 10. SNP presence in the low arsenic population was not associated with differences in as3mt transcript levels compared to fish from the medium-low site, where SNPs were noted; however, as3mt expression in fish from the high arsenic concentration site was significantly lower than the other two sites. Low sequence variation in fish populations from sites with medium-low and high arsenic concentrations suggests greater selective pressure on this allele, while higher variation in the low population suggests a relaxed selection. Our results suggest gene regulation associated with arsenic detoxification may play a more crucial role in influencing responses to arsenic than polymorphic gene sequence. Understanding microevolutionary processes to various contaminants require the evaluation of multiple populations across a wide range of pollution exposures.


2018 ◽  
Vol 21 (9) ◽  
pp. 1248-1258 ◽  
Author(s):  
Hanno C Erythropel ◽  
Sairam V Jabba ◽  
Tamara M DeWinter ◽  
Melissa Mendizabal ◽  
Paul T Anastas ◽  
...  

Abstract Introduction “Vaping” electronic cigarettes (e-cigarettes) is increasingly popular with youth, driven by the wide range of available flavors, often created using flavor aldehydes. The objective of this study was to examine whether flavor aldehydes remain stable in e-cigarette liquids or whether they undergo chemical reactions, forming novel chemical species that may cause harm to the user. Methods Gas chromatography was used to determine concentrations of flavor aldehydes and reaction products in e-liquids and vapor generated from a commercial e-cigarette. Stability of the detected reaction products in aqueous media was monitored by ultraviolet spectroscopy and nuclear magnetic resonance spectroscopy, and their effects on irritant receptors determined by fluorescent calcium imaging in HEK-293T cells. Results Flavor aldehydes including benzaldehyde, cinnamaldehyde, citral, ethylvanillin, and vanillin rapidly reacted with the e-liquid solvent propylene glycol (PG) after mixing, and upward of 40% of flavor aldehyde content was converted to flavor aldehyde PG acetals, which were also detected in commercial e-liquids. Vaping experiments showed carryover rates of 50%–80% of acetals to e-cigarette vapor. Acetals remained stable in physiological aqueous solution, with half-lives above 36 hours, suggesting they persist when inhaled by the user. Acetals activated aldehyde-sensitive TRPA1 irritant receptors and aldehyde-insensitive TRPV1 irritant receptors. Conclusions E-liquids are potentially reactive chemical systems in which new compounds can form after mixing of constituents and during storage, as demonstrated here for flavor aldehyde PG acetals, with unexpected toxicological effects. For regulatory purposes, a rigorous process is advised to monitor the potentially changing composition of e-liquids and e-vapors over time, to identify possible health hazards. Implications This study demonstrates that e-cigarette liquids can be chemically unstable, with reactions occurring between flavorant and solvent components immediately after mixing at room temperature. The resulting compounds have toxicological properties that differ from either the flavorants or solvent components. These findings suggest that the reporting of manufacturing ingredients of e-liquids is insufficient for a safety assessment. The establishment of an analytical workflow to detect newly formed compounds in e-liquids and their potential toxicological effects is imperative for regulatory risk analysis.


Water Policy ◽  
2009 ◽  
Vol 11 (3) ◽  
pp. 362-378 ◽  
Author(s):  
N. Nahar

In attempting to eliminate disease caused by drinking polluted surface water, millions of tube-wells were drilled in Bangladesh. However, owing to arsenic in groundwater, the availability of safe drinking water has declined from earlier achievement of 97% to 51.2%. This article reviews the causes and distribution of arsenic concentration in rural Bangladesh from a wide variety of literature. Scientists have converged to two hypotheses for causes of arsenic in groundwater: the pyrite oxidation hypothesis and the oxy-hydroxide reduction hypothesis. There is a positive correlation between arsenic content in irrigated groundwater and arsenic contained in soils. There is a significant presence of arsenic in rice and leafy vegetables. Today, arsenic is causing toxicity to human health and creating major social problems. This finding implies that, had there been a precautionary measure taken when a new technology tube-well was being introduced, in the form of testing water for harmful metals, the risk that the rural population is facing now could have been drastically reduced. This lack of precautionary measure, before starting a mass installation of tube-wells for drinking and irrigation should be seen as a “human error” and avoided in future water policy and planning.


Author(s):  
Silnyk O ◽  

The central part of Lviv was formed over several centuries and in several stages. Favourable demographic, economic and political prerequisites in the XIX-XX centuries positively influenced the quantitative and qualitative state of urban homes. Demolition of defensive walls, the formation of a new citywide centre, measures to improve the central part of the city, regulate the street network, and increase the population are the main factors that underlie the planning and development of the city. The city was actively built up. Most of the houses were profitable. These are buildings that brought profit to their owners through rented premises and commercial parterre floors. The modern architecture of Lviv is developing under the influence of tourist infrastructure and the ordinary household needs of Lviv residents. The urban space of the central part of modern Lviv needs to be regularly updated to perform functions that are dictated by time. It is also important to preserve the existing historical centre that attracts tourists, represents the historical value and pride of the country. Professional implementation of projects requires a detailed study and analysis of the existing architecture. Since the second half of the XIX century, the development of houses parallel to the main roads of the city became popular. Dense buildings spread in concentric circles from the city centre and gradually replaced low-rise buildings in the peripheral part of the city. During this period, housing construction is carried out on a large scale. These are mostly two- or three-story houses, often with a courtyard. The size and configuration of the houses were dictated by technical capabilities, existing buildings and streets. The sites often had a complex shape, the development was carried out already in the conditions of reconstruction, which significantly complicated the solution of new projects. The houses had rectangular forms of plans, the dimensions of which averaged 400 m2 until the end of the XIX century. During the twentieth century, slightly larger plots – 570 m2 – were already allocated for construction. The built-up area on the plots ranged from 30 to 87 per cent. The density of buildings was dictated by both economic and practical factors that are relevant even today. The houses were distinguished by interesting planning solutions with a thorough set of architectural details both in the exterior and in the interior. The range of rooms includes dining rooms, offices, boudoirs, bathrooms, corridors and storerooms. During the nineteenth century, in the decisions of facades dominated Italian neo-Renaissance and neo-Baroque; in the twentieth century – secession. The style solution was based on the choice of details that were prototypes of classical architectural images. The architecture of Lviv of the XIX-XX centuries represents a wide range of artistic interpretations. The study of houses built during this period reveals both their development and the transformation of spatial planning, compositional and stylistic solutions. The necessary formative periods of historicism opened up new angles for the development of subsequent stylistic trends in the following years. The experience of architects, which is connected with the historical past of Lviv, testifies to the significant importance and place of the architecture of the XIX-XX centuries for the further development and development of the city.


2014 ◽  
Vol 2014 (HITEC) ◽  
pp. 000034-000039 ◽  
Author(s):  
John R. Fraley ◽  
Lauren Kegley ◽  
Stephen Minden ◽  
Jimmy L. Davidson ◽  
David Kerns

In recent years, high temperature semiconductors have been utilized in wireless telemetry systems for use in military and commercial applications, wherein a high temperature environment combined with other factors such as rotating machinery or weight-constraints preclude the use of conventional silicon based wireless telemetry or wired sensor solutions. Present systems include those which can measure temperatures, pressures, vibrations, and strains. By combining the advanced electronics developed for these systems with novel sensor elements created using chemical vapor deposition (CVD) nanodiamond technology, a wide range of other high temperature sensing systems can be enabled. The unique properties of the diamond sensors have proven in principle the capability to sense, with quantifiable signal, a wide variety of parameters under extreme conditions including very high temperatures and pressures. It has been clear for some time that diamond would be the ideal material of choice for solid-state sensors, but only in recent years has the advent of CVD diamond (as opposed to natural or HPHT [high pressure, high temperature] formation) opened the door for its practical development into harsh environment sensor systems. By combining these diamond sensor elements with high temperature electronics and high temperature packaging approaches, smart sensors can be developed to measure parameters ranging from gas chemical species on the surface of Venus, to neutron flux rates outside of a nuclear reactor core. The research presented here is centered around the use of hybrid diamond sensors for neutron detection applications in Nuclear Thermal Propulsion systems. The current technology state and development needs for these hybrid high temperature diamond smart sensors will be highlighted to potentially encourage future R&D from the high-temperature electronics community.


2018 ◽  
Vol 13 (2) ◽  
pp. 285-294
Author(s):  
Borano Te ◽  
Boonchai Wichitsathian ◽  
Chatpet Yossapol ◽  
Watcharapol Wonglertarak

Abstract Many people in Cambodia consume groundwater with arsenic concentrations above the WHO guideline. In this study, an iron-mixed porous pellet adsorbent was put into a lightweight bio-sand filter to treat arsenic. The filter was intermittently charged daily with 30 L influent water until the effluent arsenic concentration exceeded 10 μg/L. The results indicated that the Morrill Dispersion Index was less than 2.0, implying that the filter had preferential plug flow. Head loss accumulation led to flow rate reduction over a period of 30 days. Arsenic removal efficiency was between 97 and 99% for the influent concentration, being in the range 355 to 587 μg/L. No significant leaching of iron or organic carbon was observed. The high dissolved oxygen concentration is likely to have contributed to the aerobic conditions in the filter bed. The filter removed arsenic more efficiently than was achieved in some previous studies and might be suitable to provide household-scale, arsenic-safe drinking water.


2015 ◽  
Vol 25 (01n02) ◽  
pp. 29-37 ◽  
Author(s):  
Jun Noda ◽  
Reika Hakamada ◽  
Kazuyki Suzuki ◽  
Teruo Miura ◽  
Koichiro Sera

This investigation focuses on the arsenic contamination problems in tube well groundwater systems and the different forms of arsenic and other toxic elements accumulated in human hair samples taken in a rural area of Allahabad, Uttar Pradesh, India. The local residents at the study site depend on groundwater as their major source of household water. The oxidation reduction potential (ORP) and pH of groundwater samples were measured directly after the sampling of groundwater. Arsenic concentrations were measured directly in water samples by a colorimetric arsenic analysis kit after the water was pumped from a tube well and/or at a nearby laboratory. Human hair samples from the residents of the villages in the study site were analyzed by PIXE to measure a wide range of elements. An atomic absorption spectrometer was also used to measure arsenic concentrations. The results indicated that the concentrations of arsenic in groundwater and human hair were significantly higher in the village of Bada Kanjasa than in the villages of Kanua and Chota Kanjasa (P< 0.05), clearly indicating that the higher arsenic concentration in groundwater reflected the accumulation of arsenic in human hair in the residents of Bada Kanjasa. The PIXE analysis also revealed an unusually high concentration of lead in human hair samples from Chota Kanjasa. Although the actual health effects and the detailed exposure mechanisms remain to be investigated, lead pollution is suspected to be the source of the exposure.


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