scholarly journals Implications and Significance of Mercury in Rice

Author(s):  
James R. Palmieri ◽  
Beverly Rzigalinski ◽  
Brooke Benjamin ◽  
Erin Collins ◽  
Gurleen Kaur ◽  
...  

Previous research on rice asserts certain heavy metals, like mercury, in the agricultural soils are incorporated into the rice plant. Mercury is considered to be the most toxic heavy metal. This study aims to investigate mercury levels in rice grown in the United States versus rice imported from Asia. In this study, 29 samples of rice were compared for mercury content (12 from Thailand, 6 from India, 6 from China, compared to 5 control samples from the USA). Samples ranged from 0.18 to 6.01 ng of element / g. Further research is needed to establish standards for mercury toxicity.

Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 


2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;


1999 ◽  
Vol 65 (2) ◽  
pp. 718-723 ◽  
Author(s):  
C. Del Val ◽  
J. M. Barea ◽  
C. Azcón-Aguilar

ABSTRACT High concentrations of heavy metals have been shown to adversely affect the size, diversity, and activity of microbial populations in soil. The aim of this work was to determine how the diversity of arbuscular mycorrhizal (AM) fungi is affected by the addition of sewage-amended sludge containing heavy metals in a long-term experiment. Due to the reduced number of indigenous AM fungal (AMF) propagules in the experimental soils, several host plants with different life cycles were used to multiply indigenous fungi. Six AMF ecotypes were found in the experimental soils, showing consistent differences with regard to their tolerance to the presence of heavy metals. AMF ecotypes ranged from very sensitive to the presence of metals to relatively tolerant to high rates of heavy metals in soil. Total AMF spore numbers decreased with increasing amounts of heavy metals in the soil. However, species richness and diversity as measured by the Shannon-Wiener index increased in soils receiving intermediate rates of sludge contamination but decreased in soils receiving the highest rate of heavy-metal-contaminated sludge. Relative densities of most AMF species were also significantly influenced by soil treatments. Host plant species exerted a selective influence on AMF population size and diversity. We conclude based on the results of this study that size and diversity of AMF populations were modified in metal-polluted soils, even in those with metal concentrations that were below the upper limits accepted by the European Union for agricultural soils.


2020 ◽  
Author(s):  
Anne Karine Boulet ◽  
Adelcia Veiga ◽  
Carla Ferreira ◽  
António Ferreira

<p>Conservation of agriculture soils is a topic of major concern, namely through the increase of soil organic matter. SoilCare project (https://www.soilcare-project.eu/) aims to enhance the quality of agricultural soils in Europe, through the implementation and testing of Soil Improving Cropping Systems in 16 study sites. In Portugal, the application of urban sewage sludge amendments in agriculture soils has been investigated. However, this application is a sensitive topic, due to the risk of long term accumulation of heavy metals and consequent contamination of the soil. The recent Portuguese legislation (Decret-Law 103/2015) is more restrictive than the precedent one (Decret-Law 276/2009) in terms of maximum concentrations of heavy metals in agricultural soils. The analytical quantification of heavy metals, however, raises some methodological questions associated with soil sample pre-treatment, due to some imprecisions in standard analytical methods. For example, the ISO 11466 regarding the extraction in Aqua Regia provides two pre-treatment options: (i) sieve the soil sample with a 2 mm mesh (but if mass for analyses is <2g, mill and sieve the sample <250µm is required), or (ii) mill and sieve the soil sample through a 150µm mesh. On the other hand, the EN 13650 requests soil samples to be sieved at 500µm. Since heavy metals in the soil are usually associated with finer particles, the mesh size used during the pre-treatment of soil samples may affect their quantification.</p><p>This study aims to assess the impact of soil particle size on total heavy metal concentrations in the soil. Soil samples were collected at 0-30cm depth in an agricultural field with sandy loam texture, fertilized with urban sludge amendment for 3 years. These samples were then divided in four subsamples and sieved with 2mm, 500µm, 250µm and 106µm meshes (soil aggregates were broken softly but soil wasn’t milled). Finer and coarser fractions were weighted and analyzed separately. Heavy metals were extracted with Aqua Regia method, using a mass for analyze of 3g, and quantified by atomic absorption spectrophotometer with graphite furnace (Cd) and flame (Cu, Ni, Pb, Zn and Cr).</p><p>Except for Cu, heavy metals concentrations increase linearly with the decline of the coarser fraction. This means that analyzing heavy metals content only in the finest fractions of the soil leads to an over estimation of their concentrations in the total soil. Results also show that coarser fractions of soil comprise lower, but not negligible, concentrations of heavy metals. Calculating heavy metal concentrations in the soil based on the weighted average of both fine and coarse fractions and associated concentrations, provide similar results to those driven by the analyses of heavy metals in the <2mm fraction. This indicates that milling and analyzing finer fractions of the soil did not influence the quantification of heavy metals in total soil. Clearer indications on analytical procedures should be provided in analytical standards, in order to properly assess heavy metal concentrations and compare the results with soil quality standards legislated.  </p>


2020 ◽  
Vol 14 (3) ◽  
pp. 420-429
Author(s):  
Guiping Xu ◽  
Chaobing Deng ◽  
Wei Guo ◽  
Hongxiang Zhu ◽  
Xiaofei Wang ◽  
...  

Seven varieties of sugarcane were grown on soil polluted with heavy metals, including Pb, Cd, and As. Sugarcane growth, the heavy metal contents in different sugarcane tissues, and the subcellular distributions of the heavy metals in the roots and leaves were analyzed. The purpose of this investigation was to study sugarcane growth tolerance, the accumulation of heavy metals and the mechanism of sugarcane tolerance to heavy metals at the subcellular level. Health risk assessments were performed according to the models recommended by the United States Environmental Protection Agency (US EPA). The patterns of heavy metal storage were demonstrated to differ among different tissues in all sugarcane varieties investigated. Most of the heavy metals that were absorbed accumulated in the roots of the sugarcane, and the heavy metals in the root cells were mostly located in the cell wall. The health risk index was used to analyze the juice and indicated that the consumption of sugarcane juice by adults and children posed no significant health risks. This study shows that sugarcane grown on heavy metal-contaminated farmland is safe for consumption. The results of this study revealed an important and positive implication regarding the cultivation of sugarcane on farmland that is polluted by heavy metals and the potential to simultaneously achieve sustainable economic output and potential environmental restoration.


2019 ◽  
Vol 5 (2) ◽  
pp. 181
Author(s):  
Rr. Febrina Anggraini Putri, Endang Dewi Masithah, Muhammad Arief

Abstract Sea cucumber is a commodity fishery that is traded international. One of the sea cucumber that has economic value is the local sea cucumber (Phyllophorus sp.) believed that contain compounds can be immunomodulatory. Phyllophorus sp. is one of the three dominant species of sea cucumbers in abundance and distribution in the Surabaya East Coast (Winarni,dkk., 2010). Coastal environmental issues that deserve the attention is the problem of heavy metal pollution in coastal waters. The highest toxicity of heavy metals for aquatic animals and humans are mercury (Hg) (Widowati dkk, 2008). The purpose of this study was to determine levels of heavy metals bioaccumulation of mercury (Hg) in the local sea cucumber (Phyllophorus sp.) From the East Coast Surabaya and to determine the heavy metal content of mercury (Hg) in the local sea cucumber (Phyllophorus sp.) has exceeded the threshold or does not. The experiment was conducted on the East Coast Surabaya and analisys of heavy metal Mercury (Hg) in Balai Besar Laboratorium Kesehatan (BBLK) Surabaya. The method used is the method of field observation and analyzed descriptively. The results showed levels of mercury bioaccumulation of heavy metals (Hg) from BCFo-w value from 454.78– 802.05 and BCFo-s from 31,42 – 111,26. This shows Phyllophorus sp. have the ability to accumulate heavy metals with low until middle accumulation level category. Mercury content of the Phyllophorus sp. obtained range from 0.031 to 0.061 ppm, sea water ranged from 0.0015 to 0.0023 ppm and sediments ranged from 0.0417 to 0.112 ppm. Mercury levels in Phyllophorus sp. and sediment is below the NAB, but the sea water has exceeded from NAB. Water quality parameters are still in normal conditions in accordance with the quality standards KMLH (2004) that temperatures 26-28 º C, pH 7-8, salinity ranged from 28-29 ‰, DO value range 4-5 mg / L and brightness between 2-3 m.


2021 ◽  
Vol 2021 ◽  
pp. 1-6
Author(s):  
Esubalew Kasaw ◽  
Zelalem Adane ◽  
Gemeda Gebino ◽  
Nakachew Assefa ◽  
Abera Kechi ◽  
...  

The rapid growth of textile industries in Ethiopia plays an important role in economic development. However, the sludge from these wastewater treatment plants, which is not an integral part of the treatment process, is often considered hazardous as it is contaminated with heavy metals of dyestuffs and chemicals. The customary transfer routines such as landfilling and incineration may not be suitable because the leachate from the landfilling destinations and the buildups from the incinerators lead to optional contamination. Moreover, such transfer choices are not financially practical. Therefore, there is a growing need to look for various applications of sludge handling for sustainable development. This study attempts to find out an environmentally friendly solution for the management of the textile sludge by incinerating the sludge and using it for partial replacement of cement in concrete production. Concrete is a composite material formed by the combination of cement, sand, coarse aggregate, and water in a particular proportion so that concrete produced meets the needs regarding its workability, strength, durability, and economy. Typical textile sludge was having high heavy metal contents as per the United States Environmental Protection Agency (USEPA) guideline and should be properly disposed of. The sludge upon incineration at 625°C for four hours gives 78.1% moisture content, 61.2% volatile organic matter, and 59.6% inorganic ash content. The main reactive oxide elements such as SiO2, Fe2O3, CaO, and Al2O3 were found to be 18.51, 3.19, 23.87, and 12.73% by weight in the ash. The calorific value determined from the dried sludge were found to be 1973 cal/gm. Concrete block was manufactured by replacement of cement with 10, 20, 30, 40, and 50% incinerated textile sludge ash, and the manufactured block was evaluated in terms of their compressive strengths, leaching behavior, and water absorption. The replacement cement by the ash increases the hydration time reduced, and up to 20%, sludge ash incorporation in the concrete mix design gives the designed compressive strength. Eventhough water absorption increases with increasing content of the incorporation of the ash, for the 20% replacement of cement, the lethal concentration of heavy metals was obtained to be below the permissible limit set by USEPA. Consequently, the experiment work indicates that the potential use of textile sludge ash for cement concrete gives the possibilities of reduction of heavy metal contamination to surroundings upon sludge disposal, reduces the use of raw materials for producing cement and reduces environmental pollution during cement production.


2021 ◽  
Vol 2021 ◽  
pp. 1-21
Author(s):  
Abate Ayele ◽  
Yakob Godebo Godeto

Heavy metals generated mainly through many anthropogenic processes, and some natural processes have been a great environmental challenge and continued to be the concern of many researchers and environmental scientists. This is mainly due to their highest toxicity even at a minimum concentration as they are nonbiodegradable and can persist in the aquatic and terrestrial environments for long periods. Chromium ions, especially hexavalent ions (Cr(VI)) generated through the different industrial process such as tanneries, metallurgical, petroleum, refractory, oil well drilling, electroplating, mining, textile, pulp and paper industries, are among toxic heavy metal ions, which pose toxic effects to human, plants, microorganisms, and aquatic lives. This review work is aimed at biosorption of hexavalent chromium (Cr(VI)) through microbial biomass, mainly bacteria, fungi, and microalgae, factors influencing the biosorption of chromium by microorganisms and the mechanism involved in the remediation process and the functional groups participated in the uptake of toxic Cr(VI) from contaminated environments by biosorbents. The biosorption process is relatively more advantageous over conventional remediation technique as it is rapid, economical, requires minimal preparatory steps, efficient, needs no toxic chemicals, and allows regeneration of biosorbent at the end of the process. Also, the presence of multiple functional groups in microbial cell surfaces and more active binding sites allow easy uptake and binding of a greater number of toxic heavy metal ions from polluted samples. This could be useful in creating new insights into the development and advancement of future technologies for future research on the bioremediation of toxic heavy metals at the industrial scale.


Author(s):  
Aiman M. Bobaker ◽  
Intisar Alakili ◽  
Sukiman B. Sarmani ◽  
Nadhir Al-Ansari ◽  
Zaher Mundher Yaseen

Henna and walnut tree bark are widely used by Libyan women as cosmetics. They may contain lead (Pb), cadmium (Cd) and arsenic (As), which, in turn, pose a high risk to their health. This study aims to determine the levels of Pb, Cd and As in henna and walnut tree bark products sold in Libyan markets. The products were analyzed for their Pb, Cd and As content by using inductively coupled plasma mass spectrometry (ICP-MS) after a microwave acid digestion. The results showed a significant difference between the henna and walnut tree bark samples in terms of their heavy metals content (p < 0.05). The highest heavy metal concentrations were observed in the walnut tree bark samples whereas the lowest was observed in the henna samples. In addition, 60% of the henna and 90% of the walnut tree bark samples contained Pb levels and approximately 80% of the henna and 90% the walnut tree bark samples contained Cd levels, which are much higher than the tolerance limit. However, As concentrations in all the samples were lower. The results indicated that such cosmetics expose consumers to high levels of Pb and Cd and hence, to potential health risks. Thus, studying the sources and effects of heavy metals in such cosmetics is strongly recommended.


2010 ◽  
Vol 46 (No. 4) ◽  
pp. 159-170 ◽  
Author(s):  
H.M. El-Sharabasy ◽  
A. Ibrahim

The continued use of waste water for irrigation of agricultural fields in Egypt may lead to accumulation of heavy metals in soils and adverse effects on soil-living communities. We investigated responses of oribatid communities to heavy metal contamination in mango plantations irrigated by the Ismailia canal in the Suez region. Mean concentrations of heavy metals determined in irrigation water were considerably above the recommended levels. Concentrations of metals in agricultural soil were however below the permissible levels. A comparison with concentrations of a typical uncontaminated soil in this area revealed that the Ismailia water canal used for irrigation of agricultural land has elevated levels of heavy metals. The results of our ecological survey showed that the abundance and structure of the soil oribatid communities were not influenced by levels of heavy metals in the soil. We also showed that the diversity index can be a valuable tool for assessing the possible impact of pollutants on different species of oribatid mites. The oribatid species appeared to be accumulating different amounts of heavy metals when characterised by their bioconcentration factors. Most species were poor zinc accumulators. The accumulation of heavy metals in the body of oribatids was not strictly determined by their body size or by the trophic level. In conclusion, our study showed that mango plantations impacted by waste water from the Ismailia canal are accumulating heavy metals in their soils above the background concentrations, but ecological effects on soil-living communities are not apparent yet.


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