Investigation of technology schemes for the production of cast composite functional materials

Author(s):  
S. V. Knyazev ◽  
A. I. Kutsenko ◽  
A. A. Usol'tsev ◽  
R. A. Gizatulin ◽  
N. V. Oznobikhina

Obtaining and using ligatures, modifiers and deoxidizers to obtain structural alloys of a given composition and properties in metallurgy and foundry is an important production task. One of the existing developments in the field of technologies for the preparation of functional composites on a matrix basis for non-ferrous and ferrous alloys is the combination of solid filler with a melt of an active metal binder. At that, from the filler material, which is selected from the group comprising iron, nickel, titanium, silicon, boron, manganese, first a porous workpiece of a given geometric shape with a technological total pore volume is formed, then it is heated to a temperature corresponding to the liquidus temperature of the active binder, the heating being carried out in a gas inert medium, after which the heated workpiece is impregnated with the melt of this binder by forced infiltration of the melt into the pores of the workpiece under pressure, mainly by the method of liquid stamping. The task of the study was to expand the scope of use of composites, to create a single flexible universal, and at the same time, simplified technology that will provide an opportunity to obtain a wide range of diverse in composition and service characteristics of deoxidizers, modifiers and ligatures for non-ferrous and ferrous alloys. The developed technology, based on vacuum impregnation (suction) of the matrix alloy through porous filler, makes it possible to obtain new functional metal-matrix composite materials of a given composition for use as inexpensive ligatures, modifiers and deoxidizers in metallurgical processes, as well as to simplify and make their use safe. The proposed method for obtaining ligatures, modifiers and deoxidizers provides a possibility of their industrial serial production and is easy to perform, and also reduces the cost of the metallurgy product obtained with their application by increasing the effective content of active components and their more complete assimilation, which reduces the consumption of scarce and expensive materials.

2021 ◽  
Vol 8 ◽  
Author(s):  
E. D. Martínez ◽  
A. Prado ◽  
M. Gonzalez ◽  
S. Anguiano ◽  
L. Tosi ◽  
...  

Nanocomposites formed by a phase-dispersed nanomaterial and a polymeric host matrix are highly attractive for nano- and micro-fabrication. The combination of nanoscale and bulk materials aims at achieving an effective interplay between extensive and intensive physical properties. Nanofillers display size-dependent effects, paving the way for the design of tunable functional composites. The matrix, on the other hand, can facilitate or even enhance the applicability of nanomaterials by allowing their easy processing for device manufacturing. In this article, we review the field of polymer-based nanocomposites acting as resist materials, i.e. being patternable through radiation-based lithographic methods. A comprehensive explanation of the synthesis of nanofillers, their functionalization and the physicochemical concepts behind the formulation of nanocomposites resists will be given. We will consider nanocomposites containing different types of fillers, such as metallic, magnetic, ceramic, luminescent and carbon-based nanomaterials. We will outline the role of nanofillers in modifying various properties of the polymer matrix, such as the mechanical strength, the refractive index and their performance during lithography. Also, we will discuss the lithographic techniques employed for transferring 2D patterns and 3D shapes with high spatial resolution. The capabilities of nanocomposites to act as structural and functional materials in novel devices and selected applications in photonics, electronics, magnetism and bioscience will be presented. Finally, we will conclude with a discussion of the current trends in this field and perspectives for its development in the near future.


Author(s):  
D Charles

Metal matrix composites (MMCs) offer considerable potential for providing lightweight components exhibiting high strength, high stiffness, good wear resistance and improved elevated temperature performance in comparison to the matrix alloy. Consequently they are applicable to a wide range of aerospace products. The potential offered by this class of materials has resulted in considerable effort being expanded to address the challenges posed by the design*** and manufacture of aerospace components from these materials. These efforts have culminated in the successful design, manufacture and test of representative aircraft components from metal matrix composites.


2020 ◽  
Vol 72 (10) ◽  
pp. 1153-1158 ◽  
Author(s):  
Yafei Deng ◽  
Xiaotao Pan ◽  
Guoxun Zeng ◽  
Jie Liu ◽  
Sinong Xiao ◽  
...  

Purpose This paper aims to improve the tribological properties of aluminum alloys and reduce their wear rate. Design/methodology/approach Carbon is placed in the model at room temperature, pour 680°C of molten aluminum into the pressure chamber, and then pressed it into the mold containing carbon felt through a die casting machine, and waited for it to cool, which used an injection pressure of 52.8 MPa and held the same pressure for 15 s. Findings The result indicated that the mechanical properties of matrix and composite are similar, and the compressive strength of the composite is only 95% of the matrix alloy. However, the composite showed a low friction coefficient, the friction coefficient of Gr/Al composite is only 0.15, which just is two-third than that of the matrix alloy. Similarly, the wear rate of the composite is less than 4% of the matrix. In addition, the composite can avoid severe wear before 200°C, but the matrix alloy only 100°C. Originality/value This material has excellent friction properties and is able to maintain this excellent performance at high temperatures. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-10-2019-0454/


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1422
Author(s):  
Viktor V. Revin ◽  
Alexander V. Dolganov ◽  
Elena V. Liyaskina ◽  
Natalia B. Nazarova ◽  
Anastasia V. Balandina ◽  
...  

Currently, there is an increased demand for biodegradable materials in society due to growing environmental problems. Special attention is paid to bacterial cellulose, which, due to its unique properties, has great prospects for obtaining functional materials for a wide range of applications, including adsorbents. In this regard, the aim of this study was to obtain a biocomposite material with adsorption properties in relation to fluoride ions based on bacterial cellulose using a highly productive strain of Komagataeibacter sucrofermentans H-110 on molasses medium. Films of bacterial cellulose were obtained. Their structure and properties were investigated by FTIR spectroscopy, NMR, atomic force microscopy, scanning electron microscopy, and X-ray structural analysis. The results show that the fiber thickness of the bacterial cellulose formed by the K. sucrofermentans H-110 strain on molasses medium was 60–90 nm. The degree of crystallinity of bacterial cellulose formed on the medium was higher than on standard Hestrin and Schramm medium and amounted to 83.02%. A new biocomposite material was obtained based on bacterial cellulose chemically immobilized on its surface using atomic-layer deposition of nanosized aluminum oxide films. The composite material has high sorption ability to remove fluoride ions from an aqueous medium. The maximum adsorption capacity of the composite is 80.1 mg/g (F/composite). The obtained composite material has the highest adsorption capacity of fluoride from water in comparison with other sorbents. The results prove the potential of bacterial cellulose-based biocomposites as highly effective sorbents for fluoride.


Pharmaceutics ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1125
Author(s):  
Raluca Nicu ◽  
Florin Ciolacu ◽  
Diana E. Ciolacu

Nanocelluloses (NCs), with their remarkable characteristics, have proven to be one of the most promising “green” materials of our times and have received special attention from researchers in nanomaterials. A diversity of new functional materials with a wide range of biomedical applications has been designed based on the most desirable properties of NCs, such as biocompatibility, biodegradability, and their special physicochemical properties. In this context and under the pressure of rapid development of this field, it is imperative to synthesize the successes and the new requirements in a comprehensive review. The first part of this work provides a brief review of the characteristics of the NCs (cellulose nanocrystals—CNC, cellulose nanofibrils—CNF, and bacterial nanocellulose—BNC), as well as of the main functional materials based on NCs (hydrogels, nanogels, and nanocomposites). The second part presents an extensive review of research over the past five years on promising pharmaceutical and medical applications of nanocellulose-based materials, which have been discussed in three important areas: drug-delivery systems, materials for wound-healing applications, as well as tissue engineering. Finally, an in-depth assessment of the in vitro and in vivo cytotoxicity of NCs-based materials, as well as the challenges related to their biodegradability, is performed.


Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 548 ◽  
Author(s):  
Leonid Agureev ◽  
Valeriy Kostikov ◽  
Zhanna Eremeeva ◽  
Svetlana Savushkina ◽  
Boris Ivanov ◽  
...  

The article presents the study of alumina nanoparticles’ (nanofibers) concentration effect on the strength properties of pure nickel. The samples were obtained by spark plasma sintering of previously mechanically activated metal powders. The dependence of the grain size and the relative density of compacts on the number of nanofibers was investigated. It was found that with an increase in the concentration of nanofibers, the average size of the matrix particles decreased. The effects of the nanoparticle concentration (0.01–0.1 wt.%) on the elastic modulus and tensile strength were determined for materials at 25 °C, 400 °C, and 750 °C. It was shown that with an increase in the concentration of nanofibers, a 10–40% increase in the elastic modulus and ultimate tensile strength occurred. A comparison of the mechanical properties of nickel in a wide range of temperatures, obtained in this work with materials made by various technologies, is carried out. A description of nanofibers’ mechanisms of influence on the structure and mechanical properties of nickel is given. The possible impact of impurity phases on the properties of nickel is estimated. The tendency of changes in the mechanical properties of nickel, depending on the concentration of nanofibers, is shown.


2020 ◽  
Vol 20 (1) ◽  
Author(s):  
Vincent Vandewalle ◽  
Alexandre Caron ◽  
Coralie Delettrez ◽  
Renaud Périchon ◽  
Sylvia Pelayo ◽  
...  

Abstract Background Usability testing of medical devices are mandatory for market access. The testings’ goal is to identify usability problems that could cause harm to the user or limit the device’s effectiveness. In practice, human factor engineers study participants under actual conditions of use and list the problems encountered. This results in a binary discovery matrix in which each row corresponds to a participant, and each column corresponds to a usability problem. One of the main challenges in usability testing is estimating the total number of problems, in order to assess the completeness of the discovery process. Today’s margin-based methods fit the column sums to a binomial model of problem detection. However, the discovery matrix actually observed is truncated because of undiscovered problems, which corresponds to fitting the marginal sums without the zeros. Margin-based methods fail to overcome the bias related to truncation of the matrix. The objective of the present study was to develop and test a matrix-based method for estimating the total number of usability problems. Methods The matrix-based model was based on the full discovery matrix (including unobserved columns) and not solely on a summary of the data (e.g. the margins). This model also circumvents a drawback of margin-based methods by simultaneously estimating the model’s parameters and the total number of problems. Furthermore, the matrix-based method takes account of a heterogeneous probability of detection, which reflects a real-life setting. As suggested in the usability literature, we assumed that the probability of detection had a logit-normal distribution. Results We assessed the matrix-based method’s performance in a range of settings reflecting real-life usability testing and with heterogeneous probabilities of problem detection. In our simulations, the matrix-based method improved the estimation of the number of problems (in terms of bias, consistency, and coverage probability) in a wide range of settings. We also applied our method to five real datasets from usability testing. Conclusions Estimation models (and particularly matrix-based models) are of value in estimating and monitoring the detection process during usability testing. Matrix-based models have a solid mathematical grounding and, with a view to facilitating the decision-making process for both regulators and device manufacturers, should be incorporated into current standards.


Transient creep following stress reductions has been analysed by the method described by McLean (1980) to determine the friction stress σ 0 as a function of temperature and directional solidification conditions for the γ-γ'-Cr 3 Cr 2 in-situ composite and for the γ-γ' matrix alloy. These values of σ 0 are identical to the flow stresses at creep strain rates and can be identified with the sums of the barriers to dislocation motion through the matrix by climb around γ'-particles and Orowan bowing between the carbide fibres. The friction stress and the kinetics of deformation of the composite are determined by the matrix behaviour, whereas its creep strength depends on the distribution of stress between fibre and matrix. When the steady-state creep behaviour of γ-γ'-Cr 3 C 2 is analysed by using the usual power law description in terms of the effective stress σ — σ 0 , rather than the applied stress σ, the stress exponent is ca 4 and the activation energy is similar to the activation energy of self-diffusion for nickel. The results provide strong evidence for the operation of recovery-creep in both the composite and matrix alloys.


2010 ◽  
Vol 649 ◽  
pp. 101-106
Author(s):  
Mária Svéda ◽  
Dóra Janovszky ◽  
Kinga Tomolya ◽  
Jenő Sólyom ◽  
Zoltán Kálazi ◽  
...  

The aim of our research was to comparatively examine Ni content surface layers on amorphisable Cu base alloy produced by different laser surface treatments. Laser surface treatment (LST) techniques, such as laser surface melting, laser alloying and laser cladding, provide a wide range of interesting solutions for the production of wear and corrosion resistant surfaces. [1,2] With LST techniques, the surface can be: i) coated with a layer of another material by laser cladding, ii) the composition of the matrix can be modified by laser alloying. [3] Two kinds of laser surface treatment technologies were used. In the case of coating-melting technology a Ni content surface layer was first developed by galvanization, and then the Ni content layer was melted together with the matrix. In the case of powder blowing technology Ni3Al powder was blown into the layer melted by laser beam and Argon gas. LST was performed using an impulse mode Nd:YAG laser. The laser power and the interaction time were 2 kW and 20÷60 ms. The characterization of the surface layer microstructure was performed by XRD, scanning electron microscopy and microhardness measurements.


2015 ◽  
Vol 1083 ◽  
pp. 32-36 ◽  
Author(s):  
Alexander Sandulyak ◽  
Anna Sandulyak ◽  
Petr Shkatov

We note that for a wide range of porous, especially granular, ferromagnetics used as matrices of magnetic filter-separators, there is still an issue of defining their demagnetizing factor N which has a dramatic effect on the values of average magnetic permeability of these operating units of filter-separators. The work aims at filling the existent gaps in the issue, we supply N values depending on the relative size of such magnets as well as a respective generalizing phenomenological dependence which is characterized by an exponential realtion between the demagnetizing factor and relative size radical. The established relation allows obtaining real values of magnetic permeability of a short filter matrix thus providing an unbiased comparative estimate of its technological workability.


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