scholarly journals PEMBUATAN ASAM OKSALAT DARI PELEPAH KELAPA SAWIT (Elaeis guineensis) DENGAN KALSIUM HIDROKSIDA

2016 ◽  
Vol 5 (1) ◽  
pp. 40-44
Author(s):  
Iloan Pandang H M ◽  
Yos Pawer Ambarita ◽  
Seri Maulina
Keyword(s):  
Reaction Time ◽  
Melting Point ◽  
Oxalic Acid ◽  
Qualitative Analysis ◽  
Elaeis Guineensis ◽  
Maximum Yield ◽  
Raw Material ◽  
Quality Product ◽  
High Quality Product ◽  
Palm Frond

Palm frond is the solid waste which is high in cellulose. Further processing of palm frond is capable of producing high quality product such as oxalic acid. The aim of this research was to obtain the effect of calcium hydroxide (Ca(OH)2) concentration and reaction time on the yield of oxalic acid produced with palm frond as raw material. This study was done with two steps. The first step was the preparation of palm frond until it was ready to be used. The second step was the conversion step which consists of fusion, filtration and crystallization. Oxalic acid produced was then analyzed with quantitative analysis of yield percentage and qualitative analysis using Fourier Transform Infra Red (FTIR) spectroscopy and plat melting point apparatus. The result showed that the maximum yield of oxalic acid was achieved at Ca(OH)2 concentration of 3.5 N and reaction time of 60 minutes, the value was 6.07 % based on weight of palm frond. The qualitative analysis showed that the vibration of functional groups had approached the standard oxalic acid with the melting point was 106.2 oC.

scholarly journals PEMBUATAN ASAM OKSALAT DARI PELEPAH KELAPA SAWIT (Elaeis guineensis) MELALUI REAKSI OKSIDASI ASAM NITRAT

2015 ◽  
Vol 4 (4) ◽  
pp. 46-50
Author(s):  
Yos Pawer Ambarita ◽  
Iloan Pandang H M ◽  
Seri Maulina
Keyword(s):  
Nitric Acid ◽  
Reaction Time ◽  
Oxalic Acid ◽  
Elaeis Guineensis ◽  
Acid Oxidation ◽  
Molecular Formula ◽  
Acid Product ◽  
Wide Range ◽  
Nitric Acid Oxidation ◽  
Palm Frond

Oxalic acid is a dicarboxylic acid with the molecular formula H2C2O4 which has a wide range of applications in industry. Oxalic acid can be used as fiber bleaching agents, reagents in chemical analysis, and also used in mineral purification of metals. This study aims to determine the effects of temperature and reaction time to quantity and quality of oxalic acid produced by nitric acid oxidation from palm frond powder. The method used for the manufacture of oxalic acid in this study is oxidation method. In this method palm frond powder will be reacted with nitric acid 40 % in the ratio 1: 6 (w/v) at temperature 65, 70, 75, 80, and 85 °C and reaction time 40, 50, 60, 70 and 80 minutes, thus obtained oxalic acid. The research was conducted in several stages: oxidation reaction stage, filtration, precipitation with CaCl2, acidification with H2SO4 and efflorescence. Oxalic acid product quality analyzed using Fourier Transform Infra Red (FTIR) and Plate Melting Point Apparatus. The maksimum yield of oxalic acid was about 23.20 % which obtained at 80 °C and at reaction time 50 minutes.

Microbiological and Sensory Suitability of a Novel Raw Material from Porcine Blood and Collagenous Rind Protein as an Ingredient in a Fermented Raw Salami-Type Sausage

2009 ◽  
Vol 72 (4) ◽  
pp. 826-836 ◽  
Author(s):  
BERNHARD NOWAK ◽  
THEDA von MUEFFLING
Keyword(s):  
Raw Materials ◽  
Meat Product ◽  
Raw Material ◽  
High Quality ◽  
B Values ◽  
Porcine Blood ◽  
Quality Product ◽  
Plate Counts ◽  
By Products ◽  
High Quality Product

The aim of this investigation was to develop a treatment for combined porcine blood corpuscle concentrate (BCC) and porcine collagenous connective tissue (rind) so as to make more use of these slaughter by-products as an ingredient in a high-quality product such as salami-type sausage. For this study, BCC was preserved, standardized (sBCC) (15% NaCl and 25% protein content), and then added (proportion of sBCC to rind, 15:85) to rind subjected to different treatments designated A, B, and C (A, 2 h at 90°C; B, 5 min at 90°C; and C, 2 h at 3°C). One half of each mixture was again heated (designated A1, B1, and C1; F70, ∼15), and the other half was only cooled (designated A2, B2, and C2). The now colored, highly proteinaceous rind mixtures (A1 to C2) were then cooled and granulated (designated GBR-A1 to GBR-C2). Three of the granulates (GBRA1, -B1, and -B2) proved to be promising new raw materials: their aerobic plate counts were <log 4.0 CFU/g, and their color was appealing (L* values, 23.9 to 25.9; a* values, 17.7 to 22.2; b* values, 11.5 to 12.7). These granulates were then substituted for part (5%) of the meat in the production of fermented raw salami-type sausages. Two of the sausages (SA1 and SB1) were microbiologically stable (containing mainly lactobacilli) and had positive sensory, chemical, and physical properties (e.g., protein, 21%; water activity, 0.90; pH, between 5.3 and 5.4 on day 36) meeting all standards for commercially produced raw sausages. Our investigation yielded a practicable way to treat and combine two slaughter by-products for use in a high-quality meat product.

Two-Step Preparation of Bio-Diesel from the Used Bleaching Clay

2012 ◽  
Vol 209-211 ◽  
pp. 1774-1777
Author(s):  
Su Xi Wu ◽  
Shuai Hang Yan ◽  
Hui Cai
Keyword(s):  
Reaction Time ◽  
Maximum Yield ◽  
Acid Value ◽  
Raw Material ◽  
Bleaching Clay ◽  
Molar Ratio ◽  
Alkaline Catalyst ◽  
Orthogonal Experiments ◽  
Optimal Reaction Condition ◽  
Optimal Reaction

with the shortage of the raw material oil for producing bio-diesel in China, the oil, recovered from the used bleaching clay which often be discarded by vegetable oil factory, was used to prepare bio-diesel in this trial. Two-step catalyzed process was adopted to produce biodiesel from the oil. The effect of methanol-to-oil molar ratio, alkaline catalyst quantity, reaction temperature and reaction time on the preesterification and transesterification reaction was investigated through orthogonal experiments. Thus the optimal reaction condition came out. Firstly, the optimal pre-esterification condition, under which the end acid value of the product was minimum (i.e. 1.88 mgKOH/g),was to react for 40 h at 60°C,with a methanol-to-oil molar ratio of 12:1, and by adding alkali catalyst 4% based on the oil weight. Secondly，the optimal transesterification condition, under which the maximum yield of bio-diesel can reach up to 98.2%, was to react for 2.5 h at 60°C,with the methanol-to-oil molar ratio of 7:1, and by adding catalyst 1.25% based on the oil weight.

scholarly journals PEMBUATAN ASAM OKSALAT DARI ALANG-ALANG (Imperata Cylindrica) DENGAN METODE PELEBURAN ALKALI

2015 ◽  
Vol 4 (1) ◽  
pp. 16-19
Author(s):  
Iriany ◽  
Andrew Faguh Sitanggang ◽  
Rahmad Dennie A. Pohan
Keyword(s):  
Melting Point ◽  
Oxalic Acid ◽  
Economic Value ◽  
Cooking Time ◽  
Imperata Cylindrica ◽  
Raw Material ◽  
Wild Plant ◽  
Cooking Temperature ◽  
Crystallization Experiments ◽  
High Cellulose

Imperata grassland is one of the wild plant which have a low economic value but containing high cellulose. Therefore it is potentially to be used as raw material for  oxalic acid manufacturing. The oxalic acid can be produced from imperata grassland through 4 steps: alkaline hydrolysis, precipitacion, acidification and crystallization. Experiments are carried out in a three necks glass equipped with thermometer, mixer, heater and condenser. Cooking solution NaOH  were varied 3,5 N; 4 N  and 4,5 N and cooking time 50, 60, 70 and 80 minutes. According to the result from the experiment, at the condition 98oC of cooking temperature, the highest yield of oxalic acid about 44,39% is obtained at 4 N concentration of sodium hydroxide and 60 minute of cooking time. Oxalic acid produced has 104oC of melting point  and 1,2 of degree of acidity (pH).

scholarly journals PEMBUATAN ASAM OKSALAT DARI PELEPAH KELAPA SAWIT MENGGUNAKAN METODE PELEBURAN ALKALI

2016 ◽  
Vol 5 (3) ◽  
pp. 44-48
Author(s):  
Seri Maulina ◽  
M Hidayat Hasibuan
Keyword(s):  
Reaction Time ◽  
Melting Point ◽  
Oxalic Acid ◽  
Water Content ◽  
Effect Of Temperature ◽  
Cellulose Content ◽  
Alkali Fusion ◽  
Melting Point Analysis ◽  
Purity Analysis ◽  
Palm Fronds

Palm frond is one of the solid waste from oil palm plantations which contains lignocellulose namely cellulose, hemicellulose, and lignin. Cellulose from waste palm fronds can be further processed into useful products and economic value, one of which is used as raw material for making oxalic acid. The purpose of this research is assess the effect of temperature and reaction time in the hydrolysis of palm fronds with alkali fusion method of producing oxalic acid. The research consisted of two stages that is the stage of preparation of palm fronds and the stage of oxalic acid synthesis, which include alkali fusion and crystallization processes. Analysis of the raw materials include the analysis of water content and cellulose content of palm fronds. From the results of this study showed water content is 53.7% and cellulose content is 30.9%. At this research for quantitative analysis includes the conversion of cellulose and yield oxalic acid. From these results obtained optimum conditions at a reaction temperature of 90 °C and a reaction time of 60 minutes the cellulosic conversion is 79.2% and a yield is 59.6% oxalic acid. For qualitative analysis includes purity analysis using FTIR and melting point analysis. FTIR analysis results indicate that the group has approached the standard of oxalic acid and melting point of 101.8 °C which indicates that the oxalic acid is obtained in the form of oxalic acid dihydrate.

scholarly journals KARAKTERISTIK KARBON AKTIF DARI PEMANFAATAN LIMBAH TANAMAN KELAPA SAWIT DENGAN PENAMBAHAN AKTIVATOR NATRIUM KARBONAT (Na2CO3) DAN NATRIUM KLORIDA (NaCl)

2018 ◽  
Vol 6 (4) ◽  
pp. 41-44
Author(s):  
Gewa Handika ◽  
Seri Maulina ◽  
Vidyanova Anggun Mentari
Keyword(s):  
Activated Carbon ◽  
Oil Palm ◽  
Activated Carbons ◽  
Elaeis Guineensis ◽  
Liquid Waste ◽  
Raw Material ◽  
Average Weight ◽  
Palm Tree ◽  
Oil Palm Frond ◽  
Palm Frond

Oil palm tree can produce 22 oil palm frond / year, the average weight of frond per rod reaches 2.2 kg, so that each hectare can produce fresh frond about 9 tons / year or equivalent to 1.64 tons / year of dry matter. Activated carbon can be used as a good absorbent agent for gas purification process and removal of organic pollutants from water, such as in liquid waste. The objective of this paper is to know the different characteristics of activated carbon from oil palm frond (elaeis guineensis jacq) as raw material with variation of activator sodium carbonate (Na2CO3) and sodium chloride (NaCl). The activator concentration used is 10% each with an activation temperature of 600 ° C. The quality of activated carbons was analyzed by surface active carbon morphology and FTIR spectra analysis on activated carbon. The result of identification with FTIR spectrophotometer showed that the activated carbon in this study contained the functional groups of O-H, C = O, C = C, C-C, and C-H.

scholarly journals PRODUKSI BIODIESEL DARI LEMAK SAPI DENGAN PROSES TRANSESTERIFIKASI DENGAN KATALIS BASA NaOH

2013 ◽  
Vol 2 (1) ◽  
pp. 1-6
Author(s):  
Ranggita Dwi Nindya Affandi ◽  
Toni Rizki Aruan ◽  
Taslim ◽  
Iriany
Keyword(s):  
Reaction Time ◽  
Beef Tallow ◽  
Low Cost ◽  
Maximum Yield ◽  
Single Step ◽  
Raw Material ◽  
Biodiesel Production ◽  
National Standard ◽  
Molar Ratio ◽  
Reflux Condenser

Biodiesel is an alternative fuel commonly produced from vegetable oil or animal fat with methanol through transesterification. Beef tallow was used as a raw material of transesterification to make biodiesel, because the price of beef tallow was driven down by the market and to reduce the pollution to the surrounding. In this research variable observed were reaction temperature, reaction time and amount of catalyst. Transesterification was carried out in a three necked spherical Pyrex vessel equipped with reflux condenser, stirrer and thermometer. In the present investigation an attempt has been made to use beef tallow as low cost sustainable potential feedstock for biodiesel production by single step transesterification process. Under optimal condition, the maximum yield of 95,67 % beef tallow methyl ester was obtained by using 6 : 1 molar ratio of beef tallow to methanol at 50 oC for a reaction time 30 minutes in the presence of 0,8 wt% of NaOH catalyst. The biodiesel properties were comparable to Indonesian National Standard (SNI). The results of this work showed that the use of beef tallow is suitable for feedstock of biodiesel production with low cost.

scholarly journals Clinoptilolite as a natural, active zeolite catalyst for the chemical transformations of geraniol

2021 ◽  
Author(s):  
Anna Fajdek-Bieda ◽  
Agnieszka Wróblewska ◽  
Piotr Miądlicki ◽  
Jadwiga Tołpa ◽  
Beata Michalkiewicz
Keyword(s):  
Reaction Time ◽  
Nitrogen Adsorption ◽  
Carbon Chain ◽  
Raw Material ◽  
Chemical Transformations ◽  
Renewable Biomass ◽  
Ft Ir ◽  
Catalyst Content ◽  
Favorable Conditions ◽  
Instrumental Methods

AbstractThis work presented the studies with the natural zeolite—clinoptilolite as the catalyst for the isomerization of geraniol. During the research, it turned out that the studied process is much more complicated, and not only isomerization takes place in it, but also dehydration, oxidation, dimerization, cyclization and fragmentation of the carbon chain. Geraniol is an organic raw material which can be obtained not only by a chemical synthesis but also from plants (renewable biomass) by distillation or extraction method, for example a source of geraniol can be a plant—geranium. Before catalytic tests clinoptilolite was characterized by the instrumental methods, such as: XRD, porosity studies—nitrogen adsorption at 77 K, SEM, EDXRF, and FT-IR. Gas chromatography analyses showed that the main products of geraniol isomerization process were 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol. The selectivity of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol depended on the temperature, catalyst content and reaction time. These parameters were changed in the following ranges: 80–150 °C (temperature), 5–15 wt% (catalyst content) and 15–1440 min. (reaction time). The most favorable conditions for 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol obtaining were: temperature 140 ºC, catalyst content 12.5 wt% and reaction time 180 min. At these conditions, the conversion of geraniol amounted to 98 mol%, and the selectivities of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol amounted to 14 and 47 mol%, respectively.

scholarly journals Continuous-Flow Processes for the Production of Floxacin Intermediates: Efficient C–C Bond Formation through a Rapid and Strong Activation of Carboxylic Acids

2020 ◽  
Vol 02 (03) ◽  
pp. e128-e132
Author(s):  
Shao-Zheng Guo ◽  
Zhi-Qun Yu ◽  
Wei-Ke Su
Keyword(s):  
Reaction Time ◽  
Continuous Flow ◽  
Flow System ◽  
Bond Formation ◽  
Product Yield ◽  
Raw Material ◽  
Material Consumption ◽  
Tank Reactor ◽  
Mild Conditions ◽  
Flow Processes

AbstractThe development of highly efficient C–C bond formation methods for the synthesis of ethyl 2-(2,4-dichloro-5-fluorobenzoyl)-3-(dimethylamino)acrylate 1 in continuous flow processes has been described, which is based on the concept of rapid and efficient activation of carboxylic acid. 2,4-Dichloro-5-fluorobenzoic acid is rapidly converted into highly reactive 2,4-dichloro-5-fluorobenzoyl chloride by treating with inexpensive and less-toxic solid bis(trichloromethyl)carbonate. And then it rapidly reacts with ethyl 3-(dimethylamino)acrylate to afford the desired 1. This process can be performed under mild conditions. Compared with the traditional tank reactor process, less raw material consumption, higher product yield, less reaction time, higher operation safety ensured by more the environmentally friendly procedure, and process continuity are achieved in the continuous-flow system.

Conservation and value of local livestock breeds: usefulness of niche products and/or adaptation to specific environments

2005 ◽  
Vol 36 ◽  
pp. 21-31 ◽  
Author(s):  
E. Verrier ◽  
M. Tixier-Boichard ◽  
R. Bernigaud ◽  
M. Naves
Keyword(s):  
Public Policy ◽  
Genetic Resources ◽  
High Quality ◽  
Mountain Areas ◽  
Chicken Breed ◽  
Animal Genetic Resources ◽  
Protected Designation Of Origin ◽  
Quality Product ◽  
High Quality Product

SummaryTwo cases of livestock production involving French local breeds are analysed. The first shows how a high quality product under AOC (Protected Designation of Origin — PDO) has been defined for the Bresse chicken breed, formely kept by fancy breeders. The second shows the role of the local cattle breeds Abondance and Tarentaise in both the use of mountain areas and the development of PDO products. How to consider such values in a public policy dealing with farm animal genetic resources is discussed.

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