scholarly journals The Importance of Being Versatile: INFN-CHNet MA-XRF Scanner on Furniture at the CCR “La Venaria Reale”

2021 ◽  
Vol 11 (3) ◽  
pp. 1197
Author(s):  
Leandro Sottili ◽  
Laura Guidorzi ◽  
Anna Mazzinghi ◽  
Chiara Ruberto ◽  
Lisa Castelli ◽  
...  

At present, the use of non-destructive, non-invasive X-ray-based techniques is well established in heritage science for the analysis and conservation of works of art. X-ray fluorescence (XRF) plays a fundamental role since it provides information on the elemental composition, contributing to the identification of the materials present on the superficial layers of an artwork. Whenever XRF is combined with the capability of scanning an area to provide the elemental distribution on a surface, the technique is referred to as macro X-ray fluorescence (MA-XRF). The heritage science field, in which the technique is extensively applied, presents a large variety of case studies. Typical examples are paintings, ceramics, metallic objects and manuscripts. This work presents an uncommon application of MA-XRF analysis to furniture. Measurements have been carried out with the MA-XRF scanner of the INFN-CHNet collaboration at the Centro di Conservazione e Restauro “La Venaria Reale”, a leading conservation centre in the field. In particular, a chinoiserie lacquered cabinet of the 18th century and a desk by Pietro Piffetti (1701–1777) have been analysed with a focus on the characterisation of decorative layers and different materials (e.g., gilding in the former and ivory in the latter). The measurements have been carried out using a telemeter for non-planar surfaces, and with collimators of 0.8 mm and 0.4 mm diameter, depending on the spatial resolution needed. The combination of the small measuring head with the use of the telemeter and of a small collimator has guaranteed the ability to scan difficult-to-reach areas with high spatial resolution in a reasonable time (20 × 10 mm2 with 0.2 mm step in less than 20 min).

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 4
Author(s):  
Alessia Coccato ◽  
Maria Cristina Caggiani ◽  
Roberta Occhipinti ◽  
Paolo Mazzoleni ◽  
Alessandro D’Alessio ◽  
...  

Fragments and micro-fragments of painted plasters from the Sphinx Room, recently discovered in the Domus Aurea Esquiline wing (Rome, Italy), were studied. They were respectively taken from the debris in the vicinity of the walls and from already damaged edges of the decorated walls. A previous study, mainly based on non-destructive and non-invasive investigations, proved effective in giving a general overview of the employed palette, allowing the comparison with paintings from the same palace and other coeval contexts, and also providing some preliminary hints concerning the pictorial technique. Nevertheless, some issues remained unsolved, concerning the pigment mixtures (e.g., lead-/iron-based yellow to red colors; copper-/iron-based green/greyish areas), and the a fresco/a secco painting technique debate. Therefore, cross sections of the above-mentioned fragments were observed by means of Optical (OM) and Scanning Electron (SEM) Microscopy and analyzed with micro-Raman spectroscopy and Energy Dispersive X-Ray Spectroscopy (EDS), with the aims of: studying the paint layer composition through point analysis and mapping of the elemental distribution; comparing these in relation to what was observed with previously reported non-destructive analyses; studying the stratigraphy of the painted plaster, focusing on the contact between the plaster and the paint.


2021 ◽  
Vol 11 (4) ◽  
pp. 1446
Author(s):  
Jacopo Orsilli ◽  
Anna Galli ◽  
Letizia Bonizzoni ◽  
Michele Caccia

Among the possible variants of X-Ray Fluorescence (XRF), applications exploiting scanning Macro-XRF (MA-XRF) are lately widespread as they allow the visualization of the element distribution maintaining a non-destructive approach. The surface is scanned with a focused or collimated X-ray beam of millimeters or less: analyzing the emitted fluorescence radiation, also elements present below the surface contribute to the elemental distribution image obtained, due to the penetrative nature of X-rays. The importance of this method in the investigation of historical paintings is so obvious—as the elemental distribution obtained can reveal hidden sub-surface layers, including changes made by the artist, or restorations, without any damage to the object—that recently specific international conferences have been held. The present paper summarizes the advantages and limitations of using MA-XRF considering it as an imaging technique, in synergy with other hyperspectral methods, or combining it with spot investigations. The most recent applications in the cultural Heritage field are taken into account, demonstrating how obtained 2D-XRF maps can be of great help in the diagnostic applied on Cultural Heritage materials. Moreover, a pioneering analysis protocol based on the Spectral Angle Mapper (SAM) algorithm is presented, unifying the MA-XRF standard approach with punctual XRF, exploiting information from the mapped area as a database to extend the comprehension to data outside the scanned region, and working independently from the acquisition set-up. Experimental application on some reference pigment layers and a painting by Giotto are presented as validation of the proposed method.


NIR news ◽  
2017 ◽  
Vol 28 (5) ◽  
pp. 7-12 ◽  
Author(s):  
Te Ma ◽  
Tetsuya Inagaki ◽  
Satoru Tsuchikawa

Wood density and microfibril angle are strongly correlated with wood stiffness, shrinkage, and anisotropy. Understanding the spatial distribution of these values is critical for solid timber applications. In this study, near infrared (NIR) hyperspectral imaging was used to evaluate wood density and microfibril angle in a non-destructive, yet effective manner. Briefly, five wood samples collected from both normal and compression parts of two different Cryptomeria japonica trees were analyzed. Partial least squares regression analysis was performed to determine the relationship between X-ray reference data and NIR spectra, and cross-validation (leave-one-out) was used for checking prediction performances. The validation coefficient of determination (r2) between predicted densities by the NIR technique and measured values by SilviScan (X-ray data) was 0.83 with a root mean squared error of cross-validation (RMSECV) of 105.18 kg/m3. Regarding microfibril angle, r2 and RMSECV were 0.77 and 5.36°, respectively. Finally, wood density and microfibril angle were successfully mapped at a high spatial resolution (156 µm) to facilitate the detection of annual growth ring features and evaluation of aspects of heterogeneous wood quality.


2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Mila Andonova

AbstractThis study proposes non-destructive assessment instrumentation, the X-ray MicroCT scanning, to evaluate archaeological basketry remains prior to any destructive analysis. Three case studies are originating from two archaeological sites in Southeast Europe, with three different stages of preservation (poor, sufficient and very good). In addition, there are two preservation modes—charring and desiccation—along with two conservation situations: treated and untreated with conservation agent fragments. The three different scenarios were chosen to explore the potential range of X-ray MicroCT scanning technology when applied to monocotyledonous small-sized archaeological remains. It was proved that this non-invasive X-ray method is particularly suitable for the often-disadvantaged ancient basketry remains.


Coatings ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 471 ◽  
Author(s):  
Philippe Colomban ◽  
Burcu Kırmızı ◽  
Bing Zhao ◽  
Jean-Baptiste Clais ◽  
Yong Yang ◽  
...  

A selection of 10 Chinese enamelled metal wares dating from the 17th–18th centuries (Qing Dynasty) was analysed on-site by mobile Raman microspectroscopy. These wares display cloisonné and/or painted enamels and belong to the collections of Musée du Louvre in Paris and Musée Chinois at the Fontainebleau Castle in France. Pigments (Naples yellow lead pyrochlore, hematite, manganese oxide etc.), opacifiers (fluorite, lead arsenates) and corresponding lead-based glassy matrices were identified. One artefact was also analysed by portable X-ray fluorescence spectrometry (pXRF) in order to confirm the Raman data. In some of these metal wares, it is suggested that cassiterite was unpredictably used as an opacifier in some parts of the decor. The results are compared to previous data obtained on Chinese cloisonné and Limoges enamels as well as recent data recorded on painted enamelled porcelains of the Qing Dynasty. Lead arsenate apatite detected in some of the 17th–18th century blue enamelled decors is related to the use of arsenic-rich European cobalt ores, as also characterized in French soft-paste porcelain and glass decors and high-quality Limoges enamels for the same period. However, lead arsenate could then also have been deliberately used for white opacification. The specific Raman signature displaying the shape of the Raman scattering background indicates the presence of colloidal gold (Au° nanoparticles) in red to violet enamelled and cloisonné areas. At least three types of Naples yellow lead pyrochlore pigments identified with Sb-rich, Sn-rich and mixed Sb–Sn–(Zn, Fe?) compositions prove the use of European pigments/recipes.


2016 ◽  
Vol 374 (6) ◽  
Author(s):  
Koen Janssens ◽  
Geert Van der Snickt ◽  
Frederik Vanmeert ◽  
Stijn Legrand ◽  
Gert Nuyts ◽  
...  

2019 ◽  
Vol 9 (5) ◽  
pp. 1005 ◽  
Author(s):  
Takashi Takiguchi

X-ray tomography and magnetic resonance imaging (MRI) are excellent techniques for non-destructive or non-invasive inspections, however, they have shotcomings including the expensive cost in both the devices themselves and their protection facilities, the harmful side effects of the X-rays to human bodies and to the environment. In view of this argument, it is necessary to develop new, inexpensive, safe and reliable tomographic techniques, especially in medical imaging and non-destructive inspections. There are new tomographic techniques under development such as optical tomography, photo-acoustic tomography, ultrasonic tomography and so on, from which we take ultrasonic tomography as the topic in this paper. We introduce a review of the known ultrasonic tomographic techniques and discuss their future development.


2001 ◽  
Vol 35 (2) ◽  
pp. 167-171 ◽  
Author(s):  
John C. Schofield ◽  
Roseanne M. Grindley ◽  
Jonathan A. Keogh

A method is described for the non-destructive, non-invasive, detection of shell lesions in the New Zealand paua, a marine gastropod Haliotis iris using diagnostic radiology. The X-ray method reliably detected the presence of shell lesions in 96% of the cases examined once lesion dimensions exceeded 6.2 × 7.1 mm. The extent of lesions above this size can be reliably and accurately determined from X-ray images viewed on a video display unit (VDU). Biofouling on the outside of the shell can cause misdiagnoses. This method is a significant animal welfare refinement in the identification of marine gastropods with shell lesions, when compared with traditional techniques which kill the animals.


2016 ◽  
Vol 6 (1) ◽  
Author(s):  
I. Bukreeva ◽  
A. Mittone ◽  
A. Bravin ◽  
G. Festa ◽  
M. Alessandrelli ◽  
...  

Abstract A collection of more than 1800 carbonized papyri, discovered in the Roman ‘Villa dei Papiri’ at Herculaneum is the unique classical library survived from antiquity. These papyri were charred during 79 A.D. Vesuvius eruption, a circumstance which providentially preserved them until now. This magnificent collection contains an impressive amount of treatises by Greek philosophers and, especially, Philodemus of Gadara, an Epicurean thinker of 1st century BC. We read many portions of text hidden inside carbonized Herculaneum papyri using enhanced X-ray phase-contrast tomography non-destructive technique and a new set of numerical algorithms for ‘virtual-unrolling’. Our success lies in revealing the largest portion of Greek text ever detected so far inside unopened scrolls, with unprecedented spatial resolution and contrast, all without damaging these precious historical manuscripts. Parts of text have been decoded and the ‘voice’ of the Epicurean philosopher Philodemus is brought back again after 2000 years from Herculaneum papyri.


2012 ◽  
Vol 1374 ◽  
pp. 17-25
Author(s):  
Jocelyn Alcántara García ◽  
José Luis Ruvalcaba Sil ◽  
Marie Van der Meeren

ABSTRACTThe necessity of studying cultural heritage through non-invasive and non-destructive techniques has led to significant advances in the last decade. One of the most recent advancements in this theme in Mexico is the portable X-ray system SANDRA, which was used to study three manuscripts directly related to the history of “San Nicolás Coatepec”, Mexico. X-ray fluorescence was chosen as the suitable technique because it can provide a fast qualitative and quantitative multielemental high sensitivity analysis. The documents were examined globally, using imaging techniques with UV and IR lighting. This research evinced a change in the composition and evolution of writing materials (inks and pigments) and provided information concerning historical use of the documents and its actual legal value as a property document. It also stressed the need of spanning these results to an extensive research attaining other regions of Mexico, in order to fully understand the Mexican documents particularities, aging and deterioration. This, in turn, will provide not only historical material information but also an invaluable scoop to understand deterioration and conservation issues.


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