scholarly journals Hydrothermal Corrosion Behaviors of Constituent Materials of SiC/SiC Composites for LWR Applications

Ceramics ◽  
2019 ◽  
Vol 2 (4) ◽  
pp. 602-611
Author(s):  
Shoko Suyama ◽  
Masaru Ukai ◽  
Megumi Akimoto ◽  
Toshiki Nishimura ◽  
Satoko Tajima
Keyword(s):  
Corrosion Resistance ◽  
Residual Strength ◽  
Pure Water ◽  
Operating Conditions ◽  
Raw Material ◽  
Stoichiometric Ratio ◽  
Sic Fibers ◽  
Corrosion Behaviors ◽  
Fiber Matrix ◽  
Sic Composites

The corrosion behaviors of SiC/SiC composite constituent materials in pure water at operating conditions, such as 300 °C and 8.5 MPa, were studied for potential application in accident-tolerant light water reactor (LWR) fuel cladding and core structures. Five kinds of SiC fibers, four kinds of SiC matrices, and three kinds of fiber/matrix interphase materials were examined in autoclaves. The potential constituent materials for future use in SiC/SiC composites were selected by considering corrosion rates and residual strength characteristics. The mass changes and the residual strength of each specimen were measured. SEM images of the surface layers were also inspected. The SiC fibers, regardless of their purity, crystallinity or stoichiometric ratio, decreased in strength due to the hydrothermal corrosion. For its part, the hydrothermal corrosion resistance of CVD-SiC, as a SiC matrix, was found to be affected by manufacturing conditions such as raw material gas type and synthesis temperature, as well as post-machining morphology. The CVD-carbon (CVD-C), as a fiber/matrix interphase material, showed good hydrothermal corrosion resistance. In order to protect the SiC fibers and the SiC matrices from hydrothermal corrosion, it would appear to be necessary to apply a dense CVD-C coating to both every fiber and the entire surface of the SiC matrices.

scholarly journals Drying of suspension and pastes in fluidized bed of inert particles

2000 ◽  
Vol 65 (12) ◽  
pp. 963-974 ◽  
Author(s):  
Zeljko Grbavcic ◽  
Zorana Arsenijevic ◽  
Radmila Garic-Grulovic
Keyword(s):  
Pure Water ◽  
Operating Conditions ◽  
Raw Material ◽  
Water Evaporation ◽  
Large Temperature ◽  
Attractive Alternative ◽  
Mechanical Agitation ◽  
Inert Particles ◽  
Fluid Bed ◽  
Drying Efficiency

A fluid bed dryer with inert particles was used for the drying of suspensions and pastes. The effects of the operating conditions on the dryer throughput and on the product quality were investigated. Experiments were performed in a cylindrical column 215 mm in diameter and 1200 mm in height with 0.925 mm diameter glass spheres as the fluidizing media. Cineb fungicide, copper hydroxide and pure water were used as the feed material. With respect to the main efficiency criteria, i.e., specific water evaporation rate, specific heat consumption and specific air consumption, a fluid bed dryer with inert particles represents a very attractive alternative to other drying technologies. A high drying efficiency results from the large contact area and from the large temperature difference between the inlet and outlet air. A rapid mixing of the particles, due to aggregative fluidization and mechanical agitation, leads to nearly isothermal conditions throughout the bed. In our experiments, suspensions and very dense pastes were successfully treated. Suspension and product hold-up in the bed varies between 6 and 8 % by mass and a product with the same particle size as the raw material is obtained.

UNITEMP HX

Alloy Digest ◽  
1964 ◽  
Vol 13 (5) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Physical Properties ◽  
Base Material ◽  
Heat Treating ◽  
Operating Conditions ◽  
High Temperature Strength ◽  
Temperature Performance ◽  
Nickel Base

Abstract Unitemp-HX is a nickel-base material recommended for high temperature applications. It has outstanding oxidation resistance at high temperatures under most operating conditions, and good high-temperature strength. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness and creep. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: Ni-91. Producer or source: Universal Cyclops Steel Corporation.

REMANIT 4306

Alloy Digest ◽  
1997 ◽  
Vol 46 (4) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Austenitic Stainless Steel ◽  
Cold Working ◽  
Heat Treating ◽  
Operating Conditions ◽  
Low Carbon ◽  
Corrosion Resistant ◽  
Temperature Performance

Abstract Remanit 4306 is a low-carbon chromium nickel austenitic stainless steel that is superior in corrosion resistance to type 302 (see Alloy Digest SS-99, revised September 1998). Due to its low carbon content, Remanit 4306 is intergranular corrosion resistant under continuous operating conditions up to 350 C (652 F). This grade is particular suitable for high degrees of cold working and for sequential drawing. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-679. Producer or source: Thyssen Stahl AG.

scholarly journals Tagasaste, leucaena and paulownia: three industrial crops for energy and hemicelluloses production

2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Alberto Palma ◽  
Javier Mauricio Loaiza ◽  
Manuel J. Díaz ◽  
Juan Carlos García ◽  
Inmaculada Giráldez ◽  
...  
Keyword(s):  
Activation Energy ◽  
Acid Hydrolysis ◽  
Energy Production ◽  
Combustion Process ◽  
Operating Conditions ◽  
Raw Material ◽  
Energy Of Combustion ◽  
Increasing Temperature ◽  
Hydrolysis Of ◽  
Chamaecytisus Proliferus

Abstract Background Burning fast-growing trees for energy production can be an effective alternative to coal combustion. Thus, lignocellulosic material, which can be used to obtain chemicals with a high added value, is highly abundant, easily renewed and usually inexpensive. In this work, hemicellulose extraction by acid hydrolysis of plant biomass from three different crops (Chamaecytisus proliferus, Leucaena diversifolia and Paulownia trihybrid) was modelled and the resulting solid residues were used for energy production. Results The influence of the nature of the lignocellulosic raw material and the operating conditions used to extract the hemicellulose fraction on the heat capacity and activation energy of the subsequent combustion process was examined. The heat power and the activation energy of the combustion process were found to depend markedly on the hemicellulose content of the raw material. Thus, a low content in hemicelluloses resulted in a lower increased energy yield after acid hydrolysis stage. The process was also influenced by the operating conditions of the acid hydrolysis treatment, which increased the gross calorific value (GCV) of the solid residue by 0.6–9.7% relative to the starting material. In addition, the activation energy of combustion of the acid hydrolysis residues from Chamaecytisus proliferus (Tagasaste) and Paulownia trihybrid (Paulownia) was considerably lower than that for the starting materials, the difference increasing with increasing degree of conversion as well as with increasing temperature and acid concentration in the acid hydrolysis. The activation energy of combustion of the solid residues from acid hydrolysis of tagasaste and paulownia decreased markedly with increasing degree of conversion, and also with increasing temperature and acid concentration in the acid hydrolysis treatment. No similar trend was observed in Leucaena diversifolia (Leucaena) owing to its low content in hemicelluloses. Conclusions Acid hydrolysis of tagasaste, leucaena and paulownia provided a valorizable liquor containing a large amount of hemicelluloses and a solid residue with an increased heat power amenable to efficient valorization by combustion. There are many potential applications of the hemicelluloses-rich and lignin-rich fraction, for example as multi-components of bio-based feedstocks for 3D printing, for energy and other value-added chemicals.

scholarly journals Chemical Composition and Corrosion Behavior of a-C:H/DLC Film-Coated Titanium Substrate in Simulated PEMFC Environment

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 820
Author(s):  
Beibei Han ◽  
Mengyuan Yan ◽  
Dongying Ju ◽  
Maorong Chai ◽  
Susumu Sato
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Metal Ion ◽  
Ion Beam ◽  
Titanium Substrate ◽  
Corrosion Current ◽  
Ion Concentration ◽  
Bipolar Plates ◽  
High Adhesion ◽  
Corrosion Behaviors

The amorphous hydrogenated (a-C:H) film-coated titanium, using different CH4/H2 and deposition times, was prepared by the ion beam deposition (IBD) method, which has the advantage of high adhesion because of the graded interface mixes at the atomic level. The chemical characterizations and corrosion behaviors of a-C:H film were investigated and evaluated by SEM, AFM, Raman spectroscopy, EPMA, TEM and XPS. An a-C:H film-coated titanium was corroded at 0.8 V, 90 °C in a 0.5 mol/L H2SO4 solution for 168 h. The metal ion concentration in the H2SO4 corrosion solution and the potentiodynamic polarization behavior were evaluated. Results indicate that a higher CH4/H2 of 1:0 and a deposition time of 12 h can result in a minimum ID/IG ratio of 0.827, Ra of 5.76 nm, metal ion concentration of 0.34 ppm in the corrosion solution and a corrosion current of 0.23 µA/cm2. The current density in this work meets the DOE’s 2020 target of 1 µA/cm2. Electrical conductivity is inversely proportional to the corrosion resistance. The significant improvement in the corrosion resistance of the a-C:H film was mainly attributed to the increased sp3 element and nanocrystalline TiC phase in the penetration layer. As a result, the a-C:H film-coated titanium at CH4/H2 = 1:0 with improved anti-corrosion behavior creates a great potential for PEMFC bipolar plates.

scholarly journals Susceptibility to Stress Corrosion of Laser-Welded Composite Arch Wire in Acid Artificial Saliva

2013 ◽  
Vol 2013 ◽  
pp. 1-8
Author(s):  
Chao Zhang ◽  
Xinhua Sun
Keyword(s):  
Weight Loss ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
Shape Memory Alloy ◽  
Artificial Saliva ◽  
Steel Wire ◽  
Niti Shape Memory Alloy ◽  
Solution Ph ◽  
Corrosion Behaviors ◽  
Cu Interlayer

The corrosion resistance of laser-welded composite arch wire (CoAW) with Cu interlayer between NiTi shape memory alloy and stainless steel wire in artificial saliva with different acidities and loads was studied. It was found that both the solution pH and the stress had a significant influence on the corrosion behaviors of the CoAW samples. Decreasing the solution pH or increasing the loading stress caused the increase of Cu release and weight loss. The corroded morphology formed on the surfaces of the CoAW was the consequence under the combined effect of corrosion and stress.

Agglomeration Technologies of Processing Powder Wastes

2015 ◽  
Vol 244 ◽  
pp. 121-129
Author(s):  
Marian Peciar ◽  
Roman Fekete ◽  
Peter Peciar
Keyword(s):  
Research Work ◽  
Operating Conditions ◽  
Airborne Particles ◽  
Raw Material ◽  
Production Cycle ◽  
Shear Forces ◽  
Material Resources ◽  
New Type ◽  
Two Phases ◽  
High Technologies

This article deals with the presentation of modern applications for processing powdered, primarily hazardous, waste to an agglomeration form appropriate for subsequent processing by classical methods, for example in the construction, automotive and consumer goods industries. The aim of the research work was to set appropriate operating conditions in order to appreciate currently non-processable wastes resulting from the intensive production of often extremely expensive materials. Technologies which enable returning powder waste back into the primary production cycle were developed and experimentally tested, thus saving raw material resources. When necessary for the fixing of fine airborne particles with a problematic compacting curve (hard to compress, repulsive due to the surface charge) extrusion processes using a patented technology enabling controlled modification of shear forces in the extrusion zone were successfully applied. A new type of axial extruder allows the elimination of the liquid phase and as a result prevents the clogging of the extrusion chamber. In the case of need for granulation of sensitive materials (for example pharmaceuticals not allowing the addition of any kind of agglomerating fluid or reacting strongly in the contact of the two phases), a process of compaction between rolls with different profiled surface was successfully applied. The developed high technologies and the resulting products thus represent a major contribution to environmental protection in the context of not only the work but also the communal environment.

Natural Convection in an Enclosure With Blend of Micro Encapsulated Phase Change Materials

2013 ◽  
Author(s):  
Yasmin Khakpour ◽  
Jamal Seyed-Yagoobi
Keyword(s):  
Heat Transfer ◽  
Thermal Expansion ◽  
Natural Convection ◽  
Phase Change ◽  
Latent Heat ◽  
Phase Change Materials ◽  
Numerical Study ◽  
Pure Water ◽  
Operating Conditions ◽  
Effective Density

This numerical study investigates the effect of using a blend of micro-encapsulated phase change materials (MEPCMs) on the heat transfer characteristics of a liquid in a rectangular enclosure driven by natural convection. A comparison has been made between the cases of using single component MEPCM slurry and a blend of two-component MEPCM slurry. The natural convection is generated by the temperature difference between two vertical walls of the enclosure maintained at constant temperatures. Each of the two phase change materials store latent heat at a specific range of temperatures. During phase change of the PCM, the effective density of the slurry varies. This results in thermal expansion and hence a buoyancy driven flow. The effects of MEPCM concentration in the slurry and changes in the operating conditions such as the wall temperatures compared to that of pure water have been studied. The MEPCM latent heat and the increased volumetric thermal expansion coefficient during phase change of the MEPCM play a major role in this heat transfer augmentation.

scholarly journals ДОСЛІДЖЕННЯ ГІГІЄНІЧНИХ ВЛАСТИВОСТЕЙ МАТЕРІАЛІВ НАТІЛЬНОЇ ЛІКАРНЯНОЇ БІЛИЗНИ

2020 ◽  
Vol 140 (6) ◽  
pp. 38-47
Author(s):  
І. О. Іванов ◽  
Н. П. Супрун ◽  
Ю. О. Ващенко
Keyword(s):  
Comparative Analysis ◽  
Materials Science ◽  
Experimental Studies ◽  
Operating Conditions ◽  
Raw Material ◽  
Experimental Investigations ◽  
Textile Materials ◽  
Composition And Structure ◽  
Innovative Materials ◽  
Basic Functions

Investigation of the influence of the peculiarities of raw material composition and structure of traditional and innovative linen textile materials on their hygienic properties. Theoretical and experimental investigations are based on the main positions of textile materials science. In experimental studies, modern standardized methods for determining the hygienic properties of textile materials were used, as well as techniques specially developed taking into account the peculiarities of the operating conditions of underwear. The peculiarities of the operating conditions and the basic functions of hospital underwear were determined. The comparative analysis of hygienic properties of traditional and modern fabrics for underwear was carried out. Using the standardized and the developed methods, adapted to the peculiarities of the conditions of use of the products, the indicators characterizing the processes of water absorption of the materials were experimentally determined. On the basis of the obtained values of quality indicators, a comprehensive assessment of the ability of materials to transfer moisture and air, with the calculation of the arithmetic complex quality index was done. This allowed to determine the material that is optimal in properties, which provides thermophysiological comfort when operating hospital underwear. Using the developed methods, which take into account the specifics of the operating conditions, a comparative analysis of the hygienic properties of traditional and innovative materials for underwear was carried out. A new range of textile materials for underwear has been proposed, taking into account the peculiarities of the operational situation of consumption.

scholarly journals Comparison of the Sub-Critical Fluid Extraction of the Essential Oil of Turmeric (Curcuma longa L.) with That of Hydrodistillation

Eng ◽  
2021 ◽  
Vol 2 (4) ◽  
pp. 608-619
Author(s):  
David Mc Gaw ◽  
Rosemarie Skeene
Keyword(s):  
Essential Oil ◽  
Curcuma Longa ◽  
Dry Weight ◽  
Weight Basis ◽  
Operating Conditions ◽  
Raw Material ◽  
Fluid Extraction ◽  
Total Extract ◽  
Pharmaceutical Properties ◽  
The Tropics

Turmeric (Curcuma longa L.) is a spice plant grown in the tropics that contains both an essential oil and an oleoresin. The essential oil is important as a flavouring and has pharmaceutical properties, while the oleoresin is bright yellow in colour and has medicinal properties. The essential oil has traditionally been extracted by hydrodistillation/steam distillation with the total extract being extracted by solvent extraction and more recently by supercritical fluid extraction (SFE). The objective of the work described in this paper was to investigate the possibility of extracting the essential oil using sub-critical fluid extraction and to compare it with hydrodistillation. The experiments using hydrodistillation showed that unpeeled fresh turmeric was the preferred raw material, giving an oil yield of ≈6% dry weight basis, which is similar to that reported in the literature. The experimental programme on the extraction of the oil from dried unpeeled turmeric was carried out over a temperature range from 25 to 30 °C and pressures from 65 to 71 bar. Yields were generally higher than hydrodistillation (up to ≈9% dry weight basis) as were the compositions of the extracted oils. The preferred operating conditions were determined to be 25 °C temperature and 65 bar pressure. Curcumin, the major component of the oleoresin, was not found in the oil, thereby demonstrating that the sub-critical extract is a pure essential oil. It is suggested that consideration be given to evaluating an SFE process whereby the essential oil is initially fully extracted under sub-critical fluid extraction conditions, after which the oleoresin is extracted separately by raising the pressure to ≈250 bar.

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