scholarly journals Experience-Based Physico-Chemical Models for Long-Term Reinforcement Corrosion

2021 ◽  
Vol 2 (1) ◽  
pp. 100-119
Author(s):  
Robert E. Melchers

The long-term corrosion progression of steel reinforcement is important for estimating the life of reinforced concrete infrastructure. Reviews of field experience and results from recent controlled long-term experiments show that the development of reinforcement corrosion is much more complex than the classical empirical Tuutti model. A new, comprehensive model is proposed, referencing observations and inferences from many field and laboratory observations and built on the bi-modal model for the corrosion of steel. It includes the critical roles of air-voids in the concrete at the concrete-steel interface and the effect of long-term alkali leaching as accelerated by the presence of chlorides. Both are affected by compaction and concrete permeability. The role of chlorides in the early stages is confined to pitting within air-voids. These are critical for allowing initiation to occur, while their size influences the severity of early corrosion. Empirical data show that for seawater with an average water temperature in the range of 10–20 °C, the corresponding rate of long-term corrosion ra is in the range of 0.012–0.015 mm/y.

2017 ◽  
Vol 10 (1) ◽  
pp. 9-14
Author(s):  
ME Huda ◽  
MR Nabi

Appropriate fertilizer and their impact on physico-chemical parameters of water and productivity is very important for aquaculture and ecology. Optimum fertilizer dose can help in fish farmer as well as aquaculture sector. From the study it was found that the total physicochemical parameters of water were suitable for aquaculture, drinking water, irrigation and domestic use. The average water temperature was 26.45±2.75oC; 26.50±3.24oC; 25.83±4.08oC; 26.57±3.02oC and 26.53±2.93oC for MCRT-1 to 5 gradually. Water pH in an average was 7.37±0.61; 7.44±0.55; 7.25±0.58; 7.33±0.54 and 7.47±0.49 for Minature Circular Research Tank (MCRT)-1 to 5 respectively. Average water DO were 6.98±1.05 mgl-1; 6.75±1.53 mgl-1; 6.90±1.64 mgl-1; 6.59±1.19mgl-1 and 6.77±1.60mgl-1 for MCRT-1 to 5 respectively. Average water hardness were 71.88 ± 20.47 mgl-1; 60.5 ±2 1.25 mgl-1; 83.38 ± 23.39 mgl-1; 59.13 ± 25.57 mgl-1 and 52.63 ± 7.92 mgl-1 for MCRT-1 to 5 gradually. Average water total phosphorus were 0.77 ± 0.18 mgl-1; 0.83 ± 0.19 mgl-1; 0.78 ± 0.21 mgl-1; 0.84 ± 0.17 mgl-1 and 0.84 ± 0.16 mgl-1 for MCRT-1 to 5 gradually. From planktonic study it was found that the highest phytoplankton and Zooplankton were in MCRT-3. Phytoplanktons were under 27 no. of genera. Their groups were Cyanophyceae, Chlorophyceae, Bacillariophyceae, Euglenophyceae and Hepatecae.Zooplankton were five major taxa and they were Protozoa, Rotifera, Cladocera, Copepod and Ostracoda respectively.J. Environ. Sci. & Natural Resources, 10(1): 9-14 2017


1993 ◽  
Vol 50 (10) ◽  
pp. 2222-2234 ◽  
Author(s):  
Kevin J. Devito ◽  
Peter J. Dillon

Annual retentions of total phosphorus (TP) (−11%) and total nitrogen (TN) (−5%) of a headwater beaver pond in central Ontario were low during 1987–88. Annually, inputs exceeded outputs of total reactive P (71%) and NO3–N (35%), and outputs exceeded inputs of total unreactive P (−33%) and total organic N (−26%), and inputs approximated outputs of NH4–N (−8%). Seasonal trends in P and N retention were inversely correlated with runoff. Monthly retention was weakly positively related to average water temperature and redox potential (ORP). Positive monthly retention coincided with low runoff and high biotic assimilation during the growing season. Winter ice cover was associated with undetectable dissolved oxygen and low ORP and increased levels of P and N, particularly NH4–N. High levels of P and N in the surface water during winter were coupled with increased runoff and potentially low biotic assimilation resulting in a net release of TP and TN. Large flow-through of waterborne inputs and flushing of regenerated P and N occurred during peak snowmelt resulting in low annual retention. Initial accumulation of flooded forest material and input of organic matter by beaver may be very important to P and N dynamics, representing a long-term source of nutrients to the pond water and outflow.


2021 ◽  
Vol 1 (01) ◽  
pp. 15-20
Author(s):  
MD. MAHADIY HASAN ◽  
MD. ASHIKUR RAHMAN LASKAR ◽  
TAHIDUL ISLAM ◽  
TANIA SULTANA

There are many man-made water reservoirs found in Barishal City. This study was aimed to assess the existing condition of physico-chemical properties of four different water reservoirs, namely Bibir Pukur (pond), Amtala Lake, Choumatha Lake and City Corporation Pond of Barishal City of Bangladesh. To evaluate the physico-chemical properties, the average of the parameters such as water temperature, total dissolved solids, electric conductivity (EC), pH, salinity, as well as depth, color, and transparency of water were analyzed. The highest average water temperature was found in the City Corporation Pond, which determined as 31.77±0.09 °C. Electric conductivity (ms/cm) and total dissolved solids (ppm) of Amtala Lake were 0.413 ±0.009 and 199±1.15. The highest average pH 7.88±0.01 and lowest salinity 140±1.73 were found in City Corporation Pond and Choumatha Lake respectively. The water depth of Bibir Pukur was 260.33± 13.98 cm which is the highest among the four water reservoirs. The highest values of dissolved oxygen and phosphate were 2.03±0.12 mg/l and 294.12±3.92 μg/l.


2021 ◽  
Vol 13 (24) ◽  
pp. 13695
Author(s):  
Robert E. Melchers ◽  
Igor A. Chaves

Even in harsh marine environments, concrete structures reinforced with steel can show excellent long-term durability, with little or no reinforcement corrosion. Very few actual reinforced concrete (RC) structures have been closely scrutinized over many years and subject to interpretation using recent state-of-the-art understanding gained from detailed laboratory observations. Such a case is described for an 80-year-old RC structure observed annually over about 30 years in what is essentially an extraordinary long experiment. Despite very high chloride concentrations, field excavation evidence showed that reinforcement corrosion overall remains minimal, except where insufficient concrete compaction permitted air-voids to initiate quite severe, very localized corrosion even with still high concrete pH. It is possible that the use of blast furnace slag as aggregate may have assisted the observed durability. The case study supports other studies that show that it is possible to achieve long-term durable and therefore sustainable RC structures without additives and using only conventional reinforcement steels and conventional cements and aggregates. However, the potential dangers of deep narrow cracking extending to the reinforcement and the potentially deleterious effects of alkali–aggregate reactivity of some aggregates needs to be considered.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Liqiang Cui ◽  
Qinya Fan ◽  
Jianxiong Sun ◽  
Guixiang Quan ◽  
Jinlong Yan ◽  
...  

AbstractFenton-like system formed in a natural soil environment deemed to be significant in the aging process of biochar. Aged biochars have distinct physico-chemical and surface properties compared to non-aged biochar. The aged biochar proved to be useful soil amendment due to its improved elements contents and surface properties. The biochar aging process resulted in increased surface area and pore volume, as well as carbon and oxygen-containing functional groups (such as C=O, –COOH, O–C=O etc.) on its surface, which were also associated with the adsorption behavior of 2,4,6-trichlorophenol (2,4,6-TCP). The biochar aging increased the adsorption capacity of 2,4,6-TCP, which was maximum at pH 3.0. The 2,4,6-TCP adsorption capacity of aged-bush biochar (ABB) and aged-peanut shell biochar (APB) was increased by 1.0–11.0% and 7.4–38.8%, respectively compared with bush biochar (BB) and peanut shell biochar (PB) at the same initial concentration of 2,4,6-TCP. All biochars had similar 2,4,6-TCP desorption rates ranging from 33.2 to 73.3% at different sorption temperatures and times. The desorbed components were mainly 2,4,6-TCP and other degraded components, which were low in concentration with small molecule substance. The results indicated that the aged-biochar could be effective for the long-term remediation of naturally organic polluted soils.


2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Ahmad Zaki ◽  
Megat Azmi Megat Johari ◽  
Wan Muhd Aminuddin Wan Hussin ◽  
Yessi Jusman

Corrosion of steel reinforcement is a major cause of structural damage that requires repair or replacement. Early detection of steel corrosion can limit the extent of necessary repairs or replacements and costs associated with the rehabilitation works. The ground penetrating radar (GPR) method has been found to be a useful method for evaluating reinforcement corrosion in existing concrete structures. In this paper, GPR was utilized to assess corrosion of steel reinforcement in a concrete slab. A technique for accelerating reinforcement bar corrosion using direct current (DC) power supply with 5% sodium chloride (NaCl) solution was used to induce corrosion to embedded reinforcement bars (rebars) in this concrete slab. A 2 GHz GPR was used to assess the corrosion of the rebars. The analysis of the results of the GPR data obtained shows that corrosion of the rebars could be effectively localized and assessed.


2019 ◽  
Vol 47 (2) ◽  
pp. 246-265
Author(s):  
A. K. Ambrosimov ◽  
N. A. Diansky ◽  
A. A. Kluvitkin ◽  
V. A. Melnikov

Based on time series of near-bottom current velocities and temperatures obtained in the period June, 2016 to July, 2017, at three points in the Atlantic Subarctic Front, along with the use of multi-year (since 1993 up to now) satellite ocean surface sounding data, multi-scale fluctuations of ocean surface and near-bottom flows over the western and eastern flanks of the Reykjanes ridge, as well as near Hatton Rise, on the Rokoll plateau, are studied. Hydrological profiles were carried out from the ocean surface to the bottom with readings every 10 m, when setting and retrieving the buoy stations. Using data from the Bank of hydrological stations (WOD13), SST satellite arrays (Pathfinder), long-term sea level and geostrophic velocities time series (AVISO), and bottom topography (model ETOPO-1), features of longterm cyclical fluctuations of SST, sea level, geostrophic currents on the ocean surface were defined in the sub-polar North Atlantic. It is shown that, in accordance with the large-scale thermohaline structure of the Subarctic front, two branches of the North Atlantic Current are detected on the ocean surface.One is directed from the Hatton towards the Icelandic-Faroese Rise, and the other – alomg the western flank of the Reykjanes Ridge toward Iceland. For the first branch, which is the main continuation of the North Atlantic Current, the average (for 25 years) water drift at a speed of 9.1±0.1 cm/s is determined to the northeast. The second branch, which forms the eastern part of the Subarctic cyclonic gyre, has the average water drift at a speed of 4.0±0.1 cm/s is directed north-northeast, along the western flank of the Reykjanes Ridge. In the intermediate waters of the frontal zone, an average water flow is observed at a speed of 2.7±0.1 cm/s to the north-northeast, along the eastern slope of the Reykjanes ridge.Due to the multy-scale components of the total variability, the average kinetic energy densities(KED) of total currents (109, 45, 97, (±3) erg/cm3, at station points from east to west) are much greater than the mean drift KED. The near-bottom flows on the Reykjanes ridge flanks are opposite to the direction of the North Atlantic Current. Outside the Subarctic gyre, the direction of average transport is maintained from the ocean surface to the bottom. The average (per year) KED of near-bottom currents are 31, 143, 27 (±3 erg/cm3), for three stations from east to west, respectively. In the intermediate waters of the frontal zone, above the eastern slope of the Reykjanes Ridge, there is a powerful reverse (relative to the North Atlantic Current) near-bottom water flow to the south-west, with a high average speed of ~ 15 cm/s. The KED of the currents during the year varies widely from zero to ~ 600 erg/cm3. The overall variability is due to cyclical variations and intermittency (“flashes”) of currents. Perennial cycles, seasonal variations, synoptic fluctuations with periods in the range of 30–300 days, as well as inertial oscillations and semi-diurnal tidal waves are distinguished. The intermittency of oscillations is partly due to changes in low-frequency flows, which can lead to a dopler frequency shift in the cyclic components of the spectrum. The amplitude of temperature fluctuations in the bottom layer for the year was (0.07–0.10) ± 0.01°C by the standard deviation. The seasonal changes of the bottom temperature are not detected. However, a linear trend with a warming of ~ (0.10–0.15) ± 0.01°С per year is noticeable.


2002 ◽  
Vol 49 (3) ◽  
pp. 781-787 ◽  
Author(s):  
Anna Szkopinska ◽  
Ewa Swiezewska ◽  
Joanna Rytka

The yeast Saccharomyces cerevisiae strain W303 synthesizes in the early logarithmic phase of growth dolichols of 14-18 isoprene residues. The analysis of the polyisoprenoids present in the stationary phase revealed an additional family which proved to be also dolichols but of 19-24 isoprene residues, constituting 39% of the total dolichols. The transfer of early logarithmic phase cells to a starvation medium lacking glucose or nitrogen resulted in the synthesis of the longer chain dolichols. The additional family of dolichols represented 13.8% and 10.3% of total dolichols in the glucose and nitrogen deficient media, respectively. The level of dolichols in yeast cells increased with the age of the cultures. Since both families of dolichols are present in stationary phase cells we postulate that the longer chain dolichols may be responsible for the physico-chemical changes in cellular membranes allowing yeast cells to adapt to nutrient deficient conditions to maintain long-term viability.


2010 ◽  
Vol 13 (3-4) ◽  
pp. 235
Author(s):  
R.Sh. Abdinov ◽  
S.S. Nurkeev ◽  
R. Silvestri

At the present time, one of the most common methods of disposing the municipal solid wastes (MSW) is burial in sanitary landfills, where take place, long-term complex of physico-chemical and biochemical processes of decomposition. It was developed modeling of the natural process of decomposition of the solid Municipal wastes in cross electromechanical fields. The synthesized pellets was studied by IR spectroscopy. Residual hydrocarbons has a complex structure, represented by δ-lactones, cyclopentanone. The results of treatment of husk show there were the characteristic frequencies related to the OH group, indicating that the synthesis of dimers of branched chain alcohols (glycerides). Analysis of model shows that hydrocarbon product formed by the method of matching the external effects of the internal response of the reacting carbon-water composition.


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