scholarly journals Effect of Ultrafine Grains on the Coating Reaction and Anticorrosion Performance of Anodized Pure Aluminum

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 216
Author(s):  
Guowei Wang ◽  
Dan Song ◽  
Zhikai Zhou ◽  
Edwin Eyram Klu ◽  
Yi Liu ◽  
...  
Keyword(s):  
Volume Fraction ◽  
Pure Aluminum ◽  
Coated Sample ◽  
Ultrafine Grain ◽  
Cast Sample ◽  
Angular Pressing ◽  
Total Input ◽  
Average Grain Size ◽  
Ultrafine Aluminum ◽  
Anticorrosion Performance

This work analyzes the effects of ultrafine aluminum (Al) grains on the anodizing coating reaction and anticorrosion performance of anodized industrial pure Al. Equal-channel angular pressing (ECAP) was applied to cast pure Al continuously for 16 passes at room temperature, and its average grain size was dramatically refined to about 1.5 μm. The ultrafine-grain (UFG) pure Al was further anodized with a cast sample via a parallel anodizing circuit at a constant total input current. Benefited by the higher volume fraction of grain boundaries and higher internal energy of the UFG substrate, the anodizing process of the ECAP-processed pure Al was significantly accelerated, showing a more intense initial anodizing reaction, a faster initial coating thickening, and much earlier porous-layer formation compared to the cast sample. As the anodizing reaction continued, the newly formed thicker coating of the ECAP-coated sample significantly hindered the diffusion process, weakening the thermodynamic advantage and decreasing the anodizing current of the ECAP-processed sample. During the entire anodizing duration, the ECAP-processed pure Al experienced gradually decreased anodizing current, while the cast sample experienced increased anodizing current. Because of the more total reaction, the ECAP-coated sample always maintained a relatively thicker coating and better anticorrosion performance during the entire anodizing duration.

Fatigue Damage Mechanism of Nanocrystals in ECAP-Processed Copper Investigated by EBSD and AFM Hybrid Methods

2007 ◽  
Vol 340-341 ◽  
pp. 943-948 ◽  
Author(s):  
Hidehiko Kimura ◽  
Yuka Kojima ◽  
Yoshiaki Akiniwa ◽  
Keisuke Tanaka ◽  
Takaaki Ishida
Keyword(s):  
Fatigue Damage ◽  
Hybrid Methods ◽  
Damage Mechanism ◽  
Fatigue Tests ◽  
Coarse Grained ◽  
Ultrafine Grain ◽  
Shear Direction ◽  
Grain Coarsening ◽  
Angular Pressing ◽  
Average Grain Size

Electron backscattering diffraction, EBSD, technique as well as atomic force microscopy, AFM, was employed to investigate fatigue damage mechanism in ultrafine-grained copper processed by equal channel angular pressing, ECAP. The fatigue damage evolution under axial tension compression was investigated. The results show that linearly shaped fatigue damage was introduced in the scale of micrometers in spite of the average grain size of 300 nm. The linear damage was randomly oriented when the shear direction of the last ECAP-pressing in perpendicular to the loading axis. The orientation analysis by EBSD revealed that the linear damage is introduced in the area with the same crystallographic orientation in the direction of the maximum Schmid factor as in the slip deformation in coarse-grained materials. The comparison before and after fatigue tests shows the grain coarsening in the area where large linear fatigue damage was formed. It is considered that strain concentration at the edge of the slips introduced in a relatively coarse ultrafine grain causes the grain rotation and deformation in the adjacent nano-sized grains, resulting in the grain coarsening and subsequent propagation of the slips in the order of micrometers.

scholarly journals The Effect of Equal-Channel Angular Pressing on Microstructure, Mechanical Properties, and Biodegradation Behavior of Magnesium Alloyed with Silver and Gadolinium

Crystals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 918
Author(s):  
Boris Straumal ◽  
Natalia Martynenko ◽  
Diana Temralieva ◽  
Vladimir Serebryany ◽  
Natalia Tabachkova ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Refinement ◽  
Equal Channel Angular Pressing ◽  
Fine Particles ◽  
Volume Fraction ◽  
Galvanic Corrosion ◽  
Angular Pressing ◽  
Average Grain Size ◽  
The Matrix ◽  
Mechanical Properties And Corrosion

The effect of equal channel angular pressing (ECAP) on the microstructure, texture, mechanical properties, and corrosion resistance of the alloys Mg-6.0%Ag and Mg-10.0%Gd was studied. It was shown that ECAP leads to grain refinement of the alloys down to the average grain size of 2–3 μm and 1–2 μm, respectively. In addition, in both alloys the precipitation of fine particles of phases Mg54Ag17 and Mg5Gd with sizes of ~500–600 and ~400–500 nm and a volume fraction of ~9% and ~8.6%, respectively, was observed. In the case of the alloy Mg-6.0%Ag, despite a significant grain refinement, a drop in the strength characteristics and a nearly twofold increase in ductility (up to ~30%) was found. This behavior is associated with the formation of a sharp inclined basal texture. For alloy Mg-10.0%Gd, both ductility and strength were enhanced, which can be associated with the combined effect of significant grain refinement and an increased probability of prismatic and basal glide. ECAP was also shown to cause a substantial rise of the biodegradation rate of both alloys and an increase in pitting corrosion. The latter effect is attributed to an increase in the dislocation density induced by ECAP and the occurrence of micro-galvanic corrosion at the matrix/particle interfaces.

Investigation of Tensile Property and Pore Closure Behavior and the Influence of Processing Route during Equal Channel Angular Pressing of Pure Aluminum Powder Compacts

2014 ◽  
Vol 592-594 ◽  
pp. 444-450 ◽  
Author(s):  
R. Venkatraman ◽  
S. Raghuraman ◽  
R. Balaji ◽  
Kumar K.S. Ajay ◽  
M. Viswanath
Keyword(s):  
Equal Channel Angular Pressing ◽  
Cell Structure ◽  
Pure Aluminum ◽  
Dislocation Cell ◽  
Grain Structure ◽  
Ultrafine Grain ◽  
Processing Route ◽  
Angular Pressing ◽  
Ecap Process ◽  
Pore Closure

This paper revolves around the idea of finding the strength enhancement of pure ‘Al’ compacts processed through Equal-Channel Angular Pressing (ECAP) process which ultimately results in fine grain structure of the material processed. The material initially prepared through conventional powder metallurgical route is processed in an ECAP die with a channel angle of 1100. The tensile test and micro-structural evaluation is done following the ECAP process and it is found that there was a substantial enhancement in the tensile properties and Ultrafine Grain (UFG) structure is obtained due to the Severe Plastic Deformation (SPD) phenomenon taking place during the process. The pore closure behavior is also analyzed using the TEM micrographs after each pass in ECAP die and promising results are obtained when the material is processed through different routes. The dislocation cell structure is also found to get refined after each pass through the die. The pore closure behavior is also confirmed using the DEFORM 3D software when the aluminum is simulated under similar conditions.

scholarly journals Enhanced Strength and Ductility of AZ80 Magnesium Alloys by Spray Forming and ECAP Techniques

2016 ◽  
Vol 1 (1) ◽  
pp. 168 ◽  
Author(s):  
L.L. Tang ◽  
Y.H. Zhao ◽  
R.K. Islamgaliev ◽  
R.Z. Valiev
Keyword(s):  
Volume Fraction ◽  
Spray Forming ◽  
Angular Pressing ◽  
Forming Technology ◽  
Ultrafine Grained ◽  
Average Grain Size ◽  
Elongation To Failure ◽  
Mechanical Tensile ◽  
Deformation Layer ◽  
Strength And Ductility

<p>Fast spray forming technology followed by equal channel angular pressing (ECAP) was employed to obtain a specific microstructure: separated coarse magnesium grains surrounded by deformation networks. The deformation layer consisted of ultrafine grained magnesium with an average grain size of 0.6 μm and ellipsoidal shaped β-Mg<sub>17</sub>Al<sub>12</sub> particles with a size of 200-300 nm and a volume fraction of 13%. Mechanical tensile test demonstrates the advantage of the specific structure: a yield strength of 235MPa combined with an elongation to failure of 14%.</p>

Tuning the Structure and the Mechanical Properties of Ultrafine Grain Al–Zn Alloys by Short Time Annealing

2018 ◽  
Vol 55 (1) ◽  
pp. 61-68 ◽  
Author(s):  
E.V. Bobruk ◽  
X. Sauvage ◽  
A.M. Zakirov ◽  
N.A. Enikeev
Keyword(s):  
Solid Solution ◽  
Yield Stress ◽  
Volume Fraction ◽  
Ultrafine Grain ◽  
Pressing Method ◽  
Angular Pressing ◽  
Grain Structures ◽  
Elongation To Failure ◽  
Static Annealing ◽  
Zn Alloys

Abstract Solid solution treated Al-Zn alloys with different Zn contents (10 and 30 wt.%) have been nanostructured by severe plastic deformation (SPD) via equal-channel angular pressing method. In-situ transmission electron microscopy observations have been used to follow microstructure evolutions upon annealing. It was shown that SPD leads to the precipitation of Zn particles and that this partial solid solution decomposition was more pronounced in the Al- 30%Zn alloy. Annealing at temperatures in range of 200 to 250 °C led to visible dissolution of Zn particles in both alloys and to formation of extensive grain boundary segregations of Zn. This approach helped to design short term annealing treatments leading to specific ultrafine grain structures that could be achieved by static annealing on bulk samples. Last, the tensile behavior of these materials has been investigated with a special emphasis on the influence of the strain rate on the yield stress and on the elongation to failure. It is shown that in any case the yield stress is mainly controlled by the grain size, while a low volume fraction of Zn phase leads to a relatively modest ductility.

Fracture and Fatigue Resistance of Ultrafine Grain CuCrZr Alloy Produced ECAP

2006 ◽  
Vol 503-504 ◽  
pp. 811-816 ◽  
Author(s):  
Alexei Vinogradov ◽  
Kazuo Kitagawa ◽  
V.I. Kopylov
Keyword(s):  
Growth Rate ◽  
Crack Growth Rate ◽  
Crack Growth ◽  
Stable Crack Growth ◽  
Ultrafine Grain ◽  
J Integral ◽  
Present Communication ◽  
Angular Pressing ◽  
Fatigue And Fracture ◽  
Anisotropy Of Mechanical Properties

Anisotropy of mechanical properties, fatigue and fracture resistance of precipitation hardened CuCrZr alloy ultrafine (UFG) grained by equal-channel angular pressing (ECAP) is in focus of the present communication. Fracture toughness was estimated in terms of J-integral and the fatigue crack growth rate was quantified. It was found that although the estimated JIC-value appeared lower than that reported in the literature for a reference alloy, the ductility, fracture and crack growth resistance remained satisfactory after ECAP while the tensile strength and fatigue limit improved considerably. The stable crack growth rate did not differ very much for ECAP and reference conventional CuCrZr and no remarkable anisotropy in the stable crack growth was noticed.

scholarly journals Experimental and Numerical Investigation of the ECAP Processed Copper: Microstructural Evolution, Crystallographic Texture and Hardness Homogeneity

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 607
Author(s):  
A. I. Alateyah ◽  
Mohamed M. Z. Ahmed ◽  
Yasser Zedan ◽  
H. Abd El-Hafez ◽  
Majed O. Alawad ◽  
...  
Keyword(s):  
Grain Size ◽  
Equal Channel Angular Pressing ◽  
Cross Section ◽  
Room Temperature ◽  
Pure Copper ◽  
High Density ◽  
Ecap Processing ◽  
Heterogeneous Distribution ◽  
Angular Pressing ◽  
Average Grain Size

The current study presents a detailed investigation for the equal channel angular pressing of pure copper through two regimes. The first was equal channel angular pressing (ECAP) processing at room temperature and the second was ECAP processing at 200 °C for up to 4-passes of route Bc. The grain structure and texture was investigated using electron back scattering diffraction (EBSD) across the whole sample cross-section and also the hardness and the tensile properties. The microstructure obtained after 1-pass at room temperature revealed finer equiaxed grains of about 3.89 µm down to submicrons with a high density of twin compared to the starting material. Additionally, a notable increase in the low angle grain boundaries (LAGBs) density was observed. This microstructure was found to be homogenous through the sample cross section. Further straining up to 2-passes showed a significant reduction of the average grain size to 2.97 µm with observable heterogeneous distribution of grains size. On the other hand, increasing the strain up to 4-passes enhanced the homogeneity of grain size distribution. The texture after 4-passes resembled the simple shear texture with about 7 times random. Conducting the ECAP processing at 200 °C resulted in a severely deformed microstructure with the highest fraction of submicron grains and high density of substructures was also observed. ECAP processing through 4-passes at room temperature experienced a significant increase in both hardness and tensile strength up to 180% and 124%, respectively.

Microstructures and Mechanical Properties of AZ61 Mg Alloy Processed by Equal Channel Angular Pressing

2012 ◽  
Vol 468-471 ◽  
pp. 2124-2127 ◽  
Author(s):  
Shao Feng Zeng ◽  
Kai Huai Yang ◽  
Wen Zhe Chen
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Equal Channel Angular Pressing ◽  
Uniform Elongation ◽  
Considerable Decrease ◽  
Angular Pressing ◽  
Az61 Magnesium Alloy ◽  
Average Grain Size ◽  
Microstructures And Mechanical Properties ◽  
Bimodal Grain Size

Equal channel angular pressing (ECAP) was applied to a commercial AZ61 magnesium alloy for up to 8 passes at temperatures as low as 473K. Microstructures and mechanical properties of as-received and ECAP deformed samples were investigated. The microstructure was initially not uniform with a “bimodal” grain size distribution but became increasingly homogeneous with further ECAP passes and the average grain size was considerably reduced from over 26 μm to below 5 μm. The ultimate tensile strength (UTS) decreases clearly after one pass, but increases significantly up to two passes, and then continuously slowly decreases up to six passes, and again increases slightly up to eight passes. In contrast, the uniform elongation increased significantly up to 3 passes, followed by considerable decrease up to 8 passes. These observations may be attributed to combined effects of grain refinement and texture development.

scholarly journals Investigation on the Microstructure of ECAP-Processed Iron-Aluminium Alloys

Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 219
Author(s):  
Bernd-Arno Behrens ◽  
Kai Brunotte ◽  
Tom Petersen ◽  
Roman Relge
Keyword(s):  
Grain Refinement ◽  
Aluminium Alloys ◽  
Aluminium Content ◽  
Microstructure Development ◽  
Chamber Furnace ◽  
Fine Grained ◽  
Angular Pressing ◽  
Ecap Process ◽  
Average Grain Size ◽  
Forming Temperature

The present work deals with adjusting a fine-grained microstructure in iron-rich iron-aluminium alloys using the ECAP-process (Equal Channel Angular Pressing). Due to the limited formability of Fe-Al alloys with increased aluminium content, high forming temperatures and low forming speeds are required. Therefore, tool temperatures above 1100 °C are permanently needed to prevent cooling of the work pieces, which makes the design of the ECAP-process challenging. For the investigation, the Fe-Al work pieces were heated to the respective hot forming temperature in a chamber furnace and then formed in the ECAP tool at a constant punch speed of 5 mm/s. Besides the chemical composition (Fe9Al, Fe28Al and Fe38Al (at.%—Al)), the influences of a subsequent heat treatment and the holding time on the microstructure development were investigated. For this purpose, the average grain size of the microstructure was measured using the AGI (Average Grain Intercept) method and correlated with the aforementioned parameters. The results show that no significant grain refinement could be achieved with the parameters used, which is largely due to the high forming temperature significantly promoting grain growth. The holding times in the examined area do not have any influence on the grain refinement.

Microstructural Control of Ductile Crack Propagation in TMCP HSLA Pipeline Steels

2014 ◽  
Vol 922 ◽  
pp. 568-573
Author(s):  
Victor Carretero Olalla ◽  
N. Sanchez Mouriño ◽  
Philippe Thibaux ◽  
Leo Kestens ◽  
Roumen H. Petrov
Keyword(s):  
Grain Size ◽  
Crack Propagation ◽  
Volume Fraction ◽  
Main Role ◽  
Charpy Test ◽  
Initiation And Propagation ◽  
Average Grain Size ◽  
Main Disadvantage ◽  
Steel Grades ◽  
Increasing Demand

Control of ductile fracture propagation is one of the major concerns for pipeline industry, particularly with the increasing demand of new control rolled steel grades required to maintain integrity at high operational pressures. The objective of this research is to understand which microstructural features govern crack propagation, and to analyse the effect of two of them (average grain size, and volume fraction of pearlite). The main disadvantage during classical Charpy test was to discriminate the crack initiation and propagation energy during fracture of a notched sample. The initiation appears to be caused by the stress state in the neighbouring of Ti-containing precipitates or pearlite particles (no presence of M/A constituents or MnS inclusions was detected in the evaluated grades), propagation-arrest of the crack is assumed to play the main role concerning the control of fracture. Our approach to characterize the fracture resistance is to measure the energy absorbed during the crack propagation stage by means of load-displacement curves obtained via instrumented Charpy test. It was observed that the energy absorbed during crack propagation is not influenced by the average grain size but by the fraction and the morphological (banded-not banded) distribution of second pearlitic phase. This suggests that a different approach to characterize the heterogeneities in grain size clustering might be followed to correlate the energy measured during crack propagation and the morphological features of the steel.

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