scholarly journals Prototype Co-Pyrolysis of Used Lubricant Oil and Mixed Plastic Waste to Produce a Diesel-Like Fuel

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2973 ◽  
Author(s):  
Natacha Phetyim ◽  
Sommai Pivsa-Art

The co-pyrolysis of used lubricant oil blended with plastic waste, namely high-density polyethylene (HDPE), polypropylene (PP), and polystyrene (PS), to produce a diesel-like fuel was studied. The proportions of the raw materials were optimized using laboratory scale pyrolysis at atmospheric pressure at a final temperature of 450 °C without a catalyst. The ratios of used lubricant oil (Oil) and plastic waste (Oil:HDPE:PP:PS) investigated were 50:30:20:0, 50:30:0:20, 50:0:30:20, and 50:30:10:10 by weight. It was found that the oil produced using an Oil:HDPE:PP:PS ratio of 50:30:20:0 exhibited most of the properties of standard diesel oil as specified by the Ministry of Energy (Thailand), except for its flash point, which was lower than the standard. Therefore, this proportion was utilized for the scaled-up testing in the co-pyrolysis prototype (10 kg/day). Three reactor temperature ranges (less than 400 °C, 400–425 °C, and 425–450 °C) were studied, and the properties of the oil products were analysed. The oil products produced at 400–425 °C exhibited diesel-like fuel properties.

2018 ◽  
Vol 15 (2) ◽  
pp. 147-156
Author(s):  
Rebeka Rudolf ◽  
Urban Ferčec ◽  
Mohammed Shariq

Background: This review provides a closer look at recent work in the field of fireworks manufacture, which could see the replacement of micron-sized particles with their nano-scaled counterparts. Moreover, we also discuss micron-sized particles as well as nanoparticles (NPs) from K, Fe, Al, Ti, Ba, etc., that are produced in the atmosphere as a result of these fireworks. One of the possible technological substitutes for fireworks is presented in detail, i.e., the use of ultrasonic spray pyrolysis (USP) technology. Method: We searched Google, Web of Science and PubMed for a literature survey of fireworks and their products: firecrackers, micron-sized and nanoparticles. Moreover, we used some of our own knowledge and experimental data to strengthen the possibility of simulating the synthesis of firework products on the laboratory scale. Results: The use of nano reactants and oxidisers has seen a substantial increase in the sound efficiency and a decrease in the amount of chemicals used, making fireworks more eco-friendly. The application of Al- and Ti-based nano flash powder in the size range from 35 nm to 50 μm resulted in a significant improvement in the ignition properties of the fireworks. Under changing aerodynamic conditions, it is difficult to collect them as samples for real-time monitoring, needed for their characterization or the testing of their harmfulness under laboratory conditions. As a result, NPs below 100 nm in the surroundings could be easily inhaled into the lungs and cause more pulmonary and respiratory problems than micron-sized particles. USP produces nanoparticles in the laboratory that could replace the conventional micron-sized firecracker raw materials, or nanoparticles that are similar to those formed by fireworks. It will also help to identify the physiochemical properties of the airborne particulates in order to understand and evaluate their impact. </P><P> This review could be valuable for a controlled economic synthesis through USP, and in the use of nanopowders in pyrotechnology that could reduce pollution to a great extent, thus contributing to the growth and good practise of the fireworks industry. With respect to the USP synthesis, we have also discussed in detail the physical (size, shape) and chemical (composition) characteristics of Al2O3 and TiO2 NPs from different precursors and their temperature ranges. An in-depth explanation for a comparative analysis for the formation mechanism of nanoparticles through both fireworks and USP is presented in the final section. We can produce nanoparticles in the laboratory with ultrasonic spray pyrolysis that have similar properties to those produced from fireworks and can then be used for further testing.


Author(s):  
A.E. Matveev ◽  
P. Yu. Nikitin ◽  
I.A. Zhukov ◽  
A.S. Zhukov
Keyword(s):  

Author(s):  
Alaeddine Oussai ◽  
◽  
Zoltán Bártfai ◽  
László Kátai ◽  
István Szalkai ◽  
...  

2021 ◽  
Vol 1 (1) ◽  
pp. 50-69
Author(s):  
Wilson Uzochukwu Eze ◽  
◽  
Reginald Umunakwe ◽  
Henry Chinedu Obasi ◽  
Michael Ifeanyichukwu Ugbaja ◽  
...  

<abstract> <p>The world is today faced with the problem of plastic waste pollution more than ever before. Global plastic production continues to accelerate, despite the fact that recycling rates are comparatively low, with only about 15% of the 400 million tonnes of plastic currently produced annually being recycled. Although recycling rates have been steadily growing over the last 30 years, the rate of global plastic production far outweighs this, meaning that more and more plastic is ending up in dump sites, landfills and finally into the environment, where it damages the ecosystem. Better end-of-life options for plastic waste are needed to help support current recycling efforts and turn the tide on plastic waste. A promising emerging technology is plastic pyrolysis; a chemical process that breaks plastics down into their raw materials. Key products are liquid resembling crude oil, which can be burned as fuel and other feedstock which can be used for so many new chemical processes, enabling a closed-loop process. The experimental results on the pyrolysis of thermoplastic polymers are discussed in this review with emphasis on single and mixed waste plastics pyrolysis liquid fuel.</p> </abstract>


2021 ◽  
Vol 905 (1) ◽  
pp. 012030
Author(s):  
R E Santoso ◽  
L A Utami

Abstract Aiming for sustainable eco-friendly craft/design practice, this design research explored upcycling-practice of OPP plastic waste using traditional technology to create an alternative raw material for textile craft. By combining cultural investigation into the textile-making tradition with Cradle-to-Cradle design principles, we identified the potential of traditional technology as an ecologically responsible production process. We also developed upcycling method to process OPP plastic waste material. This research resulted in: (1) thread-making techniques that produce different sizes of thread as raw materials and hand-woven textile, (2) revitalized endangered indigenous technology of craft-making that had been a part of human-nature ecology, (3) eco-design education that can be accepted by local textile craft community, and (4) textile craft products that express the local identity and promote environmental care.


2021 ◽  
Vol 0 (4) ◽  
pp. 6-11
Author(s):  
I.T. Nagieva ◽  
◽  
N.I. Ali-zadeh ◽  
T.М. Nagiev ◽  
◽  
...  

In recent years, hydrogen peroxide and nitrous oxide (1) "green oxidants" – have attracted much attention of researchers as a selective oxidizing agent for the catalytic oxidation of pyridine bases. In this regard, the reaction of pyridine oxidation by hydrogen peroxide and nitrous oxide under homogeneous conditions, in the gas phase, without the use of catalysts, at atmospheric pressure, has been experimentally investigated. Areas of selective oxidation of pyridine with hydrogen peroxide and nitrous oxide have been established, and optimal conditions have been found for obtaining valuable raw materials required in the petrochemical, chemical, and pharmaceutical industries


Author(s):  
Nur Syahirah Amirah Mohd Jopery ◽  
Mohammad Abdullah ◽  
Soo Kum Yoke ◽  
Ahmad Rozaimee Mustaffa

While the discovery of oil contributes a lot towards a country’s economy and technological development, it is also the cause for oil pollution. As such, this study proposes to use lemon peel waste as a low-cost adsorbent to manage oil pollution. For the untreated adsorbent, the lemon peels were cut into small pieces and dried under sunlight for 48 hours. Then, it was further dried in an oven for 24 hours and ground into powder. For the treated adsorbent, the lemon peels were soaked in 0.5 M of sodium hydroxide (NaOH) solution. The adsorbent was used to adsorb different types of oil (diesel oil, lubricant oil, waste vegetable oil) and in different types of water (ocean water, lake water, tap water) with different amounts of adsorbent which is 0.2 g, 0.4 g, 0.6 g, 0.8 g, and 1.0 g for adsorbent dosage experiment. While for types of water experiment, a ratio for volume of water and oil of 3:1, and constant mass adsorbent was used. The result showed that untreated adsorbent can adsorb higher amount of oils than treated adsorbent. The oil that could be easily adsorbed using lemon peels adsorbent is diesel oil with 89.91% adsorption. For the types of water, the result changes according to different types of water and oil used. It was found that the higher the mass adsorbent, the lower the percentage of oil removal. The highest percentage of diesel oil removed in ocean water is 81.68%. While the removal of lubricant oil and waste vegetable oil in lake water is 66.6% and 72.13%, respectively. Scanning Electron Microscopy (SEM) shows that treated lemon peels had small pores compared to untreated lemon peel waste. This study demonstrated and proposed that the lemon peel waste has a good potential in low-cost oil waste removal.


2020 ◽  
Author(s):  
Purwo Subekti

This researchs aims to to find out about the potential of palm oil as a raw material of foam firefighting peat fires in Indonesia.By using the method of literature approach to previous researchers, can be in the know that the vegetable raw materials with thepotential to be developed in Indonesia as a raw material of foam extinguishing peat fires is palm oil. In addition to theavailability of environmentally friendly palm oil is also guaranteed and sustained since 2015, Indonesia produced palm oil andits derivatives amounted to 32.5 million tons, to meet the domestic demand of 18.77% while exports amounted to 81.23%..Utilization of palm oil as a raw material foam fire extinguisher is one form of support to the Indonesian government in order toincrease the downstream and value-added palm oil products as well as reduce the level of risk of peat fires


2016 ◽  
Vol 51 (1) ◽  
pp. 13-22
Author(s):  
MB Ahmed ◽  
ATMK Hasan ◽  
M Mohiuddin ◽  
M Asadullah ◽  
MS Rahman ◽  
...  

Objective of this work was to pyrolysis woody biomass. Experiments were carried out at 300 to 500oC. Relatively bigger particles were used. Special emphasis was given to investigate the effects of heating rate and heating up time of the central mass of the particles on the product distribution. Surface temperature reached to the reactor set temperature immediately while the temperature at the central part was as low as 50oC. The center temperature gradually increased to the final temperature within 3 to 8 minutes, depending on the wood types and the reactor set temperature. For ipil-ipil wood the heating rate of the central mass was much faster than krishnachura and koroi woods, and thus the heating up time was lower. Ipil-ipil wood was experienced higher yield (65%) even at lower reactor temperature 300oC with particle temperature 450oC. In the case of krishnachura and koroi woods, the bio-oil yields were lower under the same condition due to the heating rates of the central parts were much slower. Further researchon different biomasses may be necessary to demonstrate overall process.Bangladesh J. Sci. Ind. Res. 51(1), 13-22, 2016


2020 ◽  
Vol 981 ◽  
pp. 132-137
Author(s):  
Suharno Rusdi ◽  
Ridwan A. Destian ◽  
Fitratur Rahman ◽  
Achmad Chafidz

Everyday human life cannot be separated from plastic. Almost all objects that are around us are made of plastic. In general, plastics are non-biodegradable, causing environmental problems caused by the increased volume of plastic waste. One way to overcome this is by recycling existing plastic waste. But the use of recycled plastics is very limited and considered inefficient because the process is more difficult and processing is more expensive than buying new plastic raw materials. Another alternative is to use bioplastics or biodegradable plastic. This plastic is more environmentally friendly because it is biodegradable or easily decomposed by microorganisms. Basically, bioplastics can be made from vegetable starches. In this study we will use starch extracted from banana peel waste as a base material for making bioplastics. In this research, glycerin which is used as a bioplastic adhesive or plasticizer will be used. Whether or not bioplastics depend on the resistance to water, the attractiveness of the bioplastics, the ability of the plastic to be decomposed by microorganisms. From this research, it is expected to produce bioplastics with high water resistance and high tensile strength and easy to decompose microorganisms.


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