scholarly journals Gas and Dolomite Outbursts in Ore Mines—Analysis of the Phenomenon and the Energy Balance

Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2999
Author(s):  
Katarzyna Kozieł ◽  
Norbert Skoczylas ◽  
Krzysztof Soroko ◽  
Sebastian Gola

In this paper, we present the problem of gas and dolomite outbursts in copper mines. The energy balance of the phenomenon is analyzed. An examination of the porosity of the dolomites is performed; in addition, the content and pressure of the gas accumulated in the pore structure of the rock are determined. The gas energy accumulated in the pore space of rocks is determined depending on the transformation occurring during gas decompression. The work needed to crush the rock for the grain distribution characteristic of post-outburst masses is examined. The gas energy needed to transport rocks is analyzed. The purpose of the research is to determine the limit values of parameters describing the gas and rock system for which there is a risk of dolomite and rock explosions. For the characteristic porosity of dolomites of −5%, gas and rock outbursts at 5 MPa pressure in isothermal transformation can be expected, and if the transformation is closer to adiabatic transformation, outbursts can be expected at 10 MPa pressure.

Author(s):  
C. A. Callender ◽  
Wm. C. Dawson ◽  
J. J. Funk

The geometric structure of pore space in some carbonate rocks can be correlated with petrophysical measurements by quantitatively analyzing binaries generated from SEM images. Reservoirs with similar porosities can have markedly different permeabilities. Image analysis identifies which characteristics of a rock are responsible for the permeability differences. Imaging data can explain unusual fluid flow patterns which, in turn, can improve production simulation models.Analytical SchemeOur sample suite consists of 30 Middle East carbonates having porosities ranging from 21 to 28% and permeabilities from 92 to 2153 md. Engineering tests reveal the lack of a consistent (predictable) relationship between porosity and permeability (Fig. 1). Finely polished thin sections were studied petrographically to determine rock texture. The studied thin sections represent four petrographically distinct carbonate rock types ranging from compacted, poorly-sorted, dolomitized, intraclastic grainstones to well-sorted, foraminiferal,ooid, peloidal grainstones. The samples were analyzed for pore structure by a Tracor Northern 5500 IPP 5B/80 image analyzer and a 80386 microprocessor-based imaging system. Between 30 and 50 SEM-generated backscattered electron images (frames) were collected per thin section. Binaries were created from the gray level that represents the pore space. Calculated values were averaged and the data analyzed to determine which geological pore structure characteristics actually affect permeability.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-18
Author(s):  
Xiaojun Zhang ◽  
Haodong Han ◽  
Jun Peng ◽  
Yingchun Gou

Reservoir pore space assessment is of great significance for petroleum exploration and production. However, it is difficult to describe the pore characteristics of deep-buried dolomite reservoirs with the traditional linear method because these rocks have undergone strong modification by tectonic activity and diagenesis and show significant pore space heterogeneity. In this study, 38 dolostone samples from 4 Cambrian formations of Tarim Basin in NW China were collected and 135 thin section images were analyzed. Multifractal theory was used for evaluation of pore space heterogeneity in deep-buried dolostone based on thin section image analysis. The physical parameters, pore structure parameters, and multifractal characteristic parameters were obtained from the digital images. Then, the relationships between lithology and these parameters were discussed. In addition, the pore structure was classified into four categories using K-means clustering analysis based on multifractal parameters. The results show that the multifractal phenomenon generally exists in the pore space of deep-buried dolomite and that multifractal analysis can be used to characterize the heterogeneity of pore space in deep-buried dolomite. For these samples, multifractal parameters, such as αmin, αmax, ΔαL, ΔαR, Δf, and AI, correlate strongly with porosity but only slightly with permeability. However, the parameter Δα, which is usually used to reveal heterogeneity, does not show an obvious link with petrophysical properties. Of dolomites with different fabrics, fine crystalline dolomite and medium crystalline dolomite show the best petrophysical properties and show significant differences in multifractal parameters compared to other dolomites. More accurate porosity estimations were obtained with the multifractal generalized fractal dimension, which provides a new method for porosity prediction. The various categories derived from the K-means clustering analysis of multifractal parameters show distinct differences in petrophysical properties. This proves that reservoir evaluation and pore structure classification can be accurately performed with the K-means clustering analysis method based on multifractal parameters of pore space in deep-buried dolomite reservoirs.


2019 ◽  
Vol 974 ◽  
pp. 181-186
Author(s):  
V.A. Perfilov ◽  
V.V. Gabova ◽  
Inessa A. Tomareva

The effect of superplasticizing, foam agents, various fiber aggregates on the physical and mechanical properties of cellular concrete has been studied. The article covers the results of experimental studies conducted to determine the effect of foam agents PO-6 and PB-2000, as well as polymeric and basalt fiber on the pore structure of foam concrete. The dependence between the change in density and strength of cellular concrete and the structure of its pore space has been determined.


2006 ◽  
Vol 3 (3) ◽  
pp. 219 ◽  
Author(s):  
Dawn M. Wellman ◽  
Jonathan P. Icenhower ◽  
Antoinette T. Owen

Environmental Context. The contamination of surface and subsurface geologic media by heavy metals and radionuclides is a significant problem within the United States Department of Energy complex as a result of past nuclear operations. Water-soluble phosphate compounds provide a means to inject phosphorus into subsurface contaminant plumes, to precipitate metal ions from solution. However, phosphate phases can form within the sedimentary pore structure to block a fraction of the pore space and inhibit further remediation of the contaminant plume. A series of tests have been conducted to evaluate changes in sedimentary pore structure during the application of several proposed phosphate remediation amendments. Abstract. A series of conventional, saturated column experiments have been conducted to evaluate the effect of utilizing in situ, soluble, phosphate amendments for subsurface metal remediation on sediment hydraulic conductivity. Experiments have been conducted under mildly alkaline and calcareous conditions representative of conditions commonly encountered at sites across the arid western United States, which have been used in weapons and fuel production and display significant subsurface contamination. Results indicate that the displacement of a single pore volume of either sodium monophosphate or phytic acid amendments causes approximately a 30% decrease in the hydraulic conductivity of the sediment. Long-chain polyphosphate amendments afford no measurable reduction in hydraulic conductivity. These results demonstrate (1) the efficacy of long-chain polyphosphate amendments for subsurface metal sequestration; and (2) the necessity of conducting dynamic experiments to evaluate the effects of subsurface remediation.


2019 ◽  
Vol 7 (4) ◽  
pp. SJ45-SJ65
Author(s):  
Qinhong Hu ◽  
Richard Kalteyer ◽  
Jingyi Wang ◽  
Hesham F. El-Sobky

The Mancos Shale of the San Juan Basin has been an important resource for the exploration and development of oil and gas. However, as with most unconventional plays, the shales have low porosity and extremely low permeability with predominantly nanometer-sized pores. Thus, it is critical to understand the nanopetrophysical properties of the reservoir so a proper assessment of the reservoir quality can be made. Working with three as-received core samples from three different wells of the Tacito Marine Bar and Offshore Mancos play types, we have developed an initial understanding of the nanopetrophysical properties of the pore structure as well as fluid-rock interactions in these tight reservoirs. We have performed a suite of integrated tests, such as mercury intrusion porosimetry (MIP), low-pressure nitrogen physisorption, core plug porosity and permeability, scanning electron microscopy imaging, water immersion porosimetry after vacuum pulling, contact angle, and fluid imbibition. In addition, we obtained supplementary data for total organic carbon, X-ray diffraction, and pyrolysis to further evaluate reservoir quality. The Mancos Shale samples exhibit petrophysical characteristics that are controlled by a predominant presence of nanometer-sized pore space, with 56%–96% pore volumes present as 3.4–50 nm in pore-throat sizes, as shown by the MIP approach. Contact angle and fluid imbibition tests demonstrate that samples are oil wet to mixed wet, with a tendency of pore networks to imbibe oil over water. The findings from integrated pore structure and wettability studies provide a database and some insights, from the perspectives of nanopetrophysical characterization, into the reservoir quality of the Mancos Shale.


2021 ◽  
pp. 1-59
Author(s):  
Quanpei Zhang ◽  
Tao Jiao ◽  
Hao Huang ◽  
Zhao Qi ◽  
Tao Jiang ◽  
...  

The complex pore structure and high heterogeneity of ultra-low permeability sandstone reservoirs have a significant effect on reservoir quality evaluation and hydrocarbon resource assessment. We collected 10 reservoir samples from the Upper Triassic Yanchang Formation Chang 8 in the Zhenbei area of the Ordos Basin. We measured the pore size distribution (PSD) and fluid occurrence characteristics of the reservoir by Pressure-controlled porosimetry (PCP), rate-controlled porosimetry (RCP) and nuclear magnetic resonance (NMR), and then analyzed the results via the fractal theory to determine the pore space fractal characteristics. Our analysis indicates that the three major pore types of these reservoirs are residual intergranular pores, dissolution pores and intercrystalline pores. The pore structure of the ultra-low permeability sandstone reservoirs is highly heterogeneous with pore throats of various scales, and the corresponding fractal characteristics are notably different, exhibiting multi-fractal features. Compared to macropores and mesopores, micropores are more uniform and regular in terms of their PSD and thus only slightly influence the reservoir quality. The complexity of the throat distribution and whole pore space is attributed to the development of dissolution pores and the content of feldspar minerals. Fractal features depend on the movable fluid pore space and effective pores, whose fractal dimensions reflect the complexity of interconnected pores and correlate well with the porosity and permeability. The development of different types and sizes of pore throats in these ultra-low permeability sandstone reservoirs resulted in the observed pore structure heterogeneity. The difference in mineral composition and content of these reservoirs aggravates the pore structure complexity and affects reservoir quality evaluation and further oilfield development.


2007 ◽  
Vol 567-568 ◽  
pp. 341-344
Author(s):  
Stanislav Vĕchet ◽  
Jan Kohout ◽  
Klára Hanzlíková ◽  
Vojtěch Hruby

The paper presents the results of research focused on assessment of the influence of loading cycle asymmetry on fatigue limit values. For tests two heats of unalloyed nodular cast iron were used. Test bars made of keel blocks were heat treated in salt bathes (austenitization at 900 °C during 1 hour, isothermal transformation at 380 and 400 °C) and loaded at symmetrical, repeating and pulsating loading cycles at room temperature. Evaluation of fatigue properties was based on the determination of S-N curves in high-cycle region including the fatigue limit assessment for 107 cycles to fracture. Fatigue and static tests were completed by metallographic and quantitative phase analysis. Most important result obtained from the presented study is that the dependence of stress amplitude on mean stress cannot be approached by the linear relation but by general power law with exponent lower than 1 (i.e. the Haigh diagram has convex shape).


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 527
Author(s):  
Liangwei Xu ◽  
Keji Yang ◽  
Hao Wei ◽  
Luofu Liu ◽  
Xiao Li ◽  
...  

Nanoscale pore structure characteristics and their main controlling factors are key elements affecting the gas storage capacity, permeability, and the accumulation mechanism of shale. A multidisciplinary analytical program was applied to quantify the pore structure of all sizes of Xiamaling shale from Zhangjiakou, Hebei. The result implies that Mercury injection porosimetry (MIP) and low-pressure N2 curves of the samples can be divided into three and four types, respectively, reflecting different connectivity performances. The maximum CO2 adsorbing capacity increases with increasing total organic carbon (TOC) content, pore volume (PV), and surface area (SA) of the micropores are distributed in a three-peak type. The full-scale pore structure distribution characteristics reveal the coexistence of multiple peaks with multiple dominant scales and bi-peak forms with mesopores and micropores. The porosity positively correlates with the TOC and quartz content, but negatively correlates with clay mineral content. Organic matter (OM) is the main contributor to micropore and mesopore development. Smectite and illite/smectite (I/S) assist the development of the PV and SA of pores with different size. Illite promotes the development of the nanoscale PV, but is detrimental to the development of the SA. Thermal maturity controls the evolution of pores with different size, and the evolution model for the TOC-normalized PVs of different diameter scales is established. Residual hydrocarbon is mainly accumulated in micropores sized 0.3 to 1.0 nm and mesopores sized 40 nm, 2 nm and less than 10 nm. Since the samples were extracted, the pore space occupied by residual hydrocarbon was released, resulting in a remarkable increase in PV and SA.


2019 ◽  
Vol 282 ◽  
pp. 02024
Author(s):  
Muhammad Islahuddin ◽  
Chi Feng ◽  
Steven Claes ◽  
Hans Janssen

Hygric properties can be estimated directly from pore structure information, represented by a network of regularly shaped pores, extracted from a pore structure image to conserve the real topology. On this network, pore-scale models of moisture behaviour determine the hygric properties of moisture storage and transport. The reliability of this approach is validated with a sintered-glass filter. Despite its more limited heterogeneity and pore size range relative to typical porous building materials, it provides a good basis for validating crucial pore-scale moisture processes. Measured storage data compare well to the estimated ad- and desorption moisture retention curves as well as to the saturated and capillary moisture content. Furthermore, the simulated whole-range moisture permeability curve agrees acceptably with measured data. The variation in modelling the pore space as a pore network model is also analysed by considering two distinct pore network extraction methods. The measured and simulated moisture contents agree well for the whole capillary range. Moreover, the resulting transport properties are generally accurate for the whole moisture content range. On the other hand, the estimated vapour permeabilities show notable variations between the two pore network models.


1999 ◽  
Vol 2 (02) ◽  
pp. 161-168 ◽  
Author(s):  
Z.R. Liang ◽  
P.C. Philippi ◽  
C.P. Fernandes ◽  
F.S. Magnani

Summary The main purpose of the present work is to predict the permeability of a porous medium from its three-dimensional (3D) porous structure network. In this work, 3D porous structure is reconstructed by the truncated Gaussian method using Fourier transform and starting from a 2D binary image obtained from a thin section of a porous sample. The skeleton of the 3D porous structure provides a way of visualizing the graph of the pore network. It is determined using a thinning algorithm, which is conceived to preserve topology. It gives both visual and quantitative information about the connectivity of the pore space, the coordination number for every node and local hydraulic radius. Once the network of the pore structure is obtained, the macroscopic transport properties, such as the permeability, can be predicted. The method is applied to a 500 mD Berea sandstone and the predicted permeability is in good agreement with the experimental value and empirical correlations. Introduction The prediction of equilibrium and transport properties of porous media is a long-standing problem of great theoretical and practical interest, particularly in petroleum reservoir engineering.1 Past theoretical attempts to derive macroscopic transport coefficients from the microstructure of porous media entailed a simplified representation of the pore space, often as a bundle of capillary tubes.1–3 These models have been widely applied because of their convenience and familiarity to the engineers. But they do have some limitations. For example, they are not well suited for describing the effect of the pore space interconnectivity and long range correlation in the system. Network models have been advanced to describe phenomena at the microscopic level and have been extended in the last few years to describe various phenomena at the macroscopic level. These models are mostly based on a network representation of the porous media in which larger pores (pore bodies) are connected by narrower pores (pore throats). Network models represent the most important and widely used class of geometric models for porous media.2 A network is a graph consisting of a set of nodes or sites connected by a set of links or bonds. The nodes can be chosen deterministically or randomly as in the realization of a Poisson or other stochastic point process. Similarly the links connecting different nodes may be chosen according to some deterministic or random procedure. Finally, the nodes are dressed with convex sets such as spheres representing pore bodies, and the bonds are dressed with tubes providing a connecting path between the pore bodies. The original idea of representing a porous structure by a network is rather old, but it was only in the early 1980s that systematic and rigorous procedures were developed to map, in principle, any disordered rock onto an equivalent random network of bonds and sites. Once this mapping is complete one can study a given phenomenon in porous media in great detail.3 Dullien1 reviewed the details of various pore-scale processes, including detailed descriptions of many aspects of network models. The most important features of pore network geometry and topology that affect fluid distribution and flow in reservoir rocks are the pore throat and pore body size distributions, the pore body-to-pore throat size aspect ratio and the pore body coordination number.4 These data have been tentatively assumed in the previous works. The extension of these techniques to real porous media has been complicated by the difficulty in describing the complex three-dimensional (3D) pore structure of real porous rocks. Information about the pore structure of reservoir rocks is often obtained from mercury intrusion and sorption isotherm. Mercury intrusion and sorption isotherm data provide statistical information about the pore throat size distribution, or, more correctly, the distribution of the volumes that may be invaded within specified pore throat sizes. Advanced techniques such as microcomputed tomography5 and serial sectioning6,7 do provide a detailed description of the 3D pore structures of rocks. Recently, image analysis methods used over pictures of highly polished surfaces of porous materials (e.g., Refs. 8-10), taken with an electron scanning microscope have been used to describe the porous structure. Image analysis techniques such as opening (2D and 3D)11,13 and median line graphs (2D)13 were developed. Information on porous structure is obtained from the analysis of 2D binary images. For isotropic media, a 3D microstructure may be reconstructed from any statistically homogeneous 2D section. The general objective of a reconstructed porous structure is to mimic more closely the geometry of real media. This method has been previously applied to the prediction of important petrophysical and reservoir engineering properties, such as permeability8 and formation factor14 with reasonable success. Thovert et al.15 used the reconstructed porous structure and developed thinning algorithms to obtain the graph of the 3D pore structure. Some topological characteristics such as the number of loops were derived. Bakke and O/ren16 generated 3D pore networks based on numerical modeling of the main sandstone forming geological processes. Absolute and relative permeability were computed for a Bentheimer sandstone. However, although their algorithms worked well on their models, the problem of connectivity preservation for a 3D thinning algorithm appears to be only correctly taken into account by Ma,17 who proposed sufficient conditions for providing a 3D thinning algorithm to preserve connectivity.


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