scholarly journals Assessment of Durum Wheat (Triticum durum Desf.) Genotypes Diversity for the Integrated Production of Bioethanol and Grains

Energies ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 7735
Author(s):  
Donatella Danzi ◽  
Ivana Marino ◽  
Isabella De Bari ◽  
Silvio Mastrolitti ◽  
Giacomo L. Petretto ◽  
...  
Keyword(s):  
Durum Wheat ◽  
Wheat Straw ◽  
Structural Integrity ◽  
Lignin Content ◽  
Complex Structure ◽  
Three Dimensional ◽  
Germplasm Collection ◽  
Biofuel Production ◽  
Fermentable Sugars ◽  
Uronic Acids

Wheat straw is an abundant source of lignocellulosic biomass that is generally not utilized for biofuel production, nor for other uses. Recent EU renewable energy directive fosters bioethanol production through lignocellulosic sugars fermentation, but the cost of this process is an issue that often depends on biomass characteristics. Lignin is a class of three-dimensional polymers providing structural integrity of plant tissues. Its complex structure, together with hemicelluloses and uronic acids content, could affect the ability of hydrolyzing biomass to fermentable sugars. To get insights into this variation, a set of 10 durum wheat genotypes was analyzed to determine variation of straw digestibility to fermentable sugars. The results showed that the lignin content was the major factor determining the recalcitrance to enzymatic process. The analysis of Spearman’s correlation indicated that the sugar released after enzymatic hydrolysis had a negative connection with the lignin content, while it was positively correlated with the culm length. The possible role of other cell wall components, such as arabinose and uronic acids, was also discussed. This work aimed at analyzing the diversity of lignocellulosic digestibility to fermentable sugars of wheat straw in a small germplasm collection. Some of the selected genotypes were characterized by high sugars digestibility and high grain yield, characteristics that could make biorefining of wheat straw profitable.

scholarly journals Stochastic model of lignocellulosic material saccharification

2021 ◽  
Vol 17 (9) ◽  
pp. e1009262
Author(s):  
Eric Behle ◽  
Adélaïde Raguin
Keyword(s):  
Lignin Content ◽  
Three Dimensional ◽  
Enzymatic Saccharification ◽  
Biofuel Production ◽  
Dimensional Structure ◽  
Gillespie Algorithm ◽  
Promising Alternative ◽  
Fitting Procedure ◽  
Time Courses ◽  
Pre Treatment

The processing of agricultural wastes towards extraction of renewable resources is recently being considered as a promising alternative to conventional biofuel production. The degradation of agricultural residues is a complex chemical process that is currently time intensive and costly. Various pre-treatment methods are being investigated to determine the subsequent modification of the material and the main obstacles in increasing the enzymatic saccharification. In this study, we present a computational model that complements the experimental approaches. We decipher how the three-dimensional structure of the substrate impacts the saccharification dynamics. We model a cell wall microfibril composed of cellulose and surrounded by hemicellulose and lignin, with various relative abundances and arrangements. This substrate is subjected to digestion by different cocktails of well characterized enzymes. The saccharification dynamics is simulated in silico using a stochastic procedure based on a Gillespie algorithm. As we additionally implement a fitting procedure that optimizes the parameters of the simulation runs, we are able to reproduce experimental saccharification time courses for corn stover. Our model highlights the synergistic action of enzymes, and confirms the linear decrease of sugar conversion when either lignin content or crystallinity of the substrate increases. Importantly, we show that considering the crystallinity of cellulose in addition to the substrate composition is essential to interpret experimental saccharification data. Finally, our findings support the hypothesis of xylan being partially crystalline.

The Influence of the Properties of the Material Used for Obtaining Geopolymers on Their Structure and Compressive Strength

2017 ◽  
Vol 68 (6) ◽  
pp. 1182-1187
Author(s):  
Ilenuta Severin ◽  
Maria Vlad
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Wheat Straw ◽  
Red Mud ◽  
Blast Furnace Slag ◽  
Complex Structure ◽  
Point Of View ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag ◽  
Straw Ash

This article presents the influence of the properties of the materials in the geopolymeric mixture, ground granulated blast furnace slag (GGBFS) + wheat straw ash (WSA) + uncalcined red mud (RMu), and ground granulated blast furnace slag + wheat straw ash + calcined red mud (RMc), over the microstructure and mechanical properties of the synthesised geopolymers. The activation solutions used were a NaOH solution with 8M concentration, and a solution realised from 50%wt NaOH and 50%wt Na2SiO3. The samples were analysed: from the microstructural point of view through SEM microscopy; the chemical composition was determined through EDX analysis; and the compressive strength tests was done for samples tested at 7 and 28 days, respectively. The SEM micrographies of the geopolymers have highlighted a complex structure and an variable compressive strength. Compressive strength varied from 24 MPa in the case of the same recipe obtained from 70% of GGBFS + 25% WSA +5% RMu, alkaline activated with NaOH 8M (7 days testing) to 85 MPa in the case of the recipe but replacing RMu with RMc with calcined red mud, alkaline activated with the 50%wt NaOH and 50%wt Na2SiO3 solution (28 days testing). This variation in the sense of the rise in compressive strength can be attributed to the difference in reactivity of the materials used in the recipes, the curing period, the geopolymers structure, and the presence of a lower or higher rate of pores, as well as the alkalinity and the nature of the activation solutions used.

Ab Initio Determination of a New Complex Structure (55 Non-Hydrogen Atoms) from Synchrotron Powder Data: An Uncommon Nickel Succinate, Ni7(C4H4O4)4(OH)6(H2O)3•7H2O

2004 ◽  
Vol 443-444 ◽  
pp. 333-336
Author(s):  
N. Guillou ◽  
C. Livage ◽  
W. van Beek ◽  
G. Férey
Keyword(s):  
Ab Initio ◽  
Complex Structure ◽  
Three Dimensional ◽  
Free Water ◽  
Hydrogen Atoms ◽  
Monoclinic System ◽  
Synchrotron Powder Diffraction ◽  
Chloride Hexahydrate ◽  
Autogenous Pressure

Ni7(C4H4O4)4(OH)6(H2O)3. 7H2O, a new layered nickel(II) succinate, was prepared hydrothermally (180°C, 48 h, autogenous pressure) from a 1:1.5:4.1:120 mixture of nickel (II) chloride hexahydrate, succinic acid, potassium hydroxide and water. It crystallizes in the monoclinic system (space group P21/c, Z = 4) with the following parameters a = 7.8597(1) Å, b = 18.8154(3)Å, c = 23.4377(4) Å,ϐ = 92.0288(9)°, and V = 3463.9(2) Å3. Its structure, which contains 55 non-hydrogen atoms, was solved ab initio from synchrotron powder diffraction data. It can be described from hybrid organic-inorganic layers, constructed from nickel oxide corrugated chains. These chains are built up from NiO6hexameric units connected via a seventh octahedron. Half of the succinates decorate the chains, and the others connect them to form the layers. The three dimensional arrangement is ensured by hydrogen bonds directly between two adjacent layers and via free water molecules.

French RPV PTS Assessment: An Overview of EDF Research and Development in Progress on Thermalhydraulic, Materials and Mechanical Aspects

2003 ◽  
Author(s):  
Dominique Moinereau ◽  
Jean-Michel Frund ◽  
Henriette Churier-Bossennec ◽  
Georges Bezdikian ◽  
Alain Martin
Keyword(s):  
Structural Integrity ◽  
Three Dimensional ◽  
Crack Arrest ◽  
Pressure Vessels ◽  
Short Description ◽  
Constraint Effect ◽  
Materials Properties ◽  
Integrity Assessment ◽  
Pressurized Thermal Shock ◽  
Reactor Pressure

A significant extensive Research & Development work is conducted by Electricite´ de France (EDF) related to the structural integrity re-assessment of the French 900 and 1300 MWe reactor pressure vessels in order to increase their lifetime. Within the framework of this programme, numerous developments have been implemented or are in progress related to the methodology to assess flaws during a pressurized thermal shock (PTS) event. The paper contains three aspects: a short description of the specific French approach for RPV PTS assessment, a presentation of recent improvements on thermalhydraulic, materials and mechanical aspects, and finally an overview of the present R&D programme on thermalhydraulic, materials and mechanical aspects. Regarding the last aspect on present R&D programme, several projects in progress will be shortly described. This overview includes the redefinition of some significant thermalhydraulic transients based on some new three-dimensional CFD computations (focused at the present time on small break LOCA transient), the assessment of vessel materials properties, and the improvement of the RPV PTS structural integrity assessment including several themes such as warm pre-stress (WPS), crack arrest, constraint effect ....

Swirl Flow Investigations on the Enhancement of Heat Transfer Processes in Cyclone Cooling Ducts

2012 ◽  
Author(s):  
Florian Wassermann ◽  
Sven Grundmann ◽  
Michael Kloss ◽  
Heinz-Peter Schiffer
Keyword(s):  
Heat Transfer ◽  
Mass Transfer ◽  
Complex Structure ◽  
Three Dimensional ◽  
Swirl Flow ◽  
Flow Structures ◽  
Stable Complex ◽  
Reynolds Analogy ◽  
Transfer Processes ◽  
Cooling Ducts

Cyclone cooling is a promising method to enhance heat-transfer processes in future internal turbine-blade leading-edge cooling-ducts. The basic component of such cooling channels is the swirl generator, which induces a swirling movement of the coolant. The angular momentum generates stable, complex and three-dimensional flow structures of helical shape with alternating axial flow directions. Full three-dimensional and three-component velocity measurements using magnetic resonance velocimetry (3D3C-MRV) were conducted, with the aim to understand the complex structure of pipe flows with strong swirl. In order to mimic the effect of different installation concepts of the cyclone-cooling ducts an idealized bend-duct swirl-tube configuration with variable exit orifices has been investigated. Pronounced helical flow structures and distinct velocity zones could be found in this swirl flow. One substantial result is the identification of stationary helix-shaped streaks of high axial velocity in the direct vicinity of the wall. These findings are in good agreement with mass-transfer measurements that also show helix-shaped structures with increased mass transfer at the inner surface of the tube. According to the Reynolds analogy between heat and mass transfer, augmented heat-transfer processes in these areas are to be expected.

Synthesis and properties of modified PBT for FDM

2017 ◽  
Vol 23 (4) ◽  
pp. 804-810 ◽  
Author(s):  
Shiqing Cao ◽  
Dandan Yu ◽  
Weilan Xue ◽  
Zuoxiang Zeng ◽  
Wanyu Zhu
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Fused Deposition Modeling ◽  
Complex Structure ◽  
Three Dimensional ◽  
Sebacic Acid ◽  
Wire Drawing ◽  
Content Type ◽  
Fused Deposition ◽  
Deposition Modeling

Purpose The purpose of this paper is to prepare a new modified polybutylene terephalate (MPBT) for fused deposition modeling (FDM) to increase the variety of materials compatible with printing. And the printing materials can be used to print components with a complex structure and functional mechanical parts. Design/methodology/approach The MPBT, poly(butylene terephalate-co-isophthalate-co-sebacate) (PBTIS), was prepared for FDM by direct esterification and subsequent polycondensation using terephthalic acid (PTA), isophthalic acid (PIA), sebacic acid (SA) and 1,4-butanediol (BDO). The effects of the content of PIA (20-40 mol%) on the mechanical properties of PBTIS were investigated when the mole per cent of SA (αSA) is zero. The effects of αSA (0-7mol%) on the thermal, rheological and mechanical properties of PBTIS were investigated at nPTA/nPIA = 7/3. A desktop wire drawing and extruding machine was used to fabricate the filaments, whose printability and anisotropy were tested by three-dimensional (3D) printing experiments. Findings A candidate content of PIA introducing into PBT was obtained to be about 30 per cent, and the Izod notched impact strength of PBTIS increased with the increase of αSA. The results showed that the PBTIS (nPTA/nPIA = 7/3, αSA = 3-5mol%) is suitable for FDM. Originality/value New printing materials with good Izod notched impact strength were obtained by introducing PIA and SA (nPTA/nPIA = 7/3, αSA = 3-5 mol%) into PBT and their anisotropy are better than that of ABS.

scholarly journals Advances in 3D Printing for Tissue Engineering

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3149
Author(s):  
Angelika Zaszczyńska ◽  
Maryla Moczulska-Heljak ◽  
Arkadiusz Gradys ◽  
Paweł Sajkiewicz
Keyword(s):  
Tissue Engineering ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Complex Structure ◽  
Three Dimensional ◽  
Computer Assisted ◽  
Scaffold Fabrication ◽  
Manufacturing Techniques ◽  
Printing Techniques ◽  
State Of Art

Tissue engineering (TE) scaffolds have enormous significance for the possibility of regeneration of complex tissue structures or even whole organs. Three-dimensional (3D) printing techniques allow fabricating TE scaffolds, having an extremely complex structure, in a repeatable and precise manner. Moreover, they enable the easy application of computer-assisted methods to TE scaffold design. The latest additive manufacturing techniques open up opportunities not otherwise available. This study aimed to summarize the state-of-art field of 3D printing techniques in applications for tissue engineering with a focus on the latest advancements. The following topics are discussed: systematics of the available 3D printing techniques applied for TE scaffold fabrication; overview of 3D printable biomaterials and advancements in 3D-printing-assisted tissue engineering.

Reduction in lignin peroxidase activity revealed by effects of lignin content in urea crosslinked starch under aerobic biodegradation in soil

BioResources ◽  
2021 ◽  
Vol 16 (1) ◽  
pp. 1940-1948
Author(s):  
Zahid Majeed ◽  
Zainab Ajab ◽  
Qingjie Guan ◽  
Abdul Zahir Abbasi ◽  
Qaisar Mahmood ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lignin Peroxidase ◽  
Enzyme Assay ◽  
Lignin Content ◽  
Complex Structure ◽  
Reaction Rates ◽  
Aerobic Biodegradation ◽  
Lignin Biodegradation ◽  
Research Findings ◽  
Biodegradation In Soil

This study characterized the lignin peroxidase (LiP) activity of soil via an enzyme assay to determine the reaction rates and activation energies for 5 wt%, 10 wt%, 15 wt%, and 20 wt% lignin loads in urea crosslinked starch biocomposites. The results revealed that a mixed mode of LiP inhibition occurred after the soil was mixed with these biocomposites with different loads of lignin. Loading of lignin at 5 wt% and 10 wt% lignin resulted in higher values of catalytic activity of LiP: -39.58 and 49.14 µM h-1 g-1 soil, respectively. In comparison, with higher loading of lignin at 15 wt% and 20 wt%, decreases in the catalytic activity of LiP were found and were 28.72 to 37.25 µM h-1 g-1 soil, respectively. The activation energy of LiP increased approximately 1.11- to 1.22-fold when 15 and 20 wt% of lignin was loaded in biocomposites. Research findings established the possibility of unfavorable binding of the LiP to lignin with an increase in the load of lignin, possibly due to the complex structure of intact lignin and presence of inhibitory biodegradation products of lignin accumulates during lignin biodegradation in biocomposites. It was concluded that higher lignin contents (15 wt% and 20 wt%) were effective in reducing the activity of the soil LiP. Hence, higher lignin content possibly protects against losses of lignin, while acting as a filler in the formulation of biocomposites.

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