scholarly journals Content of Toxic Elements in 12 Groups of Rice Products Available on Polish Market: Human Health Risk Assessment

Foods ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 1906
Author(s):  
Joanna Bielecka ◽  
Renata Markiewicz-Żukowska ◽  
Patryk Nowakowski ◽  
Monika Grabia ◽  
Anna Puścion-Jakubik ◽  
...  

Background: Rice is one of the most commonly consumed grains. It could be a good source of nutrients in a diet, but its consumption could also contribute to exposure to toxic elements. All rice products available on the Polish market are imported, which may pose a particular concern as to the safety of their consumption. The aim of our study was to estimate the content of As, Cd, Pb, and Hg in rice products and to assess the health risk indicators related to exposure to toxic elements consumed with rice products among the adult population in Poland. Methods: A total of 99 samples from 12 groups of rice products (basmati, black, brown, parboiled, red, wild, white rice and expanded rice, rice flakes, flour, pasta, and waffles) available in the Polish market were obtained. The content of Hg was determined using the atomic absorption spectrometry method (AAS). To measure As, Cd, and Pb, inductively coupled plasma-mass spectrometry (ICP-MS) was used. The health risk was assessed by calculating several indicators. Results: The average As, Cd, Pb, and Hg contents in all studied products were 123.5 ± 77.1 μg/kg, 25.7 ± 26.5 μg/kg, 37.5 ± 29.3 μg/kg, and 2.8 ± 2.6 μg/kg, respectively. Exceedance of the limit established by the Polish National Food Safety Standard was observed in one sample as regards the As content and exceedance of the European Commission standard in two samples for Hg. The samples of foods imported from European markets (n = 27) had statistically higher As content (p < 0.05) than those imported from Asian countries (n = 53). The values of health risk indicators did not show an increased risk for the Polish adult population. However, the daily intake of 55 g of rice corresponds to the benchmark dose lower confidence limit (BMDL) for Pb. Conclusion: The studied rice products could be regarded as safe for consumption by the Polish population as far as the content of As, Cd, Pb, and Hg is concerned.

2021 ◽  
Vol 11 (15) ◽  
pp. 7023
Author(s):  
Vannini Andrea ◽  
Martina Grattacaso ◽  
Giulia Canali ◽  
Francesco Nannoni ◽  
Luigi Antonello Di Lella ◽  
...  

The aim of this study was to provide, for the first time, data on the concentration of potentially toxic elements (PTEs) in soils and bulbs of elephant garlic (Allium ampeloprasum L.) cultivated in Valdichiana, a traditional agricultural area of Tuscany, Italy. Bulbs of elephant garlic and soil samples were collected in four cultivation fields and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to determine the concentrations of As, Cd, Co, Cr, Cu, Ni, Pb, Sb, Tl, U, V, Zn. The concentrations of these PTEs in bulbs and cultivation soils were used to calculate geochemical, ecological and health risk indices. The results of this study suggest that, although bulbs of elephant garlic from the Valdichiana area may present slightly high concentrations of Cd, Ni and Pb, the associated health risk based on the daily intake is absolutely negligible. Cultivation soils had somewhat high Cu concentrations probably due to the diffuse use of Cu-based products in agriculture, but showed overall a very low ecological risk.


2018 ◽  
Vol 29 (1) ◽  
pp. 8-24 ◽  
Author(s):  
Uchechi Bliss Onyedikachi ◽  
Donatus Chuka Belonwu ◽  
Mattew Owhonda Wegwu

Abstract In view of ensuring healthy agricultural foods for human consumption, this study assessed the human health risk implicated in selected heavy metals in some commonly consumed vegetables, tubers, nuts and fruits grown around the quarry sites at Ishiagu, Ebonyi State, Nigeria. Samples from agriculture area of Umudike, Abia State, Nigeria, constituted the control. The concentration of Mn, Zn, Fe, Cu, Cd, and Pb, were determined using atomic absorption spectrometry. The potential non-carcinogenic health risk for consumers which included Estimated Daily Intake (EDI) and Target Hazard Quotients (THQ) for Pb, Fe, Mn, Zn, Cd and Cu while carcinogenic health risk using Cancer Slope Factors (CSF) was established for Cd and Pb. Relative abundance of heavy metals across the locations and all samples was in the order Fe > Mn > Zn > Pb > Cu > Cd. There was statistical significant effect of quarrying activities on the concentration of the heavy metals (Fe, Mn, Zn, Pb, Cu, Cd) at p < 0.05 level. Based on the observed bioconcentration factors, cassava showed more hyperaccumulation potential compared to other samples. Pumpkin and bitter leaf also could be used in remediation owing to their high bioaccumulation index for Pb and Zn. THQ obtained for Mn and Pb were >1 indicating that the residents at the quarry site may be exposed to potential non-carcinogenic health risk due to Mn and Pb intoxication. With respect to US EPA prescriptions, average carcinogenic risk values obtained for Pb and Cd in this study indicated a lifetime (70 years) probability of contracting cancer suggesting that they be placed for further consideration as chemicals of concern with respect to the assessed locals.


Author(s):  
Luana C. S. Leite ◽  
Elaine S. de P. Melo ◽  
Daniela G. Arakaki ◽  
Elisvânia F. dos Santos ◽  
Valter A. do Nascimento

Data on the content of metals and metalloids in roasted meats with different types of wood and charcoal are still scarce in the literature. The concentrations of metals (Al, Cr, Cd, Cu, Fe, Mg, Mn, Mo, Ni, V, and Zn) and metalloid (As) were determined by inductively coupled plasma mass spectrometry (ICP-OES) after microwave digestion, and the estimated daily intake (EDI) for adults was assessed to determine the hazard quotient (HQ). The concentrations of Al, Cr, Cu, and Fe in raw meats were below the data obtained in other countries. The concentration of As (0.17 ± 0.42–0.23 ± 0.10 mg/kg), Mg (206.77 ± 3.99–291.95 ± 8.87 mg/kg), V (0.42 ± 0.14–6.66 ± 0.80 mg/kg), and Zn (6.66 ± 0.80–48.13 ± 0.56 mg/kg) in raw meats exceeded the values in the literature. The concentrations of Mg, As, Cr, Fe, V, and Zn are high when the meat is roasted using wood. All levels of Al, As, Cr, Cu, Fe, Mg, Mn, Mo, V, and Zn in raw meats are lower than those of meat roasted with coal and wood. The content of As in meat roasted with Chromed Copper Arsenate (CCA) wood (15.10 ± 0.27–26.25 ± 1.47 mg/kg) is higher than meat roasted with charcoal (0.46 ± 0.09–1.16 ± 0.50 mg/kg). EDI and HQ values revealed a minimal exposure of the adult population to those metals through roasted-meats consumption. However, EDI values of As in some roasted meats are above standard limits. Roast meats with wood showed higher levels of major and trace elements than meats roasted with coal. High exposures, in the long-term, may cause damage to health.


2019 ◽  
Vol 17 (1) ◽  
pp. 1050-1060
Author(s):  
Chidinma C. Ezeofor ◽  
Janefrances N. Ihedioha ◽  
Oguejiofo T.Ujam ◽  
Nwachukwu R. Ekere ◽  
Charles O. Nwuche

AbstractThe potential toxic elements (Cu, Zn, Pb, Ni, Fe, Cr, Cd, Mn and Hg) were accumulated from rice grains and soil from an Ugbawka farm, Enugu State, Nigeria, which were determined to evaluate the potential health risk to rice consumers. The mean levels of metals found in soil (mg/kg) were as follows: Ni (0.57±0.24), Pb (2.44±0.17), Zn (3.35±2.05), Cu (0.71±0.33), Mn (37.72±10.97), Fe (13 856.6±31.43), Cr (2.51±0.98), Cd (0.51±1.36), and Hg (0.02±0.38); however metals found in rice grains (mg/ kg) were: Ni (0.81±0.72), Pb (0.94±0.70), Zn (8.22±2.97), Cu (0.59±0.42), Mn (13.30±4.56), Fe (13.28±0.73), Cr (15.00±10.00), Cd (0.36±0.07), and Hg (0.002±0.23). A small percentage (2.5%) of the soil samples were above the Chinese Maximum Allowable Concentration for cadmium in soil while cadmium and lead levels in the rice grains were above WHO permissible limit. Pearson’s correlations showed significant correlations amongst some metal pairs in soil and grains showing similarity in origin. The estimated daily intake of Pb was higher than the safety levels given by JECFA. Hazard Quotient for Pb and Total Hazard Index of all the metals were above one. This indicates possible potential health risk and adverse effect resulting from consumption of rice from Ugbawka farm.


PLoS ONE ◽  
2021 ◽  
Vol 16 (6) ◽  
pp. e0252834
Author(s):  
Karolina Orywal ◽  
Katarzyna Socha ◽  
Patryk Nowakowski ◽  
Wojciech Zoń ◽  
Piotr Kaczyński ◽  
...  

Mushrooms exhibit a high ability to accumulate potentially toxic elements. The legal regulations in force in the European Union countries do not define the maximum content of elements in dried wild-grown mushrooms. This study presents the content of mercury (Hg), lead (Pb), cadmium (Cd) and arsenic (As) determined in dried wild-grown mushrooms (Boletus edulis and Xerocomus badius) available for sale. Moreover, the health risk associated with their consumption is assessed. The inductively coupled plasma mass spectrometry (Cd, Pb, As) and atomic absorption spectrometry (Hg) were used. The mean Hg, Cd, Pb and As concentration in Boletus edulis was 3.039±1.092, 1.983±1.145, 1.156±1.049 and 0.897±0.469 mg/kg and in Xerocomus badius 0.102±0.020, 1.154±0.596, 0.928±1.810 and 0.278±0.108 mg/kg, respectively. The maximum value of the hazard index (HI) showed that the consumption of a standard portion of dried Boletus edulis may have negative consequences for health and corresponded to 76.2%, 34.1%, 33% and 4.3% of the maximum daily doses of Hg, Cd, Pb and As, respectively. The results indicate that the content of toxic elements in dried wild-grown mushrooms should be monitored. The issue constitutes a legal niche where unfavourable EU regulations may pose a threat to food safety and consumer health.


Author(s):  
Patricia Rojas ◽  
Elizabeth Ruiz-Sánchez ◽  
Camilo Ríos ◽  
Ángel Ruiz-Chow ◽  
Aldo A. Reséndiz-Albor

The use of the medicinal plant Ginkgo biloba has increased worldwide. However, G. biloba is capable of assimilating both essential and toxic metals, and the ingestion of contaminated products can cause damage to health. The aim of this study was to investigate the safety of manganese (Mn), copper (Cu), lead (Pb), arsenic (As), and cadmium (Cd) in 26 items containing Ginkgo biloba (pharmaceutical herbal products, dietary supplements, and traditional herbal remedies) purchased in the metropolitan area of Mexico City. Metal analysis was performed using a graphite furnace atomic absorption spectrometer. All of the products were contaminated with Pb, 54% of them with As, and 81% with Cd. The lowest values of Pb, As, and Cd were detected in pharmaceutical herbal products > dietary supplements > traditional herbal remedies. The daily intake dose (DID) of pharmaceutical herbal products was within the established limits for the five metals. Dietary supplements and traditional herbal remedies exceeded the DID limits for Pb. The hazard quotients estimation and non-carcinogenic cumulative hazard estimation index for Mn, As, and Cd indicated no human health risk. Our results suggest that products containing G. biloba for sale in Mexico are not a health risk.


Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 613
Author(s):  
Samantha Jiménez-Oyola ◽  
Kenny Escobar Segovia ◽  
María-Jesús García-Martínez ◽  
Marcelo Ortega ◽  
David Bolonio ◽  
...  

Anthropogenic activities performed in the Ecuadorian Amazon have released potentially toxic elements (PTEs) into the rivers, causing severe environmental pollution and increasing the risk of exposure to the residents of the surrounding areas. This study aims to carry out a human health risk assessment using deterministic and probabilistic methods to estimate the hazard index (HI) and total cancer risk (TCR) related to multi-pathway human exposure to PTEs in polluted rivers. Concentrations of Al, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in surface water and sediment samples from rivers on the Ecuadorian Amazon were considered to assess the potential adverse human health effects. As a result, deterministic and probabilistic estimations of cancer and non-cancer risk through exposure to surface waters and sediments were above the safety limit. A sensitivity analysis identified the concentration of PTEs and the exposure duration (ED) as the two most important variables for probabilistic health risk assessment. The highest risk for receptors was related to exposure to polluted sediments through incidental ingestion and dermal contact routes. According to the deterministic estimation, the human health risk through ingestion of water was above the threshold in specific locations. This study reveals the potential health risk to which the population is exposed. This information can be used as a baseline to develop public strategies to reduce anthropogenic pollution and exposure to PTEs in Ecuadorian Amazon rivers.


Author(s):  
Georges-Ivo Ekosse ◽  
George Elambo Nkeng ◽  
Nenita Bukalo ◽  
Olaonipekun Oyebanjo

This study assessed the mineralogical and geochemical characteristics of geophagic clays sold in some markets in Cameroon to ascertain their provenance, contamination status and human health risk. To achieve this, 40 samples from 13 markets in Cameroon were purchased and analysed using X-ray diffractometry, X-ray fluorescence and laser ablation inductively coupled plasma mass spectrometry for their mineralogy and geochemistry, respectively. The geophagic clays were dominantly made up of kaolinite and quartz. Their chemistry was dominated by SiO2, Al2O3 and LOI with means of 48.76 wt%, 32.12 wt% and 13.93 wt%, respectively. The major, trace and rare earth elements data showed that these geophagic clays were predominantly derived from felsic rocks. The contamination assessment indicated no enrichment of metals from anthropogenic sources, except for Zn in samples from Acacia, Madagascar and Mfoudi markets. The index of geo-accumulation indicated no contamination to moderate contamination of the clays. The non-carcinogenic index values for Fe, Co, Cr, Cu, Ni, Pb and Zn were generally less than 1, suggesting no non-carcinogenic risk exposure to children and adults consuming the geophagic clays from these metals. The carcinogenic risk index (TCR) for Ni and Cr were above 10−6, which implies that children and adults are vulnerable to minimal carcinogenic health risk. The TCR values from Ni posed the highest risk, especially to children consuming clays from some markets.


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