scholarly journals Properties of Eco-Friendly Particleboards Bonded with Lignosulfonate-Urea-Formaldehyde Adhesives and pMDI as a Crosslinker

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4875 ◽  
Author(s):  
Pavlo Bekhta ◽  
Gregory Noshchenko ◽  
Roman Réh ◽  
Lubos Kristak ◽  
Ján Sedliačik ◽  
...  

The purpose of this study was to evaluate the feasibility of using magnesium and sodium lignosulfonates (LS) in the production of particleboards, used pure and in mixtures with urea-formaldehyde (UF) resin. Polymeric 4,4′-diphenylmethane diisocyanate (pMDI) was used as a crosslinker. In order to evaluate the effect of gradual replacement of UF by magnesium lignosulfonate (MgLS) or sodium lignosulfonate (NaLS) on the physical and mechanical properties, boards were manufactured in the laboratory with LS content varying from 0% to 100%. The effect of LS on the pH of lignosulfonate-urea-formaldehyde (LS-UF) adhesive compositions was also investigated. It was found that LS can be effectively used to adjust the pH of uncured and cured LS-UF formulations. Particleboards bonded with LS-UF adhesive formulations, comprising up to 30% LS, exhibited similar properties when compared to boards bonded with UF adhesive. The replacement of UF by both LS types substantially deteriorated the water absorption and thickness swelling of boards. In general, NaLS-UF-bonded boards had a lower formaldehyde content (FC) than MgLS-UF and UF-bonded boards as control. It was observed that in the process of manufacturing boards using LS adhesives, increasing the proportion of pMDI in the adhesive composition can significantly improve the mechanical properties of the boards. Overall, the boards fabricated using pure UF adhesives exhibited much better mechanical properties than boards bonded with LS adhesives. Markedly, the boards based on LS adhesives were characterised by a much lower FC than the UF-bonded boards. In the LS-bonded boards, the FC is lower by 91.1% and 56.9%, respectively, compared to the UF-bonded boards. The boards bonded with LS and pMDI had a close-to-zero FC and reached the super E0 emission class (≤1.5 mg/100 g) that allows for defining the laboratory-manufactured particleboards as eco-friendly composites.

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 220
Author(s):  
Petar Antov ◽  
Viktor Savov ◽  
Ľuboš Krišťák ◽  
Roman Réh ◽  
George I. Mantanis

The potential of producing eco-friendly, formaldehyde-free, high-density fiberboard (HDF) panels from hardwood fibers bonded with urea-formaldehyde (UF) resin and a novel ammonium lignosulfonate (ALS) is investigated in this paper. HDF panels were fabricated in the laboratory by applying a very low UF gluing factor (3%) and ALS content varying from 6% to 10% (based on the dry fibers). The physical and mechanical properties of the fiberboards, such as water absorption (WA), thickness swelling (TS), modulus of elasticity (MOE), bending strength (MOR), internal bond strength (IB), as well as formaldehyde content, were determined in accordance with the corresponding European standards. Overall, the HDF panels exhibited very satisfactory physical and mechanical properties, fully complying with the standard requirements of HDF for use in load-bearing applications in humid conditions. Markedly, the formaldehyde content of the laboratory fabricated panels was extremely low, ranging between 0.7–1.0 mg/100 g, which is, in fact, equivalent to the formaldehyde release of natural wood.


2018 ◽  
Vol 1 (1) ◽  
pp. 16-23
Author(s):  
Apri Heri Iswanto ◽  
Dita Sari Prabuningrum ◽  
Irawati Azhar ◽  
Supriyanto Supriyanto

The objective of this research was to evaluate the effect of length size particle on physical and mechanical properties of particleboard. Sorghum bagasse was cut into 3, 5, and 7 cm length size. Furthermore, particles were dried until reached of4% moisture content. Amount of 10% urea-formaldehyde (UF) resin used for binding. Hot pressing process conducted in 130C temperature for 10 minutes and 30 kg cm -2 pressure. The results showed that thickness swelling (TS) and internal bond (IB) did not fulfill of requirement of Japanese Industrial Standard (JIS) A 5908 (2003). According to all parameters, 3 cm length size of particle was resulting in the best properties.


1970 ◽  
Vol 43 (4) ◽  
pp. 581-587
Author(s):  
M Hasan Shahria ◽  
M Ashaduzzaman ◽  
M Iftekhar Shams ◽  
Arifa Sharmin ◽  
M Muktarul Islam

The study was conducted to find out the potentiality of Pitali (Trewia nudiflora) for manufacturing commercial plywood and evaluating its physical and mechanical properties. Two 9-ply plywood of 2.4m x 1.2m x 18mm size were manufactured using liquid urea formaldehyde adhesive. The physical and mechanical properties of T. nudiflora plywood were compared with the existing market available plywood manufactured by Simul (Bombax ceiba). It was found that density were 509.82 kg/m3 and 490.96 kg/m3, moisture content after curing were 10.67% and 17.61%, thickness swelling were 6.90% and 7.29%, linear expansion were 0.19% and 0.15%, water absorption were 50.89% and 64.79%, MOR were 29.94 N/mm2 and 27.05 N/mm2, MOE were 1613.89 N/mm2 and 1160.68 N/mm2, and tensile strength were 14.75 N/mm2 and 13.12 N/mm2 for T. nudiflora plywood and market plywood respectively. The evaluated physical and mechanical properties of T. nudiflora plywood were also compared with some relevant results and standards reported earlier. Key Words: Plywood, Trewia nudiflora, Physical properties, Mechanical properties. doi: 10.3329/bjsir.v43i4.2249 Bangladesh J. Sci. Ind. Res. 43(4),581-587, 2008


BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 6795-6810
Author(s):  
Nurul Fatiha Osman ◽  
Paimon Bawon ◽  
Seng Hua Lee ◽  
Pakhriazad Hassan Zaki ◽  
Syeed SaifulAzry Osman Al-Eldrus ◽  
...  

Particleboard was produced by mixing oil heat-treated rubberwood particles at different ratios, with the goal of achieving high dimensional stability. Rubberwood particles were soaked in palm oil for 2 h and heat treated at 200 °C for 2 h. The treated particles were soaked in boiling water for 30 min to remove oil and were tested for chemical alteration and thermal characterization via Fourier-transform infrared spectroscopy and thermogravimetric analysis. Particleboard was fabricated by mixing treated rubberwood particles (30%, 50%, and 70%) with untreated particles (70%, 50%, and 30%, respective to previous percentages) and bonded with urea-formaldehyde (UF) resin. The results revealed that oil-heat treated particles had greater thermal stability than the untreated particles. The addition of oil heat treated particles improved the physical properties of the particleboard with no significant reduction in mechanical strength. However, this was only valid for ratios of 70% untreated to 30% treated and 50% untreated to 50% treated. When a ratio of 70% oil heat treated particles was used, both the physical and mechanical properties were reduced drastically, due to bonding interference caused by excessive oil content. Particleboard made with a ratio of 5:5 (treated to untreated) exhibited the best physical and mechanical properties.


2021 ◽  
Vol 114 ◽  
pp. 70-75
Author(s):  
Radosław Auriga ◽  
Piotr Borysiuk ◽  
Alicja Auriga

An attempt to use „Tetra Pak” waste material in particleboard technology. The study investigates the effect of addition Tetra Pak waste material in the core layer on physical and mechanical properties of chipboard. Three-layer chipboards with a thickness of 16 mm and a density of 650 kg / m3 were manufactured. The share of Tetra Pak waste material in the boards was varied: 0%, 5%, 10% and 25%. The density profile was measured to determine the impact of Tetra Pak share on the density distribution. In addition, the manufactured boards were tested for strength (MOR, MOE, IB), thickness swelling and water absorption after immersion in water for 2 and 24 hours. The tests revealed that Tetra Pak share does not affect significantly the value of static bending strength and modulus of elasticity of the chipboard, but it significantly decreases IB. Also, it has been found that Tetra Pak insignificantly decreases the value of swelling and water absorption of the chipboards.


Holzforschung ◽  
2001 ◽  
Vol 55 (2) ◽  
pp. 214-218 ◽  
Author(s):  
Edmone Roffael ◽  
Brigitte Dix ◽  
Thomas Schneider

Summary Thermomechanical (TMP) and chemo-thermomechanical pulps (CTMP) were prepared from spruce under different pulping conditions. The fibres were dried at 70 °C and medium density fibreboards (MDF) were made therefrom in pilot plant scale using urea-formaldehyde resins as a binder. The results of testing the physical-mechanical properties reveal that the pulping temperature has a significant influence on the thickness swelling and water absorption of the boards. MDF prepared from fibres produced at high pulping temperature (180 °C) generally show lower thickness swelling and water absorption than MDF made from fibres produced at low pulping temperature (140°C and 160 °C). However, high pulping temperature may have a negative effect on the internal bond strength of the boards. In general, CTMP leads to MDF with higher internal bonding strength compared to those derived from TMP. In addition, the influence of different drying conditions (150 °C and 170 °C) of TMP and CTMP on the physical-mechanical properties of MDF was assessed. MDF made from CTMP showed lower thickness swelling when dried under high temperature.


FLORESTA ◽  
2021 ◽  
Vol 51 (2) ◽  
pp. 419
Author(s):  
Giuliano Ferreira Pereira ◽  
Setsuo Iwakiri ◽  
Rosilani Trianoski ◽  
Polliana D'angelo Rios ◽  
Renan Zunta Raia

The objective of this research was to evaluate the effects of thermal modifications, at different temperatures and exposure times, on the technological properties of mixed particleboard / OSB panels made out of Eucalyptus badjensis. Using the wood of Eucalyptus badjensis, Particleboard, OSB and mixed Particleboard/OSB panels (control and thermally modified) were manufactured. The mixed panels’ thermal modification was carried out under three temperatures (180ºC, 200ºC and 220ºC) and two exposure times (10 minutes and 12 minutes). For the panels’ manufacturing, 6% of phenol-formaldehyde adhesive and 1% of paraffin were employed, which was calculated based on the particles’ dry mass. The water absorption and thickness swelling properties were evaluated after 2 and 24 hours of immersion, in addition to the panels’ modulus of elasticity, modulus of rupture and internal bond. Based on the results, we were able to conclude that the thermal modification affected most of the physical properties positively. From the different exposure times studied, the most effective one was the period of 12 minutes, especially for water absorption after 2 hours, which caused a reduction of 11.27%. In turn, the most effective temperature was of 220ºC, highlighting the thickness swelling after 24 hours, which caused a swelling decrease of 23.76% in comparison with the control panels. Regarding the mechanical properties, the thermal modification, in terms of the studied exposure times and temperatures, did not affect the results of the mixed particleboard /OSB panels. 


2021 ◽  
Vol 9 (3) ◽  
pp. 454-465
Author(s):  
Tengku Muhammad Renzy Hariz ◽  
Indra Agus Santosa ◽  
Muhammad Iqbal Maulana ◽  
Marwanto ◽  
Denni Prasetia ◽  
...  

The objectives of this research were to evaluate bamboo-oriented strand board (BOSB) characteristics made from betung (Dendrocalamus asper), ampel (Bambusa vulgaris), and their mixtures at two different contents (3% and 5%) of methylene diphenyl di-isocyanate (MDI) adhesives. The strands were steam-treated at 126°C for 1 h under the pressure of 0.14 MPa. Three-layered BOSBs with a target density of 0.7 g/cm3 were made with the size of 30 cm x 30 cm x 0.9 cm and a shelling ratio of 1:2:1 (face:core:back layers). The physical and mechanical properties of BOSB were evaluated following JIS A 5908 (2003) standard, and the results were compared with the CSA 0437.0 Grade O-1 standard. The results show that BOSB from the mixtures of betung and ampel bamboo strands has higher dimensional stability as shown by the decrease in water absorption and thickness swelling and higher mechanical properties than single BOSB. All BOSBs with 5% resin content have higher dimensional stability, MOE, and MOR than BOSB with 3% resin content. The physical and mechanical properties of all BOSB manufactured met the CSA 0437.0 Grade O-1 standard. This study proved that BOSBs from the mixture of betung and ampel strands have the potential to be developed due to having better physical and mechanical qualities than a single BOSB. Keywords: ampel (Bambusa vulgaris), bamboo oriented strand board, betung (Dendrocalamus asper), resin content, strand mixtures


BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 3566-3584
Author(s):  
Qingde Li ◽  
Yingyi Liang ◽  
Feng Chen ◽  
Tonghui Sang

Wood fiber was modified by impulse-cyclone drying treatment with poplar and montmorillonite as reinforcing materials; mMMT/polypropylene/wood fiber foaming composite was prepared by the hot compression process. The effects of modification, temperature, and content of montmorillonite on physical and mechanical properties of the composite were analyzed. Mechanical properties, porosity, shrinkage, water absorption, and thickness swelling tests showed that when mMMT reinforcement was 5 wt%, the best performance was achieved. The scanning electron microscopy observations showed that bubble holes were distributed widely and evenly, and mMMT appeared in the cell gap and was encapsulated by polypropylene, which maximized the bonding effect. Flexural strength was 27.5 MPa, flexural modulus was 2110 MPa, tensile strength was 20.0 MPa, and impact strength was 6.30 KJ/m2. When absolute volume of dense solid reached 70.8 cm3, porosity was 21.4% and shrinkage was 1.17%, which indicated that the water absorption increased most remarkably under that test condition. When equilibrium water absorption reached 9.28%, the thickness swelling decreased by 25%. The results showed that mMMT effectively optimized mechanical properties of wood-based foamed composites and improved hygroscopic properties.


2011 ◽  
Vol 3 (1) ◽  
pp. 7
Author(s):  
Sari Mirad Noor

The need of log increace rapidly, mean while forest product decrease, so efficiency on wood process should be done wisely, in the other hand plastic waste is uncompossed material, become an environmental problems. This research aims to determine the impact of particles of type HDPE plastic wastes and twigs/branches of rubber on some physical and mechanical properties of wood. Physical properties have been tested for water content, density, thickness, and water absorption. Although mechanical properties tests were tough Broken/Module of Rufture (MOR) and the preservation of architecture/modulus of elasticity (MOE).     The raw materials used are polyethylene of high density of waste plastic and rubber adhesive urea formaldehyde branch branch. Experimental design used the randomized Completely Design (RCD) 5 x 4, in which each treatment became much like 5 times replicated).The treatment used is the diversity of the composition of the waste of plastic of different types of polyethylene of high density provides a significant effect on the content of water, water absorption, the density and the development of thickness. With regard to the persistence and the fracture of the arch determination not to give a significant effect.Keywords: physical and mechanical properties, particle board, HDPE plastic waste, branch/twig of  rubber.


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