scholarly journals Microstructure and Mechanical Properties of Inverse Nanocomposite Made from Polylactide and Hydroxyapatite Nanoparticles

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 184
Author(s):  
Elżbieta Pietrzykowska ◽  
Barbara Romelczyk-Baishya ◽  
Agnieszka Chodara ◽  
Iwona Koltsov ◽  
Hilary Smogór ◽  
...  

Polymer nanocomposites have been extensively researched for a variety of applications, including medical osteoregenerative implants. However, no satisfactory solution has yet been found for regeneration of big, and so-called critical, bone losses. The requirement is to create a resorbable material which is characterised by optimum porosity, sufficient strength, and elastic modulus matching that of the bone, thus stimulating tissue regrowth. Inverse nanocomposites, where the ceramic content is larger than the polymer content, are a recent development. Due to their high ceramic content, they may offer the required properties for bone implants, currently not met by polymer nanocomposites with a small number of nanoparticles. This paper presents inverse nanocomposites composed of bioresorbable nano crystalline hydroxyapatite (HAP NPs) and polylactide (PLLA), produced by cryomilling and a warm isostatic pressing method. The following compositions were studied: 25%, 50%, and 75% of HAP NPs by volume. The mechanical properties and structure of these composites were examined. It was discovered that 50% volume content was optimal as far as compressive strength and porosity are concerned. The inverse nanocomposite with 50% nanoceramics volume displayed a compressive strength of 99 ± 4 MPa, a contact angle of 50°, and 25% porosity, which make this material a candidate for further studies as a bioresorbable bone implant.

2011 ◽  
Vol 306-307 ◽  
pp. 76-81
Author(s):  
Hao Wen Hou ◽  
Wen Ting Wei ◽  
Zhi Xuan Chen

For bone implant NiTi foams with a structure (69.3-69.9% porosity and 150-400μm pore size) were fabricated by CIP and sintering with NaCl space-holders. A maximum compressive strength of 30.90Mpa and a ultimate compressive ductility of 33.5% were obtained. Moreover, 81-89% of the strain recovered after inducing shape-memory effect. In particular, the pores completely replicate the shape and size of the NaCl powders. It provides a powerful tool to tailor the pore structure and mechanical properties of NiTi foams to match the demand of bone implant. Simple processing route and low cost allow these foams to be a suitable candidate for bone implant applications.


2015 ◽  
Vol 815 ◽  
pp. 321-326 ◽  
Author(s):  
Jian Xiao ◽  
Yi Long Liao ◽  
Gui Bao Qiu

Titanium (Ti) foams used in biomedical application has been attracted scientific and technological interest because of their excellent mechanical properties, superior corrosion resistance and good biocompability. In this article, Ti foam with semi-open cell was prepared using the acicular carbamide as a space holder without any adhesives. The pore structure was characterized by SEM and the mechanical properties were determined by compressive tests. The results show that the porosity is 56.8%, the compressive strength and Young’s modulus are 104.6 MPa and 2.9 GPa, respectively. These results demonstrated that the obtained foam has a great potential as a substitute biomaterial for cortical bone.


2020 ◽  
Vol 14 (2) ◽  
pp. 6734-6742
Author(s):  
A. Syamsir ◽  
S. M. Mubin ◽  
N. M. Nor ◽  
V. Anggraini ◽  
S. Nagappan ◽  
...  

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study.  The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.    


2012 ◽  
Vol 4 (1) ◽  
pp. 1
Author(s):  
Djoko Purwanto

Timber Acacia mangium (Acacia mangium, Willd) for Furniture. The study aims to determine the mechanical and physical properties and the decorative value (color and fiber) wood of acacia mangium with using finishing materials. This type of finishing material used is ultran lasur natural dof ,ultran lasur classic teak, aqua politur clear dof, aqua politur akasia dan aqua politur cherry. After finishing the wood is stored for 3 months. Test parameters were observed, namely, physical and mechanical properties of wood, adhesion of finishing materials, color and appearance of the fiber, and timber dimensions expansion. The results showed that the mechanical physical properties of acacia wood qualified SNI. 01-0608-89 about the physical and mechanical properties of wood for furniture, air dry the moisture content from 13.78 to 14.89%, flexural strength from 509.25 to 680.50 kg/cm2, and compressive strength parallel to fiber 342.1 - 412.9 kg/cm2. Finishing the treatment process using five types of finishing materials can increase the decorative value (color and fiber) wood. Before finishing the process of acacia mangium wood has the appearance of colors and fibers and less attractive (scale scores 2-3), after finishing acacia wood fibers have the appearance of colors and interesting and very interesting (scale 4-5).Keywords: mangium wood, mechanical properties, decorative value, finishing, furniture.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2694 ◽  
Author(s):  
Shansuo Zheng ◽  
Lihua Niu ◽  
Pei Pei ◽  
Jinqi Dong

In order to evaluate the deterioration regularity for the mechanical properties of brick masonry due to acid rain corrosion, a series of mechanical property tests for mortars, bricks, shear prisms, and compressive prisms after acid rain corrosion were conducted. The apparent morphology and the compressive strength of the masonry materials (cement mortar, cement-lime mortar, cement-fly ash mortar, and brick), the shear behavior of the masonry, and the compression behavior of the masonry were analyzed. The resistance of acid rain corrosion for the cement-lime mortar prisms was the worst, and the incorporation of fly ash into the cement mortar did not improve the acid rain corrosion resistance. The effect of the acid rain corrosion damage on the mechanical properties for the brick was significant. With an increasing number of acid rain corrosion cycles, the compressive strength of the mortar prisms, and the shear and compressive strengths of the brick masonry first increased and then decreased. The peak stress first increased and then decreased whereas the peak strain gradually increased. The slope of the stress-strain curve for the compression prisms gradually decreased. Furthermore, a mathematical degradation model for the compressive strength of the masonry material (cement mortar, cement-lime mortar, cement-fly ash mortar, and brick), as well as the shear strength attenuation model and the compressive strength attenuation model of brick masonry after acid rain corrosion were proposed.


Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2303
Author(s):  
Congyu Zhong ◽  
Liwen Cao ◽  
Jishi Geng ◽  
Zhihao Jiang ◽  
Shuai Zhang

Because of its weak cementation and abundant pores and cracks, it is difficult to obtain suitable samples of tectonic coal to test its mechanical properties. Therefore, the research and development of coalbed methane drilling and mining technology are restricted. In this study, tectonic coal samples are remodeled with different particle sizes to test the mechanical parameters and loading resistivity. The research results show that the particle size and gradation of tectonic coal significantly impact its uniaxial compressive strength and elastic modulus and affect changes in resistivity. As the converted particle size increases, the uniaxial compressive strength and elastic modulus decrease first and then tend to remain unchanged. The strength of the single-particle gradation coal sample decreases from 0.867 to 0.433 MPa and the elastic modulus decreases from 59.28 to 41.63 MPa with increasing particle size. The change in resistivity of the coal sample increases with increasing particle size, and the degree of resistivity variation decreases during the coal sample failure stage. In composite-particle gradation, the proportion of fine particles in the tectonic coal sample increases from 33% to 80%. Its strength and elastic modulus increase from 0.996 to 1.31 MPa and 83.96 to 125.4 MPa, respectively, and the resistivity change degree decreases. The proportion of medium particles or coarse particles increases, and the sample strength, elastic modulus, and resistivity changes all decrease.


2021 ◽  
Vol 13 (8) ◽  
pp. 4546
Author(s):  
Kaiyue Zhao ◽  
Peng Zhang ◽  
Bing Wang ◽  
Yupeng Tian ◽  
Shanbin Xue ◽  
...  

Cement-based materials prepared with activated water induced by a magnetic field or electric field represent a possible solution to environmental issues caused by the worldwide utilization of chemical admixtures. In this contribution, electric- and magnetic-activated water have been produced. The workability and mechanical properties of cement mortar prepared with this activated water have been investigated. The results indicate that the pH and absorbance (Abs) values of the water varied as the electric and magnetic field changed, and their values increased significantly, exhibiting improved activity compared with that of the untreated water. In addition, activated water still retains activity within 30 min of the resting time. The fluidity of the cement paste prepared with electric-activated water was significantly larger than that of the untreated paste. However, the level of improvement differed with the worst performance resulting from cement paste prepared with alternating voltage activated water. In terms of mechanical properties, both compressive strength and flexural strength obtained its maximum values at 280 mT with two processing cycles. The compressive strength increased 26% as the curing time increased from 7 days to 28 days and flexural strength increased by 31%. In addition, through the introduction of magnetic-activated water into cement mortar, the mechanical strength can be maintained without losing its workability when the amount of cement is reduced.


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