scholarly journals Extraction of High Value Triterpenic Acids from Eucalyptus globulus Biomass Using Hydrophobic Deep Eutectic Solvents

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 210 ◽  
Author(s):  
Nuno H. C. S. Silva ◽  
Eduarda S. Morais ◽  
Carmen S. R. Freire ◽  
Mara G. Freire ◽  
Armando J. D. Silvestre
Keyword(s):  
Ursolic Acid ◽  
Eucalyptus Globulus ◽  
Room Temperature ◽  
Eutectic Mixture ◽  
Value Added ◽  
Deep Eutectic Solvents ◽  
Biological Properties ◽  
Outer Bark ◽  
Triterpenic Acids ◽  
By Products

Triterpenic acids (TTAs), known for their promising biological properties, can be found in different biomass sources and related by-products, such as Eucalyptus globulus bark, and have been extracted using organic volatile solvents such as dichloromethane. Recently, deep eutectic solvents (DES) have been identified as promising alternatives for the extraction of value-added compounds from biomass. In the present work, several hydrophobic DES were tested for the extraction of TTAs from E. globulus bark. Initial solubility studies revealed that DES based on menthol and thymol as the most promising solvents for these compounds given the highest solubilities obtained for ursolic acid (UA) at temperatures ranging from room temperature up to 90 °C. Accordingly, an eutectic mixture of menthol:thymol (1:2) was confirmed as the best candidate for the TTAs extraction from E. globulus outer bark, leading to extraction yields (weight of TTA per weight of biomass) at room temperature of 1.8 wt% for ursolic acid, 0.84 wt% for oleanolic acid and 0.30 wt% for betulinic acid. These values are significantly higher than those obtained with conventional organic solvents under similar conditions. The results obtained using these DES are promising for the recovery of TTAs for nutraceutical and pharmacological applications, while reinforcing the potential of DES as promising solvents to be applied in biorefinery processes.

scholarly journals Microbial Transglutaminase as a Tool to Improve the Features of Hydrocolloid-Based Bioplastics

2020 ◽  
Vol 21 (10) ◽  
pp. 3656 ◽  
Author(s):  
C. Valeria L. Giosafatto ◽  
Antonio Fusco ◽  
Asmaa Al-Asmar ◽  
Loredana Mariniello
Keyword(s):  
Value Added ◽  
Environmentally Friendly ◽  
Biological Properties ◽  
Microbial Transglutaminase ◽  
Plant Origin ◽  
Technological Characteristics ◽  
Microbial Enzyme ◽  
The Matrix ◽  
Isopeptide Bonds ◽  
By Products

Several proteins from animal and plant origin act as microbial transglutaminase substrate, a crosslinking enzyme capable of introducing isopeptide bonds into proteins between the aminoacids glutamines and lysines. This feature has been widely exploited to modify the biological properties of many proteins, such as emulsifying, gelling, viscosity, and foaming. Besides, microbial transglutaminase has been used to prepare bioplastics that, because made of renewable molecules, are able to replace the high polluting plastics of petrochemical origin. In fact, most of the time, it has been shown that the microbial enzyme strengthens the matrix of protein-based bioplastics, thus, influencing the technological characteristics of the derived materials. In this review, an overview of the ability of many proteins to behave as good substrates of the enzyme and their ability to give rise to bioplastics with improved properties is presented. Different applications of this enzyme confirm its important role as an additive to recover high value-added protein containing by-products with a double aim (i) to produce environmentally friendly materials and (ii) to find alternative uses of wastes as renewable, cheap, and non-polluting sources. Both principles are in line with the bio-economy paradigm.

Lipophilic Extractives of the Inner and Outer Barks of Eucalyptus globulus

Holzforschung ◽  
2002 ◽  
Vol 56 (4) ◽  
pp. 372-379 ◽  
Author(s):  
C. S. R. Freire ◽  
A. J. D. Silvestre ◽  
C. Pascoal Neto ◽  
J.A.S. Cavaleiro
Keyword(s):  
Mass Spectrometry ◽  
Eucalyptus Globulus ◽  
Gas Chromatography Mass Spectrometry ◽  
Bark Extract ◽  
Chemical Compositions ◽  
Outer Bark ◽  
Inner Bark ◽  
Triterpenic Acids ◽  
First Time ◽  
Acid Esters

Summary The chemical compositions of the dichloromethane extracts of inner and outer barks of E. globulus were studied by gas chromatography-mass spectrometry. The two fractions show very different chemical compositions: triterpenic acids, such as betulinic, ursolic and oleanolic acids, were the major components of the outer bark extract, whereas β-sitosterol and β-amirin along with palmitic, linoleic and oleic acids predominate in the inner bark extract. Several α-and β-hydroxy fatty acids, recently reported for the first time as E. globulus wood components, were also identified in the outer and inner barks. In the outer bark extract, minor amounts of ferulic acid esters, also previously reported to occur in E. globulus wood were identified. In general, the inner bark lipophilic extractives resemble more closely that of E. globulus wood.

scholarly journals Synergistic Effects of Limosilactobacillus fermentum ASBT-2 with Oxyresveratrol Isolated from Coconut Shell Waste

Foods ◽  
2021 ◽  
Vol 10 (11) ◽  
pp. 2548
Author(s):  
Vidhya Prakash ◽  
Akshaya S Krishnan ◽  
Reshma Ramesh ◽  
Chinchu Bose ◽  
Girinath G. Pillai ◽  
...  
Keyword(s):  
Therapeutic Potential ◽  
Synergistic Effects ◽  
Value Added ◽  
Biological Properties ◽  
Probiotic Properties ◽  
Inhibitory Effects ◽  
Pharmacokinetic Properties ◽  
Negative Impacts ◽  
Coconut Shells ◽  
By Products

Value-added phytochemicals from food by-products and waste materials have gained much interest and among them, dietary polyphenolic compounds with potential biological properties extend a promising sustainable approach. Oxyresveratrol (Oxy), a stilbenoid polyphenol, possesses great therapeutic potential, though its pharmacokinetic issues need attention. A good source of oxyresveratrol was found in underutilized coconut shells and the synbiotic applications of the compound in combination with a potential probiotic isolate Limosilactobacillus fermentum ASBT-2 was investigated. The compound showed lower inhibitory effects on the strain with minimum inhibitory concentration (MIC) of 1000 µg/mL. Oxyresveratrol at sub-MIC concentrations (500 µg/mL and 250 µg/mL) enhanced the probiotic properties without exerting any inhibitory effects on the strain. The combination at sub- MIC concentration of the compound inhibited Salmonella enterica and in silico approaches were employed to elucidate the possible mode of action of oxy on the pathogen. Thus, the combination could target pathogens in the gut without exerting negative impacts on growth of beneficial strains. This approach could be a novel perspective to address the poor pharmacokinetic properties of the compound.

Introducing deep eutectic solvents as biorenewable media for Au(i)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system

2014 ◽  
Vol 50 (85) ◽  
pp. 12927-12929 ◽  
Author(s):  
María J. Rodríguez-Álvarez ◽  
Cristian Vidal ◽  
Josefina Díez ◽  
Joaquín García-Álvarez
Keyword(s):  
Catalytic System ◽  
Room Temperature ◽  
Eutectic Mixture ◽  
Deep Eutectic Solvents ◽  
Co Catalysts ◽  
System P

Cycloisomerisation reactions of γ-alkynoic acids can be conveniently performed in the eutectic mixture 1ChCl/2Urea at room temperature, under air and in the absence of co-catalysts by using a novel iminophosphorane–Au(i) complex.

scholarly journals Valorization of food industry waste and by-products using 3D printing: A study on the development of value-added functional cookies

Future Foods ◽  
2021 ◽  
pp. 100036
Author(s):  
Bhagya Jagadiswaran ◽  
Vishvaa Alagarasan ◽  
Priyadharshini Palanivelu ◽  
Radhika Theagarajan ◽  
J.A. Moses ◽  
...  
Keyword(s):  
3D Printing ◽  
Food Industry ◽  
Value Added ◽  
Industry Waste ◽  
Food Industry Waste ◽  
By Products

Thermal Conductivity of Room Temperature Deep Eutectic Solvents

2021 ◽  
Author(s):  
Noor Albayati ◽  
Mohammed Kadhom ◽  
Ghassan Abdullah ◽  
Suhaib Salih
Keyword(s):  
Thermal Conductivity ◽  
Room Temperature ◽  
Deep Eutectic Solvents

scholarly journals Anthocyanins Recovered from Agri-Food By-Products Using Innovative Processes: Trends, Challenges, and Perspectives for Their Application in Food Systems

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2632
Author(s):  
Henrique Silvano Arruda ◽  
Eric Keven Silva ◽  
Nayara Macêdo Peixoto Araujo ◽  
Gustavo Araujo Pereira ◽  
Glaucia Maria Pastore ◽  
...  
Keyword(s):  
Food Systems ◽  
Food Industry ◽  
Biological Properties ◽  
Extraction Techniques ◽  
Naturally Occurring ◽  
Current Review ◽  
Natural Colorants ◽  
Conventional Extraction ◽  
The Stability ◽  
By Products

Anthocyanins are naturally occurring phytochemicals that have attracted growing interest from consumers and the food industry due to their multiple biological properties and technological applications. Nevertheless, conventional extraction techniques based on thermal technologies can compromise both the recovery and stability of anthocyanins, reducing their global yield and/or limiting their application in food systems. The current review provides an overview of the main innovative processes (e.g., pulsed electric field, microwave, and ultrasound) used to recover anthocyanins from agri-food waste/by-products and the mechanisms involved in anthocyanin extraction and their impacts on the stability of these compounds. Moreover, trends and perspectives of anthocyanins’ applications in food systems, such as antioxidants, natural colorants, preservatives, and active and smart packaging components, are addressed. Challenges behind anthocyanin implementation in food systems are displayed and potential solutions to overcome these drawbacks are proposed.

Recent advances to recover value-added compounds from avocado by-products following a biorefinery approach

2021 ◽  
Vol 28 ◽  
pp. 100433
Author(s):  
Alexandra Del Castillo-Llamosas ◽  
Pablo G. del Río ◽  
Alba Pérez-Pérez ◽  
Remedios Yáñez ◽  
Gil Garrote ◽  
...  
Keyword(s):  
Value Added ◽  
Recent Advances ◽  
By Products

scholarly journals Recovery of Anthocyanins and Monosaccharides from Grape Marc Extract by Nanofiltration Membranes

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2003
Author(s):  
Paul Muñoz ◽  
Karla Pérez ◽  
Alfredo Cassano ◽  
René Ruby-Figueroa
Keyword(s):  
Functional Foods ◽  
General Trend ◽  
Value Added ◽  
Operating Conditions ◽  
Permeate Flux ◽  
Ultrasound Assisted Extraction ◽  
Grape Marc ◽  
Assisted Extraction ◽  
The One ◽  
By Products

Wastewaters and by-products generated in the winemaking process are important and inexpensive sources of value-added compounds that can be potentially reused for the development of new products of commercial interest (i.e., functional foods). This research was undertaken in order to evaluate the potential of nanofiltration (NF) membranes in the recovery of anthocyanins and monosaccharides from a clarified Carménère grape marc obtained through a combination of ultrasound-assisted extraction and microfiltration. Three different flat-sheet nanofiltration (NF) membranes, covering the range of molecular weight cut-off (MWCO) from 150 to 800 Da, were evaluated for their productivity as well as for their rejection towards anthocyanins (malvidin-3-O-glucoside, malvidin 3-(acetyl)-glucoside, and malvidin 3-(coumaroyl)-glucoside) and sugars (glucose and fructose) in selected operating conditions. The selected membranes showed differences in their performance in terms of permeate flux and rejection of target compounds. The NFX membrane, with the lowest MWCO (150–300 Da), showed a lower flux decay in comparison to the other investigated membranes. All the membranes showed rejection higher than 99.42% for the quantified anthocyanins. Regarding sugars rejection, the NFX membrane showed the highest rejection for glucose and fructose (100 and 92.60%, respectively), whereas the NFW membrane (MWCO 300–500 Da) was the one with the lowest rejection for these compounds (80.57 and 71.62%, respectively). As a general trend, the tested membranes did not show a preferential rejection of anthocyanins over sugars. Therefore, all tested membranes were suitable for concentration purposes.

scholarly journals Brewing By-Product Upcycling Potential: Nutritionally Valuable Compounds and Antioxidant Activity Evaluation

Antioxidants ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 165
Author(s):  
Elisabetta Bravi ◽  
Giovanni De Francesco ◽  
Valeria Sileoni ◽  
Giuseppe Perretti ◽  
Fernanda Galgano ◽  
...  
Keyword(s):  
Antioxidant Activity ◽  
Phenolic Acids ◽  
Liquid Waste ◽  
Value Added ◽  
Total Phenolic ◽  
Antioxidant Compounds ◽  
Brewing Industry ◽  
Antioxidant Power ◽  
Spent Grains ◽  
By Products

The brewing industry produces high quantities of solid and liquid waste, causing disposal issues. Brewing spent grains (BSGs) and brewing spent hop (BSH) are important by-products of the brewing industry and possess a high-value chemical composition. In this study, BSG and BSH, obtained from the production process of two different types of ale beer (Imperial red and Belgian strong beer) were characterized in terms of valuable components, including proteins, carbohydrates, fat, dietary fiber, β-glucans, arabinoxylans, polyphenols, and phenolic acids, and antioxidant activity (Ferric Reducing Antioxidant Power Assay (FRAP), 2,2-Diphenyl-1-picrylhydrazyl (DPPH) and 2,2′-Azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS)). Significant concentrations of total polyphenols were observed in both BSH and BSG samples (average of about 10 mg GAE/g of dry mass); however, about 1.5-fold higher levels were detected in by-products of Belgian strong ale beer compared with Imperial red. Free and bound phenolic acids were quantified using a validated chromatographic method. A much higher level of total phenolic acids (TPA) (about 16-fold higher) was found in BSG samples compared with BSHs. Finally, their antioxidant potential was verified. By-products of Belgian strong ale beer, both BSG and BSH, showed significantly higher antioxidative capacity (about 1.5-fold lower inhibitory concentration (IC50) values) compared with spent grains and hop from the brewing of Imperial red ale. In summary, BSG and BSH may be considered rich sources of protein, carbohydrates, fiber, and antioxidant compounds (polyphenols), and have the potential to be upcycled by transformation into value-added products.

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