scholarly journals Synthesis and Performance of Large-Scale Cost-Effective Environment-Friendly Nanostructured Thermoelectric Materials

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1091
Author(s):  
Farheen F. Jaldurgam ◽  
Zubair Ahmad ◽  
Farid Touati

Thermoelectricity is a promising technology that directly converts heat energy into electricity and finds its use in enormous applications. This technology can be used for waste heat recovery from automobile exhausts and industrial sectors and convert the heat from solar energy, especially in hot and humid areas such as Qatar. The large-scale, cost-effective commercialization of thermoelectric generators requires the processing and fabrication of nanostructured materials with quick, easy, and inexpensive techniques. Moreover, the methods should be replicable and reproducible, along with stability in terms of electrical, thermal, and mechanical properties of the TE material. This report summarizes and compares the up-to-date technologies available for batch production of the earth-abundant and ecofriendly materials along with some notorious works in this domain. We have also evaluated and assessed the pros and cons of each technique and its effect on the properties of the materials. The simplicity, time, and cost of each synthesis technique have also been discussed and compared with the conventional methods.

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


2020 ◽  
Vol 13 (7) ◽  
pp. 3383-3438 ◽  
Author(s):  
Veronika Eyring ◽  
Lisa Bock ◽  
Axel Lauer ◽  
Mattia Righi ◽  
Manuel Schlund ◽  
...  

Abstract. The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool designed to improve comprehensive and routine evaluation of Earth system models (ESMs) participating in the Coupled Model Intercomparison Project (CMIP). It has undergone rapid development since the first release in 2016 and is now a well-tested tool that provides end-to-end provenance tracking to ensure reproducibility. It consists of (1) an easy-to-install, well-documented Python package providing the core functionalities (ESMValCore) that performs common preprocessing operations and (2) a diagnostic part that includes tailored diagnostics and performance metrics for specific scientific applications. Here we describe large-scale diagnostics of the second major release of the tool that supports the evaluation of ESMs participating in CMIP Phase 6 (CMIP6). ESMValTool v2.0 includes a large collection of diagnostics and performance metrics for atmospheric, oceanic, and terrestrial variables for the mean state, trends, and variability. ESMValTool v2.0 also successfully reproduces figures from the evaluation and projections chapters of the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5) and incorporates updates from targeted analysis packages, such as the NCAR Climate Variability Diagnostics Package for the evaluation of modes of variability, the Thermodynamic Diagnostic Tool (TheDiaTo) to evaluate the energetics of the climate system, as well as parts of AutoAssess that contains a mix of top–down performance metrics. The tool has been fully integrated into the Earth System Grid Federation (ESGF) infrastructure at the Deutsches Klimarechenzentrum (DKRZ) to provide evaluation results from CMIP6 model simulations shortly after the output is published to the CMIP archive. A result browser has been implemented that enables advanced monitoring of the evaluation results by a broad user community at much faster timescales than what was possible in CMIP5.


Stroke ◽  
2016 ◽  
Vol 47 (suppl_1) ◽  
Author(s):  
Olli S Mattila ◽  
Heini Harve ◽  
Saana Pihlasviita ◽  
Juhani Ritvonen ◽  
Gerli Sibolt ◽  
...  

Background and purpose: Blood-based biomarkers could enable early and cost-effective diagnostics for acute stroke patients in the prehospital setting to support early initiation of treatments. However, large prehospital sample sets required for biomarker discovery and validation are missing, and the feasibility of large-scale blood sampling by emergency medical services (EMS) has not been determined. We set out to establish extensive prehospital blood sampling of thrombolysis candidates in the catchment area of our comprehensive stroke center, with a 1.5 million population base. Methods: EMS personnel were trained to collect prehospital blood samples using a cannula-adapter technique. Time delays, sample quality and performance bottlenecks were investigated between May 20, 2013 and May 19, 2014. Results: Prehospital blood sampling and study recruitment were successfully performed in 430 thrombolysis candidates, of which 55.3% were admitted outside office hours. The median (interquartile range) emergency call to prehospital sample time was 33 minutes (25-41), and the median time from reported symptom onset or wake-up to prehospital sample was 53 minutes (38-85; n=394). Prehospital sampling was performed 31 minutes (25-42) earlier than admission blood sampling, and 37 minutes (30-47) earlier than admission neuroimaging. Quality control data from 25 participating EMS units indicated a 4-minute increase in median transport time (from arrival on-scene to hospital door) for study patients compared to patients of the preceding year. The hemolysis rate in serum and plasma samples was 6.5% and 9.3% for EMS samples, and 0.7% and 1.6% for admission samples collected with venipuncture. Conclusions: Prehospital biomarker sampling is feasible in standard EMS units and provides a median timesaving of over 30 minutes to obtain first blood samples. Large biobanks of prehospital blood samples will facilitate development of ultra-acute stroke biomarkers.


2021 ◽  
Vol 09 ◽  
Author(s):  
Sarvat Zafar ◽  
Aiman Zafar ◽  
Fakhra Jabeen ◽  
Miad Ali Siddiq

: Nanotechnology studies the various phenomena of physio-chemical procedures and biological properties for the generation of nanosized particles, and their rising challenges in the various sectors, like medicine, engineering, agriculture, electronic, and environmental studies. The nanosized particles exhibit good anti-microbial, anti-inflammatory, cytotoxic, drug delivery, anti-parasitic, anti-coagulant and catalytic properties because of their unique dimensions with large surface area, chemical stability and higher binding density for the accumulation of various bio-constituents on their surfaces. Biological approaches for the synthesis of silver nanoparticles (AgNPs) have been reviewed because it is an easy and single-step protocol and a viable substitute for the synthetic chemical-based procedures. Physical and chemical approaches for the production of AgNPs are also mentioned herein. Biological synthesis has drawn attention because it is cost-effective, faster, non-pathogenic, environment-friendly, easy to scale-up for large-scale synthesis, and having no demand for usage of high pressure, energy, temperature, or noxious chemical ingredients, and safe for human therapeutic use. Therefore, the collaboration of nanomaterials with bio-green approaches could extend the utilization of biological and cytological properties compatible with AgNPs. In this perspective, there is an immediate need to develop ecofriendly and biocompatible techniques, which strengthen efficacy against microbes and minimize toxicity for human cells. The present study introduces the biological synthesis of silver nanoparticles, and their potential biomedical applications have also been reviewed.


Micromachines ◽  
2020 ◽  
Vol 11 (2) ◽  
pp. 148 ◽  
Author(s):  
Francisco J. Romero ◽  
Almudena Rivadeneyra ◽  
Markus Becherer ◽  
Diego P. Morales ◽  
Noel Rodríguez

In this paper, we present a simple, fast, and cost-effective method for the large-scale fabrication of high-sensitivity humidity sensors on flexible substrates. These sensors consist of a micro screen-printed capacitive structure upon which a sensitive layer is deposited. We studied two different structures and three different sensing materials by modifying the concentration of poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT:PSS) in a graphene oxide (GO) solution. The results show that the aggregation of the PEDOT:PSS to the GO can modify its electrical properties, boosting the performance of the capacitive sensors in terms of both resistive losses and sensitivity to relative humidity (RH) changes. Thus, in an area less than 30 mm2, the GO/PEDOT:PSS-based sensors can achieve a sensitivity much higher (1.22 nF/%RH at 1 kHz) than other similar sensors presented in the literature which, together with their good thermal stability, time response, and performance over bending, demonstrates that the manufacturing approach described in this work paves the way for the mass production of flexible humidity sensors in an inexpensive way.


Author(s):  
V.V. Shevchenko

Since the early 1990s, in analytical reviews, experts have increasingly been paying attention to the growing scarcity of rare and rare earth metals (REM) necessary for the development of advanced technologies in modern industry. The volume of the world market has increased over the past 50 years from 5,000 to 125,000 tons per year, which is explained by the extensive use of REM in the rapidly developing areas of industry associated with the advancement of high technology. Unique properties of REM are primarily used in the aerospace and other industrial sectors of the economy, and therefore are strategic materials. For example, platinum is an indispensable element that is used as a catalyst for chemical reactions. No battery can do without platinum. If all the millions of vehicles traveling along our roads installed hybrid batteries, all platinum reserves on Earth would end in the next 15 years! Consumers are interested in six elements known as the platinum group of metals (PGM): iridium (Ir), osmium (Os), palladium (palladium, Pd), rhodium (rhodium, Rh), ruthenium (ruthenium, Ru), and platinum itself. These elements, rare on the Earth, possess unique chemical and physical properties, which makes them vital industrial materials. To solve this problem, projects were proposed for the utilization of the substance of asteroids approaching the Earth. According to modern estimates, the number of known asteroids approaching the Earth reaches more than 9,000. Despite the difficulties of seizing, transporting, and further developing such an object in space, this way of solving the problem seemed technologically feasible and cost-effectively justified. A 10 m iron-nickel asteroid could contain up to 75 tons of rare metals and REM, primarily PGM, equivalent to a commercial price of about $2.8 billion in 2016 prices. However, the utilization of an asteroid substance entering the lunar surface can be technologically simpler and economically more cost-effective. Until now, it was believed that the lunar impact craters do not contain the rocks of the asteroids that formed them, since at high velocities the impactors evaporate during a collision with the lunar surface. According to the latest research, it turned out that at a fall rate of less than 12 km/s falling body (drummer) can partially survive in a mechanically fractured state. Consequently, the number of possible resources present on the lunar surface can be attributed to nickel, cobalt, platinum, and rare metals of asteroid origin. The calculations show that the total mass, for example, of platinum and platinoids on the lunar surface as a result of the fall of asteroids may amount more than 14 million tons. It should be noted that the world’s known reserves of platinum group metals on the Earth are about 80,000 tons.


Author(s):  
Ankita Yadav ◽  
◽  
Mohammad Arif ◽  

This research is conducted in order to deal with the main problem of traffic congestion and road accidents that is basically caused because of the improper parking management. . Hence, it is important that cities have a well-managed parking system. In the past various researches has been done to design a suitable smart paring algorithm. However, each research had their own pros and cons. Our research leads to a smart algorithm that is secure and is convenient enough to develop a system that can be manage the available slots and can notify the users about the available parking slot beforehand to the client. The result analysis clearly shows that the algorithm proposed and designed is more accurate than other algorithms used in the past. The proposed algorithm is designed using ACO, decision tree, and GPS mapping. The idea of working on this research was to provide a solution that is cost effective, helps people on large scale and maintains the laws and order.


Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3206 ◽  
Author(s):  
◽  
George Kosmadakis ◽  
Francesco Giacalone ◽  
Bartolomé Ortega-Delgado ◽  
Andrea Cipollina ◽  
...  

In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 °C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at about 0.03 €/kWh, is achieved using potassium acetate salt and six MED effects while reheating the solutions. A similar analysis has been conducted when using the system in energy storage mode, where the two regenerated solutions are stored in reservoir tanks and the RED is operating for a few hours per day, supplying valuable peak power, resulting in a LCOE just below 0.10 €/kWh. A life-cycle assessment has been also carried out, showing that the case with the lowest environmental impact is the same as the one with the most attractive economic performance. Results indicate that the material manufacturing has the main impact; primarily the metallic parts of the MED. Overall, this study highlights the development efforts required in terms of both membrane performance and cost reduction, in order to make this technology cost effective in the future.


2021 ◽  
Author(s):  
Diwakar Kafle ◽  
Sushil Dumre ◽  
Saroj Tripathi ◽  
Shankar Shrestha

Abstract Hydrogen production by electrolysis of water is seen as a promising technique as it is environment friendly and it can use renewable energy source for the production of hydrogen gas. However, this technology has less than 4% contribution to the production of commercial hydrogen in the market. This is due to the high electricity consumption of the water splitting reaction. The main challenge to make this technology efficient and economically viable is to develop cost effective and highly efficient electrolyzer. Here we have developed a three electrode electrolyzer in which an extra electrode is inserted between conventional electrodes: cathode and anode. This novel electrolyzer utilizes an extra voltage source which reduces the overpotential and increases the anode current of the cell, which is responsible for the hydrogen production. Furthermore, we observed that, the operating resistance of the cell decreases under the application of the new voltage source. Our results demonstrate that the introduction of third electrode improves the performance of electrolysis by consuming less power as compared to the traditional or conventional two electrode electrolyzer system.


Author(s):  
Salman Imtiaz ◽  
Ashar Alam

Abstract Chronic kidney disease (CKD) has shown a rising trend in the last two decades. It is one of the most devastating diseases which has enormous psychosocial and economic burden. The treatment available includes haemodialysis, peritoneal dialysis and kidney transplantation. All treatment options have their pros and cons, needs and preferences, though haemodialysis is one of the most available entity in Pakistan. There are a few intrinsic problems associated with haemodialysis which has significant environmental as well as economic impact. One of the most important is the need of huge quantity of water to carry out the haemodialysis procedure along with production of solid waste in the form of disposables and electricity consumption. Peritoneal dialysis on the other hand is more environment-friendly and cost-effective and it should be one of the preferred options for our CKD patients. Keywords: Pakistan, haemodialysis, peritoneal dialysis, Continuous...


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