scholarly journals Cotton Wastes Functionalized Biomaterials from Micro to Nano: A Cleaner Approach for a Sustainable Environmental Application

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1006
Author(s):  
Samsul Rizal ◽  
Abdul Khalil H. P. H. P. S. ◽  
A. A. Oyekanmi ◽  
Niyi G. Olaiya ◽  
C. K. Abdullah ◽  
...  

The exponential increase in textile cotton wastes generation and the ineffective processing mechanism to mitigate its environmental impact by developing functional materials with unique properties for geotechnical applications, wastewater, packaging, and biomedical engineering have become emerging global concerns among researchers. A comprehensive study of a processed cotton fibres isolation technique and their applications are highlighted in this review. Surface modification of cotton wastes fibre increases the adsorption of dyes and heavy metals removal from wastewater. Cotton wastes fibres have demonstrated high adsorption capacity for the removal of recalcitrant pollutants in wastewater. Cotton wastes fibres have found remarkable application in slope amendments, reinforcement of expansive soils and building materials, and a proven source for isolation of cellulose nanocrystals (CNCs). Several research work on the use of cotton waste for functional application rather than disposal has been done. However, no review study has discussed the potentials of cotton wastes from source (Micro-Nano) to application. This review critically analyses novel isolation techniques of CNC from cotton wastes with an in-depth study of a parameter variation effect on their yield. Different pretreatment techniques and efficiency were discussed. From the analysis, chemical pretreatment is considered the most efficient extraction of CNCs from cotton wastes. The pretreatment strategies can suffer variation in process conditions, resulting in distortion in the extracted cellulose’s crystallinity. Acid hydrolysis using sulfuric acid is the most used extraction process for cotton wastes-based CNC. A combined pretreatment process, such as sonication and hydrolysis, increases the crystallinity of cotton-based CNCs. The improvement of the reinforced matrix interface of textile fibres is required for improved packaging and biomedical applications for the sustainability of cotton-based CNCs.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Bendadi Hanumantha Rao ◽  
Peddireddy Sreekanth Reddy ◽  
Bijayananda Mohanty ◽  
Krishna R. Reddy

AbstractMicrolevel properties such as mineralogical and chemical compositions greatly control the macro behaviour of expansive soils. In this paper, the combined effect of mineral (i.e. montmorillonite, MMC) and chemical contents (i.e. Ca and Na in their total (T), leachable (L) and exchangeable form (CEC)) on swelling behaviour is investigated in a comprehensive way. Several 3-dimensional (3D) graphs correlating MMC and Ca/Na ratio, together, with swelling property (swelling potential, Sa, and swelling pressure, Sp) are developed. 3D plots, in general, portrayed a non-linear relationship of Sa and Sp with MMC and Ca/Na ratio, together. It is hypothesized that swelling initially is triggered by chemical parameters due to their quick and rapid ionization capability, but the overall swelling phenomenon is largely controlled by MMC. It is importantly found that expansive soils are dominant with divalent Ca++ ions up to MMC of 67% and beyond this percentage, monovalent Na+ ions are prevalent. From the interpretation of results, the maximum Sa of 18% and Sp of 93 kPa is measured at MMC of 43%, (Ca/Na)T of 10–14 and (Ca/Na)L of 2–7. It is concluded from study that total CEC + MMC for determining Sa and (Ca/Na)T + MMC for determining Sp are superior parameters to be considered. The findings of the study also excellently endorsed the results of Foster32, who stated that ionization of Na or Ca depends on the constituent mineral contents. The findings presented herein are unique, interesting and bear very practical significance, as no earlier research work reported such findings by accounting for chemical and mineralogical parameters impact, in tandem, on swelling properties.



2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Ranjit K. Nath ◽  
M. F. M. Zain ◽  
Abdul Amir H. Kadhum

The addition of a photocatalyst to ordinary building materials such as concrete creates environmentally friendly materials by which air pollution or pollution of the surface can be diminished. The use of LiNbO3photocatalyst in concrete material would be more beneficial since it can produce artificial photosynthesis in concrete. In these research photoassisted solid-gas phases reduction of carbon dioxide (artificial photosynthesis) was performed using a photocatalyst, LiNbO3, coated on concrete surface under illumination of UV-visible or sunlight and showed that LiNbO3achieved high conversion of CO2into products despite the low levels of band-gap light available. The high reaction efficiency of LiNbO3is explained by its strong remnant polarization (70 µC/cm2), allowing a longer lifetime of photoinduced carriers as well as an alternative reaction pathway. Due to the ease of usage and good photocatalytic efficiency, the research work done showed its potential application in pollution prevention.



2021 ◽  
Vol 251 ◽  
pp. 02058
Author(s):  
Feng Xuehua ◽  
Tao Ali ◽  
Song Zurong ◽  
Gong Panpan

The aqueous enzymatic method was applied to extract the common pistache oil and the optimal extraction process conditions were identified. By observing the effect of enzymatic hydrolysis time, pH value, temperature on aqueous enzymatic extraction process and performing the orthogonal experiment based on the single factor test, the optimal process parameters were obtained, namely, the optimal time, temperature, and pH value were respectively 3 h, 50℃, and 7 with a final extraction rate of 25.38 %.



2020 ◽  
Vol 54 (9-10) ◽  
pp. 983-991
Author(s):  
MAHESHANI P. A. NANAYAKKARA ◽  
WALAGEDARA G.A. PABASARA ◽  
ADIKARI M.P.B. SAMARASEKARA ◽  
DON A.S. AMARASINGHE ◽  
LALEEN KARUNANAYAKE

As rice is the staple food of most Asian countries, rice straw has become one of the largest agricultural wastes in Asia. It has not been subjected to adequate value additions yet. However, it has excellent potential to be converted to valuable materials, as it contains a significant amount of cellulose. Therefore, it would be beneficial in many ways to identify the cellulose yields of straws of different rice varieties. In general, the cellulose content of biomass is determined by wet chemical methods. Though these methods are accurate, they are not convenient to use under industrial conditions. This research work focuses on investigating the potential of thermal analysis as an alternative way to predict cellulose yields. For the study, rice straws of most frequently cultivated traditional Sri Lankan rice varieties: Suwandel and Raththal, as well as technically modified Sri Lankan rice varieties: BG300 and BG352, were selected. The results obtained by the proposed method were validated by an established three-step chemical extraction process.



2022 ◽  
Vol 1048 ◽  
pp. 403-411
Author(s):  
A. Chithambar Ganesh ◽  
K. Mukilan ◽  
B.P.V. Srikar ◽  
L.V.S. Teja ◽  
K.S.V. Prasad ◽  
...  

Infrastructural developments are inevitable for the developing countries and hence the production of sustainable building materials is promoted worldwide. Sustainable development in the vicinity of tiles is bewildered for more than a decade. Production of conventional tiles such as cement concrete tiles, clay tiles and ceramic tiles is energy intensive approach and levies lot of strain over the adjunct ecosystem. On the other hand there are serious problems related to the disposal of flyash, Rice Husk Ash throughout the world. An approach has been taken to synthesis tiles based on these industrial byproducts as the base materials through Geopolymer technology. In this work, Geopolymer mortar after heat curing is applied as tiles. In this work, Flyash is replaced by Rice Husk Ash in various proportions such as 20, 40, 60, 80 and 100 percent. Tests such as workability, flatness, straightness, perpendicularity, water absorption, modulus of rupture and abrasion are conducted and fair results are obtained. This research also portrays the effect of Rise Husk Ash addition over the flyash based Geopolymer binder in the utility as tiles. The findings of this research work encourages the development of energy efficient tiles using industrial wastes. Keywords: Geopolymer, Rice Husk Ash, Tiles



2021 ◽  
Author(s):  
Vinay Kishnani ◽  
Ankur Gupta

Over the last few years, the microfluidics phenomenon coupled with the Internet of Things (IoT) using innovative nano-functional materials have been recognized as one of the sustainable and economical tools for point of care testing (POCT) of various pathogens influencing the human health. The sensors based on these phenomena are aimed to be designed for their cost-effectiveness, to make it handy, environment-friendly and to get an accurate, easy, and rapid response. Considering the burgeoning importance of analytical devices in the healthcare domain, this review paper is based on the gist of sensing aspects of the micro fabricated paper-based analytical devices (μPADs). The article discusses not only the various used design methodologies and fabrication approaches, but also elucidates the recently reported surface modification strategies, detection mechanisms viz., colorimetric, electrochemical, fluorescence, electrochemiluminescence etc., and sensing characteristics of μPADs along with reported works equipped with the IoT platform for digital readout. In a nutshell, this article summarizes the state-of-the-art research work carried out over the nano functionalized paper-based analytical devices and associated challenges/solutions in the point of care testing domain.



2018 ◽  
Vol 7 (2.25) ◽  
pp. 74
Author(s):  
Soundarya M.K ◽  
Bhuvaneshwari S ◽  
Prasanna Kumar.S

The deterioration of the structures which are built on the expansive soils is due to its volume change behavior, due to the presence of Mont-morillonite minerals in soil. Hence this soil requires adequate stabilization before commencement of any construction activities. The stabili-zation phenomenon in which addition suitable additives completely alters the behavior of the soil by changing the basic properties and there-by increasing the bearing strength of soil. The choice of the additives depends on the ease and permanence of the stabilizing characteristics achieved for the expansive soil. In this paper, an attempt is done to evaluate the behavior of soil when blended with additives like saw dust ash, lime and lignosulphonate at varying blending ratio. The objective of the research work is to focus on the change in the plasticity charac-teristics by utilizing the industrial waste as additive due to its cementitious value, making it eco-friendly and reduction in cost. Lignosulpho-nate is a by-product of paper pulp industry, generated during the sulphite process. From the literature, the optimum percentage for stabilizing works for lime and lignosulphonate was found to be two to eight percent and one to three percent respectively. Basic Index properties and compaction characteristics test were determined for both virgin and treated soil. The additives decreased the plasticity index, causing ag-glomeration of clay particles involving pozzolanic reaction. 



Processes ◽  
2019 ◽  
Vol 7 (2) ◽  
pp. 60 ◽  
Author(s):  
Javier Fragoso-Jiménez ◽  
Ernesto Tapia-Campos ◽  
Mirna Estarron-Espinosa ◽  
Rodrigo Barba-Gonzalez ◽  
Ma. Castañeda-Saucedo ◽  
...  

Supercritical fluid extracts from flowers of Polianthes tuberosa var. double were ob tained using carbon dioxide as a solvent. Yield extract obtained was 2.5%. The effects of the pressure process (18 MPa, 28 MPa, and 38 MPa) and temperature process (313 K, 323 K, and 333 K) on the volatile composition of tuberose flowers extracts were evaluated, and a significant variation in chemical composition was found. Characteristic compounds of tuberose as methyl isoeugenol, benzyl benzoate, methyl anthranilate, pentacosene, and heptacosene were obtained mainly at 18 MPa and 333 K process conditions, and could be used in the perfume or fragrance industry. Components such as geraniol, farnesol, and methyl eugenol were also obtained, these extracts could be used in the development of cosmeceutical products. This work allowed to identification of the chemical composition profile and evaluation of the changes in tuberose extracts due to the extraction process.



Molecules ◽  
2020 ◽  
Vol 25 (12) ◽  
pp. 2774 ◽  
Author(s):  
Tanja Gagić ◽  
Željko Knez ◽  
Mojca Škerget

The aim of the work was the optimization of the subcritical water extraction process of chestnut bark using Box–Behnken response surface methodology. The influence of process parameters, such as temperature, extraction time and solvent-solid ratio, on extraction yield, yield of the main compounds, total phenol content, total tannin content and antioxidant activity has been investigated. The identified compounds were ellagic and gallic acids, ellagitannins (vescalagin, castalagin, 1-o-galloyl castalagin, vescalin and castalin), sugars (maltose, glucose, fructose and arabinose) and sugar derivatives (5-HMF, furfural and levulinic acid). Finally, the optimal process conditions for obtaining the bark extract highly rich in ellagic acid and with satisfactory levels of total phenols and total tannins have been determined.



1988 ◽  
Vol 15 (2) ◽  
pp. 159-165 ◽  
Author(s):  
Barbara E. Brown ◽  
Richard P. Dunne

Demand of the construction industry for coral rock in the Maldives will soon reach the limit of supply capacity using existing collection techniques. It is estimated that, at the current rate of consumption, the supply of living coral rock from inner atoll ‘faros’ in North Malé will be exhausted within 30 years. Current mining practice has already necessitated the collection of living coral rock from outer atoll ‘faros’ which actually protect the integrity of the islands against the erosive influences of monsoon storms.Biological surveys of mined sites (compared with controls where no mining activity has taken place) indicate a dramatic reduction in coral variety and abundance and in some cases an almost total depletion of living coral after mining. At intensively-mined sites, diversity and abundance of coral-reef fishes is also markedly reduced, with some reef species commonly used as baitfish entirely absent. The time taken for reefs to recover from mechanical damage has been shown by other research work to be extremely variable, with some cases showing no recovery in some circumstances. Shallow-water reefs that have been colonized by slow-growing ‘massive’ corals, such as those which have been mined in the Maldives, may take a minimum of 50 years to recover to their former state—under optimum conditions.Observations on mined reefs in the Maldives show that recovery over the last 10 years has been minimal, and therefore suggest that recovery times may be much in excess of 50 years. Indeed many of these reefs may not recover at all unless some attempts are made to re-establish corals at these sites. It is also clear from the study of reclaimed and dredged sites and those where less-intensive mining has taken place, that regeneration of corals is occurring. It is quite probable that the rate of recovery is dependent on the intensity of the disturbance which initially took place.Alternative building materials are available in the form of concrete blocks. Use of these blocks is more cost-effective than use of coral rock; however, there is a lack of any quality control, which would be needed to promote the widespread use of concrete blocks as a substitute for coral. Recently, recommendations have been approved by the Government of Maldives for the execution of a feasibility study on mining an inner atoll faro which could potentially provide building material for as long as the next 500 years.



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