scholarly journals Operation of a 2-Stage Bioelectrochemical System for Groundwater Denitrification

Water ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 959 ◽  
Author(s):  
Arianna Callegari ◽  
Silvia Bolognesi ◽  
Daniele Cecconet
Keyword(s):  
Total Nitrogen ◽  
Removal Rate ◽  
Nitrate Removal ◽  
Complete Removal ◽  
Bioelectrochemical System ◽  
Second Stage ◽  
In Series ◽  
Global Concern ◽  
Synthetic Groundwater ◽  
The Eu

Nitrate groundwater contamination is an issue of global concern that has not been satisfactorily and efficiently addressed, yet. In this study, a 2-stage, sequential bioelectrochemical system (BES) was run to perform autotrophic denitrification of synthetic groundwater. The system was run at a 75.6 mgNO3−-N L−1NCC d−1 nitrate loading rate, achieving almost complete removal of nitrate (>93%) and Total Nitrogen (TN) (>93%). After treatment in the first stage reactor values of effluent nitrate compatible with the EU and USA limits for drinking water (<11.3 and 10 mgNO3−-N L−1, respectively) were achieved. Nitrite and nitrous oxide were observed in the first stage’s effluent, and were then successfully removed in the second stage. The observed nitrate removal rate was 73.4 ± 1.3 gNO3−-N m−3NCC d−1, while the total nitrogen removal rate was 73.1 ± 1.2 gN m−3NCC d−1. Specific energy consumptions of the system were 0.80 ± 0.00 kWh m−3, 18.80 ± 0.94 kWh kgNO3−-N−1 and 18.88 ± 0.95 kWh kgN−1. Combination of two denitrifying BES in series herein described proved to be effective.

Nitrate removal from water using cyclically operated fixed-film bio-denitrification reactors

1996 ◽  
Vol 34 (1-2) ◽  
pp. 331-338 ◽  
Author(s):  
M. F. Dahab ◽  
J. Kalagiri
Keyword(s):  
Drinking Water ◽  
Nitrate Removal ◽  
Single Stage ◽  
Organic Loading ◽  
Loading Rates ◽  
Second Stage ◽  
Fixed Film ◽  
In Series ◽  
Stage System

In this paper, a study of cyclically-operated fixed-film bio-denitrification to remove nitrates from drinking water is reported. The purpose of the study was to investigate the ability of these two-stage systems to remove nitrate and residual organics from treated water as compared to single-stage units. In the cyclically-operated system, the second stage (i.e. follow) reactor is operated in series with the first stage (i.e. lead) reactor. After a given period of operation, the flow regime is reversed so that the follow reactor becomes the lead one and vice versa. The active solids remaining in the follow reactor (previously the lead one) are capable of removing residual soluble organics and nitrates to levels below the concentrations provided by single-stage units. Cyclically operated fixed-film bio-denitrification reactors were found to reduce long term effluent residual organics concentrations without adverse effects on the nitrate concentrations. The system also was found to be more effective in reducing nitrates, nitrites and soluble organic concentrations in the effluent than a single-stage system operated at the same hydraulic retention times and organic loading rates.

scholarly journals Effects of the Feeding Solution Composition on a Reductive/Oxidative Sequential Bioelectrochemical Process for Perchloroethylene Removal

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 405
Author(s):  
Edoardo Dell’Armi ◽  
Marco Zeppilli ◽  
Bruna Matturro ◽  
Simona Rossetti ◽  
Marco Petrangeli Papini ◽  
...  
Keyword(s):  
Reductive Dechlorination ◽  
Nitrate Reduction ◽  
Coulombic Efficiency ◽  
Reducing Power ◽  
Mineral Medium ◽  
Process Conditions ◽  
Microbial Electrolysis Cells ◽  
Dehalococcoides Mccartyi ◽  
In Series ◽  
Synthetic Groundwater

Chlorinated aliphatic hydrocarbons (CAHs) are common groundwater contaminants due to their improper use in several industrial activities. Specialized microorganisms are able to perform the reductive dechlorination (RD) of high-chlorinated CAHs such as perchloroethylene (PCE), while the low-chlorinated ethenes such as vinyl chloride (VC) are more susceptible to oxidative mechanisms performed by aerobic dechlorinating microorganisms. Bioelectrochemical systems can be used as an effective strategy for the stimulation of both anaerobic and aerobic microbial dechlorination, i.e., a biocathode can be used as an electron donor to perform the RD, while a bioanode can provide the oxygen necessary for the aerobic dechlorination reaction. In this study, a sequential bioelectrochemical process constituted by two membrane-less microbial electrolysis cells connected in series has been, for the first time, operated with synthetic groundwater, also containing sulphate and nitrate, to simulate more realistic process conditions due to the possible establishment of competitive processes for the reducing power, with respect to previous research made with a PCE-contaminated mineral medium (with neither sulphate nor nitrate). The shift from mineral medium to synthetic groundwater showed the establishment of sulphate and nitrate reduction and caused the temporary decrease of the PCE removal efficiency from 100% to 85%. The analysis of the RD biomarkers (i.e., Dehalococcoides mccartyi 16S rRNA and tceA, bvcA, vcrA genes) confirmed the decrement of reductive dechlorination performances after the introduction of the synthetic groundwater, also characterized by a lower ionic strength and nutrients content. On the other hand, the system self-adapted the flowing current to the increased demand for the sulphate and nitrate reduction, so that reducing power was not in defect for the RD, although RD coulombic efficiency was less.

Performance of intermittent aeration reactor on NH4-N removal from groundwater resources

2010 ◽  
Vol 61 (12) ◽  
pp. 3061-3069 ◽  
Author(s):  
W. Khanitchaidecha ◽  
T. Nakamura ◽  
T. Sumino ◽  
F. Kazama
Keyword(s):  
Removal Rate ◽  
Groundwater Resources ◽  
Ammonium Nitrogen ◽  
Total Carbon ◽  
Intermittent Aeration ◽  
Reactor Performance ◽  
Total Carbon Content ◽  
Term Operation ◽  
N Removal ◽  
Synthetic Groundwater

To study the effect of intermittent aeration period on ammonium–nitrogen (NH4-N) removal from groundwater resources, synthetic groundwater was prepared and three reactors were operated under different conditions – “reactor A” under continuous aeration, “reactor B” under 6 h intermittent aeration, and “reactor C” under 2 h intermittent aeration. To facilitate denitrification simultaneously with nitrification, “acetate” was added as an external carbon source with step-wise increase from 0.5 to 1.5 C/N ratio, where C stands for total carbon content in the system, and N for NH4-N concentration in the synthetic groundwater. Results show that complete NH4-N removal was obtained in “reactor B” and “reactor C” at 1.3 and 1.5 C/N ratio respectively; and partial NH4-N removal in “reactor A”. These results suggest that intermittent aeration at longer interval could enhance the reactor performance on NH4-N removal in terms of efficiency and low external carbon requirement. Because of consumption of internal carbon by the process, less amount of external carbon is required. Further increase in carbon in a form of acetate (1.5 to 2.5 C/N ratios) increases removal rate (represented by reaction rate coefficient (k) of kinetic equation) as well as occurrence of free cells. It suggests that the operating condition at reactor B with 1.3 C/N ratio is more appropriate for long-term operation at a pilot-scale.

scholarly journals CEE LABOUR MARKETS – HOMOGENEITY OR DIVERSITY?

2021 ◽  
Vol 0 (0) ◽  
pp. 1-17
Author(s):  
Ewa Rollnik-Sadowska ◽  
Marta Jarocka
Keyword(s):  
Labour Market ◽  
Initial Point ◽  
Multiple Regression Model ◽  
Labour Markets ◽  
Labour Market Situation ◽  
Second Stage ◽  
Market Situation ◽  
The Moment ◽  
Two Stages ◽  
The Eu

The aim of the article is to assess real changes taking place on CEE labour markets over the last fifteen years, taking into account as the initial point of analysis – 2004, i.e. the moment of extension of the EU by the first CEE countries and as a final point of analysis – 2019. The research was conducted in two stages. The authors made comparisons with the use of the TOPSIS method, which allowed for creating rankings of CEE countries in terms of labour market situation in the analysed years. The second stage of the study involved the analysis of relations between employment and GDP by an estimation of the multiple regression model. The conducted analysis proves that CEE countries are diversified when it comes to the labour market situation. These countries are also characterized by significant dynamics of changes in the labour market.

Nutrient Removal from Polluted River Water by Combining Vertical and Horizontal Subsurface Flow Constructed Wetlands

2013 ◽  
Vol 663 ◽  
pp. 1029-1032 ◽  
Author(s):  
Cheng Xin Qin ◽  
Gang He ◽  
Yu Huan Duan ◽  
Xiao Ping Pang ◽  
Zong Lian She
Keyword(s):  
River Water ◽  
Removal Rate ◽  
Subsurface Flow ◽  
Ammonia Removal ◽  
Polluted River ◽  
Main Layer ◽  
Second Stage ◽  
N Removal ◽  
Different Depths ◽  
Horizontal Subsurface Flow

A lab-scale hybrid constructed wetland system was constructed to purify polluted river water. The system was composed of a first stage of the vertical subsurface flow filter, followed by a second stage of horizontal subsurface flow bed. Both beds used furnace slag with a size of 4-60 mm for the main layer. The system was continuously fed. Different depths of unsaturated layer (0 cm, 15 cm and 30 cm) in vertical filter were tested. The unsaturated layer of 30 cm in vertical filter presented the most effective ammonia removal of 89.1%, while lowest NO3--N removal rate of 74.1% for the system. High TN removal efficiencies (77.3%-81.0%) could be observed during operation of three depths. The removals of COD and TP were in the range of 97.1%-98.4% and 76.4%-88.9%, respectively.

Total nitrogen removal from high-strength ammonia recycle stream using a single submerged attached growth bioreactor

2007 ◽  
Vol 55 (8-9) ◽  
pp. 59-65 ◽  
Author(s):  
A. Onnis-Hayden ◽  
P.B. Pedros ◽  
J. Reade
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Treatment Plant ◽  
High Strength ◽  
Nitrogen Loading ◽  
Digested Sludge ◽  
Attached Growth ◽  
Anaerobically Digested Sludge ◽  
Total Nitrogen Removal

An experimental study investigating the nitrogen removal efficiency from the recycle stream generated in the dewatering facility of the anaerobically digested sludge at the Deer Island wastewater treatment plant (WWTP) in Boston was conducted using a single submerged attached growth bioreactor (SAGB), designed for simultaneous nitrification and denitrification. The applied nitrogen loading to the reactor ranged from 0.7 to 2.27 kg-N/m3·d, and the corresponding total nitrogen (TN) removal rate ranged from 0.38 to 1.8 kg-N/m3·d. The observed nitrification rates varied from 0.42 kg-N/m3·d to 1.45 kg-N/m3·d with an ammonia load of 0.5 kg-N/m3·d and 1.8 kg-N/m3·d, respectively. An average nitrification efficiency of 91% was achieved throughout the experiment. Denitrification efficiency varied from 55%, obtained without any addition of carbon source, to 95% when methanol was added in order to obtain a methanol/nitrate ratio of about 3 kg methanol/kg NO3−-N.

scholarly journals Evaluation of Parallel-Series Configurations of Two-Phase Partitioning Biotrickling Filtration and Biotrickling Filtration for Treating Styrene Gas-Phase Emissions

2020 ◽  
Vol 12 (17) ◽  
pp. 6740 ◽  
Author(s):  
Pau San-Valero ◽  
Javier Álvarez-Hornos ◽  
Pablo Ferrero ◽  
Josep M. Penya-Roja ◽  
Paula Marzal ◽  
...  
Keyword(s):  
High Throughput Sequencing ◽  
Silicone Oil ◽  
Sharp Decrease ◽  
Complete Removal ◽  
Industrial Applications ◽  
Biotrickling Filter ◽  
Gaseous Emissions ◽  
Two Phase ◽  
Phase Partitioning ◽  
In Series

The removal of styrene from industrial representative gaseous emissions was studied using two reactors connected in series: a two-phase partitioning biotrickling filter (TPPB-BTF) and a conventional biotrickling filter (BTF). The system was operated under industrial conditions, which included steady and transient conditions and intermittent spraying. Silicone oil was used in the TPPB-BTF with a quantity as low as 25 mL L−1, promoting a faster start-up compared to the BTF. By working at a styrene loading of 30 g m−3 h−1, nearly complete removal efficiency (RE) was obtained. In addition, the removal was not adversely impacted by using non-steady emission patterns such as overnight shutdowns (97% RE) and oscillating concentrations (95% RE), demonstrating its viability for industrial applications. After 2 months from inoculation, two additional configurations (reverse series BTF + TPPB-BTF and parallel) were tested, showing the series configuration as the best approach to consistently achieve RE > 95%. After 51 days of operation, high throughput sequencing revealed a sharp decrease in the bacterial diversity. In both reactors, the microorganisms belonging to the Comamonadaceae family were predominant and other styrene degraders such as Pseudomonadaceae proliferated preferably in the first reactor.

scholarly journals Impact of Temperature on Biological Denitrification Process

1970 ◽  
Vol 7 (1) ◽  
pp. 121-126 ◽  
Author(s):  
Iswar Man Amatya ◽  
Bhagwan Ratna Kansakar ◽  
Vinod Tare ◽  
Liv Fiksdal
Keyword(s):  
Filtration Rate ◽  
Nitrate Nitrogen ◽  
Nitrate Removal ◽  
Biological Method ◽  
Biological Denitrification ◽  
Nitrite Nitrogen ◽  
Nitrogen Concentrations ◽  
In Series ◽  
Nitrate And Nitrite ◽  
Denitrification Process

Nitrate removal in groundwater was carried out by biological method of denitrification process. The denitrification and without denitrification were performed in two different sets of reactors. Each reactor consists of two columns connected in series packed with over burnt bricks as media. The filtration rate varied from 5.3 to 52.6 m/day for denitrification process. The ammonia, nitrate and nitrite nitrogen concentrations were measured at inlet, intermediate ports and outlet. The temperature varied from 10 to 30°C at 2°C intervals. The results demonstrated that high amount of nitrate nitrogen removed in groundwater at denitrification process. The nitrate nitrogen removed by denitrification varied from 3.50 to 39.08 gm/m3/h at influent concentration from 6.32 to 111.04 gm/m3/h. Denitrification was found more significant above 16°C.Key words: Over burnt brick, Denitrification, Filtration rate and TemperatureJournal of the Institute of Engineering, Vol. 7, No. 1, July, 2009 pp. 121-126doi: 10.3126/jie.v7i1.2070 

Toward Decarbonized Power Generation With Gas Turbines by Using Sequential Combustion for Burning Hydrogen

2019 ◽  
Vol 141 (12) ◽  
Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Tuning Parameter ◽  
Stable Combustion ◽  
Second Stage ◽  
Fuel Flexibility ◽  
Mild Reduction ◽  
In Series ◽  
Exit Temperature

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas (NG) will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia's gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e., the temperature between the first and the second stage. The standard constant pressure sequential combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of NG and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e., without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.

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