scholarly journals Temperature-Dependent Mechanical Properties of Graphene/Cu Nanocomposites with In-Plane Negative Poisson’s Ratios

Research ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-12 ◽  
Author(s):  
Yin Fan ◽  
Yang Xiang ◽  
Hui-Shen Shen

Negative Poisson’s ratio (NPR), also known as “auxetic”, is a highly desired property in a wide range of future industry applications. By employing molecular dynamics (MD) simulation, metal matrix nanocomposites reinforced by graphene sheets are studied in this paper. In the simulation, single crystal copper with crystal orientation 1 1 0 is selected as the matrix and an embedded-atom method (EAM) potential is used to describe the interaction of copper atoms. An aligned graphene sheet is selected as reinforcement, and a hybrid potential, namely, the Erhart-Albe potential, is used for the interaction between a pair of carbon atoms. The interaction between the carbon atom and copper atom is approximated by the Lennard-Jones (L-J) potential. The simulation results showed that both graphene and copper matrix possess in-plane NPRs. The temperature-dependent mechanical properties of graphene/copper nanocomposites with in-plane NPRs are obtained for the first time.

2012 ◽  
Vol 2012 ◽  
pp. 1-13 ◽  
Author(s):  
Nouari Saheb ◽  
Zafar Iqbal ◽  
Abdullah Khalil ◽  
Abbas Saeed Hakeem ◽  
Nasser Al Aqeeli ◽  
...  

Metal matrix nanocomposites (MMNCs) are those metal matrix composites where the reinforcement is of nanometer dimensions, typically less than 100 nm in size. Also, it is possible to have both the matrix and reinforcement phases of nanometer dimensions. The improvement in mechanical properties of MMNCs is attributed to the size and strength of the reinforcement as well as to the fine grain size of the matrix. Spark plasma sintering has been used extensively over the past years to consolidate wide range of materials including nanocomposites and was shown to be effective noneconventional sintering method for obtaining fully dense materials with preserved nanostructure features. The objective of this work is to briefly present the spark plasma sintering process and review published work on spark-plasma-sintered metals and metal matrix nanocomposites.


2013 ◽  
Vol 26 ◽  
pp. 53-58 ◽  
Author(s):  
Mohsen Barmouz ◽  
A. Araee

Friction stir processing (FSP) has been found as a promising method for surface modification of materials such as grain refinement and hardness increment. FSP is also widely used for fabrication of in situ micro-and nanocomposites on the surface of materials. In this research FSP is used for inserting the nanosized SiC particles into the copper matrix. Subsequently, 4-pass FSP is applied to obtain good dispersion of SiC particles in copper matrix leading to improve the mechanical properties of the fabricated composite. The optical microscopy and scanning electron microscopy are used for microstructural evaluation. Results show that an increase in the number of FSP passes considerably enhances the dispersion of the SiC particles in the stir zone and also breaks down the SiC particles. These phenomena lead to reduction of the grain size and improvement of mechanical properties in 4-pass composite compared to that of fabricated by 1-pass FSP.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 125
Author(s):  
Seyed Kiomars Moheimani ◽  
Mehran Dadkhah ◽  
Mohammad Hossein Mosallanejad ◽  
Abdollah Saboori

Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.


Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 548 ◽  
Author(s):  
Leonid Agureev ◽  
Valeriy Kostikov ◽  
Zhanna Eremeeva ◽  
Svetlana Savushkina ◽  
Boris Ivanov ◽  
...  

The article presents the study of alumina nanoparticles’ (nanofibers) concentration effect on the strength properties of pure nickel. The samples were obtained by spark plasma sintering of previously mechanically activated metal powders. The dependence of the grain size and the relative density of compacts on the number of nanofibers was investigated. It was found that with an increase in the concentration of nanofibers, the average size of the matrix particles decreased. The effects of the nanoparticle concentration (0.01–0.1 wt.%) on the elastic modulus and tensile strength were determined for materials at 25 °C, 400 °C, and 750 °C. It was shown that with an increase in the concentration of nanofibers, a 10–40% increase in the elastic modulus and ultimate tensile strength occurred. A comparison of the mechanical properties of nickel in a wide range of temperatures, obtained in this work with materials made by various technologies, is carried out. A description of nanofibers’ mechanisms of influence on the structure and mechanical properties of nickel is given. The possible impact of impurity phases on the properties of nickel is estimated. The tendency of changes in the mechanical properties of nickel, depending on the concentration of nanofibers, is shown.


2021 ◽  
Vol 1035 ◽  
pp. 925-930
Author(s):  
Ya Zhou Li ◽  
Yu Zhao ◽  
Xu Ran

To reduce the agglomeration of graphene and enhance the interface bonding between reduced graphene oxide (RGO) and copper substrate, copper plating on the graphene surface was prepared by the in-situ reduction method. To improve the strength of the copper matrix, the microalloying strategy of adding titanium to the matrix was adopted. By changing the mass fraction of titanium in the matrix, the optimum ratio of RGO was obtained( Ti mass fraction was 5:1), and the tensile strength was maximized. The results show that RGO did not agglomerate obviously in the matrix. At the same time, the composite powder could be densified rapidly by spark plasma sintering (SPS), which could effectively protect the original distribution of the additive phase in the matrix. In this paper, Cu@RGO/Cu-Ti was prepared and the strengthening mechanism of the composites discussed, providing a new insights into the interface design and carbide formation mechanism of advanced graphene/copper composites with high mechanical properties.


2020 ◽  
Vol 979 ◽  
pp. 28-33 ◽  
Author(s):  
Lakshmanan Poovazhgan ◽  
S. Vijayananth ◽  
S. Sivaganesan

In this work, aluminum (Al) alloy reinforced with boron carbide (B4C) nanoparticles were fabricated using ultrasonic assisted casting process. To investigate the effect of ultrasonic power on processing the metal matrix nanocomposites (MMNCs), the MMNC samples were processed with 1.0 kW, 1.5 kW and 2.0 kW of ultrasonic power. The results indicate that the ultrasonic power play a significant role in dispersing the B4C nanoparticles uniformly in Al melt and it also affects the mechanical properties of the fabricated MMNCs. From microstructural analysis it was observed that the MMNC sample processed with 2.0 kW ultrasonic powers possessed the good dispersion of B4C in the Al melt which is the prime criteria for the good mechanical properties.


2019 ◽  
Vol 945 ◽  
pp. 493-497
Author(s):  
Y. Shchetinin ◽  
Y. Kopylov ◽  
A. Zhirkov

The presented work reviews the research in the field of production of nanostructured composite materials based on copper, reinforced with carbon nanostructures. Particular attention is paid to the use of composites with high thermal conductivity as structural materials. The method of manufacturing a composite material based on copper is described in detail: modes of preliminary annealing, pre-pressing, hot isostatic pressing. The characteristics of the matrix and alloying components are given, and also preliminary treatment of copper powder and carbon nanotubes is described. Different mechanisms of component mixing are considered, the process of mechanical alloying in a planetary mill is described in detail, the results of measuring the thermal conductivity of samples are given. The mechanical characteristics of the samples are considered in detail: ultimate strength, yield strength, elongation. The degree of influence of surfactants on the uniformity of the distribution of alloying components and the mechanical properties of the composite material is determined.


Author(s):  
Mohan Bangaru ◽  
Thirumal Azhagan Murugan ◽  
Rajadurai Arunachalam

In the recent days, aerospace, automotive and defense sectors have been the main driving force behind the search of lighter and stronger materials in order to use in the production of vehicles. The growing demand for the production of light weight structural components and systems is fulfilled by the development of innovative metallic materials such as composites and alloys particularly based on aluminium because of their desirable properties such as low density, good castability, excellent strength and excellent corrosion resistance. Widely employed processes such as gravity and pressure die casting are used for processing aluminium alloys but the components exhibit several casting defects such as porosity, cracks, segregation and hot tears etc. This drives the industries to develop new processes which produce defect free components in shorter time as they have been under competitive pressure. Of the many such processes, squeeze casting has good capacity to produce less defective components. Squeeze casting is the process in which the molten metal solidifies under the application of pressure. The development of Aluminium Matrix Composites (AMCs) through squeeze casting has been one of the major areas of research in recent times. Research works on AMCs reinforced with micrometric particles have shown that the ability to strengthen the matrix alloy by them is lesser than nanometric particles. Metal matrices reinforced with nanoparticles are characterized by significant improvement in strength and wear resistance, improved ductility and improved dimensional stability at elevated temperatures. But, nanosized ceramic particles constitute problems during fabrication as it is extremely difficult to obtain uniform dispersion of nanoparticles in liquid metals owing to their high viscosity, poor wettability in the metal matrix, and a large surface-to-volume ratio. These problems induce agglomeration and clustering of nanoparticles. The nanoparticles can be dispersed uniformly in the metal matrix by means of employing ultrasonic cavitations. Ultrasonic cavitations include the formation, growth and collapse of micro-bubbles in liquids, under cyclic high intensity ultrasonic waves. The cavitation bubbles collapse and generate a huge amount of energy, which could be used in dispersion of the nanoparticles more uniformly in the melt. In this study, squeeze casting is combined with ultrasonic cavitations to develop Metal Matrix Nanocomposites (MMNCs) of AA6061 – SiCp as a maiden attempt. The impact of varying volume percentage of SiCp nanoparticles (average size of 45 nm – 65 nm) by ultrasonic cavitations on mechanical properties such as ultimate tensile strength and hardness exhibited by MMNCs were analyzed. In this research, volume percentage of SiCp nanoparticles was varied at 0.4%, 0.8% and 1.2% respectively by employing ultrasonic vibrations at the amplitude of 70 μm to the melt of AA6061. The melt of AA6061-SiCp was poured into the pre heated die cavity and squeeze pressure of 105 Mpa was applied over it for a certain period while developing MMNCs. Scanning Electron Microscope (SEM) images showed the uniform distribution of SiCp nanoparticles in AA6061 matrix. Energy Dispersive Spectroscopy (EDS) in SEM confirmed the incorporation of SiCp in AA6061 matrix. The obtained results confirmed the effectiveness of ultrasonic cavitations in squeeze casting process to disperse the nanoparticles of SiCp uniformly in AA6061 matrix. The mechanical properties of MMNCs such as ultimate tensile strength and hardness exhibited an increasing trend with respect to the increase in volume percentage of SiCp nanoparticles. Thus there prevails a great scope to develop MMNCs of aluminium using ultrasonic cavitations in squeeze casting process.


Author(s):  
Seunghyun Baik ◽  
Byeongsoo Lim ◽  
Bumjoon Kim ◽  
Untae Sim ◽  
Seyoung Oh ◽  
...  

Carbon nanotubes have received considerable attention because of their excellent mechanical properties. In this study, carbon nanotube - copper composites have been sintered by a mechanical mixing process. The interfacial bonding between nanotubes and the copper matrix was improved by coating nanotubes with nickel. Sintered pure copper samples were used as control materials. The displacement rate of nanotube-copper composites was found to increase at 200°C whereas that of nickel-coated nanotue-copper composites significantly decreased. The incorporation of carbon nanotubes and nickel-coated carbon nanotubes in the copper matrix decreased friction coefficients and increased the time up to the onset of scuffing compared with those of pure copper specimens.


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