scholarly journals THE STRUCTURE OF THE VARIABILITY OF THE HYDROCHEMICAL COMPOSITION OF WATER IN LAKE-TYPE RESERVOIR

Author(s):  
D. Y. Nokhrin ◽  
M. A. Derkho ◽  
L. G. Mukhamedyarova ◽  
A. V. Zhivetina

A qualitative and quantitative analysis of hydrochemical parameters of water is given in order to identify the factors that determine their spatial and temporal changes in a lake-type reservoir. Water samples were taken in 2019 and 2020 from the average level in spring (April), summer (July) and autumn (September) in the first week of the month in accordance with the requirements of GOST R 51592-2000 in three sections. The first target (1) is the shallow upper part (depth from 2 to 4 m); the second target (2) is the central part (depth from 5 to 7 m) and the third target (3) is the near – dam part (depth up to 12.2 m). Statistical analysis of the obtained data was performed using the unlimited Principal component analysis (PCA) technique and the limited redundancy analysis (RDA) technique. The effects were considered statistically significant at P<0.05, and useful for discussion-at P<0.10. It was found that, despite the flood increase in the level of chemical components in the water of the reservoir, most of them meet the requirements for fishing waters, with the exception of iron, copper, manganese, zinc, nickel and lead, which exceed the MPCVR from 1.1 to 45.0 times. The total variability of the hydrochemical composition of water in the reservoir, estimated by the PCA method, depends on the season of the year by 71.4 %. A similar result was obtained by the RDA method in a model with a single regressor. When all factors are taken into account in the RDA model, the variability of the water chemical composition is affected by the season of the year by 74.3 %, the year of research by 11.1 %, and the location of the target by 1.9 %. The primary indicators of water for the proportion of unexplained variability in both the PCA and RDA methods are manganese, bicarbonates, lead and aluminum, and pH.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Alessandro Bitetto ◽  
Paola Cerchiello ◽  
Charilaos Mertzanis

AbstractEpidemic outbreaks are extreme events that become more frequent and severe, associated with large social and real costs. It is therefore important to assess whether countries are prepared to manage epidemiological risks. We use a fully data-driven approach to measure epidemiological susceptibility risk at the country level using time-varying information. We apply both principal component analysis (PCA) and dynamic factor model (DFM) to deal with the presence of strong cross-section dependence in the data. We conduct extensive in-sample model evaluations of 168 countries covering 17 indicators for the 2010–2019 period. The results show that the robust PCA method accounts for about 90% of total variability, whilst the DFM accounts for about 76% of the total variability. Our index could therefore provide the basis for developing risk assessments of epidemiological risk contagion. It could be also used by organizations to assess likely real consequences of epidemics with useful managerial implications.


2021 ◽  
Vol 11 (13) ◽  
pp. 5855
Author(s):  
Samantha Reale ◽  
Valter Di Cecco ◽  
Francesca Di Donato ◽  
Luciano Di Martino ◽  
Aurelio Manzi ◽  
...  

Celery (Apium graveolens L.) is a vegetable belonging to the Apiaceae family that is widely used for its distinct flavor and contains a variety of bioactive metabolites with healthy properties. Some celery ecotypes cultivated in specific territories of Italy have recently attracted the attention of consumers and scientists because of their peculiar sensorial and nutritional properties. In this work, the volatile profiles of white celery “Sedano Bianco di Sperlonga” Protected Geographical Indication (PGI) ecotype, black celery “Sedano Nero di Torricella Peligna” and wild-type celery were investigated using head-space solid-phase microextraction combined with gas-chromatography/mass spectrometry (HS-SPME/GC-MS) and compared to that of the common ribbed celery. Exploratory multivariate statistical analyses were conducted using principal component analysis (PCA) on HS-SPME/GC-MS patterns, separately collected from celery leaves and petioles, to assess similarity/dissimilarity in the flavor composition of the investigated varieties. PCA revealed a clear differentiation of wild-type celery from the cultivated varieties. Among the cultivated varieties, black celery “Sedano Nero di Torricella Peligna” exhibited a significantly different composition in volatile profile in both leaves and petioles compared to the white celery and the prevalent commercial variety. The chemical components of aroma, potentially useful for the classification of celery according to the variety/origin, were identified.


2021 ◽  
pp. 096703352098731
Author(s):  
Adenilton C da Silva ◽  
Lívia PD Ribeiro ◽  
Ruth MB Vidal ◽  
Wladiana O Matos ◽  
Gisele S Lopes

The use of alcohol-based hand sanitizers is recommended as one of several strategies to minimize contamination and spread of the COVID-19 disease. Current reports suggest that the virucidal potential of ethanol occurs at concentrations close to 70%. Traditional methods of verifying the ethanol concentration in such products invite potential errors due to the viscosity of chemical components or may be prohibitively expensive to undertake in large demand. Near infrared (NIR) spectroscopy and chemometrics have already been used for the determination of ethanol in other matrices and present an alternative fast and reliable approach to quality control of alcohol-based hand sanitizers. In this study, a portable NIR spectrometer combined with classification chemometric tools, i.e., partial least square discriminant analysis (PLS–DA) and linear discriminant analysis with successive algorithm projection (SPA–LDA) were used to construct models to identify conforming and non-conforming commercial and laboratory synthesized hand sanitizer samples. Principal component analysis (PCA) was applied in an exploratory data study. Three principal components accounted for 99% of data variance and demonstrate clustering of conforming and non-conforming samples. The PLS–DA and SPA–LDA classification models presented 77 and 100% of accuracy in cross/internal validation respectively and 100% of accuracy in the classification of test samples. A total of 43% commercial samples evaluated using the PLS–DA and SPA–LDA presented ethanol content non-conforming for hand sanitizer gel. These results indicate that use of NIR spectroscopy and chemometrics is a promising strategy, yielding a method that is fast, portable, and reliable for discrimination of alcohol-based hand sanitizers with respect to conforming and non-conforming ethanol concentrations.


2014 ◽  
Vol 926-930 ◽  
pp. 4085-4088
Author(s):  
Chuan Jun Li

This article uses the PCA method (Principal component analysis) to evaluate the level of corporate governance. PCA is used to analyze the correlation among 10 original indicators, and extract some principal components so that most of the information of the original indicators is extracted. The formulation of the index of corporate governance can be got by calculating the weight based on the variance contribution rate of the principal component, which can comprehensively evaluate corporate governance.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Tai-Xiang Jiang ◽  
Ting-Zhu Huang ◽  
Xi-Le Zhao ◽  
Tian-Hui Ma

We have proposed a patch-based principal component analysis (PCA) method to deal with face recognition. Many PCA-based methods for face recognition utilize the correlation between pixels, columns, or rows. But the local spatial information is not utilized or not fully utilized in these methods. We believe that patches are more meaningful basic units for face recognition than pixels, columns, or rows, since faces are discerned by patches containing eyes and noses. To calculate the correlation between patches, face images are divided into patches and then these patches are converted to column vectors which would be combined into a new “image matrix.” By replacing the images with the new “image matrix” in the two-dimensional PCA framework, we directly calculate the correlation of the divided patches by computing the total scatter. By optimizing the total scatter of the projected samples, we obtain the projection matrix for feature extraction. Finally, we use the nearest neighbor classifier. Extensive experiments on the ORL and FERET face database are reported to illustrate the performance of the patch-based PCA. Our method promotes the accuracy compared to one-dimensional PCA, two-dimensional PCA, and two-directional two-dimensional PCA.


2021 ◽  
Author(s):  
Amélie Fischer ◽  
Philippe Gasnier ◽  
Philippe Faverdin

ABSTRACTBackgroundImproving feed efficiency has become a common target for dairy farmers to meet the requirement of producing more milk with fewer resources. To improve feed efficiency, a prerequisite is to ensure that the cows identified as most or least efficient will remain as such, independently of diet composition. Therefore, the current research analysed the ability of lactating dairy cows to maintain their feed efficiency while changing the energy density of the diet by changing its concentration in starch and fibre. A total of 60 lactating Holstein cows, including 33 primiparous cows, were first fed a high starch diet (diet E+P+), then switched over to a low starch diet (diet E−P−). Near infra-red (NIR) spectroscopy was performed on each individual feed ingredient, diet and individual refusals to check for sorting behaviour. A principal component analysis (PCA) was performed to analyse if the variability in NIR spectra of the refusals was explained by the differences in feed efficiency.ResultsThe error of reproducibility of feed efficiency across diets was 2.95 MJ/d. This error was significantly larger than the errors of repeatability estimated within diet over two subsequent lactation stages, which were 2.01 MJ/d within diet E−P− and 2.40 MJ/d within diet E+P+. The coefficient of correlation of concordance (CCC) was 0.64 between feed efficiency estimated within diet E+P+ and feed efficiency estimated within diet E−P−. This CCC was smaller than the one observed for feed efficiency estimated within diet between two subsequent lactation stages (CCC = 0.72 within diet E+P+ and 0.85 within diet E−P−). The first two principal components of the PCA explained 90% of the total variability of the NIR spectra of the individual refusals. Feed efficiency was poorly correlated to those principal components, which suggests that feed sorting behaviour did not explain differences in feed efficiency.ConclusionsFeed efficiency was significantly less reproducible across diets than repeatable within the same diet over subsequent lactation stages, but cow’s ranking for feed efficiency was not significantly affected by diet change. The differences in sorting behaviour between cows were not associated to feed efficiency differences in this trial neither with the E+P+ diet nor with the E−P− diet. Those results have to be confirmed with cows fed with more extreme diets (for example roughage only) to ensure that the least and most efficient cows will not change.


2019 ◽  
Vol 4 (2) ◽  
pp. 359-366
Author(s):  
Irfan Maibriadi ◽  
Ratna Ratna ◽  
Agus Arip Munawar

Abstrak,  Tujuan dari penelitian ini adalah mendeteksi kandungan dan kadar formalin pada buah tomat dengan menggunakan instrument berbasis teknologi Electronic nose. Penelitian ini menggunakan buah tomat yang telah direndam dengan formalin dengan kadar 0.5%, 1%, 2%, 3%, 4%, dan buah tomat tanpa perendaman dengan formalin (0%). Jumlah sampel yang digunakan pada penelitian ini adalah sebanyak 18 sampel. Pengukuran spektrum beras menggunakan sensor Piezoelectric Tranducer. Klasifikasi data spektrum buah tomat menggunakan metode Principal Component Analysis (PCA) dengan pretreatment nya adalah Gap Reduction. Hasil penelitian ini diperoleh yaitu: Hidung elektronik mulai merespon aroma formalin pada buah tomat pada detik ke-8.14, dan dapat mengklasifikasikan kandungan dan kadar formalin pada buah tomat pada detik ke 25.77. Hidung elektronik yang dikombinasikan dengan metode principal component analysis (PCA) telah berhasil mendeteksikandungan dan kadar formalin pada buah tomat dengan tingkat keberhasilan sebesar 99% (PC-1 sebesar 93% dan PC-2 sebesar 6%). Perbedaan kadar formalin menjadi faktor utama yang menyebabkan Elektronik nose mampu membedakan sampel buah tomat yang diuji, karena semakin tinggi kadar formalin pada buah tomat maka aroma khas dari buah tomat pun semakin menghilang, sehingga Electronic nose yang berbasis kemampuan penciuman dapat membedakannya.Detect Formaldehyde on Tomato (Lycopersicum esculentum Mill) With Electronic Nose TechnologyAbstract, The purpose of this study is to detect the contents and levels of formalin in tomatoes by using instruments based on Electronic nose technology. This study used tomatoes that have been soaked in formalin with a concentration of 0.5%, 1%, 2%, 3%, 4%, 5% and tomatoes without soaking with formalin (0%). The samples in this study were 18 samples. The measurements of the intensity on tomatoes aroma were using Piezoelectric Transducer sensors. The classification of tomato spectrum data was using the Principal Component Analysis (PCA) method with Gap Reduction pretreatment. The results of this study were obtained: the Electronic nose began to respond the smell of formalin on tomatoes at 8.14 seconds, and it could classify the content and formalin levels in tomatoes at 25.77 seconds. Electronic nose combined with the principal component analysis (PCA) method have successfully detected the content and levels of formalin in tomatoes with a success rate at 99% (PC-1 of 93% and PC-2 of 6%). The difference of grade formalin levels is the main factor that causes Electronic nose to be able to distinguish the tomato samples tested, because the higher of formalin content in tomatoes, the distinctive of tomatoes aroma is increasingly disappearing. Thereby, the Electronic nose based on  the olfactory ability can distinguish them. 


2021 ◽  
Vol 10 (1) ◽  
pp. 49-63
Author(s):  
Hefdhallah Al Aizari ◽  
Rachida Fegrouche ◽  
Ali Al Aizari ◽  
Saeed S. Albaseer

The fact that groundwater is the only source of drinking water in Yemen mandates strict monitoring of its quality. The aim of this study was to measure the levels of fluoride in the groundwater resources of Dhamar city. Dhamar city is the capital of Dhamar governorate located in the central plateau of Yemen. For this purpose, fluoride content in the groundwater from 16 wells located around Dhamar city was measured. The results showed that 75% of the investigated wells contain fluoride at or below the permissible level set by the World Health Organization (0.5 – 1.5 mg/L), whereas 25% of the wells have relatively higher fluoride concentrations (1.59 – 184 mg/L). The high levels of fluoride have been attributed to the anthropogenic activities in the residential areas near the contaminated wells. Interestingly, some wells contain very low fluoride concentrations (0.30 – 0.50 mg/L).  Data were statistically treated using the principal component analysis (PCA) method to investigate any possible correlations between various factors. PCA shows a high correlation between well depth and its content of fluoride. On the other hand, health problems dominating in the study area necessitate further studies to investigate any correlation with imbalanced fluoride intake.


2020 ◽  
Vol 12 (8) ◽  
pp. 160
Author(s):  
Gislaine Gabardo ◽  
Maristella Dalla Pria ◽  
Henrique Luis da Silva ◽  
Mônica Gabrielle Harms

Soybean mildew caused by Oomycota Peronospora manshurica, is a disease widely spread in Brazil. In order to study the efficiency of soybean mildew control due to the application of alternative products and fungicide in the field, experiments were conducted in Ponta Grossa, PR, Brazil, during the 2013/2014 and 2014/2015 growing seasons. The design used was randomized blocks with four replications. The treatments were: 1-witness; 2-acibenzolar-S-methyl; 3-calcium; 4-micronutrients: copper, manganese and zinc; 5-micronutrients: manganese, zinc and molybdenum; 6-NK fertilizer; 7-Ascophyllum nodosum and 8-azoxystrobin + cyproconazole with the addition of Nimbus adjuvant. Four applications of alternative products (phenological stages V3, V6, R1 and R5.1) and two of fungicide (phenological stages R1 and R5.1) were performed. The mildew severity was estimated using a diagrammatic scale. The severity data made it possible to calculate the area under the disease progress curve (AUDPC). In the 2014/2015 harvest the disease was more severe. The control of downy mildew by the use of fungicide did not reduce the epidemic. The fungicide was not efficient in the two evaluated seasons. All tested alternative products reduced the disease severity and AUDPC in both seasons. The best results in reducing downy mildew were found with the application of acibenzolar-S-methyl, micronutrients (Cu, Mn, Zn) and A. nodosum.


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