scholarly journals NITRATE REMOVAL IN WOODCHIP DENITRIFICATION BIOREACTOR – AN APPROACH COMBINING MATHEMATICAL MODELLING AND PI CONTROL

2022 ◽  
Vol 30 (1) ◽  
pp. 13-21
Author(s):  
Anatolij Nečiporenko ◽  
Feliksas Ivanauskas ◽  
Jurgita Dabulytė-Bagdonavičienė ◽  
Arvydas Povilaitis ◽  
Valdas Laurinavičius
Keyword(s):  
Flow Rate ◽  
Nonlocal Condition ◽  
Nitrate Concentration ◽  
Nitrate Removal ◽  
Pi Controller ◽  
Mathematical Relationship ◽  
Proposed Model ◽  
Custom Software ◽  
Denitrification Bioreactor ◽  
Reaction Equations

A mathematical model of nitrate removal in woodchip denitrification bioreactor based on field experiment measurements was developed in this study. The approach of solving inverse problem for nonlinear system of differential convection-reaction equations was applied to optimize the efficiency of nitrate removal depending on bioreactor’s length and flow rate. The approach was realized through the developed algorithm containing a nonlocal condition with an incorporated PI controller. This allowed to adjust flow rate for varying inflow nitrate concentrations by using PI controller. The proposed model can serve as a useful tool for bioreactor design. The main outcome of the model is a mathematical relationship intended for bioreactor length selection when nitrate concentration at the inlet and the flow rate are known. Custom software was developed to solve the system of differential equations aiming to ensure the required nitrate removal efficiency.

scholarly journals Techno-economical evaluation of nitrate removal using continuous flow electro-coagulation process: optimization by Taguchi model

2017 ◽  
Vol 17 (6) ◽  
pp. 1703-1711 ◽  
Author(s):  
E. Karamati Niaragh ◽  
M. R. Alavi Moghaddam ◽  
M. M. Emamjomeh
Keyword(s):  
Removal Efficiency ◽  
Flow Rate ◽  
Current Density ◽  
Nitrate Concentration ◽  
Nitrate Removal ◽  
Operating Costs ◽  
Inlet Flow ◽  
Inlet Flow Rate ◽  
Initial Ph ◽  
Electro Coagulation

Abstract This study aims to investigate the effect of the main parameters on the performance of a continuous flow electro-coagulation (EC) process for nitrate removal efficiency and its operating costs. For this purpose, the Taguchi experimental design with orthogonal array L27 (313) was applied to analyze the effects of selected parameters, namely initial nitrate concentration, inlet flow rate, current density and initial pH. According to the analysis of variance results, the inlet flow rate and the current density were recognized to be the most effective factors playing a pivotal role in nitrate removal efficiency by using an EC process. The optimum conditions of initial nitrate concentration, inlet flow rate, current density and initial pH were found to be 100 mg/L, 50 mL/min, 80 A/m2 and 8, respectively. As a result, the observed nitrate removal efficiency under these conditions was 61.70%. In addition, operating costs were evaluated as 1.278 US$/g NO3-removed. Finally, a high correlation was observed between the experimental and predicted results indicating an appropriate accuracy of the Taguchi model for nitrate removal efficiency and its operating costs in an EC system.

Innovative process using Fe0/CO2 for the removal of nitrate from groundwater

2005 ◽  
Vol 5 (5) ◽  
pp. 41-48 ◽  
Author(s):  
C. Ruangchainikom ◽  
C.H. Liao ◽  
J. Anotai ◽  
M.T. Lee
Keyword(s):  
Flow Rate ◽  
Nitrate Concentration ◽  
Air Flow ◽  
Nitrate Removal ◽  
Operation Mode ◽  
Nitrate Solution ◽  
Process Efficiency ◽  
Ammonium Concentration ◽  
Air Flow Rate ◽  
Solution Ph

In this study, the Fe0/CO2 process was investigated for removing nitrate from aqueous solution, in terms of process efficiency, process operation mode, and post-treatment of the end product ammonium. The results show that nitrate at 30 mg/L could be removed from solution within 30 min under the conditions of 2 g/L Fe0 and 200 mL/min CO2 flow rate. Additionally, nitrite was not detected in treated solution, whereas ammonium is the predominant nitrogen-containing species. The normalized residual nitrate concentration decreased with increasing nitrate concentration (2.18–24.19 mg N/L). Nitrate removal was inhibited significantly in the presence of humic acid. Comparing operation modes, NO3− reduction efficiency with increasing number of batch operations in Mode 2 (treated solution was emptied and refilled with freshly prepared solution for the next batch treatment, containing the same level of nitrate as the previous batch) is better than that with Mode 1 (treated solution was retained in the reactor and spiked with concentrated nitrate solution to raise nitrate concentration to a level close to the one in the previous batch). However, to guarantee satisfactory nitrate removal in batch operation mode, zero-valent iron supplementation needs to be taken into consideration. For example, the nitrate removal efficiency without Fe0 supplementation is decreasing in the third batch, compared with those with supplements of 0.25 and 1 g/L. According to a preliminary study, the undesired end-product ammonium can be removed from solution by about 95% within 22.5 h with an air flow rate of 500 mL/min and a solution pH around 12; the ammonium concentration decreased from 6.4 to 0.3 mg 12 N/L. Stripping time can be further shortened by increasing air flow rate and using an efficient air diffuser.

Nitrate removal in riparian wetland soils: Effects of flow rate, temperature, nitrate concentration and soil depth

1997 ◽  
Vol 31 (4) ◽  
pp. 841-849 ◽  
Author(s):  
Hans P.L. Willems ◽  
Matthew D. Rotelli ◽  
Duane F. Berry ◽  
Eric P. Smith ◽  
Raymond B. Reneau ◽  
...  
Keyword(s):  
Flow Rate ◽  
Nitrate Concentration ◽  
Soil Depth ◽  
Nitrate Removal ◽  
Wetland Soils ◽  
Riparian Wetland

Comparison of denitrification performances using PLA/starch with different mass ratios as carbon source

2015 ◽  
Vol 71 (7) ◽  
pp. 1019-1025 ◽  
Author(s):  
Chuanfu Wu ◽  
Danqi Tang ◽  
Qunhui Wang ◽  
Juan Wang ◽  
Jianguo Liu ◽  
...  
Keyword(s):  
Carbon Source ◽  
Groundwater Remediation ◽  
Nitrate Concentration ◽  
Starch Content ◽  
Nitrate Removal ◽  
Carbon Sources ◽  
National Standard ◽  
Biofilm Carrier ◽  
Carbon Release ◽  
Biological Nitrate Removal

A suitable carbon source is significant for biological nitrate removal from groundwater. In this study, slow-release carbon sources containing polylactic acid (PLA) and starch at 8:2, 7:3, 6:4, 5:5, 4:6, and 3:7 ratios were prepared using a blending and fusing technique. The PLA/starch blend was then used as a solid carbon source for biological nitrate removal. The carbon release rate of PLA/starch was found to increase with increased starch content in leaching experiments. PLA/starch at 5:5 mass ratio was found to have the highest denitrification performance and organic carbon consumption efficiency in semi-continuous denitrification experiments, and was also revealed to support complete denitrification at 50 mg-N/L influent nitrate concentration in continuous experiments. The effluent nitrate concentration was <2 mg NO3–-N/L, which met the national standard (GB 14848-93) for groundwater. Scanning electron microscopy results further showed that the surface roughness of PLA/starch increased with prolonged experimental time, which may be conducive to microorganism attachment. Therefore, PLA/starch was a suitable carbon source and biofilm carrier for groundwater remediation.

Mechanism underlying diuretic effect of l-NAME at a subpressor dose

2001 ◽  
Vol 281 (3) ◽  
pp. F414-F419 ◽  
Author(s):  
Mingyu Liang ◽  
Theresa J. Berndt ◽  
Franklyn G. Knox
Keyword(s):  
Proximal Tubule ◽  
Flow Rate ◽  
Nitrate Concentration ◽  
Distal Tubule ◽  
No Synthase ◽  
Urine Flow ◽  
Sprague Dawley ◽  
Sprague Dawley Rats ◽  
Renal Tubular ◽  
Nitrite Nitrate

The diuretic effects of nitric oxide (NO) synthase inhibitors administered at subpressor dose in rats are controversial, and the tubular segments involved are not known. In the present study, we examined the effect of N ω-nitro-l-arginine methyl ester (l-NAME) at a subpressor dose on renal interstitial NO and cGMP activity and on renal tubular segmental reabsorption of fluid in the rat. Intravenous infusion of l-NAME at 1 μg · kg−1 · min−1 in Sprague-Dawley rats ( N = 8), which did not alter mean arterial pressure or glomerular filtration rate, significantly increased urine flow rate (Uv; from 78.2 ± 12.7 to 117.1 ± 14.9 μl/min, P < 0.05). Paradoxically, this effect of l-NAME was concomitant with significant increases in nitrite/nitrate (from 10.79 ± 1.20 to 16.50 ± 2.60 μM, P < 0.05) and cGMP (from 0.65 ± 0.09 to 0.98 ± 0.18 nM, P < 0.05) concentrations in renal cortical microdialysate as well as the nitrite/nitrate concentration in the medullary microdialysate. Micropuncture studies in the superficial nephron revealed that l-NAME significantly increased the flow rate (from 8.3 ± 0.9 to 12.2 ± 1.2 nl/min, P < 0.05) and fractional delivery of fluid to the distal tubule, but not those in the late proximal tubule. In conclusion, l-NAME, at the subpressor dose used in this study, increased renal nitrate/nitrite and cGMP and inhibited fluid reabsorption in tubular segments between the late proximal tubule and the distal tubule of superficial nephrons.

Optimized Refrigerant Flow Rate and Dimensions of the Ejector Employed in a Modified Ejector Vapor Compression System

2020 ◽  
Vol 28 (04) ◽  
pp. 2050038
Author(s):  
Dishant Sharma ◽  
Gulshan Sachdeva ◽  
Dinesh Kumar Saini
Keyword(s):  
Flow Rate ◽  
Cooling System ◽  
Cooling Capacity ◽  
Coefficient Of Performance ◽  
Vapor Compression ◽  
Evaporator Temperature ◽  
Proposed Model ◽  
Condenser Temperature ◽  
Vapor Compression System ◽  
Vapor Compression Cooling

This paper presents the analysis of a modified vapor compression cooling system which uses an ejector as an expansion device. Expanding refrigerant in an ejector enhances the refrigeration effect and reduces compressor work. Therefore, it yields a better coefficient of performance. Thermodynamic analysis of a constant area ejector model has been done to obtain primary dimensions of the ejector for given condenser and evaporator temperature and cooling capacity. The proposed model has been used to design the ejector for three refrigerants; R134a, R152a and R1234yf. The refrigerant flow rate and the diameters at various sections of the ejector have been obtained by doing numerical modeling in Engineering Equation Solver (EES). Refrigerant R1234yf demanded the highest diameter requirements at a fixed 5∘C evaporator temperature and 40∘C condenser temperature for a given range of cooling load. Both primary and secondary refrigerants flow rates are higher for R1234yf followed by R134a and then R152a.

scholarly journals Experimental Analysis and Modeling of Nitrate Removal through Zero-Valent Magnesium Particles

Water ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1276 ◽  
Author(s):  
Siciliano ◽  
Curcio ◽  
Limonti
Keyword(s):  
Nitrate Concentration ◽  
Nitrate Removal ◽  
Experimental Results ◽  
Process Efficiency ◽  
Main Reaction ◽  
Main Reaction Product ◽  
Nitrogen Forms ◽  
Sustainable Technologies ◽  
Batch Tests ◽  
Effects Of Ph

The pollution of water by nitrates represents an important environmental and health issue. The development of sustainable technologies that are able to efficiently remove this contaminant is a key challenge in the field of wastewater treatment. Chemical denitrification by means of zero-valent metallic elements is an interesting method to reduce the oxidized forms of nitrogen. Compared to other metallic reactants, zero-valent magnesium (ZVM) has many profitable aspects, but its use for nitrate removal has scarcely been investigated. In the present work, several batch tests were conducted to examine the concurrent effects of pH, initial nitrate concentration and Mg0 quantity on process performance. The experimental results proved that at pH 3, for a given initial nitrate concentration, the dose of ZVM largely influences process efficiency. In particular, with a ratio between Mg0 and initial N-NO3− amount (Mg/NNi) of 0.33 g/mg, it is possible to obtain complete denitrification within 30 min. Beyond this ratio, no further improvement of treatment was observed. The experiments allowed us to identify the nitrogen forms produced during the treatment. Nitrogen gas was generally the main reaction product, but the trends of the different compounds (NO3−, NO2−, NH4+ and N2) notably changed in response to the modification of operating parameters. Moreover, the results demonstrated that, in a highly acidic environment, when treating solutions with a low nitrate concentration, process performances are unsatisfactory even when using a high Mg/NNi ratio. By increasing the process pH to 5 and 7, a significant denitrification decline occurred. Furthermore, at these pH levels, the enhancement of nitrate concentration caused a progressive process deterioration. Through detailed analysis of experimental results, reactions kinetics and new mathematical equations, able to describe the trends of different nitrogen forms, have been defined. Moreover, reactions pathways have been proposed. Finally, the characterization of exhausted material allowed us to identify the corrosion products formed during the treatment.

scholarly journals Global Internal Recirculation Alternative Operation to Reduce Nitrogen and Ammonia Limit Violations and Pumping Energy Costs in Wastewater Treatment Plants

Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1606
Author(s):  
Ignacio Santín ◽  
Ramon Vilanova ◽  
Carles Pedret ◽  
Marian Barbu
Keyword(s):  
Wastewater Treatment ◽  
Flow Rate ◽  
Biological Treatment ◽  
Fuzzy Controller ◽  
Wastewater Treatment Plants ◽  
Nitrate Concentration ◽  
Great Influence ◽  
Energy Costs ◽  
Recirculation Flow ◽  
Operational Costs

The internal recirculation plays an important role in different areas of the biological treatment of wastewater treatment plants because it has a great influence on the concentration of pollutants, especially nutrients. A usual manipulation of the internal recirculation flow rate is based on the target of controlling the nitrate concentration in the last anoxic tank. This work proposes an alternative for the manipulation of the internal recirculation flow rate instead of nitrate control, with the objective of avoiding limit violations of nitrogen and ammonia concentrations and reducing operational costs. A fuzzy controller is proposed to achieve it based on the effects of the internal recirculation flow rate in different areas of the biological treatment. The proposed manipulation of the internal recirculation flow rate is compared to the application of the usual nitrate control in an already established and published operation strategy by using the internationally known benchmark simulation model no. 2 as a working scenario. The results show improvements with reductions of 59.40% in ammonia limit violations, 2.35% in total nitrogen limit violations, and 38% in pumping energy costs.

A Semianalytical Model for Simulating Combined Electromagnetic Heating and Solvent-Assisted Gravity Drainage

SPE Journal ◽  
2018 ◽  
Vol 23 (04) ◽  
pp. 1248-1270 ◽  
Author(s):  
Lanxiao Hu ◽  
Huazhou Andy Li ◽  
Tayfun Babadagli ◽  
Majid Ahmadloo
Keyword(s):  
Flow Rate ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Influential Factors ◽  
Sensitivity Analyses ◽  
Gravity Drainage ◽  
Hybrid Technique ◽  
Solvent Injection ◽  
Proposed Model ◽  
Oil Flow

Summary Solvent/thermal hybrid methods have been proposed recently to enhance heavy-oil recovery and to overcome the shortcomings that are encountered when either method is solely applied. One of the methods for this hybridization is to combine electromagnetic (EM) heating and solvent injection to facilitate heavy-oil production by gravity drainage. This approach has several advantages including reduced CO2 emissions, decreased water consumption, and appropriateness for water-hostile reservoirs. We are currently lacking any mathematical model for better understanding, designing, and optimizing this hybrid technique, which is partly attributed to this technique still being in its infancy. We propose a semianalytical model to predict the oil-flow rate resulting from the combined EM heating and solvent-assisted gravity drainage. The model first calculates the temperature distribution within the EM-excited zone caused by the radiation-dominated EM heating. Using different attenuation coefficients within and beyond the vapor chamber, the model can properly describe the corresponding temperature responses in these regions. Next, an average temperature of the chamber edge contributed by EM heating is used to estimate the temperature-dependent properties, such as vapor/liquid equilibrium ratios (K-values), heavy-oil/solvent-mixture viscosity, and solvent diffusivity. Subsequently, a 1D diffusion equation is used to calculate the solvent-concentration distribution ahead of the chamber edge. Eventually, the oil-flow rate is evaluated with the calculated temperature and solvent distributions ahead of the chamber edge. The proposed model is validated against the experimental results obtained in our previous study, and the predicted oil-flow rate agrees reasonably well with the experimental data. The proposed model can efficiently predict the oil-flow rate of this hybrid process. We conduct sensitivity analyses to examine the effect of major influential factors on the performance of this hybrid technique, including EM heating powers, solvent types, solvent-injection pressures, and initial reservoir temperatures. The modeling results demonstrate that a higher EM heating power, a heavier solvent, and a higher solvent-injection pressure could accelerate the oil-recovery rate, but tend to lower the net present value (NPV) and increase the energy consumption. In summary, the newly proposed model provides an efficient tool to understand, design, and optimize the combined technique of EM heating and solvent-assisted gravity drainage.

Removal of nitrate using activated carbon-based electrodes for capacitive deionization

2018 ◽  
Vol 18 (6) ◽  
pp. 2028-2034 ◽  
Author(s):  
Shaojie Jiang ◽  
Hongwu Wang ◽  
Guanquan Xiong ◽  
Xinlei Wang ◽  
Siying Tan
Keyword(s):  
Activated Carbon ◽  
Phosphoric Acid ◽  
Flow Rate ◽  
Nitrate Removal ◽  
Cell Voltage ◽  
Solution Concentration ◽  
Capacitive Deionization ◽  
Optimal Conditions ◽  
Ion Removal ◽  
Initial Solution Concentration

Abstract The removal performance of nitrate using capacitive deionization (CDI) of activated carbon (AC)-based electrodes were studied. The AC electrode was prepared and the effect of cell voltage, flow rate and initial solution concentration on ion removal were investigated. Furthermore, the AC was modified with phosphoric acid (ACP) and the surface structure of AC and ACP were analyzed. The results showed that the specific surface area of AC increased by 10.71% after the modification. The mesopore ratio and micropore ratio increased by 14.69% and 24.06%, respectively. The optimal conditions of AC electrode was a voltage of 1.4 V and flow rate of 20 mL/min while the ACP electrode was a voltage of 1.4 V and flow rate of 10 mL/min. The electrosorption capacity of ACP electrode was improved and the unit of electrosorption load was high to 19.28 mg/L. For the AC or ACP electrode, the nitrate removal efficiency decreases with the increase in the initial feed solutions, but the unit electrosorption load gradually increased with the improvement of initial feed solutions' concentration and the ACP electrode was superior to the AC electrode. Therefore, the ACP electrode would be suitable for the application of CDI on the nitrate removal.

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