Study on Anti-Fog Films of Polyethylene Modified with Inorganic Micrometer Diatomite

2012 ◽  
Vol 200 ◽  
pp. 347-350
Author(s):  
Wei He ◽  
Qing Hong Fang ◽  
Wei Lin ◽  
A.S. Luyt ◽  
Tie Jun Ge
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Surface Treatment ◽  
Fourier Transform Infrared ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Treatment Agent ◽  
Infrared Spectrometer

Anti-fog films of low density polyethylene (LDPE) modified with micrometer diatomite were prepared by a process of blow molding. Through examination of antifogging property of the film added the anti-fog agents, the modification effectiveness of inorganic micrometer diatomite and the influence of different treating agents were studied with Fourier transform infrared spectrometer (FTIR), mechanical properties, and antifogging performances. The results indicate that the anti-fog property of the film can be improved by premixing inorganic micrometer diatomite with the anti-fog agents; the film modified by inorganic micrometer diatomite added surface treatment agent has obviously effectiveness anti-fog properties than that the films modified only by the anti-fog agents. Addition of polyacrylamide can make the anti-fog durability of the films modified by inorganic micrometer diatomite be further prolonged. It was observed that the tensile strength does not show any decrease, however, elongation at break show a massive decreased.

Investigation of Epoxidized Natural Rubber (ENR 50) as a Compatibilizer on Cogon Grass Filled Low Density Polyethylene/Soya Spent Flour

2014 ◽  
Vol 803 ◽  
pp. 310-316 ◽  
Author(s):  
S.T. Sam ◽  
Nurul Hani ◽  
H. Ismail ◽  
Nik Noriman ◽  
S. Ragunathan
Keyword(s):  
Tensile Strength ◽  
Fourier Transform ◽  
Natural Rubber ◽  
Water Absorption ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Fourier Transform Infrared ◽  
Epoxidized Natural Rubber ◽  
Low Density Polyethylene ◽  
Low Density

Natural fiber reinforced composites are increasingly being used in various applications area. Therefore, the processing method and physical properties of these composites are very important parameters in product quality and quaranty. This paper focused on the tensile properties, Fourier transform infrared (FTIR) and water absorption of cogon grass (CG) with low density polyethylene (LDPE)/soya spent flour (SSF) composites. The tensile strength and elongation at break (Eb) of uncompatibilized CG with LDPE/ SSF decreased significantly with increasing of fiber content. However, the Young’s modulus increased with increasing of CG loading. The presence of epoxidized natural rubber (ENR 50) as a compatibilizer increased the tensile strength, Eband Young’s modulus of the composites when compared to uncompatibilized composites. Fourier transform infrared results show distinguishable peaks for compatibilized and uncompatibilized composites. The water absorption for both uncompatibilized and compatibilized composites increased from day 1 until day 21. The presence of ENR 50 as compatibilizer showed lower water absorption percentage compared to uncompatibilized composites.

Changes of Some Mechanical Properties of Different Low-Density Polyethylene (LDPE) Films during the Service Life

2017 ◽  
Vol 33 (6) ◽  
pp. 913-918 ◽  
Author(s):  
Nefise Yasemin Emekli ◽  
Kenan Büyüktas ◽  
Ali Basçetinçelik
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Service Life ◽  
Impact Resistance ◽  
Physical Structure ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Greenhouse Cultivation ◽  
The Impact

Abstract. In this study, changes on some mechanical properties such as impact resistance, tensile strength, and elongation at break of the low density polyethylene (LDPE) greenhouse films produced by CO-EX technology were investigated under natural weathering conditions during their service life of 24 months. With multi-layered UV+IR+EVA and UV+IR+EVA+AF-added two different type greenhouse cover films were used as a material. For this purpose, a construction with a slope roof of 26.5° was used. Initially, the impact resistances of UV+IR+EVA and UV+IR+EVA+AF films were determined as 1161.4 and 1164.1 g, respectively. But at the end of 24 months, it was determined that the impact resistance of these films reduced as 45.5% and 38.8%, respectively. In addition, tensile strength of the films decreased by 3.5% and 8.5% and the value of elongation at break decreased by 14% and 12%, respectively, at the end of 24 months period. The results showed that the physical structure of the films changed from the elastic form to the fragile form at the end of product life depending on environmental conditions and aging. This situation is very important for all manufacturers who engaged in greenhouse cultivation in Antalya where the greenhouse cultivation is common. Keywords: Aging, Impact strength, Low-density polyethylene film, Mechanical properties, Tensile strength.

scholarly journals Low-Temperature Mechanical Properties of High-Density and Low-Density Polyethylene and Their Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1821
Author(s):  
Ildar I. Salakhov ◽  
Nadim M. Shaidullin ◽  
Anatoly E. Chalykh ◽  
Mikhail A. Matsko ◽  
Alexey V. Shapagin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Low Temperature ◽  
Impact Strength ◽  
Relative Elongation ◽  
High Density ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Subzero Temperatures ◽  
Izod Impact

Low-temperature properties of high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and their blends were studied. The analyzed low-temperature mechanical properties involve the deformation resistance and impact strength characteristics. HDPE is a bimodal ethylene/1-hexene copolymer; LDPE is a branched ethylene homopolymer containing short-chain branches of different length; LLDPE is a binary ethylene/1-butene copolymer and an ethylene/1-butene/1-hexene terpolymer. The samples of copolymers and their blends were studied by gel permeation chromatography (GPC), differential scanning calorimetry (DSC), 13С NMR spectroscopy, and dynamic mechanical analysis (DMA) using testing machines equipped with a cryochamber. It is proposed that such parameters as “relative elongation at break at −45 °C” and “Izod impact strength at −40 °C” are used instead of the ductile-to-brittle transition temperature to assess frost resistance properties because these parameters are more sensitive to deformation and impact at subzero temperatures for HDPE. LLDPE is shown to exhibit higher relative elongation at break at −45 °C and Izod impact strength at −20 ÷ 60 °C compared to those of LDPE. LLDPE terpolymer added to HDPE (at a content ≥ 25 wt.%) simultaneously increases flow properties and improves tensile properties of the blend at −45 °C. Changes in low-temperature properties as a function of molecular weight, MWD, crystallinity, and branch content were determined for HDPE, LLDPE, and their blends. The DMA data prove the resulting dependences. The reported findings allow one to understand and predict mechanical properties in the HDPE–LLDPE systems at subzero temperatures.

Effect of fillers on mechanical properties of recycled low density polyethylene composites under weathered condition

2020 ◽  
Vol 15 (3) ◽  
pp. 44-49
Author(s):  
Ibiyemi A. Idowu ◽  
Olutosin O. Ilori
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Pure Water ◽  
Mechanical Tests ◽  
Filler Loading ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Hardness Property ◽  
Recycled Low Density Polyethylene ◽  
Polyethylene Composites

The study examined the effect of fillers on the mechanical properties of the recycled low density polyethylene composites under weathered condition with a view of managing the generation and disposal of plastic wastes. Discarded pure water sachets and fillers (glass and talc) were sourced and recycled. Recycled low density polyethylene (RLDPE) and preparation of RLDPE/glass, RLDPE/talc and RLDPE/glass/talc composites were carried out using a furnace at compositions of 0 – 40% in steps of 10% by weight. The mixtures were poured into hand-laid mould. The samples produced were exposed to sunlight for eight (8) weeks and their mechanical properties were studied. The results of mechanical tests revealed that tensile strength decreased with increasing filler loading while impact strength and hardness property increased marginally and considerably with increasing filler loading for all the composites respectively. The study concluded that glass and talc were able to reinforce recycled low density polyethylene under weathered condition. Keywords: Recycled Low Density Polyethylene (RLDPE); Fillers; Glass, Talc; Weathering condition; Sunlight; and Mechanical properties; Tensile strength, Impact and hardness

Preparation and characterizations of ternary biodegradable blends composed of polylactide, poly(ε-caprolactone), and wood flour

2012 ◽  
Vol 32 (6-7) ◽  
pp. 435-444 ◽  
Author(s):  
Hsin-Tzu Liao ◽  
Chin-San Wu
Keyword(s):  
Mechanical Properties ◽  
Weight Loss ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Wood Flour ◽  
High Price ◽  
Infrared Analysis ◽  
Melt Blending ◽  
Ternary Blends ◽  
Elongation At Break

Abstract Melt blending of polylactide (PLA), poly(ε-caprolactone) (PCL), and wood flour (WF) was performed in an effort to overcome the major drawbacks (brittleness and high price) of PLA. In addition, the acrylic acid (AA)-grafted PLA70PCL30 (PLA70PCL30-g-AA) was used as the alternative for the preparation of ternary blends to improve the compatibility and the dispersability of WF within the PLA70PCL30 matrix. As expected, PCL improved the elongation at break and the toughness of PLA but decreased the tensile strength and modulus. Because the hydrophilic WF is dispersed physically in the hydrophobic PLA70PCL30 matrix, as the result of Fourier transform infrared analysis, the mechanical properties of PLA70PCL30 became noticeably worse when it was blended with WF. This problem was successfully conquered by using PLA70PCL30-g-AA to replace PLA70PCL30 due to the formation of an ester carbonyl group between PLA70PCL30-g-AA and WF. Furthermore, the PLA70PCL30-g-AA/WF blend provided a plateau tensile strength at break when the WF content was up to 50 wt%. PLA70PCL30/WF exhibited a tensile strength at break of approximately 3–25 MPa more than PLA70PCL30-g-AA/WF. By using p-cresol and tyrosinase, the enzymatic biodegradable test showed that PLA70PCL30-g-AA is somewhat more biodegradable than PLA70PCL30 because the former has better water absorption. After 16 weeks, the weight loss of the PLA70PCL30/WF (50 wt%) composite was >80%. PLA70PCL30-g-AA/WF exhibited a weight loss of approximately 1–12 wt% more than PLA70PCL30-g-AA/WF. It was also found that the addition of WF to PLA70PCL30 or PLA70PCL30-g-AA decreased the crystallinity of PLA and PCL in PLA70PCL30 or PLA70PCL30-g-AA and then increased their biodegradable property.

Cable and Wire Application: Adoption of Nanomagnesium Hydroxide Blended with LDPE/EVA for Mechanical and Physical Properties

2013 ◽  
Vol 701 ◽  
pp. 202-206
Author(s):  
Ahmad Aroziki Abdul Aziz ◽  
Sakinah Mohd Alauddin ◽  
Ruzitah Mohd Salleh ◽  
Mohammed Iqbal Shueb
Keyword(s):  
Mechanical Properties ◽  
Physical Properties ◽  
Melt Flow Index ◽  
Low Density Polyethylene ◽  
Flow Index ◽  
Low Density ◽  
Elongation At Break ◽  
Mechanical And Physical Properties ◽  
Poly Ethylene ◽  
Loading Amount

Effect of nanoMagnesium Hydroxide (MH) nloading amount to the mechanical and physical properties of Low Density Polyethylene (LDPE)/ Poly (ethylene-co vinyl acetate)(EVA) nanocomposite has been described and investigated in this paper. The tensile strength results show that increased amount of nanofiller will decrease and deteriorate the mechanical properties. The elongation at break decreased continuously with increasing loading of nanofiller. Generally, mechanical properties become poorer as loading amount increase. Melt Flow Index values for physical properties also provide same trend as mechanical properties results. Increase filler amount reduced MFI values whereby increased resistance to the flow.

Effect of Functionalized MWCNTs with Surfactant and Coupling Agent on Properties of LDPE/POE Blends

2011 ◽  
Vol 43 (6) ◽  
pp. 543-558 ◽  
Author(s):  
Z. Chen ◽  
S. Chen ◽  
J. Zhang
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Multiwalled Carbon Nanotubes ◽  
Crystallization Behavior ◽  
Low Density Polyethylene ◽  
Favorable Effect ◽  
Low Density ◽  
Multiwalled Carbon ◽  
Polyolefin Elastomer

The surfactant, sodium dodecylbenzenesulfonate (NaDDBS) and coupling agents, γ-aminopropyltriethoxy sliane (KH550) and isopropyl dioleic(dioctylphosphate) titanate (NDZ101) were used to treat multiwalled carbon nanotubes in this work. The effects of surface modification of multiwalled carbon nanotubes on crystallization behavior, mechanical properties, and electrical properties of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites were studied. The results showed that NaDDBS, KH550, and NDZ101 had a favorable effect of improving the dispersion of multiwalled carbon nanotubes, but it cannot improve the interfacial interactionbetween multiwalled carbon nanotubes and the matrix. The improvement in dispersion favored the crystallization behavior and mechanical properties. Modified multiwalled carbon nanotubes had a better acceleration nucleation effect than raw multiwalled carbon nanotubes on low density polyethylene/polyolefin elastomer blends at low content (≤1 wt%). The tensile strength of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites with modified multiwalled carbon nanotubes increased with lower multiwalled carbon nanotubes content (≤1 wt%), and KH550 and NDZ101 led low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites to possess a higher tensile strength than that of NaDDBS with 1 wt% content. NaDDBS, KH550, and NDZ101 had a minor influence on the dielectric properties of the composites and even caused a decrease in the dielectric loss of composites with 10 wt% multiwalled carbon nanotubes content.

Preparation of Chitosan - Hydroxyapatite Nanocomposites

2011 ◽  
Vol 284-286 ◽  
pp. 1760-1763
Author(s):  
Jing Xian Zhang ◽  
Dong Liang Jiang ◽  
Qing Ling Lin ◽  
Zhong Ming Chen ◽  
Zheng Ren Huang
Keyword(s):  
Mechanical Properties ◽  
Fourier Transform ◽  
Phase Composition ◽  
Fourier Transform Infrared ◽  
Chitosan Solution ◽  
Precipitation Method ◽  
Solution Ph ◽  
Cylindrical Form ◽  
Infrared Spectrometer ◽  
Co Precipitation

Chitosan/Hydroxyapatite composites with a homogeneous nanostructure have been prepared by a co-precipitation method. Initially, a chitosan solution was prepared and mixed with the (NH4)2HPO4 solution. After homogenizing, the obtained chitosan/ (NH4)2HPO4 solution was gradually dropped into the Ca (NO3)2.4H2O solution under stirring. The solution pH was adjusted to 9 using NH3.H2O. The precipitate was compressed into a cylindrical form followed by post treatment. The microstructure, phase composition and mechanical properties of the resulting chitosan-HAp composites were characterized. In the presence of chitosan, HAp crystallites were found to be well aligned along the c-axes in the respective aggregates. Fourier transform infrared spectrometer results indicated that an intermolecular bridging complexes might have been developed between the chitosan and HAp. The compact composites obtained were mechanically flexible, the highest strength was found to be 38.4 MPa for chitosan/HAp samples with a 20 wt% of chitosan.

scholarly journals Effect of Heat Drawing Process on Mechanical Properties of Dry-Jet Wet Spun Fiber of Linear Low Density Polyethylene/Carbon Nanotube Composites

2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
Jong Won Kim ◽  
Joon Seok Lee
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Tensile Strength ◽  
Polymer Materials ◽  
Degree Of Crystallinity ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Drawing Process ◽  
Linear Low Density Polyethylene ◽  
Crystallinity Degree

Polyethylene is one of the most commonly used polymer materials. Even though linear low density polyethylene (LLDPE) has better mechanical properties than other kinds of polyethylene, it is not used as a textile material because of its plastic behavior that is easy to break at the die during melt spinning. In this study, LLDPE fibers were successfully produced with a new approach using a dry-jet wet spinning and a heat drawing process. The fibers were filled with carbon nanotubes (CNTs) to improve the strength and reduce plastic deformation. The crystallinity, degree of orientation, mechanical properties (strength to yield, strength to break, elongation at break, and initial modulus), electrical conductivity, and thermal properties of LLDPE fibers were studied. The results show that the addition of CNTs improved the tensile strength and the degree of crystallinity. The heat drawing process resulted in a significant increase in the tensile strength and the orientation of the CNTs and polymer chains. In addition, this study demonstrates that the heat drawing process effectively decreases the plastic deformation of LLDPE.

scholarly journals Development of technology for producing biodegradable hybrid composites based on polyethylene, starch, and monoglycerides

2021 ◽  
Vol 15 (6) ◽  
pp. 44-55
Author(s):  
I. Yu. Vasilyev ◽  
V. V. Ananyev ◽  
V. V. Kolpakova ◽  
A. S. Sardzhveladze
Keyword(s):  
Tensile Strength ◽  
Mechanical Performance ◽  
Hybrid Composites ◽  
Composite Films ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Biodegradable Composite ◽  
Develop Technology ◽  
Distilled Monoglycerides

Objectives. This work aimed to develop technology to produce biodegradable hybrid composite (BHC) films based on low-density polyethylene (LDPE) 115030-070 and thermoplastic starches (TPS) of various origins (corn, pea, and rice), with distilled monoglycerides as the plasticizer. The properties of the produced BHC films were studied and the optimal native starch : glycerol : monoglycerides ratio is proposed.Methods. TPS and BHC films based on this material were produced from different types of native starches in laboratory extruders (Brabender and MashPlast, Russia), and the extruded melts were subjected to ultrasonic vibrations. The structure and appearance of the BHC films were studied using scanning electron microscopy and rheology. Their biodegradability was assessed by immersing them in biocompost for three months. To evaluate the mechanical performance of the BHC films produced with and without ultrasound, the changes in tensile stress and elongation at break were determined during the biodegradation process.Results. The BHC films had a homogeneous structure, except small agglomerates (non-melted starch grains), which did not reduce their quality. The films with monoglycerides had high tensile strength, which was comparable with low-density polyethylene. After removing samples of the BHC films from the biocompost, their tensile strength decreased by 20%, which shows their biodegradability.Conclusions. The produced biodegradable composite films and the technology used to produce them will be applicable for the packaging industry to reduce environmental impact.

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