Mechanical Properties of Epoxidized Palm Oil/Epoxy Resin Blend

2014 ◽  
Vol 695 ◽  
pp. 655-658 ◽  
Author(s):  
Zyad Salem Alsagayar ◽  
Abdul Razak Rahmat ◽  
Agus Arsad ◽  
Alireza Fakhari ◽  
Wan Nurhayati binti Wan Tajulruddin

In this paper, a blend of epoxy resin and epoxidized palm oil (EPO) was prepared to investigate its mechanical properties. Epoxy and EPO were mixed for 20 minutes at room temperature before mixed with hardener and followed by curing for 2 hours at 100 °C. Tensile, flexural and impact tests were conducted to characterize the blend. In general, the tensile and flexural properties of epoxy resin/EPO decreased when the amount of EPO increased. However, strain at break, toughness and impact strength was slightly increased when the amount of EPO was increased up to 20%.The mechanical properties were reduced due to the reduction of the cross linking density and effect of plasticizer.

2015 ◽  
Vol 1113 ◽  
pp. 13-18 ◽  
Author(s):  
Zyad Salem Alsagayar ◽  
Abdul Razak Rahmat ◽  
Agus Arsad ◽  
Alireza Fakhari ◽  
Amirali Khalili

Epoxidized vegetable oils based thermoset materials are widely used to develop biopolymers and to replace the fossil-fuel based polymers. In this paper, a blend of epoxy resin and epoxidized palm oil (EPO) were prepared and characterized by direct and pre-mixed methods to investigate its mechanical properties. For direct method, epoxy and EPO were mixed for 20 minutes at room temperature followed by curing for 2 hours at 100 °C. On other hand, for pre-mixed method, the EPO was reacted with hardener at 120 °C for 1 and 2 hours. Then it was mixed with epoxy resin at room temperature for 20 minutes followed by curing for 2 hours at 100 °C. Fourier transforms infrared spectroscopy [FTIR] and mechanical properties tests were used to characterize the blend. FTIR showed that, a reaction of epoxide group in EPO with active hydrogen atom from hardener and produced a hydroxyl group at 3300 cm-1. In general, the mechanical properties of epoxy resin/EPO were decreased when the amount of EPO was increased. However, at constant amount of EPO Young’s modulus, toughness, flexural strength, and flexural modulus were slightly increased when the time of EPO/hardener was increased. The mechanical properties were reduced due to the reduction of the cross linking density and effect of plasticizer.


SINERGI ◽  
2021 ◽  
Vol 25 (3) ◽  
pp. 361
Author(s):  
Muhamad Fitri ◽  
Shahruddin Mahzan ◽  
Imam Hidayat ◽  
Nurato Nurato

The development of composite materials is increasingly widespread, which require superior mechanical properties. From many studies, it is found that the mechanical properties of composite materials are influenced by various factors, including the reinforcement content, both in the form of fibers and particle powder. However, those studies have not investigated the effect of the hardener weight fraction on the mechanical properties of resin composite materials. Even though its function as a hardener is likely to affect its mechanical properties, it might obtain the optimum composition of the reinforcing content and hardener fraction to get the specific mechanical properties. This study examines the effect of hardener weight fraction combined with fiber powder content on mechanical properties of EPR-174 epoxy resin matrix composite and determines the optimum of Them. The research was conducted by testing a sample of composite matrix resin material reinforced with coconut fiber powder. The Powder content was made in 3 levels, i.e.: 6%, 8%, and 10%. While the hardener fraction of resin was made in 3 levels, i.e.: 0.4, 0.5, and 0.6. The test results showed that pure resin had the lowest impact strength of 1.37 kJ/m2. The specimen with a fiber powder content of 6% has the highest impact strength i.e.: 4.92 kJ/m2. The hardener fraction of 0.5 has the highest impact strength i.e.: 4.55 kJ/m2. The fiber powder content of 8% produced the highest shear strength i.e.: 1.00 MPa. Meanwhile, the hardener fraction of 0.6 has the highest shear strength i.e.: 2.03 MPa.


2015 ◽  
Vol 1113 ◽  
pp. 23-27 ◽  
Author(s):  
Alireza Fakhari ◽  
Abdul Razak Rahmat ◽  
Mat Uzir Wahit ◽  
Amirali Khalili ◽  
Zyad Salem Alsagayar

In this study a series of green thermoset resins have been produced from blending acrylated epoxidized palm oil (AEPO) and unsaturated polyester (UPE). The UPE/AEPO ratio was changed between 90/10 and 70/30 wt%. The curing behavior and morphology of hybrid systems were investigated by differential scanning calorimeter (DSC) and Scanning electron microscope (SEM). Moreover, studies on mechanical properties were performed by tensile and flexural tests. The results revealed that, these green thermoset resins exhibit thermo mechanical properties comparable to those of commercial unsaturated polyesters.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Jong Sung Won ◽  
Ji Eun Lee ◽  
Da Young Jin ◽  
Seung Goo Lee

The effective utilization of original natural fibers as indispensable components in natural resins for developing novel, low-cost, eco-friendly biocomposites is one of the most rapidly emerging fields of research in fiber-reinforced composite. The objective of this study is to investigate the interfacial adhesion properties, water absorption, biodegradation properties, and mechanical properties of the kenaf/soy protein isolate- (SPI-) PVA composite. Experimental results showed that 20 wt% poly (vinyl alcohol) (PVA) and 8 wt% glutaraldehyde (GA) created optimum conditions for the consolidation of the composite. The increase of interfacial shear strength enhanced the composites flexural and tensile strength of the kenaf/SPI-PVA composite. The kenaf/SPI-PVA mechanical properties of the composite also increased with the content of cross-linking agent. Results of the biodegradation test indicated that the degradation time of the composite could be controlled by the cross-linking agent. The degradation rate of the kenaf/SPI-PVA composite with the cross-linking agent was lower than that of the composite without the cross-linking agent.


RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58821-58831 ◽  
Author(s):  
Yiqun Wang ◽  
Kaichang Kou ◽  
Guanglei Wu ◽  
Ailing Feng ◽  
Longhai Zhuo

A high-performance polymer composite was fabricated using Bz-allyl/BMI/BADCy resin, in which the BMI/BADCy resin was modified with Bz-allyl to improve its dielectric, thermal and mechanical properties and the cross-linking degree after curing.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Chern Chiet Eng ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Hidayah Ariffin ◽  
Wan Md. Zin Wan Yunus

Natural fiber as reinforcement filler in polymer composites is an attractive approach due to being fully biodegradable and cheap. However, incompatibility between hydrophilic natural fiber and hydrophobic polymer matrix restricts the application. The current studies focus on the effects of incorporation of silane treated OPMF into polylactic acid (PLA)/polycaprolactone (PCL)/nanoclay/OPMF hybrid composites. The composites were prepared by melt blending technique and characterize the composites with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR spectra indicated that peak shifting occurs when silane treated OPMF was incorporated into hybrid composites. Based on mechanical properties results, incorporation of silane treated OPMF enhances the mechanical properties of unmodified OPMF hybrid composites with the enhancement of flexural and impact strength being 17.60% and 48.43%, respectively, at 10% fiber loading. TGA thermogram shows that incorporation of silane treated OPMF did not show increment in thermal properties of hybrid composites. SEM micrographs revealed that silane treated OPMF hybrid composites show good fiber/matrix adhesion as fiber is still embedded in the matrix and no cavity is present on the surface. Water absorption test shows that addition of less hydrophilic silane treated OPMF successfully reduces the water uptake of hybrid composites.


2010 ◽  
Vol 139-141 ◽  
pp. 235-238
Author(s):  
De Qiang Wei

In this paper, the low alloy bainite ductile cast iron has been obtained by a new heat treatment technique of the step austempering in room-temperature machine oil. The effects of element boron, manganese and copper on structure and mechanical properties of the bainite ductile cast Iron in above-mentioned process are investigated. The phenomenon, hardness lag of the alloyed bainite ductile cast Iron, has been discussed. It shows that after the step austempering in room-temperature machine oil, the hardness will increases with the time. It is found that boron and manganese can increase the hardness and reduce the impact strength while copper can increase the impact strength. The results show that reasonable alloyed elements can improve mechanical properties of the bainite ductile cast Iron. Essentially, hardness lag of the alloyed bainite ductile cast Iron is resulted from solute drag-like effect.


2017 ◽  
Vol 748 ◽  
pp. 39-44 ◽  
Author(s):  
Stefano Merighi ◽  
Emanuele Maccaferri ◽  
Juri Belcari ◽  
Andrea Zucchelli ◽  
Tiziana Benelli ◽  
...  

Interaction between poly (m-phenylene isophtalamide) (PMIA) electrospun nanofibers and commercial epoxy resin precursor during the cross-linking process was investigated, in order to use such polyaramidic nanofibers for composite materials reinforcement. Hence nanofibrous PMIA mats were produced via electrospinning technique to be used for the functional modification of the epoxy matrix composite properties. When adding such fibers to an epoxy resin precursor, it was observed a strong influence on the kinetics of its curing process. The final results, however, demonstrates that boosting the reaction condition (raising the temperature and the reaction time) the curing is pushed to completion, indicating that the cross-linking process of the resin is just delayed and not completely hampered. It will be therefore necessary to rethink the composite cure cycle when PMIA nanofibers are added to the composite material, in order to attain significant improvement of the final composite performance.


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