Study of Dielectric and Physicochemical Parameters Dependencies in Engine Oils during Exploitation

2016 ◽  
Vol 838 ◽  
pp. 71-77
Author(s):  
Nikolay Sugatov ◽  
Anvar Ashatovich Khaziev

This paper gives a study of working oil with the dielectric parameters determining device. The correlation analysis of the dielectric and the physicochemical properties of motor oils was carried out.

Foods ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 86
Author(s):  
So-Ra Yoon ◽  
Yun-Mi Dang ◽  
Su-Yeon Kim ◽  
Su-Yeon You ◽  
Mina K. Kim ◽  
...  

Capsaicinoid content, among other factors, affects the perception of spiciness of commercial kimchi. Here, we investigated whether the physicochemical properties of kimchi affect the spicy taste of capsaicinoids perceived by the tasting. High-performance liquid chromatography (HPLC) was used to evaluate the capsaicinoid content (mg/kg) of thirteen types of commercial kimchi. The physicochemical properties such as pH, titratable acidity, salinity, free sugar content, and free amino acid content were evaluated, and the spicy strength grade was determined by selected panel to analyze the correlation between these properties. Panels were trained for 48 h prior to actual evaluation by panel leaders trained for over 1000 h according to the SpectrumTM method. Partial correlation analysis was performed to examine other candidate parameters that interfere with the sensory evaluation of spiciness and capsaicinoid content. To express the specific variance after eliminating the effects of other variables, partial correlations were used to estimate the relationships between two variables. We observed a strong correlation between spiciness intensity ratings and capsaicinoid content, with a Pearson’s correlation coefficient of 0.78 at p ≤ 0.001. However, other specific variables may have influenced the relationship between spiciness intensity and total capsaicinoid content. Partial correlation analysis indicated that the free sugar content most strongly affected the relationship between spiciness intensity and capsaicinoid content, showing the largest first-order partial correlation coefficient (rxy/z: 0.091, p ≤ 0.01).


Agriculture ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 374
Author(s):  
Teresa Szczęsna ◽  
Ewa Waś ◽  
Piotr Semkiw ◽  
Piotr Skubida ◽  
Katarzyna Jaśkiewicz ◽  
...  

The aim of this study was to determine the influence of storage temperature and time on physicochemical parameters of starch syrups recommended for the winter feeding of bee colonies. The studies included commercially available three starch syrups and an inverted saccharose syrup that were stored at different temperatures: ca. 20 °C, 10–14 °C, and ca. 4 °C. Physicochemical parameters of fresh syrups (immediately after purchase) and syrups after 3, 6, 9, 12, 15, 18, 21, and 24 months of storage at the abovementioned temperatures were measured. It was observed that the rate of unfavorable changes in chemical composition of starch syrups and the inverted saccharose syrup, mainly the changes in the 5-hydroxymethylfurfural (HMF) content, depended on the type of a syrup and storage conditions (temperature, time). Properties of tested starch syrups intended for winter feeding of bees stored at ca. 20 °C maintained unchanged for up to 6 months, whereas the same syrups stored at lower temperatures (10–14 °C) maintained unchanged physicochemical parameters for about 12 months. In higher temperatures, the HMF content increased. To date, the influence of this compound on bees has not been thoroughly investigated.


Biomedicines ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 10
Author(s):  
Feby Wijaya Pratiwi ◽  
Chien-Chung Peng ◽  
Si-Han Wu ◽  
Chiung Wen Kuo ◽  
Chung-Yuan Mou ◽  
...  

Mesoporous silica nanoparticles (MSNs) have emerged as a prominent nanomedicine platform, especially for tumor-related nanocarrier systems. However, there is increasing concern about the ability of nanoparticles (NPs) to penetrate solid tumors, resulting in compromised antitumor efficacy. Because the physicochemical properties of NPs play a significant role in their penetration and accumulation in solid tumors, it is essential to systematically study their relationship in a model system. Here, we report a multihierarchical assessment of the accumulation and penetration of fluorescence-labeled MSNs with nine different physicochemical properties in tumor spheroids using two-photon microscopy. Our results indicated that individual physicochemical parameters separately could not define the MSNs’ ability to accumulate in a deeper tumor region; their features are entangled. We observed that the MSNs’ stability determined their success in reaching the hypoxia region. Moreover, the change in the MSNs’ penetration behavior postprotein crowning was associated with both the original properties of NPs and proteins on their surfaces.


2021 ◽  
Vol 9 (3) ◽  
pp. 039-047
Author(s):  
Edori ES ◽  
Iyama WA ◽  
Awari JO

The levels of physicochemical properties of Mini Whuo Stream in Port Harcourt, Rivers State, Nigeria was evaluated. The physicochemical parameters were analyzed using standard conventional procedures. The average values recorded for the physicochemical parameters during the months of investigation were in the range; temperature; 30.00±0.42-30.26±0.83oC, with all-round mean of 30.14±0.47oC, pH; 6.22±0.33-6.42±0.25 (6.29±0.29), electrical conductivity; 146.01±74.04-147.26±75.13µS/cm (146.58±74.69 µS/cm), total alkalinity; 61.63±6.37-62.20±6.41mg/L (61.91±6.41 mg/L), sulphates; 109.67±51.34-110.67±51.88mg/L (110.22±51.81 mg/L), nitrates; 12.20±2.38-12.60±2.86mg/L (12.31±2.65 mg/L), turbidity; 49.32±1.49-50.18±2.02 NTU(49.83±1.55 NTU), TDS; 74.20±36.43-75.61±37.50 mg/L (75.00±36.81 mg/L), TSS; 27.14±2.12-28.37±0.78mg/L (27.64±1.89 mg/L), chlorides; 15.17±2.90-15.66±2.70mg/L (15.34±2.65 mg/L) and salinity; 24.36±4.83-24.82±4.97mg/L (24.66±4.78 mg/L). The evaluation of the physicochemical parameters showed that the Mini Whuo Stream has been contaminated due to human activities within the stream and therefore adequate measures should be taken to forestall the present situation of the stream in order to mitigate any possible increase in deterioration of the studied physicochemical parameters in the stream beyond acceptable limit.


Author(s):  
AKM Sarwar Inam ◽  
R Ahmmed ◽  
MA Haque

This study described the comparison of different physicochemical parameters between fresh and frozen lamb meat. The pH measurement for fresh and frozen lamb meat did not show a significant difference. CIE L*a*b* (Commission Internationale de l'éclairage) color measurement technique was used and ∆E (distance between 2 colors) was found 5.32. On shrinkage measurement, there were significant differences (p<0.05) between the fresh and frozen meat. Frozen lamb sample showed 26.99% shrinkage compared to the fresh lamb which showed 18.09% shrinkage. The thawing loss did not show any significant difference. For texture analysis force and work were evaluated together for both fresh and frozen samples through Warner Bratzler texture analysis. The values did not show any significant difference. The absolute values of force and work were significantly different (p<0.05). Water binding capacity of the frozen and fresh sample were 56.57% and 59.27%, respectively. The moisture contents of fresh and frozen sample were 73.64% and 72.85%, respectively. Fat contents of fresh and frozen sample were 5.08% and 6.09% respectively. The study concludes that while comparing fresh and frozen lamb, only shrinkage and texture analysis showed significant difference whereas other physicochemical properties showed minor differences.J. Bangladesh Agril. Univ. 15(2): 281-288, December 2017


Tribologia ◽  
2020 ◽  
Vol 290 (2) ◽  
pp. 47-53
Author(s):  
Jarosław MOLENDA ◽  
Zbigniew PAWELEC ◽  
Ewa PAWELEC ◽  
Bernadetta KAŹMIERCZAK

The article presents the results of tests on tribological and physicochemical properties of plastic greases, in which the dispersing phase was highly refined mineral oil and the dispersed phase (thickener) lithium stearate. The functional additives were biocarbon, which were obtained in the pyrolysis process of waste of natural origin, i.e. stems with corn leaves, wheat straw, flax straw, and cherry stones. The compositions containing 5% m/m biocarbon were prepared. Their evaluated on the functional properties of plastic greases was assessed. Tribological characteristics of the greases compositions were determined using the T-02 tester in accordance with the requirements of the subject standards. The effect of biocarbon used on anti-wear (Goz) and anti-seizing (Pt, poz) plastic greases was determined. An assessment was also made of the effect of plant biocarbon on changes in basic physicochemical properties of the composition of plastic greases, i.e. penetration, dropping temperature, and thermo-oxidative stability. It was found that some of the biocarbon significantly improve the tribological properties of plastic greases without significantly affecting the change of key physicochemical parameters. The most beneficial impact of the tested additives on the operational properties of plastic greases was observed when using biocarbon from wheat straw. In some cases, a lower oxidative resistance of biocarbon grease is observed compared to grease without the addition of biocarbon.


Author(s):  
А.А. СИМДЯНКИН ◽  
И.А. УСПЕНСКИЙ ◽  
М.Н. СЛЮСАРЕВ

Проблема и цель. Целью настоящего исследования является оценка влияния частоты ультразвука на смазочные свойства моторных масел и износ узлов трения двигателей при ультразвуковой обработке масел. Методология. Предметом исследований является ультразвуковая обработка моторных масел и вызываемые ею изменения износа узлов трения. Были проведены следующие эксперименты: оценка влияния частоты ультразвука на изменение коэффициента поверхностного натяжения моторных масел при их ультразвуковой обработке; оценка влияния частоты ультразвуковой обработки смазки на износ образцов пар трения при износных испытаниях образцов на машине трения 2070 СМТ 1М. Обработка моторного масла ультразвуком проводилась с помощью экспериментального устройства для генерации ультразвука переменной частоты. Обработке подвергались моторные масла: масло моторное «LukoilDIESELOIL» 10W-40 минеральное; масло моторное «SHELL Helix HX7 Diesel» 10W-40 полусинтетическое; масло моторное «ZIC X7 Diesel» 10W-40 синтетическое. Результаты. Были получены расчетно-экспериментальные зависимости коэффициента поверхностного натяжения от частоты ультразвукового сигнала для минерального, полусинтетического и синтетического моторных масел, а также зависимости фактора износа образцов пар трения от частоты ультразвука длясинтетического моторного масла.Определен диапазон частот ультразвука (17-44 кГц), при котором ультразвуковая обработка синтетического моторного масла дает наибольшее снижение износа пар трения Заключение. На основании проведенных исследований рекомендуется проводить обработку моторного масла ультразвуком в диапазоне частот от 17 до 44 кГц. Рекомендуется также продолжение работ по доработке устройства для генерации ультразвука оптимальной частоты и адаптации его в систему смазки реальных дизельных автотракторных двигателей. Problem and purpose. The purpose of this study was to assess the efect of ultrasound frequency on lubricating properties of engine oils and the wear of friction units of engines when ultrasonic treatment of oils. Methodology. The subject of the research was the ultrasonic treatment of engine oils and the changes in the wear of friction units caused by it. The following experiments were carried out: evaluation of the efect of the ultrasound frequency on the change in the surface tension coefcient of motor oils when their ultrasonic treatment; evaluation of the efect of the frequency of ultrasonic treatment of the lubricant on the wear of samples of friction pairs during wear tests of samples on a 2070 SMT 1M friction machine. Ultrasonic treatment of engine oil was carried out using an experimental device for generating ultrasound of variable frequency. The following engine oils were processed: motor oil "Lukoil DIESEL OIL" 10W-40 mineral; motor oil "SHELL Helix HX7 Diesel" 10W-40 semi-synthetic and motor oil "ZIC X7 Diesel" 10W-40 synthetic. Results. Authors got calculated and experimental dependences of the surface tension coefcient on the frequency of an ultrasonic signal for mineral, semi-synthetic and synthetic motor oils, as well as the dependence of the wear factor of samples of friction pairs on the frequency of ultrasound for synthetic engine oil. The frequency range of ultrasound (17-44 kHz) was determined, in which the ultrasonic treatment of synthetic motor oil gave the greatest reduction in the wear of friction pairs. Conclusion. Based on the studies carried out, it is recommended to treat engine oil with ultrasound in the frequency range from 17 to 44 kHz. It is also recommended to continue work on improving the device for generating ultrasound of the optimal frequency and adapting it to the lubrication system of real diesel automotive engines.


2021 ◽  
Vol 264 ◽  
pp. 04043
Author(s):  
Nargiza Kholikova ◽  
Bakhodir Khakimov ◽  
Saydilla Alikulov ◽  
Nargiza Ravshanova ◽  
Ajargul Mambetsheripova

The study aims to substantiate the parameters and operating mode of the oil purification device from oxidation products to improve the efficiency of the use of lubricants. The methods of mathematical analysis and mathematical statistics, comparative comparison, generalization, and testing methods of agricultural machinery are used in the research process. It is established that engine oils are intensively polluted by oxidation products during processing, thereby accelerating the friction process due to the overload of tractor engines. During the performance of agricultural work in the oil composition, the content of oxidation products in the form of carbon, carbon dioxide, and asphalt products increases by 1.2%. Analytical coupling dependences for the process of cleaning motor oils from oxidizing products are obtained, and the dependence of the cleaning efficiency on the device parameters is established. The developed device consists of a container for collecting oils, a steam generator, a container for a sump mixer, a separate container for pure and sedimentary oils, and a vessel for re-collecting acetone. An installation has been developed to implement the technology of collecting and renewing oils in the conditions of the farm. In this case, the amount of contamination and the composition of oils is determined, and the operating mode of the device is selected for their resumption.


Author(s):  
Vojtěch Kumbár ◽  
Adam Polcar ◽  
Jiří Čupera

The objective of this paper is to find changes of a rheological profile of the new engine oil if the used engine oil will be add. And also find changes of a rheological profile of the used engine oil if the new engine oil will be add. For these experiments has been created the blends of the new and the used engine oil. The temperature dependence of the density [kg.m−3] has been measured in the range of −10 °C and +60 °C. The instrument Densito 30PX with the scale for measuring engine oils has been used. The dynamic viscosity [mPa.s] has been measured in the range of −10 °C and +100 °C. The Anton Paar digital viscometer with the concentric cylinders geometry has been used. In the accordance with the expected behaviour, the density and the kinematic viscosity of all oils was decreasing with the increasing temperature. To the physical properties has been the mathematical models created. For the temperature dependence of the density has been used the linearly mathematical model and the exponentially mathematical model. For the temperature dependence of the dynamic viscosity has been used the polynomial 6th degree. The knowledge of density and viscosity behaviour of an engine oil as a function of its temperature is of great importance, especially when considering running efficiency and performance of combustion engines. Proposed models can be used for description and prediction of rheological behaviour of engine oils.


Sign in / Sign up

Export Citation Format

Share Document