Preparation of Chitosan-Alginate/PES Pervaporation Membranes for Bioethanol Dehydration

2015 ◽  
Vol 1123 ◽  
pp. 182-186 ◽  
Author(s):  
Mumpuni Asih Pratiwi ◽  
Ronny Windu Sudrajat ◽  
Sri Sutanti ◽  
Heru Susanto
Keyword(s):  
Surface Morphology ◽  
Surface Chemistry ◽  
Composite Membrane ◽  
Membrane Surface ◽  
Composite Membranes ◽  
Solution Concentration ◽  
Wave Number ◽  
Water Mixture ◽  
Coating Solution ◽  
Degree Of Swelling

In the last decade pervaporation membrane has become an antractive dehydration processs for azeotropic ethanol-water mixture. In this paper, chitosan-alginate/polyethersulfone (PES) composite membranes were prepared (by coating method) characterized as pervaporation membranes. The composite membranes were then examined to purify ethanol-water mixture. The characterization included degree of swelling both in water and ethanol, permeability measurement, surface morphology (by SEM) and surface chemistry (by FTIR). The results show that the increase in concentration of coating solution increases the degree of swelling in the water on the one hand, whereas the permeability and the degree of swelling in the ethanol decreases on the other hand. The highest permeability was obtained for the composite membrane prepared from a coating solution concentration of 1% with the ratio of chitosan to alginate was 0,33. The surface chemistry shows that the increase in concentration of chitosan - alginate solution increases the intensity of a specific wave number of C-O and C-N groups. Surface morphology indicates that the PES membrane surface is clearly covered by chitosan - alginate mixture. Performance examination demonstrates that the composite membrane prepared by 3% a coating solution (with the ratio of chitosan to alginate 3) can increase the bioethanol concentration from 95.5% to 99.6%.

scholarly journals EFFECT OF BENTONITE AS FILLER IN COMPOSITE MEMBRANE PERFORMANCE POLYVINYLIDENE FLUORIDE (PVDF)-POLYMETHYLMETHACRYLATE (PMMA)

2018 ◽  
Vol 18 (1) ◽  
pp. 26-31
Author(s):  
Erda Marniza ◽  
Marlina . ◽  
M Nasir
Keyword(s):  
Composite Membrane ◽  
Polyvinylidene Fluoride ◽  
Oil And Gas ◽  
Tween 80 ◽  
Composite Membranes ◽  
Wave Number ◽  
Water Model ◽  
Inversion Method ◽  
Ftir Characterization ◽  
Oily Waste

Abstract. The effect of bentonite as filler on the performance of the composite membrane of PVDF-PMMA has been performed. This study was conducted to determine the performance PVDF-PMMA composite membranes and membrane applications PVDF-PMMA-Bentonite on oily wastes. Bentonite is obtained from North Aceh while PVDF membrane-PMMA by phase inversion method. This study uses an oily waste water model was made by mixing surfactant tween 80 with concentration of 2% with palm oil and gas oil. Membrane PVDF-PMMA-Bentonite is analyzing using cell ultrafiltration (flux test), FTIR and SEM-EDX. The results showed that the value of flux with the addition of bentonite is greater than without bentonite. Good flux values contained in the PVDF-PMMA-Bentonite (1:1:2) amounted to 32.143 L/m2.h.bar with permeability of 21.428 L/m2.h. FTIR characterization analysis results show that bentonite can add to pore at wave number 1520 cm -1 and 1660 cm-1 SEM and EDX results showed regular shape and uniform pore. Keywords: Membrane, bentonite, filler, FTIR, SEM-EDX, Oily wastewater 

Pervaporation of Ethyl Acetate-Water Mixture through Sago/PVA Blend Membranes Cross-Linked with Glutaraldehyde

2014 ◽  
Vol 695 ◽  
pp. 167-169
Author(s):  
Abdulhakim M. Alamaria ◽  
Mohd Ghazali Mohd Nawawi ◽  
Zafifah Zamrud
Keyword(s):  
Ethyl Acetate ◽  
Composite Membrane ◽  
Water Concentration ◽  
Feed Solution ◽  
Scanning Electron Micrographs ◽  
Water Mixture ◽  
Varied Temperature ◽  
Degree Of Swelling ◽  
Blend Membranes ◽  
Scanning Electron

Sago composite membrane possesses a microporous polysulfone substrate were prepared and tested for dehydration of ethyl acetate/water mixture. Sago composite membrane has been cross-linked successfully by glutaraldehyde. The membranes were characterized by Degree of swelling (DS) and scanning electron micrographs (SEM). Pervaporation of ethyl acetate –water mixture was conducted over a range of water concentration (1-4wt %) in feed solution at varied temperature from 30°C to 60°C. KeywordsSagostarch:Pervaporation;Ethylacetate;Polyvinylalcohol;CompositeMembrane;

scholarly journals Performance of Composite Membrane for Palm Oil Wastewater Treatment

2019 ◽  
Vol 23 (2) ◽  
Author(s):  
E. Yuliwati ◽  
H. Porawati ◽  
Elfidiah Elfidiah ◽  
A. Melani
Keyword(s):  
Pore Size ◽  
Surface Properties ◽  
Composite Membrane ◽  
Palm Oil ◽  
Average Pore Size ◽  
Membrane Surface ◽  
Composite Membranes ◽  
Separation Performance ◽  
Average Pore ◽  
Oil Wastewater

Polyvinylidene fluoride (PVDF) composite membranes were prepared via phase inversion method by dispersing titanium dioxide (TiO2) in the dope solution. It is aimed to study the effects of TiO2 on the membrane surface properties and thus its separation performance. The PVDF membranes modified by various TiO2 contents were characterized with respect to cross-sectional structure, average pore size, effective porosity, hydrophilicity, permeability and rejection. Maximum values of membrane hydrophilicity, membrane porosity and average pore size were achieved upon addition of 1.95% TiO2. It is found that changes in the membrane surface properties are closely corresponded with the membrane fouling. The maximum flux and rejection of organic pollutants from palm oil wastewater were recorded at 82.5 L/m2 h and 98.8 %, respectively using PVDF composite membrane incorporated with 1.95% TiO2.

Preparation of Pd Composite Membrane and its Surface Morphological Changes after Elevating Temperature in Different Atmoshphere

2014 ◽  
Vol 941-944 ◽  
pp. 1602-1605 ◽  
Author(s):  
Yu Guo ◽  
Yu Jia Jin ◽  
Hong Mei Wu ◽  
Dong Xin Li ◽  
Li Dai Zhou ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Composite Membrane ◽  
Morphological Changes ◽  
Membrane Surface ◽  
Composite Membranes ◽  
X Ray ◽  
Air Atmosphere ◽  
Pd Membrane ◽  
Ideal Selectivity ◽  
Scanning Electron

Pd composite membranes were prepared on macroporous α-Al2O3 tubes modified by silicalite-1 zeolite. Permeation tests of the Pd composite membranes were performed at 773 K to observe the H2 permeance and H2/N2 selectivity. The H2 flux and ideal selectivity for Pd composite membrane was 0.120 mol m−2 s−1 and 450 under 0.1 MPa, respectively. The variation of the membrane surface after elevating temperature in N2 and air atmosphere was characterized in scanning electron microscopy (SEM) and energy dispersive X-ray spectrometer (EDS) analyses. As a result, it can be concluded that the formation of pinholes and defects on the membrane surface can be attributed to the oxidation of the Pd membrane.

scholarly journals Engineered Nanoparticles with Decoupled Photocatalysis and Wettability for Membrane-Based Desalination and Separation of Oil-Saline Water Mixtures

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1397
Author(s):  
Bishwash Shrestha ◽  
Mohammadamin Ezazi ◽  
Gibum Kwon
Keyword(s):  
Membrane Fouling ◽  
Municipal Wastewater ◽  
Uv Light ◽  
Saline Water ◽  
Membrane Surface ◽  
Sio2 Nanoparticles ◽  
Engineered Nanoparticles ◽  
Water Mixture ◽  
Organic Substances ◽  
Suspended Substances

Membrane-based separation technologies are the cornerstone of remediating unconventional water sources, including brackish and industrial or municipal wastewater, as they are relatively energy-efficient and versatile. However, membrane fouling by dissolved and suspended substances in the feed stream remains a primary challenge that currently prevents these membranes from being used in real practices. Thus, we directly address this challenge by applying a superhydrophilic and oleophobic coating to a commercial membrane surface which can be utilized to separate and desalinate an oil and saline water mixture, in addition to photocatalytically degrading the organic substances. We fabricated the photocatalytic membrane by coating a commercial membrane with an ultraviolet (UV) light-curable adhesive. Then, we sprayed it with a mixture of photocatalytic nitrogen-doped titania (N-TiO2) and perfluoro silane-grafted silica (F-SiO2) nanoparticles. The membrane was placed under a UV light, which resulted in a chemically heterogeneous surface with intercalating high and low surface energy regions (i.e., N-TiO2 and F-SiO2, respectively) that were securely bound to the commercial membrane surface. We demonstrated that the coated membrane could be utilized for continuous separation and desalination of an oil–saline water mixture and for simultaneous photocatalytic degradation of the organic substances adsorbed on the membrane surface upon visible light irradiation.

scholarly journals New Synthetic Methods of Novel Nanoporous Polycondensates and Excellent Oxygen Permselectivity of Their Composite Membranes

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 859
Author(s):  
Yu Zang ◽  
Toshiki Aoki ◽  
Masahiro Teraguchi ◽  
Takashi Kaneko ◽  
Hongge Jia ◽  
...  
Keyword(s):  
Contact Angle ◽  
Upper Bound ◽  
Oxygen Permeability ◽  
Membrane Surface ◽  
Composite Membranes ◽  
Synthetic Methods ◽  
Preparation Methods ◽  
First Time

Two kinds of novel nanoporous polycondensates (sc(Rf)) have been synthesized by two new preparation methods consisting of polycondensation and highly selective photocyclicaromataization of 1/3 helical cis-cis polyphenylacetylenes with polymerizable groups. By the original methods, new well-defined sheet polymers having nanopores or nanospaces have been synthesized for the first time. Their composite membranes, containing small amounts (1.0 wt%) of sc(Rf), had ultrahigh oxygen permeability (Po2 > 1000 barrer), and their plots were beyond the Robeson’s upper bound line in the graph of oxygen permselectivity (α = Po2/PN2) versus Po2. Both α and Po2 values were enhanced by adding only small amounts (1.0 wt%) of sc(Rf). One of the sc(Rf)s synthesized on the base membrane surface showed the best performance, i.e., Po2 = 5300 barrer and α = 2.5. The membrane surface was effectively covered by sc(Rf), judging from the contact angle values. It is thought that nanopores and nanospaces created in and between sc(Rf) molecules played an important role for the enhancement of both α and Po2/PN2.

Nafion/PBI Nanofiber Composite Membranes for Fuel Cells Applications

2010 ◽  
Author(s):  
Tzyy-Lung Leon Yu ◽  
Shih-Hao Liu ◽  
Hsiu-Li Lin ◽  
Po-Hao Su
Keyword(s):  
Thin Film ◽  
Fuel Cell ◽  
Composite Membrane ◽  
Fiber Composite ◽  
Composite Membranes ◽  
Cell Performance ◽  
Membrane Electrode ◽  
Membrane Thickness ◽  
Fuel Cell Performance ◽  
Nano Fiber

The PBI (poly(benzimidazole)) nano-fiber thin film with thickness of 18–30 μm is prepared by electro-spinning from a 20 wt% PBI/DMAc (N, N′-dimethyl acetamide) solution. The PBI nano-fiber thin film is then treated with a glutaraldehyde liquid for 24h at room temperature to proceed chemical crosslink reaction. The crosslink PBI nano-fiber thin film is then immersed in Nafion solutions to prepare Nafion/PBI nano-fiber composite membranes (thickness 22–34 μm). The morphology of the composite membranes is observed using a scanning electron microscope (SEM). The mechanical properties, conductivity, and unit fuel cell performance of membrane electrode assembly (MEA) of the composite membrane are investigated and compared with those of Nafion-212 membrane (thickness ∼50 μm) and Nafion/porous PTFE (poly(tetrafluoro ethylene)) composite membrane (thickness ∼22 μm). We show the present composite membrane has a similar fuel cell performance to Nafion/PTFE and a better fuel cell performance than Du Pont Nafion-212.

scholarly journals Unprecedented SPEEK-trimetal Oxide Composites: Physicochemical and Electrochemical Performance in Fuel Cell

2021 ◽  
Author(s):  
Gandhimathi Sivasubramanian ◽  
Senthil Andavan Gurusamy Thangavelu ◽  
Berlina Maria Mahimai ◽  
Krishnan Hariharasubramanian ◽  
PARADESI DEIVANAYAGAM
Keyword(s):  
Fuel Cell ◽  
Electrochemical Performance ◽  
Composite Membrane ◽  
Composite Membranes ◽  
Membrane Electrode Assembly ◽  
Membrane Electrode ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Maximum Water ◽  
Oxide Composites

Abstract Advanced polymer composite membranes were prepared from a linear sulfonated poly(ether ether ketone) (SPEEK) with bismuth cobalt zinc oxide [BCZO, (Bi2O3)0.07(CoO)0.03(ZnO)0.90] nanopowder as an inorganic additive for the application of H2-O2 fuel cell. Morphology data tend to provide evidences for the incorporation of BCZO into SPEEK polymer. Indeed, composite membrane loaded with 7.5 wt.% of BCZO was identified to uptake maximum water, while the pristine SPEEK membrane occurred to retain only 24.0 %. As such SPEEK matrix loaded with 7.5 wt.% of BCZO was found to exhibit the maximum proton conductivity of 0.030 S cm-1, whereas the pristine membrane was restricted to 0.021 S cm-1. Evidently, TGA profile of the composite membrane was measured to exhibit sufficient thermal stability to employ as electrolyte in fuel cell. The membrane electrode assembly of pristine SPEEK and SP-BCZO-7.5 wt.% membranes were fabricated and studied for their electrochemical performance. Indeed, the characteristics of newly developed composite membranes led to possess incredible feature towards fuel cell applications.

scholarly journals Thin Film Nanofibrous Composite Membrane for Dead-End Seawater Desalination

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Baturalp Yalcinkaya ◽  
Fatma Yalcinkaya ◽  
Jiri Chaloupek
Keyword(s):  
Thin Film ◽  
Active Layer ◽  
Composite Membrane ◽  
Interfacial Polymerization ◽  
Composite Membranes ◽  
Nanofibrous Scaffold ◽  
Filtration Method ◽  
Salt Ions ◽  
Dead End ◽  
Supporting Material

The aim of the study was to prepare a thin film nanofibrous composite membrane utilized for nanofiltration technologies. The composite membrane consists of a three-layer system including a nonwoven part as the supporting material, a nanofibrous scaffold as the porous surface, and an active layer. The nonwoven part and the nanofibrous scaffold were laminated together to improve the mechanical properties of the complete membrane. Active layer formations were done successfully via interfacial polymerization. A filtration test was carried out using solutions of MgSO4, NaCl, Na2SO4, CaCl2, and real seawater using the dead-end filtration method. The results indicated that the piperazine-based membrane exhibited higher rejection of divalent salt ions (>98%) with high flux. In addition, them-phenylenediamine-based membrane exhibited higher rejection of divalent and monovalent salt ions (>98% divalent and >96% monovalent) with reasonable flux. The desalination of real seawater results showed that thin film nanofibrous composite membranes were able to retain 98% of salt ions from highly saline seawater without showing any fouling. The electrospun nanofibrous materials proved to be an alternative functional supporting material instead of the polymeric phase-inverted support layer in liquid filtration.

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