Thermal Characterization of Bacterial Cellulose/Polyvinyl Alcohol Nanocomposite

2015 ◽  
Vol 1123 ◽  
pp. 303-307 ◽  
Author(s):  
Akhmad Zainal Abidin ◽  
Hafis Pratama Rendra Graha
Keyword(s):  
Bacterial Cellulose ◽  
Melting Temperature ◽  
Healing Process ◽  
Thermal Characteristics ◽  
Cost Effective ◽  
Thermal Characterization ◽  
Fermentation Medium ◽  
Scanning Calorimetry ◽  
Regeneration Rate

Bacterial cellulose (BC) is a natural polymer which can be produced from various substrates easily found in Indonesia. Bacterial cellulose is believed to be a promising and cost effective bone scaffold in which a bone regeneration rate enhanced so the healing process is faster. In this experiment, Bacterial Cellulose (BC)/ Polyvin y l Alcohol (PVA) nanocomposite was made to give a further improvement in the properties. This nanocomposite was made thorough BC biosynthesis in Gluconacetobacter xylinus fermentation medium that was modified by addition of PVA. The PVA concentrations were varied as 0, 3, 6, 9, and 12 % w of fermentation medium. The culture had been agitated by magnetic stirrer for 28 days before freeze drying method was conducted to obtain dry BC/PVA nanocomposite. The product of BC/PVA nanocomposite was then studied for thermal characteristics using Differential Scanning Calorimetry (DSC) and Thermogravimetry Analysis (TGA). Pure BC has melting temperature (Tm) at 350 . 3oC and pure PVA at 181 . 3oC. Experimental results showed that the higher PVA content in fermentation medium decreased the melting temperature of BC/PVA nanocomposite produced.

Mechanical and thermal characterization of grafted PP-NCC nanocomposites

2019 ◽  
pp. 089270571987822
Author(s):  
Saud Aldajah ◽  
Mohammad Y Al-Haik ◽  
Waseem Siddique ◽  
Mohammad M Kabir ◽  
Yousef Haik
Keyword(s):  
Thermal Properties ◽  
Interfacial Adhesion ◽  
Thermal Characterization ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
Three Point Bending ◽  
Twin Screw ◽  
Thermal Stability Of

This study reveals the enhancement of mechanical and thermal properties of maleic anhydride-grafted polypropylene (PP- g-MA) with the addition of nanocrystalline cellulose (NCC). A nanocomposite was manufactured by blending various percentages of PP, MA, and NCC nanoparticles by means of a twin-screw extruder. The influence of varying the percentages of NCC on the mechanical and thermal behavior of the nanocomposite was studied by performing three-point bending, nanoindentation, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR) spectroscopy tests. The novelty of this study stems on the NCC nanoparticles and their ability to enhance the mechanical and thermal properties of PP. Three-point bending and nanoindentation tests revealed improvement in the mechanical properties in terms of strength, modulus, and hardness of the PP- g-MA nanocomposites as the addition of NCC increased. SEM showed homogeneity between the mixtures which proved the presence of interfacial adhesion between the PP- g-MA incorporated with NCC nanoparticles that was confirmed by the FTIR results. DSC and TGA measurements showed that the thermal stability of the nanocomposites was not compromised due to the addition of the coupling agent and reinforced nanoparticles.

scholarly journals Structural, thermal and electrical properties of composites electrolytes (1−x) CsH2PO4/x ZrO2 (0 ≤ x ≤ 0.4) for fuel cell with advanced electrode

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Deshraj Singh ◽  
Pawan Kumar ◽  
Jitendra Singh ◽  
Dharm Veer ◽  
Aravind Kumar ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Solid Acid ◽  
Thermal Characterization ◽  
Dihydrogen Phosphate ◽  
Conducting Material ◽  
Scanning Calorimetry ◽  
Milling Method ◽  
Thermal And Electrical Properties ◽  
Properties Of Composites

AbstractComposites proton conducting material based on cesium dihydrogen phosphate (CDP) doped with zirconium oxide (1−x) CsH2PO4/x ZrO2 were synthesized with different concentration having in the range such as x = 0.1, 0.2, 0.3 and 0.4 by ball milling method. The prepared solid acid composites were dried at 150 °C for 6 h. Structural and thermal characterization of solid acid composite proton electrolytes were carried out by X-ray diffractometer, Fourier transform infrared spectroscopy, and Raman spectroscopy respectively. Phase transition of the prepared materials was carried out by using differential scanning calorimetry and conductivity was measured by LC Impedance meter in the range 1 Hz to 400 kHz. The ionic conductivity of ZrO2 doped CsH2PO4 (CDP) was increased up to 1.3 × 10–2 S cm−1 at the 280 °C under environment atmospheric humidification which showed high stability as compared to pure CsH2PO4 (CDP). This obtaining result would be useful for establishing and design the next generation fuel cell.

scholarly journals Synthesis and Characterization of a Multifunctional Conjugated Polymer

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Emerson C. G. Campos ◽  
Cristiano Zanlorenzi ◽  
Bruno F. Nowacki ◽  
Gabriela M. Miranda ◽  
Denis A. Turchetti ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Molar Mass ◽  
Photophysical Properties ◽  
Gel Permeation Chromatography ◽  
Thermal Characterization ◽  
Polymer Structure ◽  
Synthesis And Characterization ◽  
Metallic Ions ◽  
Scanning Calorimetry

This work reports the synthesis and characterization of a conjugated polymer based on fluorene and terpyridine, namely, poly[(9,9-bis(3-((S)-2-methylbutylpropanoate))fluorene-alt-6,6′-(2,2′:6′,2′′-terpyridin-6-yl)] (LaPPS71). The structure was characterized by 1H and 13C nuclear magnetic resonance (NMR) and Fourier-transform infrared (FTIR) spectroscopy. The molar mass was measured by gel permeation chromatography (GPC). As thermal characterization, the glass transition temperature (Tg) was measured by differential scanning calorimetry (DSC). The polymer structure contains two sites capable of complexation with metallic ions, affording the possibility of obtainment of independent or electronically coupled properties, depending on the complexation site. The photophysical properties were fully explored in solution and solid state, presenting ideal results for the preparation of various metallopolymers, in addition to potential application as a metamaterial, due to the presence of the chiral center in the side chains of the polymer.

scholarly journals Impact of spineless cactus cultivation (O. Ficus-indica) on the thermal characteristics of soil

2018 ◽  
Vol 13 (1) ◽  
pp. 1
Author(s):  
Willames De Albuquerque Soares
Keyword(s):  
Heat Capacity ◽  
Thermal Characteristics ◽  
Thermal Characterization ◽  
Biological Processes ◽  
Volumetric Heat Capacity ◽  
Average Value ◽  
Brazilian Semiarid ◽  
Cultivation Techniques ◽  
Soil Changes

Temperature is a fundamentally important factor for understanding the physical, chemical, and biological processes that occur in soil. However, there are few studies in the Brazilian semiarid zone that seek to understand how soil degradation affects its thermal characteristics. The objective of this study was to evaluate the influence of cultivation techniques on the thermal characterization of soil, using the model proposed by Johansen. The study was conducted in the Agreste region of the state of Pernambuco, Brazil on two plots of land, one with native vegetation (Caatinga) and the other with spineless cactus (O. ficus - indica). It was observed that the procedures used to prepare the soil for cultivation of spineless cactus caused a reduction in the capacity to transmit the surface temperature to the interior of the soil. Changes in the physical properties of the soil required for cultivation resulted in a reduction in the average value of the volumetric heat capacity of about 22%; an increase of approximately 5% in the average volumetric heat capacity and a 26% increase in the thermal diffusivity of the soil, as well as a reduction of approximately 50% in the heat flux from the surface of the soil.

scholarly journals A Facile Synthesis and Characterization of Highly Crystalline Submicro-Sized BiFeO3

Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 3035
Author(s):  
Dovydas Karoblis ◽  
Diana Griesiute ◽  
Kestutis Mazeika ◽  
Dalis Baltrunas ◽  
Dmitry V. Karpinsky ◽  
...  
Keyword(s):  
Bismuth Ferrite ◽  
Cost Effective ◽  
Xrd Analysis ◽  
Synthetic Approach ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Dsc Measurements ◽  
Optimal Annealing Temperature ◽  
Synthesized Materials

In this study, a highly crystalline bismuth ferrite (BFO) powder was synthesized using a novel, very simple, and cost-effective synthetic approach. It was demonstrated that the optimal annealing temperature for the preparation of highly-pure BFO is 650 °C. At lower or higher temperatures, the formation of neighboring crystal phases was observed. The thermal behavior of BFO precursor gel was investigated by thermogravimetric and differential scanning calorimetry (TG-DSC) measurements. X-ray diffraction (XRD) analysis and Mössbauer spectroscopy were employed for the investigation of structural properties. Scanning electron microscopy (SEM) was used to evaluate morphological features of the synthesized materials. The obtained powders were also characterized by magnetization measurements, which showed antiferromagnetic behavior of BFO powders.

scholarly journals THERMAL CHARACTERIZATION OF THE FAVELONE DERIVATIVES (CNIDOSCOLUS QUERCIFOLIUS) BY THERMOGRAVIMETRY AND DIFFERENTIAL SCANNING CALORIMETRY

2006 ◽  
Vol 05 (3) ◽  
pp. 8-20
Author(s):  
José Carlos Oliveira SANTOS ◽  
Lionete Dantas NUNES ◽  
Sylvia Berenice NÓBREGA ◽  
Dantas José Pires PUZINSKI ◽  
Antonio Gouveia SOUZA
Keyword(s):  
Differential Scanning Calorimetry ◽  
Arid Region ◽  
Agricultural Practices ◽  
Thermal Characterization ◽  
Northeastern Brazil ◽  
Scanning Calorimetry ◽  
Semi Arid Region ◽  
Derivatives Of ◽  
Semi Arid

A thermal analysis has been applied to characterization of food and food products. Taking into account the problems of desertification and agricultural practices able to provide income to the population at the semi-arid region of Northeastern Brazil, this work presents the results of the chemical, thermal and kinetic characterization by thermogravimetry and differential scanning calorimetry of the seed derivatives of favelone (cnidoscolus quercifolius), aiming at the application of these materials as an alternative of food source for animals and for the human population at this brazilian region.

Thermal Characterization of Non-Isolated DC to DC Convertor

2011 ◽  
Author(s):  
Shiladitya Chakravorty ◽  
Bahgat Sammakia ◽  
Varaprasad Calmidi
Keyword(s):  
Power Dissipation ◽  
High Performance ◽  
Field Effect Transistors ◽  
Thermal Characteristics ◽  
Thermal Characterization ◽  
Input Voltage ◽  
Thermal Design ◽  
Power Module ◽  
Improved Performance

Improved performance of semiconductor devices in recent years has resulted in consequent increase in power dissipation. Hence thermal characterization of components becomes important from an overall thermal design perspective of the system. This study looks at a high performance non-isolated point of load power module (a DC to DC converter) meant for advanced computing and server applications. Thermal characteristics of the module were experimentally analyzed by placing the power module on a bare test board (with no insulation) inside a wind tunnel with thermocouples attached to it. There were three devices on this module that dissipate power. There were two FETs (Field Effect Transistors) and an inductor which can be considered as sources. The consolidated power dissipation from the module was calculated by measuring the input voltage and input current while keeping the output voltage and current constant. Temperatures at various points on the module and the test card were recorded for different air flow velocities and overall power dissipation. Subsequently this set up was numerically analyzed using a commercially available computational fluid dynamics (CFD) code with the objective of comparing the results with experimental data previously obtained.

scholarly journals Thermal characterization of fibrous aerogel blanket

2019 ◽  
Vol 282 ◽  
pp. 01001 ◽  
Author(s):  
Ákos Lakatos ◽  
Anton Trnik
Keyword(s):  
Thermal Annealing ◽  
Thermal Insulation ◽  
Thermal Characterization ◽  
Insulation Material ◽  
Scanning Calorimetry ◽  
Solid Materials ◽  
Plastic Foams ◽  
Isothermal Heat Treatments ◽  
New Buildings

Nowadays, the application of thermal insulation materials both by the existing and by new buildings is one of the most important actions in order to reduce the energy loss of buildings. Besides the use of the conventional insulations (plastic foams and wool materials) aerogel is one of the most promising thermal insulation material. Aerogels, one of the lightest solid materials available today, are manufactured through the combination of a polymer with a solvent forming a gel. For buildings the fibre reinforced ones are the mainly used types. It is produced by adding the liquid-solid solution to the fibrous batting. In this paper changes in the thermal performance of the aerogel blanket will be followed after thermal annealing. The samples will be put under isothermal heat treatments at 70 °C for 6 weeks, as well as they will be put under thermal treatment at higher temperatures (from 70 °C till 210 °C) for 1 day. The changes in the thermal conductivity will be followed by Holometrix Lambda heat flow meter, as well as, Differential Scanning Calorimetry results will be presented. From the measured values, thermal properties will be calculated. In this paper we will try to clarify the role played by thermal annealing in thermal diffusivity.

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