Thermodynamics Analysis of Hot Metal Dephosphorization Flux Reaction Process

2011 ◽  
Vol 402 ◽  
pp. 354-357
Author(s):  
Hui Ding ◽  
Yan Jin ◽  
Zhi Bing Tian ◽  
Dan Jiang Wu
Keyword(s):  
Calcium Phosphate ◽  
Solid Phase ◽  
Equilibrium Temperature ◽  
Quality Data ◽  
Hot Metal ◽  
Phosphate Capacity ◽  
Different Temperatures ◽  
Factsage Software ◽  
The Right ◽  
Calculation Software

In this paper, CaO-Fe2O3-CaCl2and CaO-Fe3O4-CaCl2system dephosphorizer depho- -sphorization of the thermodynamics of the use of FactSage thermodynamic calculation software Equilib module of hot metal dephosphorization flux and the balance between the response calculated, to find the right dephosphorizer dephosphorization ratio and the conditions for optimal phosphorus removal. First of all, by the beginning of slag and the final calculated optical basicity slag and phosphate capacity, calculated on the balance FactSage software phosphorus content mapping, and comparative analysis. Followed by software at different temperatures to calculate the iron liquid, liquid slag, slag liquid solid phase of calcium phosphate and calcium phosphate and quality data on the thermodynamic equilibrium temperature mapping analysis..

scholarly journals The Effect of Slag on the Effectiveness of Phosphorus Removal from Ferrous Alloys Containing Carbon, Chromium and Nickel

2016 ◽  
Vol 61 (1) ◽  
pp. 301-306
Author(s):  
E. Kawecka-Cebula ◽  
M. Karbowniczek ◽  
I. Suliga
Keyword(s):  
Phosphorus Removal ◽  
Solid Phase ◽  
Equilibrium Composition ◽  
Favourable Effect ◽  
Chemical Compositions ◽  
Regression Equations ◽  
Hot Metal ◽  
Ferrous Alloys ◽  
Phosphate Capacity ◽  
The Impact

The aim of this study was to determine the impact of slag composition on phosphorus removal from ferrous solutions containing carbon, chromium and nickel. Additions of cryolite, Na3AlF6, were applied for better fluxing and higher phosphate capacity of the slag. An X-ray analysis of final slags formed during dephosphorization of ferrous solutions containing chromium and nickel with CaO-CaF2or CaO-CaF2-Na3AlF6mixtures of different chemical compositions was carried out. The equilibrium composition of the liquid and the solid phase while cooling the slags from 1673K to 298K was computed using FactSage 6.2 software. The performed equilibrium computations indicated that the slags were not entirely liquid at those temperatures. The addition of cryolite causes a substantial increase of the liquid phase of the slag. It also has a favourable effect on the dephosphorization grade of hot metal. The obtained results were statistically processed and presented in the form of regression equations.

scholarly journals Influence of Cu on the Improvement of Magnetic Properties and Structure of L10 FePt Nanoparticles

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1097
Author(s):  
Luran Zhang ◽  
Xinchen Du ◽  
Hongjie Lu ◽  
Dandan Gao ◽  
Huan Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Annealing Temperature ◽  
Reduction Method ◽  
Solid Phase ◽  
Average Particle Size ◽  
Fept Nanoparticles ◽  
Average Particle ◽  
Phase Reduction ◽  
Different Temperatures ◽  
One Step

L10 ordered FePt and FePtCu nanoparticles (NPs) with a good dispersion were successfully fabricated by a simple, green, one-step solid-phase reduction method. Fe (acac)3, Pt (acac)2, and CuO as the precursors were dispersed in NaCl and annealed at different temperatures with an H2-containing atmosphere. As the annealing temperature increased, the chemical order parameter (S), average particle size (D), coercivity (Hc), and saturation magnetization (Ms) of FePt and FePtCu NPs increased and the size distribution range of the particles became wider. The ordered degree, D, Hc, and Ms of FePt NPs were greatly improved by adding 5% Cu. The highest S, D, Hc, and Ms were obtained when FePtCu NPs annealed at 750 °C, which were 0.91, 4.87 nm, 12,200 Oe, and 23.38 emu/g, respectively. The structure and magnetic properties of FePt and FePtCu NPs at different annealing temperatures were investigated and the formation mechanism of FePt and FePtCu NPs were discussed in detail.

scholarly journals Effect of 2CaO·SiO2 particles addition on dephosphorization behavior

2020 ◽  
Vol 39 (1) ◽  
pp. 219-227
Author(s):  
Aijun Deng ◽  
Yunjin Xia ◽  
Jie Li ◽  
Dingdong Fan
Keyword(s):  
Liquid Slag ◽  
Solid Phase ◽  
Solid Particles ◽  
Hot Metal ◽  
Liquid Silicate ◽  
Phase Complex ◽  
Dephosphorization Slag ◽  
Stage 1 ◽  
Two Stages ◽  
Complex Liquid

AbstractThe effect of the addition of 2CaO·SiO2 solid particles on dephosphorization behavior in carbon-saturated hot metal was investigated. The research results showed that the addition of 2CaO·SiO2 particles have little influence on desilication and demanganization, and the removal of [Si] and [Mn] occurred in the first 5 min with different conditions where the contents of 2CaO·SiO2 particles addition for the conditions 1, 2, 3, 4, and 5 are 0, 2.2, 6.4, 8.6, and 13.0 g, respectively. The final dephosphorization ratios for the conditions 1, 2, 3, 4, and 5 are 61.2%, 66.9%, 79.6%, 63.0%, and 78.1%, respectively. The dephosphorization ratio decreases with the increase of 2CaO·SiO2 particles in the first 3 min. The reason for this is that the dephosphorization process between hot metal and slag containing C2S phase consisted of two stages: Stage 1, [P] transfers from hot metal to liquid slag and Stage 2, the dephosphorization production (3CaO·P2O5) in liquid slag reacts with 2CaO·SiO2 to form C2S–C3P solid solution. The increase of 2CaO·SiO2 particles increases the viscosity of slag and weakens the dephosphorization ability of the stage 1. The SEM and XRD analyses show that the phase of dephosphorization slag with the addition of different 2CaO·SiO2 particles is composed of white RO phase, complex liquid silicate phase, and black solid phase (C2S or C2S–C3P). Because the contents of C2S–C3P and 2CaO·SiO2 in slag and the dephosphorization ability of the two stages are different, the dephosphorization ability with different conditions is different.

scholarly journals Wind Speed Retrieval from Simulated RADARSAT Constellation Mission Compact Polarimetry SAR Data for Marine Application

2019 ◽  
Vol 11 (14) ◽  
pp. 1682 ◽  
Author(s):  
Torsten Geldsetzer ◽  
Shahid K. Khurshid ◽  
Kerri Warner ◽  
Filipe Botelho ◽  
Dean Flett
Keyword(s):  
Wind Speed ◽  
Low Noise ◽  
Quality Data ◽  
Band Model ◽  
Data Set ◽  
Wind Retrieval ◽  
Wind Speeds ◽  
Geophysical Model ◽  
The Right ◽  
Quality Threshold

RADARSAT Constellation Mission (RCM) compact polarimetry (CP) data were simulated using 504 RADARSAT-2 quad-pol SAR images. These images were used to samples CP data in three RCM modes to build a data set with co-located ocean wind vector observations from in situ buoys on the West and East coasts of Canada. Wind speeds up to 18 m/s were included. CP and linear polarization parameters were related to the C-band model (CMOD) geophysical model functions CMOD-IFR2 and CMOD5n. These were evaluated for their wind retrieval potential in each RCM mode. The CP parameter Conformity was investigated to establish a data-quality threshold (>0.2), to ensure high-quality data for model validation. An accuracy analysis shows that the first Stokes vector (SV0) and the right-transmit vertical-receive backscatter (RV) parameters were as good as the VV backscatter with CMOD inversion. SV0 produced wind speed retrieval accuracies between 2.13 m/s and 2.22 m/s, depending on the RCM mode. The RCM Medium Resolution 50 m mode produced the best results. The Low Resolution 100 m and Low Noise modes provided similar results. The efficacy of SV0 and RV imparts confidence in the continuity of robust wind speed retrieval with RCM CP data. Three image-based case studies illustrate the potential for the application of CP parameters and RCM modes in operational wind retrieval systems. The results of this study provide guidance to direct research objectives once RCM is launched. The results also provide guidance for operational RCM data implementation in Canada’s National SAR winds system, which provides near-real-time wind speed estimates to operational marine forecasters and meteorologists within Environment and Climate Change Canada.

scholarly journals Sequential extraction and thermal desorption of mercury from contaminated soil and tailings from Mongolia

2012 ◽  
Vol 10 (5) ◽  
pp. 1565-1573 ◽  
Author(s):  
Pavel Coufalík ◽  
Pavel Krásenský ◽  
Marek Dosbaba ◽  
Josef Komárek
Keyword(s):  
Sequential Extraction ◽  
Thermal Desorption ◽  
Solid Phase ◽  
Extraction Procedure ◽  
Speciation Analysis ◽  
Water Soluble ◽  
Mercury Species ◽  
Different Temperatures ◽  
Acidic Conditions ◽  
Desorption Method

AbstractMercury forms in contaminated environmental samples were studied by means of sequential extraction and thermal desorption from the solid phase. The sequential extraction procedure involved the following fractions: water soluble mercury, mercury extracted in acidic conditions, mercury bound to humic substances, elemental Hg and mercury bound to complexes, HgS, and residual mercury. In addition to sequential extraction, the distribution of mercury species as a function of soil particles size was studied. The thermal desorption method is based on the thermal decomposition or desorption of Hg compounds at different temperatures. The following four species were observed: Hg0, HgCl2, HgS and Hg(II) bound to humic acids. The Hg release curves from artificial soils and real samples were obtained and their applicability to the speciation analysis was considered.

scholarly journals The β-cyclodextrin/benzene complex and its hydrogen bonds – a theoretical study using molecular dynamics, quantum mechanics and COSMO-RS

2013 ◽  
Vol 9 ◽  
pp. 118-134 ◽  
Author(s):  
Jutta Erika Helga Köhler ◽  
Nicole Grczelschak-Mick
Keyword(s):  
Molecular Dynamics ◽  
Quantum Mechanics ◽  
Hydrogen Bonds ◽  
Md Simulations ◽  
Benzene Molecule ◽  
Glucose Unit ◽  
Hand Orientation ◽  
Different Temperatures ◽  
Dynamics Simulations ◽  
The Right

Four highly ordered hydrogen-bonded models of β-cyclodextrin (β-CD) and its inclusion complex with benzene were investigated by three different theoretical methods: classical quantum mechanics (QM) on AM1 and on the BP/TZVP-DISP3 level of approximation, and thirdly by classical molecular dynamics simulations (MD) at different temperatures (120 K and 273 to 300 K). The hydrogen bonds at the larger O2/O3 rim of empty β-CDs prefer the right-hand orientation, e.g., O3-H…O2-H in the same glucose unit and bifurcated towards …O4 and O3 of the next glucose unit on the right side. On AM1 level the complex energy was −2.75 kcal mol−1 when the benzene molecule was located parallel inside the β-CD cavity and −2.46 kcal mol−1 when it was positioned vertically. The AM1 HOMO/LUMO gap of the empty β-CD with about 12 eV is lowered to about 10 eV in the complex, in agreement with data from the literature. AM1 IR spectra displayed a splitting of the O–H frequencies of cyclodextrin upon complex formation. At the BP/TZVP-DISP3 level the parallel and vertical positions from the starting structures converged to a structure where benzene assumes a more oblique position (−20.16 kcal mol−1 and −20.22 kcal mol−1, resp.) as was reported in the literature. The character of the COSMO-RS σ-surface of β-CD was much more hydrophobic on its O6 rim than on its O2/O3 side when all hydrogen bonds were arranged in a concerted mode. This static QM picture of the β-CD/benzene complex at 0 K was extended by MD simulations. At 120 K benzene was mobile but always stayed inside the cavity of β-CD. The trajectories at 273, 280, 290 and 300 K certainly no longer displayed the highly ordered hydrogen bonds of β-CD and benzene occupied many different positions inside the cavity, before it left the β-CD finally at its O2/O3 side.

The extraction and characterization of porous HA/β-TCP biphasic calcium phosphate from sole fish bones at different temperatures

2019 ◽  
Vol 6 (12) ◽  
pp. 125412 ◽  
Author(s):  
Haiwen Chen ◽  
Wenxue Dou ◽  
Qingfeng Zhu ◽  
Danyu Jiang ◽  
Jinfeng Xia ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Biphasic Calcium Phosphate ◽  
Fish Bones ◽  
Different Temperatures

KINETICS OF SOLIDIFICATION

1956 ◽  
Vol 34 (5) ◽  
pp. 473-490 ◽  
Author(s):  
K. A. Jackson ◽  
Bruce Chalmers
Keyword(s):  
Free Energy ◽  
Kinetic Theory ◽  
Experimental Observation ◽  
Homogeneous Nucleation ◽  
Solid Phase ◽  
Equilibrium Temperature ◽  
Point Of View ◽  
Theory Of Melting ◽  
Kinetics Of ◽  
Thermodynamic Equations

The kinetic theory of melting and freezing is developed from consideration of atom movements at an interface between solid and liquid. The equations developed are shown to have the same form as the corresponding thermodynamic equations. The homogeneous nucleation of a solid phase in a liquid is then considered from the point of view of this theory. Agreement with experimental observation is obtained on the following points. (1) The supercooling at which homogeneous nucleation occurs is proportional to the absolute equilibrium temperature. (2) The surface free energy per atom used in the quasi-thermodynamic treatment of nucleation should be equal to one-half the latent heat per atom. (3) The amount of liquid supercooled has a very small effect on the temperature at which homogeneous nucleation occurs.

Effect of Synthesis Temperature and Ca/P Ratios on Specific Surface Area of Amorphous Calcium Phosphate

2016 ◽  
Vol 721 ◽  
pp. 172-176 ◽  
Author(s):  
Jana Vecstaudza ◽  
Janis Locs
Keyword(s):  
Calcium Phosphate ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Amorphous Calcium Phosphate ◽  
Calcium Phosphates ◽  
Synthesis Temperature ◽  
Molar Ratios ◽  
Different Temperatures ◽  
Low Crystalline

Amorphous and low crystalline calcium phosphates are prospective candidates for bone implant manufacturing. Amorphous calcium phosphate (ACP) preparation technologies could be improved in terms of specific surface area (SSA) of obtained products. Current study is dedicated to the effect of synthesis temperature and Ca and P molar ratios (Ca/P) on SSA of ACP. Higher SSA can improve bioactivity of biomaterials. ACP was characterized by XRD, FT-IR, SEM and BET N2 adsorption techniques. Spherical nanoparticles (<45 nm in size) were obtained independently of initial Ca/P ratio and synthesis temperature. For the first time comparison of SSA was shown for ACP obtained at different temperatures (0 °C and 20 °C) and Ca/P molar ratios (1.5, 1.67 and 2.2).

pH-Induced dissociation of bovine casein micelles. II. Mineral solubilization and its relation to casein release

1989 ◽  
Vol 56 (5) ◽  
pp. 727-735 ◽  
Author(s):  
Douglas G. Dalgleish ◽  
Andrew J. R. Law
Keyword(s):  
Calcium Phosphate ◽  
Inorganic Phosphate ◽  
Bovine Milk ◽  
Universal Relation ◽  
Casein Micelles ◽  
Neutral Ph ◽  
Quantitative Studies ◽  
A Value ◽  
Different Types ◽  
Different Temperatures

SummaryMeasurements of the release of Ca, Mg and inorganic phosphate(Pi) from the casein micelles of bovine milk have been made, as functions of the pH, in the range 4·9–6·7, and at temperatures of 4, 20 and 30 °C. The results are in general agreement with earlier published studies in giving a value of 1·75–1·84 for the micellar Ca:Pi ratio. Mg appeared to behave similarly to Ca, although the amounts of micellar material were much smaller. The results on the acid-solvation of calcium phosphate are considered in relation to published quantitative studies of the pH-induced dissociation of the different types of caseins from the micelle, and of the micellar dissociation caused when micellar calcium phosphate is dissolved at neutral pH. It is evident from this that at present it is not possible to derive a universal relation between the dissociation of minerals and of caseins from the micelles at different temperatures and under different conditions.

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