Corrosion Behavior of Various Surface Treatments Ti-6Al-4V Alloy - A Review

2013 ◽  
Vol 849 ◽  
pp. 58-61 ◽  
Author(s):  
Yusliza Yusuf ◽  
Nooririnah Binti Omar ◽  
Muhamad Azwar Azhari ◽  
Md Ashadi Bin Md Johari

A Ti-6Al-4V alloy has been widely used as suitable materials for several of application such as aerospace, marine and biomedical application. Although this alloy is excellent in its properties and good corrosion resistance, the applications are limited because of their poor tribological property referring to the wear resistance property due to their low surface hardness. Therefore, it is inevitable to improve the wear properties of Ti-6Al-4V without detrimental the initial corrosion resistance properties even increasing it for better result. Over the years, various methods of surface treatments for Ti-6Al-4V have been studied and most frequently used are laser treatment, plasma nitriding process, PVD coating and also duplex coating. For each of the surface treatment discussed, several type of corrosion behavior have been studied with the conclusion is comparable to each other. In general, throughout these techniques, the wear resistance property of Ti-6Al-4V was improved and simultaneously improving the corrosion resistance property.

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 98 ◽  
Author(s):  
Francesca Borgioli ◽  
Emanuele Galvanetto ◽  
Tiberio Bacci

Low-temperature nitriding of austenitic stainless steels produces modified surface layers, consisting mainly of the S phase, which improve surface hardness and corrosion resistance. Because of the localized plastic deformations, owing to modified layer formation, and ion bombardment occurring during the process itself, this treatment produces also modifications of surface morphology and roughness, which can affect wettability and corrosion behavior. In this study the effects of plasma nitriding, performed using different treatment conditions, on the surface morphology and roughness, and thus on wettability and corrosion resistance, of AISI 202 specimens with different initial finishings (2D and polished finishing) were investigated. Different probe liquids, having both high (bi-distilled water and solution of 3.5% NaCl) and low (ethanol and rapeseed oil) surface tension, were employed for assessing the wetting behavior with the sessile drop method. The contact angle values for water increased markedly when nitriding was performed on polished samples, while this increase was smaller for 2D samples, and on selected specimens a hydrophobic behavior was observed. Very low contact angle values were registered using low surface tension liquids, suggesting an oleophilic behavior. Corrosion resistance in a 5% NaCl solution was assessed, and it depended on the characteristics of the nitrided specimens.


2007 ◽  
Vol 14 (04) ◽  
pp. 597-600
Author(s):  
A. BISWAS ◽  
U. BHATTACHARJEE ◽  
I. MANNA ◽  
J. DUTTA MAJUMDAR

The present study aims at enhancing the wear resistance and biocompatibility of Ti -6 Al -4 V by forming a thin layer of oxide. Surface oxidation has been carried out by controlled heating of the surface of Ti -6 Al -4 V substrate in air at the temperature ranging from 400–600°C and time from 25–60 h. The phase formed under thermal oxidation was predominantly the rutile and anatase phase. The thickness of the oxide layer varied from 1.5–7.0 μm. The microhardness on the surface was significantly improved as compared to the as-received substrate. Both the corrosion resistance property and biocompatibility were improved.


2013 ◽  
Vol 750-752 ◽  
pp. 2052-2056 ◽  
Author(s):  
Lu Miao ◽  
Ya Nan Wang ◽  
Yan Hui Li

By vacuum fusion sintering technique made different CeO2 addition Ni-WC composite coatings on 45 steel. Hardness, wear resistance property and corrosion resistance property of the Rare-earth Ni-WC composite coatings were measured and analyzed by Rockwell hardness tester,micro-hardness tester, friction wear testing machine and Salt spray corrosion box. The results showed that:The CeO2 content comes up to 0.75% of the coatings` hardness, wear resistance and corrosion resistance property better than those of other coatings.


2017 ◽  
Vol 36 (1) ◽  
pp. 63-68 ◽  
Author(s):  
Ilhan Çelik

AbstractTitanium and its alloys are widely used in many fields, including aerospace and the chemical and biomedical industries. This is due to their mechanical properties, excellent corrosion resistance, and biocompatibility although they do have poor wear resistance. In this study, a duplex layer was successfully formed on the commercially pure titanium surface by duplex treatments (plasma nitriding and physical vapor deposition (PVD)). In the initial treatment, plasma nitriding was performed on the pure titanium samples and in the second treatment, the nitrided samples were coated with CrN by PVD. The friction and wear properties of the duplex-treated samples were investigated for tribological applications. Surface morphology and microstructure of the duplex-treated samples were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). In addition, the tribological properties were investigated using pin-on-disc tribometer. A compound layer composed of ε-Ti2N and δ-TiN phases and a diffusion layer formed under the compound layer were obtained on the surface of pure titanium after the nitriding treatments. CrN coated on the nitrided surface provided an increase in the surface hardness and in the wear resistance.


2014 ◽  
Vol 881-883 ◽  
pp. 1263-1267 ◽  
Author(s):  
Shuo Zhao ◽  
Liang Wang ◽  
Jiu Jun Xu ◽  
Y. Shan

The duplex stainless steel has better pitting corrosion resistance but lacks of hardness and wear resistance. Therefore, the low temperature nitriding treatment can be used to increase its hardness and wear resistance or to gain more perfect corrosion resistance. The plasma nitriding of SS2205 stainless steel was carried out at temperatures from 693k to 753k for 4 hours at anodic potential. The nitrided samples were analyzed by optical microscopy, X-ray diffraction, SEM-EDX analysis, microhardness testing, wear and corrosion evaluation. The XRD analysis of all treated samples showed that the nitrogen-expanded austenite phase was formed. Both α and γ phase of the substrate were transformed into γNduring plasma nitriding. Observing the nitrided layers formed on α and γ phase, the ones situated in the austenite were thinner than the ones in the ferrite. This phenomenon was more evident at low temperature, which confirmed that the nitrogen has a higher diffusion rate in the ferrite during plasma nitriding treatment. The surface hardness of nitrided layer was increased with the nitriding temperature. The highest hardness value obtained in this experiment was about 1300 HV0.05which was 4 times as the original sample (380 HV0.05). Furthermore, through the wear and corrosion property tests, it was shown that anodic plasma nitriding improved the wear resistance and corrosion resistance of the duplex stainless steel.


2014 ◽  
Vol 789 ◽  
pp. 495-500
Author(s):  
Bing Ying Wang ◽  
Qing Hao Shi ◽  
Wen Long Zhang

The polyurea was modified by adding different amounts of nanometer ZnO. The corrosion behavior of polyurea/primer composite coating system in wet-dry cyclic environment of 3.5% NaCl solution was studied by using the Electrochemical Impedance Spectroscopy (EIS) measurement and adhesion test technology. The experimental result showed that, different mass fractions of nanometer ZnO had different influences on the corrosion resistance property of coating. When the mass fraction of nanometer ZnO was 5%, the composite coating had the largest protective action. The corrosion resistance property of nanometer ZnO can be improved by increasing the density of polyurea coating, however, the corrosion resistance property of polyurea coating will be weakened in case of exceeding the critical adding amount.


2021 ◽  
Vol 19 (2) ◽  
pp. 77-82
Author(s):  
Fadhil K. Farhan ◽  
Aws Abbas Hussein ◽  
Ali Q. Tuama

The liquid and mechanical mixing method was used in addition to ultrasound technology to prepare samples according to standard conditions. The percentage of cementing with ceramic powder was adopted from 1% to 4% as a weight ratio, and by using mixing drivers, nanocomposites were prepared depending on the theoretical density of the components. The velvet density was measured using Archimedes' method, and the results showed a successive improvement and increase in density with the weight ratio of addition. The results of the particulate hardness test showed a significant improvement in the results of the prepared nanostructures compared to the base sample (pure epoxy). With regard to the properties of wear resistance (wear modulus) using the screw-on-disk method, the cemented samples showed a higher wear resistance compared to the base sample. The results were interpreted based on the values of density and hardness in addition to the properties possessed by the ceramic powder of high surface area and average granular size of 32 nanometers through scanning electron microscopy. In this work, nanostructures based on (a polymer) supported with nanoscale zirconium dioxide powder were developed.


2010 ◽  
Vol 154-155 ◽  
pp. 1170-1177
Author(s):  
Yuan Fang Chen ◽  
Xiao Dong Peng ◽  
Jian Jun Hu ◽  
Hong Bin Xu ◽  
Chan Hao

Surface modification of 40Cr steel by high current pulsed electron beam has been investigated . The pulsed times of HCPEB was changed from 1 to 25 to prepare different specimens. Surface microstructures and section microstructures after HCPEB irradiation were detected by using metallurgical microscope, SEM and X-ray diffractometer. It is shown that crater defects were found on the surface after the irradiation of HCPEB and the density of craters will decrease with increasing pulses times. When treated by 27Kev accelerating voltage, with increasing pulse times, the particles located in surface layer were obviously refined .The surface roughness, hardness, wear properties and corrosion resistance were analyzed after irradiation of HCPEB. The wear resistance and corrosion resistance were obviously enhanced after 10 pulses treatment.


2019 ◽  
Vol 26 (07) ◽  
pp. 1850217 ◽  
Author(s):  
O. ÇOMAKLI ◽  
A. F. YETIM ◽  
B. KARACA ◽  
A. ÇELIK

The 31CrMoV9 steels were plasma nitrided under different gas mixture ratios to investigate an influence of nitrogen amount on wear behavior. The structure, mechanical and tribological behavior of untreated and nitrided 31CrMoV9 steels were analyzed with X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), microhardness device, 3D profilometer and pin-on-disk wear tester. The analysis outcomes displayed that the compound layer consists of nitride phases (Fe2N, Fe3N, Fe4N and CrN). Additionally, the thickness of the compound layers, surface hardness and roughness increased with increasing nitrogen amount in the gas mixture. The highest friction coefficient value was obtained at nitrogen amount of 50%, but the lowest value was seen at nitrogen amount of 6%. It was observed that wear resistance of 31CrMoV9 steel improved after plasma nitriding, and the best wear resistance was also obtained from plasma nitrided sample at the gas mixture of 94% H[Formula: see text]% N2.


2013 ◽  
Vol 701 ◽  
pp. 370-374
Author(s):  
Yusliza Yusuf ◽  
Zulkifli Mohd Rosli ◽  
Jariah Mohamad Juoi ◽  
Zainab Mahamud ◽  
Kwan Wai Loon

Ti6Al4V alloy are among the most widely used materials in engineering applications. This is because their relatively beneficial properties. However, inadequate wear properties of Ti6Al4V alloy have largely constrained the application for this material. In this study, Plasma nitriding of the Ti6Al4V was performed using microwave plasma technique at 600°C for 1hour, 3 hours and 5 hours then followed with deposition of CrN on plasma nitrided samples for duplex coating purposes. Microstructural analysis and hardness measurement revealed that formation of Ti2N and TiN phases indicating the formation of compound layer is observed for substrate nitrided at temperature as low as 600°C 1 hour and a substantial increase on the surface hardness of plasma nitrided Ti6Al4V is observed with an increase of process time. The duplex coating obtained in this study has significant surface hardness property and superior as compared with CrN coatings deposited on as received Ti6Al4V.


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