Microstructure and Mechanical Properties of Sintered Ti-Cu Alloys

2010 ◽  
Vol 93-94 ◽  
pp. 99-104 ◽  
Author(s):  
P. Pripanapong ◽  
Luangvaranunt Tachai
Keyword(s):  
Mechanical Properties ◽  
Cast Alloy ◽  
Exothermic Reaction ◽  
Equilibrium Phase ◽  
Pure Titanium ◽  
Equilibrium Phase Diagram ◽  
Cu Alloys ◽  
Effect Of Copper ◽  
Sintered Alloys ◽  
Dental Applications

The use of titanium for medical and dental applications is on the rise because of their excellent biocompatibility. However, some properties of pure titanium are not sufficient. Alloying with copper can improve mechanical properties needed for dental use. A recent research on Ti-Cu cast alloy indicated that ductility decreased with increasing copper concentration, but addition of copper improved grindability and wear resistance, with lower corrosion resistance. The objective of this research is to study sintering of Ti-Cu alloys; their microstructure and hardness, and the effect of copper content to their sintered density. Ti-Cu alloys were produced via powder metallurgy. Titanium powder was mixed with copper powder with chemical composition of 2, 4, 7 and 10 wt%. Lubricant was added in alloy powder with 0.5% of total weight, followed by cold compaction under 254 MPa pressure. Debinding and sintering was carried out at 400oC for 0.5 hr and 1000oC for 1 hr respectively in argon atmosphere. Condition with highest density was found in 10wt%Cu composition; having highest hardness of 317 Hv. Differential thermal analysis of Ti-15Cu under N2 atmosphere showed exothermic reaction at 1078oC. Phase formation of the sintered alloys followed the Ti-Cu equilibrium phase diagram.

scholarly journals Phase Formation, Microstructure and Mechanical Properties of Mg67Ag33 as Potential Biomaterial

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 461
Author(s):  
Konrad Kosiba ◽  
Konda Gokuldoss Prashanth ◽  
Sergio Scudino
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Equilibrium Phase ◽  
Antibacterial Properties ◽  
Equilibrium Phase Diagram ◽  
Compressive Yield Strength ◽  
X Ray ◽  
Fine Grained ◽  
Equilibrium Phases

The phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg67Ag33 (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. Instead, the microstructure is mainly composed of oversaturated hexagonal closest packed Mg-based dendrites surrounded by a mixture of phases, as probed by X-ray diffraction, electron microscopy and energy dispersive X-ray spectroscopy. A possible non-equilibrium phase diagram is suggested. Mainly because of the fine-grained dendritic and interdendritic microstructure, the material shows appreciable mechanical properties, such as a compressive yield strength and Young’s modulus of 245 ± 5 MPa and 63 ± 2 GPa, respectively. Due to this low Young’s modulus, the Mg67Ag33 alloy has potential for usage as biomaterial and challenges ahead, such as biomechanical compatibility, biodegradability and antibacterial properties are outlined.

scholarly journals Mechanical Properties of Selective Laser Sintering Pure Titanium and Ti-6Al-4V, and Its Anisotropy

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5081
Author(s):  
Yuu Harada ◽  
Yoshiki Ishida ◽  
Daisuke Miura ◽  
Satoru Watanabe ◽  
Harumi Aoki ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Tensile Strength ◽  
Titanium Powder ◽  
Selective Laser Sintering ◽  
Pure Titanium ◽  
Color Difference ◽  
Laser Sintering ◽  
Great Performance ◽  
Dental Applications

Selective laser sintering (SLS) is being developed for dental applications. This study aimed to investigate the properties of Ti-6Al-4V and pure titanium specimens fabricated using the SLS process and compare them with casting specimens. Besides, the effect of the building direction on the properties of the SLS specimens was also investigated. Specimens were prepared by SLS using Ti-6Al-4V powder or pure titanium powder. Casting specimens were also prepared using Ti-6Al-4V alloys and pure titanium. The mechanical properties (tensile strength and elongation), physical properties (surface roughness, contact angle, and Vickers hardness); corrosion resistors (color difference and corrosion), and surface properties (chemical composition and surface observation) were examined. Both Ti-6Al-4V and pure titanium specimens produced using the SLS process had comparable or superior properties compared with casting specimens. In comparing the building directions, specimens fabricated horizontally to the printing platform showed the greatest tensile strength, and the surface roughness scanned in the horizontal direction to the platform showed the smallest. However, there was no significant effect on other properties. Thus, the SLS process with Ti-6Al-4V powder and pure titanium powder has great performance for the fabrication of dental prosthesis, and there is a possibility for it to take the place of conventional methods.

Effect of the Cyclic Extrusion and Compression Processing on Microstructure and Mechanical Properties of Al-1%Cu Alloy

2018 ◽  
Vol 780 ◽  
pp. 93-97
Author(s):  
Walaa Abdelaziem ◽  
Atef Hamada ◽  
Mohsen Abdel-Naeim Hassan
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Cast Alloy ◽  
Surface Hardness ◽  
Grain Structure ◽  
Cu Alloy ◽  
Cu Alloys ◽  
Microstructure And Mechanical Properties ◽  
Elongation To Failure

The Simple Cyclic extrusion compression (SCEC) has been developed for producing Al-1%Cu alloys with fine microstructures and superior properties. SCEC method was applied for only two-passess.It was found that the grain structure was significantly reduced from 1500 μm to 100 μm after two passes of cyclic extrusion. The ultimate tensile strength and elongation to failure of as-cast alloy were 110 MPa and 12 %, respectively. However, the corresponding mechanical properties of the two pass CEC deformed alloy are 275 MPa and 35%, respectively. These findings ensure that a significant improvement in the grain structure has been achieved. In addition, cyclic extrusion deformation increased the surface hardness of the alloy by 50 % after two passes.

Microstructure and Mechanical Characterization of an Al-Zn-Mg Alloy after Various Heat Treatments and Room Temperature Deformation

2008 ◽  
Vol 604-605 ◽  
pp. 67-76 ◽  
Author(s):  
Paola Leo ◽  
Emanuela Cerri ◽  
H.J. McQueen ◽  
Samanta Chiozzi
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
High Strain ◽  
Cast Alloy ◽  
Equilibrium Phase ◽  
Heat Treatments ◽  
Temperature Deformation ◽  
Dislocation Network ◽  
Lower Temperature

In this study, the effect of various solution and aging treatments on microstructure and mechanical properties of an as cast Al-5.5Zn-1.2Mg alloy has been investigated by optical microscopy, hardness measurements and room temperature tensile test. The solution heat treatments performed at temperatures between 400 and 490°C have little effects on hardness while electrical conductivity values increased at the lower temperature because of dissolved atoms and vacancy rich clusters. Concerning aging, only T6 improves mechanical properties of the undeformed alloy, while aging performed on tensile tested samples results in a decrease of hardness due to accelerated kinetics and heterogeneous nucleation of equilibrium phase stimulated by dislocation network. Tensile tested samples of the as cast alloy exhibits the fastest recrystallization time during annealing because of the absence of fine precipitates and the high strain hardening.

Magnetic Percolation in New Crystalline FCC Fe-Cu Alloys

1986 ◽  
Vol 80 ◽  
Author(s):  
C. L. Chien ◽  
S. H. Liou ◽  
Gang Xiao ◽  
M. A. Gatzke
Keyword(s):  
Equilibrium Phase ◽  
Magnetic Ordering ◽  
Equilibrium Phase Diagram ◽  
Squid Magnetometry ◽  
Cu Alloys ◽  
Fcc Lattice ◽  
Percolation Phenomena ◽  
Quenching Method ◽  
Vapor Quenching ◽  
Dilute Limit

AbstractMagnetic percolation has rarely been realized in Fe-based binary alloys either because Fe does not retain its moment in the dilute limit or because the solubility is too low. By using a vapor quenching method, which in our case is highrate sputtering, we have succeeded in making new metastable crystalline alloys of fcc FexCu1−x which do not appear in the equilibrium phase diagram. These alloys spanning the percolation threshold allow magnetic percolation phenomena on an fcc lattice to be observed by SQUID magnetometry and Mössbauer spectroscopy. Above xc, the magnetic ordering temperature varies as (x−xc)γ with xc = 0.185 and γ = 0.63. Below xc, spin glass ordering has been observed.

Formation of Primary Intermetallic Compounds in Sn-Ag-Cu Alloys

2010 ◽  
Vol 654-656 ◽  
pp. 1397-1399 ◽  
Author(s):  
Yoshiko Takamatsu ◽  
Hisao Esaka ◽  
Kei Shinozuka
Keyword(s):  
Liquid Phase ◽  
Intermetallic Compounds ◽  
Ternary Eutectic ◽  
Equilibrium Phase ◽  
Solidification Process ◽  
Equilibrium Phase Diagram ◽  
Primary Phase ◽  
Cu Alloys ◽  
Binary Eutectic ◽  
Free Solder

Sn-Ag-Cu alloys are considered one of the most favorable lead-free solder systems. In slowly-cooled eutectic Sn-Ag-Cu alloys, sometimes large primary Ag3Sn or Cu6Sn5 intermetallic compounds (IMCs) form. These IMCs may affect the mechanical properties of solders. However, explanations for the formation of these IMCs are still not clear. This study deals with interrupted tests in order to clarify the nucleation of IMCs in the liquid phase. In this study, Sn-4.41Ag-0.63Cu and Sn-3.30Ag-1.47Cu alloys were prepared. According to the thermodynamic calculation, Pandat, the equilibrium solidification paths are described as follows: Sn-4.41Ag-0.63Cu :L → primary Ag3Sn → binary eutectic (Ag3Sn +Sn) → ternary eutectic; Sn-3.30Ag-1.47Cu :L → primary Cu6Sn5 → binary eutectic (Cu6Sn5 + Sn)→ ternary eutectic. The actual solidification process was different from the estimation from the equilibrium phase diagram. In the case of Sn-4.41Ag-0.63Cu, only Ag3Sn grew as a primary phase in the liquid, while in the case of Sn-3.30Ag-1.47Cu, not only primary Cu6Sn5 but also pseudo-primary Ag3Sn grew in the liquid. Ag3Sn may nucleate easily in the liquid phase, but Cu6Sn5 would not nucleate in the liquid.

scholarly journals The Effect of Interface Morphology on the Electro-Mechanical Properties of Ti/Cu Clad Composites Produced by Explosive Welding

2019 ◽  
Vol 51 (2) ◽  
pp. 750-766 ◽  
Author(s):  
Henryk Paul ◽  
Wojciech Skuza ◽  
Robert Chulist ◽  
Magdalena Miszczyk ◽  
Aleksander Gałka ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Volume Fraction ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Interfacial Microstructure ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Equilibrium Phases ◽  
The Waves

Abstract The effect of interfacial microstructure on the electro-mechanical properties of explosively welded titanium and copper plates is discussed. Mechanical testing proved that using detonation velocities ranging from 2000 to 3000 m s−1 and stand-off distances from 1.5 to 9.0 mm, joints that satisfy the strength criteria for a good quality clad were produced. Scanning electron microscopy images show that all interfaces exhibit a wave character. It was noticed that as the stand-off distances and detonation velocities increase, the amplitude and period of the waves, as well as the quantity of the melt zones, increase as well. Also, as the interface waviness and volume fraction of the melt zones increase, the resistivity increases substantially. The experimental data demonstrate that the bonding between both metals is always achieved by surface melting of several tenths of a nanometer, which can be detected only by transmission electron microscopy. Most of the phases that form within the melt zones do not appear in the equilibrium phase diagram and show an amorphous/nano-grained structure. Only a very small amount of equilibrium phases such as CuTi3, Cu3Ti, Cu4Ti3 was revealed employing synchrotron X-ray diffraction.

Imaging of Al-Li-Cu alloys with a Scanning Ion Microprobe

1990 ◽  
Vol 48 (2) ◽  
pp. 314-315
Author(s):  
K.K. Soni ◽  
D.B. Williams ◽  
J.M. Chabala ◽  
R. Levi-Setti ◽  
D.E. Newbury
Keyword(s):  
Mass Spectrometry ◽  
Secondary Ion Mass Spectrometry ◽  
Equilibrium Phase ◽  
Icosahedral Symmetry ◽  
Ion Microprobe ◽  
X Ray ◽  
Cu Alloys ◽  
Two Phases ◽  
The University ◽  
Secondary Ion

In contrast to the inability of x-ray microanalysis to detect Li, secondary ion mass spectrometry (SIMS) generates a very strong Li+ signal. The latter’s potential was recently exploited by Williams et al. in the study of binary Al-Li alloys. The present study of Al-Li-Cu was done using the high resolution scanning ion microprobe (SIM) at the University of Chicago (UC). The UC SIM employs a 40 keV, ∼70 nm diameter Ga+ probe extracted from a liquid Ga source, which is scanned over areas smaller than 160×160 μm2 using a 512×512 raster. During this experiment, the sample was held at 2 × 10-8 torr.In the Al-Li-Cu system, two phases of major importance are T1 and T2, with nominal compositions of Al2LiCu and Al6Li3Cu respectively. In commercial alloys, T1 develops a plate-like structure with a thickness <∼2 nm and is therefore inaccessible to conventional microanalytical techniques. T2 is the equilibrium phase with apparent icosahedral symmetry and its presence is undesirable in industrial alloys.

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